CN100406642C - Flame Retardant Coating Process for Heavy Fabrics - Google Patents

Flame Retardant Coating Process for Heavy Fabrics Download PDF

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CN100406642C
CN100406642C CNB2003101254172A CN200310125417A CN100406642C CN 100406642 C CN100406642 C CN 100406642C CN B2003101254172 A CNB2003101254172 A CN B2003101254172A CN 200310125417 A CN200310125417 A CN 200310125417A CN 100406642 C CN100406642 C CN 100406642C
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flame retardant
coating
flame
retardant
glue
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CN1635211A (en
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潘跃进
魏征
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Suzhou jierunsi new materials Co. Ltd.
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SHANGHAI JAROS NEW MATERIAL CO Ltd
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Abstract

本发明公开一种厚重织物的阻燃涂层工艺,涉及一种织物阻燃加工工艺。其采用对低粘的阻燃胶进行机械发泡达到增稠的目的,使它具有可涂层加工性,经过刮刀涂层后,在刮涂挤压过程中泡沫破碎,重新变成低粘的阻燃胶,渗透到被涂层基材中,然后烘干,使织物的整体阻燃性能达到要求。解决了厚重织物阻燃中存在的工艺繁复,阻燃效果不佳、织物舒适性和安全性差、成本偏高的问题。The invention discloses a flame retardant coating process for heavy fabrics, and relates to a fabric flame retardant processing process. It adopts mechanical foaming of low-viscosity flame-retardant glue to achieve the purpose of thickening, so that it has coating processability. After scraper coating, the foam is broken during the scraping and extrusion process and becomes low-viscosity again. The flame retardant glue penetrates into the coated substrate and then dries to make the overall flame retardant performance of the fabric meet the requirements. It solves the problems of complicated process, poor flame retardant effect, poor fabric comfort and safety, and high cost in the flame retardant of heavy fabrics.

Description

厚重织物的阻燃涂层工艺 Flame Retardant Coating Process for Heavy Fabrics

技术领域 technical field

本发明公开一种厚重织物的阻燃涂层工艺,涉及一种织物阻燃加工工艺。The invention discloses a flame retardant coating process for heavy fabrics, and relates to a fabric flame retardant processing process.

背景技术: Background technique:

对织物的阻燃处理目前多采用阻燃整理(浸轧)和阻燃涂层方法。阻燃涂层方法因为不影响非涂层面的织物性能,有更好的安全性和舒适性,正为越来越多的人所接受。但对于厚重紧密的织物,普通阻燃涂层很难达到整体的阻燃要求,因为厚重紧密的织物阻隔了阻燃胶的渗透性,造成了非涂层面得不到阻燃保护,从而整体织物的阻燃性能不能达到阻燃要求。所以,目前对于厚重的织物,大多采用阻燃整理或先阻燃整理,后阻燃涂层的方法。这样就存在工艺复杂,且阻燃效果不佳、织物舒适性和安全性差、成本偏高的问题。Flame retardant finishing (padding) and flame retardant coating methods are mostly used in the flame retardant treatment of fabrics. The flame retardant coating method is being accepted by more and more people because it does not affect the fabric performance of the non-coated surface and has better safety and comfort. However, for thick and dense fabrics, it is difficult for ordinary flame-retardant coatings to meet the overall flame-retardant requirements, because the thick and tight fabrics block the permeability of flame-retardant adhesives, resulting in non-coated surfaces that cannot be protected by flame-retardant protection, so that the overall The flame retardant performance of the fabric cannot meet the flame retardant requirements. Therefore, at present, for thick and heavy fabrics, flame-retardant finishing or flame-retardant finishing first, and then flame-retardant coating are mostly used. In this way, there are problems such as complex process, poor flame retardant effect, poor fabric comfort and safety, and high cost.

发明内容 Contents of the invention

本发明的目的旨在克服现有技术的缺陷,提出一种泡沫阻燃涂层工艺,解决了厚重织物阻燃中存在的工艺繁复,阻燃效果不佳、织物舒适性和安全性差、成本偏高的问题。The purpose of the present invention is to overcome the defects of the prior art, and propose a foam flame retardant coating process, which solves the complicated process in the flame retardant of heavy fabrics, poor flame retardant effect, poor fabric comfort and safety, and high cost. high question.

本发明的技术方案是:采用对低粘的阻燃胶进行机械发泡达到增稠的目的,使它具有可涂层加工性,经过刮刀涂层后,在刮涂挤压过程中泡沫破碎,重新变成低粘的阻燃胶,渗透到被涂层基材中,然后烘干,使织物的整体阻燃性能达到要求。The technical solution of the present invention is: use mechanical foaming of low-viscosity flame-retardant glue to achieve the purpose of thickening, so that it has coating processability, after the scraper coating, the foam is broken during the scraping and extrusion process, It turns into a low-viscosity flame-retardant glue again, penetrates into the coated substrate, and then dries to make the overall flame-retardant performance of the fabric meet the requirements.

具体实施方式 Detailed ways

将阻燃涂层胶加入机械发泡机中,阻燃涂层胶自配,主要成分有水性涂层粘合剂(含固量30-50%,粘度1000-5000mpa·s),是丙烯酸聚合物,也可以是聚氨酯、乙烯氯乙烯、聚酯、聚酰胺、丁苯等聚合物;阻燃剂可以是卤化物,(三氧化二锑,或其它氮磷类阻燃剂,市售),加入量为5-70%,发泡比控制在1∶1.2-10之间(视织物厚重密度情况调整)。上述发泡胶通过管道施于涂层平台上的待加工布面上,刀口的向下刀距1-30mm,前后刀距1-30mm,车速5-50m/min,温度110-170℃,经涂层后,织物上胶量控制在20-250g/m2(干重)范围。Add the flame retardant coating glue into the mechanical foaming machine, the flame retardant coating glue is self-prepared, the main component is water-based coating adhesive (solid content 30-50%, viscosity 1000-5000mpa·s), which is acrylic polymer It can also be polymers such as polyurethane, vinyl chloride, polyester, polyamide, styrene-butadiene; the flame retardant can be a halide, (antimony trioxide, or other nitrogen and phosphorus flame retardants, commercially available), The addition amount is 5-70%, and the foaming ratio is controlled between 1:1.2-10 (adjusted according to the thickness and density of the fabric). The above-mentioned styrofoam is applied on the surface of the cloth to be processed on the coating platform through the pipeline, the downward knife distance of the knife edge is 1-30mm, the front and rear knife distance is 1-30mm, the vehicle speed is 5-50m/min, the temperature is 110-170℃, after After coating, the amount of sizing on the fabric is controlled within the range of 20-250g/m 2 (dry weight).

比较现有技术,发明的优点在于:1)加工工艺简单,可操作性强;2)阻燃性能优良、成本低、保持织物的原有舒适性和安全性,有效地解决了厚重紧密织物阻燃困难问题;3)半耐久的,可耐40℃的水浸。Compared with the prior art, the advantages of the invention are: 1) the processing technology is simple and the operability is strong; 2) the flame retardant performance is excellent, the cost is low, the original comfort and safety of the fabric are maintained, and the thick and compact fabric is effectively solved. 3) semi-durable, can withstand 40 ℃ water immersion.

与现有技术阻燃性能的比较Comparison of Flame Retardant Performance with Existing Technology

Figure C20031012541700041
Figure C20031012541700041

实施例1Example 1

阻燃涂层胶(丙烯酸酯粘合剂100kg,购于National Startch & ChemicalLtd.粘度4000mpa·s,1~15μm粒径的十溴联苯醚15kg,1~15μm粒径的三氧化二锑5kg,市售,0.5kg的磷酸盐类分散剂,高速剪切机分散三十分钟)放入机械发泡机中,发泡比1∶2,通过刀涂方式涂敷在300g/m2全涤仿麂皮织物上,调节上下刀距为向下2-7mm,前后刀距为2-15mm,车速25m/min,温度150-170℃,上胶量100g/m2(干重),经实验测试,可通过BS5852等标准。Flame-retardant coating glue (acrylic adhesive 100kg, purchased from National Startch & Chemical Ltd. Viscosity 4000mpa s, 15kg of decabromodiphenyl ether with a particle size of 1-15μm, 5kg of antimony trioxide with a particle size of 1-15μm, Commercially available, 0.5kg of phosphate dispersant, high-speed shearing machine disperses for 30 minutes) is put into mechanical foaming machine, and foaming ratio is 1: 2, is coated on 300g/m 2 full polyester imitation by knife coating mode On suede fabrics, adjust the upper and lower knife distances to 2-7mm downward, the front and rear knife distances to 2-15mm, the speed of the machine at 25m/min, the temperature at 150-170℃, and the amount of glue applied at 100g/m 2 (dry weight), tested by experiment , can pass BS5852 and other standards.

实施例2Example 2

阻燃涂层胶(丙烯酸酯粘合剂100kg,购于National Startch & ChemicalLtd.粘度4000mpa·s,1~15μm粒径的十溴联苯醚15kg,1~15μm粒径的三氧化二锑5kg,市售,0.5kg的磷酸盐类分散剂,高速剪切机分散三十分钟)通过刀涂方式涂敷在290g/m2全棉帆布织物上,调节调节上下刀距为向下2-7mm,前后刀距为2-15mm,车速25m/min,温度150-170℃,上胶量90g/m2(干重),经实验测试,可通过BS5852等标准。Flame-retardant coating glue (acrylic adhesive 100kg, purchased from National Startch & Chemical Ltd. Viscosity 4000mpa s, 15kg of decabromodiphenyl ether with a particle size of 1-15μm, 5kg of antimony trioxide with a particle size of 1-15μm, Commercially available, 0.5kg of phosphate-based dispersant, high-speed shearing machine for 30 minutes) is coated on 290g/ m2 cotton canvas fabric by knife coating, and the upper and lower knife distance is adjusted to be 2-7mm downward. The front and rear cutter distance is 2-15mm, the vehicle speed is 25m/min, the temperature is 150-170℃, and the amount of glue applied is 90g/m 2 (dry weight). After experimental testing, it can pass BS5852 and other standards.

实施例3Example 3

阻燃涂层胶(乙烯一氯乙烯共聚物粘合剂100kg,粘度3000mpa·s,十溴联苯醚5kg粒径1-15μm,15kg三氧化二锑1-15μm,0.3kg的磷酸盐类分散剂,市售,高速剪切机分散三十分钟)放入机械发泡机中,发泡比1∶1.5.通过刀涂方式涂敷在400g/m2的麂皮绒与全棉纱布的复合布上,调节上下刀距为向下5-15mm,前后刀距2-15mm,车速15m/min,温度150-170℃,上胶量110g/m2(干重),经实验测试,可通过BS5852等标准。Flame retardant coating glue (ethylene-vinyl chloride copolymer adhesive 100kg, viscosity 3000mpa s, decabromodiphenyl ether 5kg particle size 1-15μm, 15kg antimony trioxide 1-15μm, 0.3kg phosphate dispersion agent, commercially available, high-speed shearing machine dispersed for 30 minutes) into a mechanical foaming machine, the foaming ratio is 1:1.5. It is coated on the composite of 400g/ m2 suede and cotton gauze by knife coating On the cloth, adjust the upper and lower knife distances to be 5-15mm downward, the front and rear knife distances to 2-15mm, the speed of the machine to be 15m/min, the temperature to be 150-170°C, and the amount of glue to be applied to be 110g/ m2 (dry weight). After experimental testing, it can pass BS5852 and other standards.

实施例4Example 4

阻燃涂层胶(乙烯一氯乙烯共聚物粘合剂100kg,粘度3000mpa-s,十溴联苯醚5kg粒径1-15μm,三氧化二锑1-15μm,15kg,0.3kg的磷酸盐类分散剂,市售,高速剪切机分散三十分钟)放入机械发泡机中,发泡比1∶1.5.通过刀涂方式涂敷在350g/m2的T/C织物上,调节上下刀距为向下5-15mm,前后刀距2-15mm,车速181m/min,温度150-170℃,上胶量120g/m2(干重),经实验测试,可通过BS5852等标准。Flame retardant coating glue (ethylene-vinyl chloride copolymer adhesive 100kg, viscosity 3000mpa-s, decabromodiphenyl ether 5kg particle size 1-15μm, antimony trioxide 1-15μm, 15kg, 0.3kg phosphate Dispersant, commercially available, high-speed shearing machine disperses for 30 minutes) into a mechanical foaming machine with a foaming ratio of 1:1.5. It is coated on the T/C fabric of 350g/ m2 by knife coating, and adjusted up and down The knife distance is 5-15mm downward, the front and rear knife distance is 2-15mm, the speed is 18 1 m/min, the temperature is 150-170°C, the amount of glue is 120g/m 2 (dry weight), and the experimental test can pass BS5852 and other standards .

Claims (2)

1. the flame retardant coating technology of a heavy fabric, it is characterized in that adopting and low sticking flame-retardant coatings glue is carried out mechanical foaming reach thickening, after passing through the scraper coating again, foam fragmentation in blade coating extrusion process, again become low sticking fire retardant glue, be penetrated in the coated base material, dry then and make, wherein
The flame-retardant coatings glue main component has aqueous coating adhesive 30-95%, solid content 30-50%, and viscosity 1000-5000mpas, fire retardant is 5-70%, blowing ratio is controlled at 1: between the 1.2-10;
Adhesive is selected from acrylate copolymer, polyurethane, ethene vinyl chloride, polyester, polyamide, butylbenzene;
Fire retardant is a halide, is selected from antimonous oxide or nitrogen phosphorus type flame retardant.
2. flame retardant coating technology as claimed in claim 1, it is characterized in that the fire retardant glue after the above-mentioned foaming is imposed on the cloth cover to be processed on the coating platform by pipeline, the downward cutter of the edge of a knife is apart from 1-30mm, and the front and back cutter is apart from 1-30mm, speed of a motor vehicle 5-50m/min, temperature 110-170 ℃.
CNB2003101254172A 2003-12-31 2003-12-31 Flame Retardant Coating Process for Heavy Fabrics Expired - Fee Related CN100406642C (en)

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Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101498105B (en) * 2008-07-11 2011-10-05 浙江传化股份有限公司 Aqueous foaming flame-retardant coating glue for textile and preparation thereof
TW201026763A (en) * 2008-12-08 2010-07-16 Albemarle Corp Phosphorus flame retardants and applications therefor
CN102108639A (en) * 2011-03-15 2011-06-29 江苏旷达汽车织物集团股份有限公司 Process for manufacturing smokeless high flame retardant seat fabric of high-speed train
CN103215807A (en) * 2012-01-20 2013-07-24 辽宁腾达集团股份有限公司 Method for producing knitted fabric having functions of strong acid resistance, strong base resistance and oil resistance
CN103211336A (en) * 2012-01-21 2013-07-24 昆山华阳复合材料科技有限公司 Coated fabric with safety protection and long-term flame-retardant effect and manufacturing process of coated fabric
CN103668996A (en) * 2013-11-09 2014-03-26 孙光华 Flame-retardant ribbon
CN104313893A (en) * 2014-11-03 2015-01-28 江苏苏美达轻纺科技产业有限公司 After finishing process of novel environment-friendly home textile fabric
CN106401113A (en) * 2015-07-31 2017-02-15 江苏田园新材料股份有限公司 Novel sound-absorbing flame-retardant wall fabric
CN105568689A (en) * 2015-12-31 2016-05-11 湖州睿高新材料有限公司 Sofa fabric flame retardation finished Styrofoam and preparation method thereof
CN108179632A (en) * 2017-12-29 2018-06-19 绵阳佳联印染有限责任公司 A kind of polyamide fabric fire-retardant layer material and its complex method
CN109868657B (en) * 2019-03-15 2022-04-29 绍兴艾乐格思纺织有限公司 Preparation method of flame-retardant wear-resistant curtain
CN113789670B (en) * 2021-09-17 2023-06-23 苏州同构科技有限公司 Special flame retardant for nylon fabric and preparation method thereof

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Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
EP0388338A1 (en) * 1989-03-17 1990-09-19 SENFA, Société Anonyme : Coating complex for fibrous supports for use in coating processes with a compressed foam

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