CN102926292B - Flame retardant wallpaper and preparation method thereof - Google Patents
Flame retardant wallpaper and preparation method thereof Download PDFInfo
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- CN102926292B CN102926292B CN201210421358.2A CN201210421358A CN102926292B CN 102926292 B CN102926292 B CN 102926292B CN 201210421358 A CN201210421358 A CN 201210421358A CN 102926292 B CN102926292 B CN 102926292B
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 12
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 26
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 26
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000003381 stabilizer Substances 0.000 claims abstract description 16
- 238000007639 printing Methods 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000004014 plasticizer Substances 0.000 claims abstract description 12
- 238000004049 embossing Methods 0.000 claims abstract description 11
- 239000000779 smoke Substances 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 9
- 230000008569 process Effects 0.000 claims abstract description 8
- 239000000945 filler Substances 0.000 claims abstract description 7
- 238000002485 combustion reaction Methods 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 19
- 239000004744 fabric Substances 0.000 claims description 17
- 239000002131 composite material Substances 0.000 claims description 13
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 11
- 125000001477 organic nitrogen group Chemical group 0.000 claims description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- 239000011574 phosphorus Substances 0.000 claims description 8
- 229920000742 Cotton Polymers 0.000 claims description 6
- FECYWCXKWXPHPP-UHFFFAOYSA-N [Ca][Zn][Ba] Chemical compound [Ca][Zn][Ba] FECYWCXKWXPHPP-UHFFFAOYSA-N 0.000 claims description 6
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 6
- 230000008030 elimination Effects 0.000 claims description 6
- 238000003379 elimination reaction Methods 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 5
- 239000004745 nonwoven fabric Substances 0.000 claims description 5
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 4
- 239000007822 coupling agent Substances 0.000 claims description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 4
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 claims description 4
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical class [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims description 2
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 claims description 2
- 238000010030 laminating Methods 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- CSHCPECZJIEGJF-UHFFFAOYSA-N methyltin Chemical compound [Sn]C CSHCPECZJIEGJF-UHFFFAOYSA-N 0.000 claims description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims description 2
- 238000005096 rolling process Methods 0.000 claims description 2
- 150000003573 thiols Chemical class 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 7
- 231100000331 toxic Toxicity 0.000 abstract description 3
- 230000002588 toxic effect Effects 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 238000011031 large-scale manufacturing process Methods 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000004566 building material Substances 0.000 description 8
- 229910001385 heavy metal Inorganic materials 0.000 description 7
- 239000011265 semifinished product Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000001514 detection method Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000004154 testing of material Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 102100035474 DNA polymerase kappa Human genes 0.000 description 2
- 101710108091 DNA polymerase kappa Proteins 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Paper (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention relates to flame retardant wallpaper. The flame retardant wallpaper comprises a wallpaper substrate, a PVC (Poly Vinyl Chloride) layer, a printing layer and an embossing layer, wherein the PVC layer comprises PVC resin, a plasticizer, a stabilizer, titanium dioxide, a flame retardant and a smoke abatement filling agent. The invention also relates to preparation method of the flame retardant wallpaper. The flame retardant wallpaper provided by the invention adopts the novel flame retardant which is collaboratively compounded with the novel smoke abatement filling agent, thus being good in flame retardant effect and avoiding a highly toxic metal flame retardant. The preparation method provided by the invention is simple and convenient in process, can be used for obtaining the environmentally-friendly flame retardant wallpaper, is suitable for large-scale production, and has excellent economic value and social value.
Description
Technical field
The present invention relates to interior decoration field of constructional ornament, be specifically related to a kind of environment-friendly type difficulty combustion wallpaper and preparation method thereof.
Background technology
On market, mostly existing one Bucky wall paper is with non-woven paper, nonwoven fabric, grid pure cotton cloth, chemical fabric or blended cloth etc. for base material, surface calendering compound common PVC film or containing PVC special material after, republish, embossing formed ornament materials.
Wallpaper is as a kind of important house decorative material, and its fire protecting performance is extremely important.After the fire protecting performance new standard GB8624-2006 of wallpaper replaces old plant GB8624-1997, to the intension of wallpaper combustion characteristics also from simple flame propagation with spread, extend to comprehensive parameters such as comprising combustion heat rate of release, Heat liberation unit, smoke density and product toxicity.Therefore, the wallpaper produced from now on must redesign material type selecting and formula and optimize, and makes it meet new fire protection requirement.
According to the regulation of old plant GB8624-1997, select conventional PVC flame retardant antimonous oxide (Sb
2o
3) and general filler calcium carbonate (CaCO
3) arrange in pairs or groups and can meet design requirement; And according to the regulation of new standard GB8624-2006, as still used Sb
2o
3as fire retardant, can because of Sb
2o
3the a large amount of smog produced during burning and make smoke density severe overweight.In addition according to the regulation of national environmental standard GB18585-2001, antimony (Sb) belongs to eight large heavy metal limited ranges and can not use, and novel environment friendly fire retardant and auxiliary aid therefore must be selected could to meet new wallpaper designing requirement.
Summary of the invention
For existing wallpaper under overcoming new national standard cannot meet the technological deficiency of fire protecting performance, avoid using highly toxic heavy metal, the object of this invention is to provide a kind of new environment-friendly type difficulty combustion wallpaper, avoid the use of harmful heavy metal.
Another object of the present invention is to provide the preparation method of described difficulty combustion wallpaper.
Difficulty combustion wallpaper provided by the invention, comprise wallpaper base material, layer of PVC, printed layers and embossed layers, wherein, described layer of PVC comprises following composition by weight:
Preferably, described layer of PVC comprises following composition by weight:
Wherein, described fire retardant is organic nitrogen phosphorus expansion type fire retardant.
Wherein, described smoke elimination filler is the aluminium hydroxide of titanate esters or aluminate coupling agent modification.Preferably, the particle diameter of the aluminium hydroxide of described modification is at 500-2000 order.
Organic nitrogen phosphorus expansion type fire retardant (IFR) is a kind of fire retardant containing acid source, charcoal source and source of the gas, the uniform carbonaceous froth bed of one deck can be produced at polymer surfaces when burning, this carbonaceous foam material is by the acid of acid source generation when burning by charcoal source dehydration production carbonaceous, and the foam that the gas produced when being burnt by source of the gas makes it to generate is formed.Carbonaceous froth bed once after being formed, just can heat insulation, oxygen barrier, smoke elimination, and the drip (drip can make propagation of flame) by thermogenetic molten plastic can be prevented.From on fire retardant mechanism mainly insulating effect, and have cooling effect concurrently due to the generation of gas.In addition, modified aluminium hydroxide easily discharges the crystallization water and plays endothermic effect after being heated, and have collaborative smoke elimination effect with organic nitrogen phosphorus expansion type fire retardant, organic nitrogen phosphorus expansion type fire retardant and other conventional antismoke agent composite, itself and the composite flame retardant effect reached of modified aluminium hydroxide cannot be obtained.
Wherein, described plasticizer is one or more in dibutyl phthalate, dioctyl phthalate, diisobutyl phthalate, dioctyl adipate, di-n-octyl sebacate, diisononyl phthalate.
Wherein, described stabilizing agent is one or more in barium calcium-zinc composite stabilizing agent, calcium-zinc composite stabilizing agent, mercaptan tin octylate, thiol methyl tin, thiol-butyl tin.
Above-mentioned plasticizer, stabilizing agent select any one model conventional in PVC wallpaper all can.
Wherein, described wallpaper base material is non-woven paper, nonwoven fabric, grid pure cotton cloth, chemical fabric or blended cloth.
The preparation method of difficulty combustion wallpaper provided by the invention is: first mixed with plasticizer, stabilizing agent by polyvinyl chloride resin, then under agitation add titanium dioxide, fire retardant and smoke elimination filler successively and be made into mixed paste; The mixed paste obtained and wallpaper base material are carried out compound, finally carries out printing, namely embossing obtain described wallpaper.
Wherein, the mode of described mixed paste and wallpaper base material compound is rolling process, laminating method or rubbing method.
Wherein, before described print steps, the step of press polish process can also be comprised.Described press polish process is preferably mechanical press polish, can improve planarization and make it be applicable to printing.
Wherein, in described print steps, printing-ink can be the ink of water-based, oiliness and other any type, and mode of printing can be intaglio printing, screen painting and other any mode of printing.
Wherein, in described embossing step, difficult combustion wallpaper can be formed after embossing machine high temperature embossing, or can first high temperature embossing, then on its surface by other mode of printing printings such as developing and printing or summit printings, form uneven, in picturesque disorder wall paper products.
Difficulty combustion wallpaper provided by the invention have employed novel fire retardant, and carries out composite with novel antismoke agent, and good flame retardation effect, avoids highly toxic metal fire retardant, can reach GB8624-2006 standard B level qualified through National Fire building material testing Spot detection; Detect through national building materials test center simultaneously and can reach the large heavy metal limit requirement of GB18585-2001 standard eight, meet the designing requirement of new difficulty combustion wallpaper completely.
Preparation method's simple process provided by the invention, can obtain the difficulty combustion wallpaper of environment-friendly type, suitable for mass production, has excellent economic worth and social value.
Accompanying drawing explanation
The vertical section structure schematic diagram of Fig. 1 difficulty combustion of the present invention wallpaper;
In figure: 1, base material; 2, layer of PVC; 3, printed layers; 4, embossed layers.
Detailed description of the invention
Following examples for illustration of the present invention, but are not used for limiting the scope of the invention.
Embodiment 1
The batching of layer of PVC: be polyvinyl chloride resin QS-1000F 50%, DOP plasticizer 17%, Plastistab 4000 barium calcium-zinc composite stabilizing agent (OMG company of the U.S.) 2%, titanium dioxide 7%, organic nitrogen phosphorus expansion type fire retardant KY2303(Jinan Taixing Fine Chemicals Co., ltd by weight percentage) 4%, modified aluminium hydroxide ATH-1000(Zhengzhou Fu Long chemical company, 1000 orders) 20%.
The manufacture process of wallpaper is as follows:
(1) first by polyvinyl chloride resin and DOP plasticizer, barium calcium-zinc composite stabilizing agent mixing and stirring, then under agitation add titanium dioxide, fire retardant and modified aluminium hydroxide successively and be made into mixed paste.
(2) mixed paste that step (1) obtains is configured as 300-400g/m through calender
2pVC film, 170 DEG C, under the condition of 70m/min with 40g/m
2grid pure cotton cloth base material be compounded to form wallpaper semi-finished product.
(3) the wallpaper semi-finished product of gained are carried out mechanical press polish, printing and embossing, form novel difficulty combustion wallpaper, its vertical section structure schematic diagram as shown in Figure 1.
It is qualified that this wallpaper reaches GB8624-2006 standard B level through National Fire building material testing Spot detection; Detect through national building materials test center simultaneously and reach the large heavy metal limit requirement of GB18585-2001 standard eight, meet the new designing requirement of difficult combustion wallpaper completely.
Embodiment 2
The batching of layer of PVC: be PVC paste resin PSM-3160%, DINP plasticizer 13%, Plastistab 4000 barium calcium-zinc composite stabilizing agent 3%, titanium dioxide 6%, organic nitrogen phosphorus expansion type fire retardant KY23033%, 500 object titanate coupling agent modified aluminium hydroxides 15% by weight percentage.
The manufacture process of wallpaper is as follows:
(1) first by polyvinyl chloride resin and DINP plasticizer, barium calcium-zinc composite stabilizing agent mixing and stirring, then under agitation add titanium dioxide, fire retardant and modified aluminium hydroxide successively and be made into mixed paste.
(2) mixed paste step (1) obtained through coating machine at 85g/m
2non-woven paper base material on be coated with one deck 265-365g/m
2pVC paste, 180 DEG C, heating plasticizing forms wallpaper semi-finished product under 50m/min.
(3) the wallpaper semi-finished product of gained are carried out printing and embossing, form novel difficulty combustion wallpaper.
It is qualified that this wallpaper reaches GB8624-2006 standard B level through National Fire building material testing Spot detection; Detect through national building materials test center simultaneously and reach the large heavy metal limit requirement of GB18585-2001 standard eight, meet the new designing requirement of difficult combustion wallpaper completely.
Embodiment 3
The batching of layer of PVC: be polyvinyl chloride resin QS-1000F 42%, DOP plasticizer 20%, Plastistab 3000 calcium-zinc composite stabilizing agent 5%, titanium dioxide 8.5%, organic nitrogen phosphorus expansion type fire retardant KY2303 4.5%, 2000 object aluminate coupling agent modified aluminium hydroxide 20% by weight percentage.
The manufacture process of wallpaper is as follows:
(1) first by polyvinyl chloride resin and DOP plasticizer, calcium-zinc composite stabilizing agent mixing and stirring, then under agitation add titanium dioxide, fire retardant and modified aluminium hydroxide successively and be made into mixed paste.
(2) mixed paste that step (1) obtains is configured as 300-400g/m through calender
2pVC film, 170 DEG C, under 70m/min with 40g/m
2blended cloth base material be compounded to form wallpaper semi-finished product.
(3) the wallpaper semi-finished product of gained are carried out mechanical press polish, printing and embossing, form novel difficulty combustion wallpaper
It is qualified that this wallpaper reaches GB8624-2006 standard B level through National Fire building material testing Spot detection; Detect through national building materials test center simultaneously and reach the large heavy metal limit requirement of GB18585-2001 standard eight, meet the new designing requirement of difficult combustion wallpaper completely.
Although above the present invention is described in detail with a general description of the specific embodiments, on basis of the present invention, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, all belong to the scope of protection of present invention.
Claims (10)
1. a difficult combustion wallpaper, comprise wallpaper base material, layer of PVC, printed layers and embossed layers, it is characterized in that, described layer of PVC is prepared from by following composition by weight:
Described fire retardant is organic nitrogen phosphorus expansion type fire retardant;
Described smoke elimination filler is the aluminium hydroxide of titanate esters or aluminate coupling agent modification.
2. wallpaper according to claim 1, is characterized in that, described layer of PVC is prepared from by following composition by weight:
3. wallpaper according to claim 1 and 2, it is characterized in that, described plasticizer is one or more in dibutyl phthalate, dioctyl phthalate, diisobutyl phthalate, dioctyl adipate, di-n-octyl sebacate, diisononyl phthalate.
4. wallpaper according to claim 1 and 2, is characterized in that, described stabilizing agent is one or more in barium calcium-zinc composite stabilizing agent, calcium-zinc composite stabilizing agent, mercaptan tin octylate, thiol methyl tin, thiol-butyl tin.
5. wallpaper according to claim 1 and 2, is characterized in that, described wallpaper base material is non-woven paper, nonwoven fabric, grid pure cotton cloth, chemical fabric or blended cloth.
6. wallpaper according to claim 3, is characterized in that, described wallpaper base material is non-woven paper, nonwoven fabric, grid pure cotton cloth, chemical fabric or blended cloth.
7. wallpaper according to claim 4, is characterized in that, described wallpaper base material is non-woven paper, nonwoven fabric, grid pure cotton cloth, chemical fabric or blended cloth.
8. the preparation method of wallpaper described in any one of claim 1-7, is characterized in that, is first mixed with plasticizer, stabilizing agent by polyvinyl chloride resin, then under agitation adds titanium dioxide, fire retardant and smoke elimination filler successively and is made into mixed paste; The mixed paste obtained and wallpaper base material are carried out compound, finally carries out printing, namely embossing obtain described wallpaper.
9. preparation method according to claim 8, is characterized in that, the mode of described mixed paste and wallpaper base material compound is rolling process, laminating method or rubbing method.
10. preparation method according to claim 8 or claim 9, is characterized in that, before described print steps, also comprise the step of press polish process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210421358.2A CN102926292B (en) | 2012-10-29 | 2012-10-29 | Flame retardant wallpaper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210421358.2A CN102926292B (en) | 2012-10-29 | 2012-10-29 | Flame retardant wallpaper and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102926292A CN102926292A (en) | 2013-02-13 |
| CN102926292B true CN102926292B (en) | 2015-04-15 |
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| CN103305013B (en) * | 2013-06-24 | 2015-09-23 | 地球卫士（天津）环保新材料有限公司 | A kind of diatomite height fills fire-retardant temp. controllable wallpaper base material and preparation method |
| CN103556801B (en) * | 2013-11-14 | 2017-02-01 | 广东玉兰集团股份有限公司 | Manufacturing process for wallpaper with patterns having manual three-dimensional effect |
| CN103722922B (en) * | 2013-11-27 | 2015-09-09 | 天津玥旸谷建筑科技有限公司 | A kind of preparation method with cubic texture effect wallpaper |
| CN103790076A (en) * | 2013-11-29 | 2014-05-14 | 淮北龙盘工贸有限责任公司 | Novel flame-retardant wallpaper |
| CN103952946A (en) * | 2014-05-20 | 2014-07-30 | 上海欣旺壁纸有限公司 | Scratch-resistant wallpaper and production method thereof |
| CN105755905A (en) * | 2014-12-16 | 2016-07-13 | 谢泽波 | Wallpaper and processing method thereof |
| CN104763121A (en) * | 2015-02-04 | 2015-07-08 | 滁州市莎朗新材料科技有限公司 | Environment-friendly composite wallpaper and production process thereof |
| CN105034630A (en) * | 2015-08-31 | 2015-11-11 | 刘惠强 | Inflaming retarding PVC (polyvinyl chloride) wallpaper printing technology |
| CN105172406A (en) * | 2015-08-31 | 2015-12-23 | 刘惠强 | Printing process for diatomite wallpaper |
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| CN105568775A (en) * | 2015-12-28 | 2016-05-11 | 杨洋 | Flame-retardant and pollutant-adsorbing wallpaper and preparation method thereof |
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| CN106283877A (en) * | 2016-08-17 | 2017-01-04 | 福建农林大学 | Polrvinyl chloride wallpaper with non-woven paper as base material of high flame retardant and preparation method thereof |
| CN106638132A (en) * | 2016-08-17 | 2017-05-10 | 福建农林大学 | Polyvinyl chloride flame-retardant wallpaper taking plant fiber paper as base material, and preparation method thereof |
| CN106638158A (en) * | 2016-11-02 | 2017-05-10 | 天津毅兴彩科技有限公司 | Polyvinyl chloride plastic wallpaper and production method thereof |
| CN106480785A (en) * | 2016-11-02 | 2017-03-08 | 天津毅兴彩科技有限公司 | A kind of hectographic printing wallpaper and preparation method thereof |
| CN107489073A (en) * | 2017-08-24 | 2017-12-19 | 浙江科屹耐火材料有限公司 | A kind of environmental-protection fireproof wallpaper and preparation method thereof |
| CN107299559A (en) * | 2017-08-30 | 2017-10-27 | 陈雪珍 | The production method of environmental protection flame retardant wallpaper |
| CN109338738B (en) * | 2018-10-18 | 2021-08-13 | 安徽紫荆花壁纸股份有限公司 | Preparation method of multifunctional composite decorative material |
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| CN87105201A (en) * | 1987-07-31 | 1988-03-16 | 北京市建筑塑料制品厂 | PVC flame retardant wallpaper |
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| JPH01207497A (en) * | 1988-02-15 | 1989-08-21 | Dainippon Printing Co Ltd | phosphorescent wallpaper |
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| CN87105201A (en) * | 1987-07-31 | 1988-03-16 | 北京市建筑塑料制品厂 | PVC flame retardant wallpaper |
| CN101235666A (en) * | 2007-01-30 | 2008-08-06 | Lg化学株式会社 | Decorative wall paper and its production method |
| CN102587218A (en) * | 2011-12-12 | 2012-07-18 | 公安部四川消防研究所 | Composite wallpaper containing polyvinyl chloride |
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