CN102995388A - Preparation method of water-washable anion wool fiber and application in home textile product - Google Patents

Preparation method of water-washable anion wool fiber and application in home textile product Download PDF

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Publication number
CN102995388A
CN102995388A CN2012105300215A CN201210530021A CN102995388A CN 102995388 A CN102995388 A CN 102995388A CN 2012105300215 A CN2012105300215 A CN 2012105300215A CN 201210530021 A CN201210530021 A CN 201210530021A CN 102995388 A CN102995388 A CN 102995388A
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Prior art keywords
anion
wool
preparation
wool fiber
agent
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CN2012105300215A
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CN102995388B (en
Inventor
沈守兵
宋春常
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Shanghai Shuixing Home Textile Co Ltd
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Shanghai Shuixing Home Textile Co Ltd
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Abstract

A preparation method of a water-washable anion wool fiber and an application in home textile products. The preparation method comprises the following steps of: (1) wool pretreatment: carding, wool scouring, degreasing, and bleaching; (2) wool nonshrink treatment: treating by using a shrinkproof finishing agent and a penetrating agent at a temperature of 50-60 DEG C for 30-40 min; (3) anion wool fiber preparation: adding an anion compound finishing agent at 50-60 DEG C, simultaneously adding a hydrophilic softener, adjusting the pH value to 5-7, heating to 70-80 DEG C, then performing heat preservation for 30 min. The water-washable anion wool fiber can release anions, has antibiotic effect, is washable when in use, is not easy for felting shrinkage, can release anions lastingly, prevent problems of easy bacterium breeding, mildewing, skin allergy of consumers and the like during wool using process, greatly increase the using population of wool products, make wool comforter an optimal choice of bedclothes for people, realize better application of anions to human daily life, improve air quality of home life, and improve sleep quality of human body.

Description

A kind ofly wash the preparation method of anion wool fiber and the application in home textile product thereof
Technical field
The present invention relates to a kind of preparation method of wool fibre and the application in home textile product thereof, particularly a kind ofly wash the preparation method of anion wool fiber and the application in home textile product thereof.
Background technology
Anion can not only be facilitated the synthetic and vitamin storage of human body, the physiological activity of reinforcement and human activin, therefore it is otherwise known as " air vitamin ", thinks it as the vitamin of food, and the vital movement of human body and other biological is had very important impact.
In recent years, people's living standard improves constantly, operating pressure is increasing, more and more higher to anion product acceptance, a series of anion generation product has wide selling market, but the application on the textiles adopt more can anion releasing the ore fine powder add fiber or the anionic finishing agent that synthetic fiber spinning liquid makes and be added on the fabric by rear arrangement also untappedly go out can wash the anion wool fiber because rear finishing technique persistence is poor.
Wool surfaces has scale layer, available technology adopting chlorine-containing compound or hydrogen peroxide clean wool, cause thus wool fibre impaired, the wool fibre security performance reduces simultaneously, the shrink phenomenon occurs easily, and the processing adhesives that adopt carry out more behind the conventional anionic finishing agent in addition, can affect like this burst size of anion, through after a while washing, function also can disappear simultaneously.
Therefore, need especially a kind of the wash preparation method of anion wool fiber and the application in home textile product thereof, to solve the above-mentioned existing problem that exists.
Summary of the invention
The object of the present invention is to provide a kind of the wash preparation method of anion wool fiber and the application in home textile product thereof, for the deficiencies in the prior art, wool fibre felting, easily breed bacteria and the easy problem such as mouldy have been overcome, improved simultaneously the functional of wool fibre, has negative ion-releasing function, widened the range of application of anion product, improved the quality of relevant home textile product and the raising of class, so that its product quality has realized qualitative leap.
Technical problem solved by the invention can realize by the following technical solutions:
On the one hand, the invention provides a kind of preparation method who washes the anion wool fiber, it is characterized in that it comprises the steps:
(1) wool pre-treatment: carding → scouring of wool → degreasing → bleaching;
(2) wool shrinkproof is processed: adopt shrink-resistant agent and bleeding agent at temperature 50-60 ℃, process 30-40min;
(3) preparation of anion wool fiber: add the composite finishing agent of anion 50-60 ℃ of condition, and add simultaneously hydrophilic softener, adjust the pH value to 5-7, be warmed up to 70-80 ℃, then be incubated 30min, make and to wash the anion wool fiber.
In one embodiment of the invention, described wool-cleaning technology is processed 40-60min for adopting neutral scouring washing agent 30-50g/L and neutral salt glauber salt 10-15g/L at temperature 50-60 ℃.
Further, described neutral scouring washing agent is the w-90 of blue or green upper chemical industry.
In one embodiment of the invention, described degreasing process is processed 30-40min for adopting degreasing agent 15-20g/L and glauber salt 8-10g/L at temperature 50-60 ℃.
Further, described degreasing agent is the TB2706 of Threebond.
In one embodiment of the invention, described bleaching process is processed 30-40min for adopting hydrogen peroxide 20-30g/L, sodium metasilicate 8-10g/L and bleeding agent 5-8g/L at temperature 50-60 ℃.
Further, described bleeding agent is Rapid Panetrant T.
In one embodiment of the invention, described shrink-resistant agent is 1600 of permanent safe chemical industry, and described bleeding agent is the JFC of permanent safe chemical industry.
In one embodiment of the invention, the composite finishing agent of described anion is for adopting Japan to carry out composite getting with the Iorina powder that spins company's exploitation and the anionic finishing agent Kayacera of Nippon Kayaku Colors company greatly, and composite mass ratio is 1:3-5.
In one embodiment of the invention, described hydrophilic softener is the 856D of permanent safe chemical industry.
In one embodiment of the invention, described anion burst size of washing the anion wool fiber is 〉=3000/cm 3, wash 10 times after the anion burst size be 〉=2000/cm 3, fiber tangles with the felting degree as not being worse than 3-4 level (wool famous special product standard: IB-2) after the washing.
On the other hand, the invention provides a kind of application of anion wool fiber in home textile product of washing, it is characterized in that, described wash the anion wool fiber can be used for the preparation can wash the anion wool quilt.
Of the present inventionly wash the preparation method of anion wool fiber and the application in home textile product thereof, compared with prior art, it is not only capable of releasing negative ion to wash the anion wool fiber, antibiotic effect is arranged simultaneously, use procedure can be washed, avoided producing peculiar smell in the wool use procedure, easily breed bacteria is mouldy, causes the problems such as the consumer is allergic, greatly increased the use crowd of wool product, make wool comforter become the excellent selection of people's bedding, anion is better applied to people's daily life, improve the at home air quality of life, improve sleep quality of human body, realize purpose of the present invention.
Characteristics of the present invention can be consulted the detailed description of the following better embodiment of this case and be obtained to be well understood to.
The specific embodiment
For technological means, creation characteristic that the present invention is realized, reach purpose and effect is easy to understand, below in conjunction with specifically, further set forth the present invention.
The preparation method who washes the anion wool fiber of the present invention is characterized in that it comprises the steps:
(1) wool pre-treatment: carding → scouring of wool → degreasing → bleaching;
(2) wool shrinkproof is processed: adopt shrink-resistant agent and bleeding agent at temperature 50-60 ℃, process 30-40min;
(3) preparation of anion wool fiber: add the composite finishing agent of anion 50-60 ℃ of condition, and add simultaneously hydrophilic softener, adjust the pH value to 5-7, be warmed up to 70-80 ℃, then be incubated 30min, make and to wash the anion wool fiber.
In the present invention, described wool-cleaning technology is processed 40-60min for adopting neutral scouring washing agent 30-50g/L and neutral salt glauber salt 10-15g/L at temperature 50-60 ℃.Described neutral scouring washing agent is the w-90 of blue or green upper chemical industry.
In the present invention, described degreasing process is processed 30-40min for adopting degreasing agent 15-20g/L and glauber salt 8-10g/L at temperature 50-60 ℃.Described degreasing agent is the TB2706 of Threebond.
In the present invention, described bleaching process is processed 30-40min for adopting hydrogen peroxide 20-30g/L, sodium metasilicate 8-10g/L and bleeding agent 5-8g/L at temperature 50-60 ℃.Described bleeding agent is RapidPanetrant T.
In the present invention, described shrink-resistant agent is 1600 of permanent safe chemical industry, and described bleeding agent is the JFC of permanent safe chemical industry; Less to wool damage, shrinkproof result is good, and security performance is high simultaneously.Add hydrophilic softener in the later stage simultaneously, make wool fibre coat one deck clear water diaphragm, reduce the felting of wool fibre in water-washing process, and can be shrinkproof lastingly.
In the present invention, the composite finishing agent of described anion is for adopting Japan to carry out composite getting with the Iorina powder that spins company's exploitation and the anionic finishing agent Kayacera of Nippon Kayaku Colors company greatly, and composite mass ratio is 1:3-5.
In the present invention, described hydrophilic softener is the 856D of permanent safe chemical industry; Greatly improved negative ion releasing function, feel and persistence all are greatly improved simultaneously.
In the present invention, described anion burst size of washing the anion wool fiber is 〉=3000/cm 3, wash 10 times after the anion burst size be 〉=2000/cm 3, fiber tangles with the felting degree as not being worse than 3-4 level (wool famous special product standard: IB-2) after the washing.
Of the present inventionly wash the application of anion wool fiber in home textile product, the described anion wool fiber of washing can be used for preparation and can wash the anion wool quilt.
Embodiment 1
The wool pre-treatment:
Carding → scouring of wool → degreasing → bleaching;
Described wool-cleaning technology is processed 40min for adopting neutral scouring washing agent 30g/L and neutral salt glauber salt 10g/L at temperature 50 C.Described neutral scouring washing agent is the w-90 of blue or green upper chemical industry.
Described degreasing process is processed 30min for adopting degreasing agent 15g/L and glauber salt 8g/L at temperature 50 C.Described degreasing agent is the TB2706 of Threebond.
Described bleaching process is processed 30min for adopting hydrogen peroxide 20g/L, sodium metasilicate 8g/L and bleeding agent 5g/L at temperature 50 C.Described bleeding agent is Rapid Panetrant T.
Wool shrinkproof is processed:
Adopt shrink-resistant agent and bleeding agent at temperature 50 C, process 30min; Described shrink-resistant agent is 1600 of permanent safe chemical industry, and described bleeding agent is the JFC of permanent safe chemical industry;
The preparation of anion wool fiber:
Add the composite finishing agent of anion 50 ℃ of conditions, and add simultaneously hydrophilic softener, adjust pH value to 5, be warmed up to 70 ℃, then be incubated 30min, make and to wash the anion wool fiber.
The composite finishing agent of described anion is for adopting Japan to carry out composite getting with the Iorina powder that spins company's exploitation and the anionic finishing agent Kayacera of Nippon Kayaku Colors company greatly, and composite mass ratio is 1:3; Described hydrophilic softener is the 856D of permanent safe chemical industry.
The anion burst size of the anion wool the washed fiber that makes is 〉=3000/cm 3, wash 10 times after the anion burst size be 〉=2000/cm 3, fiber tangles with the felting degree as not being worse than 3-4 level (wool famous special product standard: IB-2) after the washing.
Embodiment 2
The wool pre-treatment:
Carding → scouring of wool → degreasing → bleaching;
Described wool-cleaning technology is processed 60min for adopting neutral scouring washing agent 50g/L and neutral salt glauber salt 15g/L at temperature 60 C.Described neutral scouring washing agent is the w-90 of blue or green upper chemical industry.
Described degreasing process is processed 40min for adopting degreasing agent 20g/L and glauber salt 10g/L at temperature 60 C.Described degreasing agent is the TB2706 of Threebond.
Described bleaching process is processed 40min for adopting hydrogen peroxide 30g/L, sodium metasilicate 10g/L and bleeding agent 8g/L at temperature 60 C.Described bleeding agent is Rapid Panetrant T.
Wool shrinkproof is processed:
Adopt shrink-resistant agent and bleeding agent at temperature 60 C, process 40min; Described shrink-resistant agent is 1600 of permanent safe chemical industry, and described bleeding agent is the JFC of permanent safe chemical industry;
The preparation of anion wool fiber:
Add the composite finishing agent of anion 60 ℃ of conditions, and add simultaneously hydrophilic softener, adjust pH value to 7, be warmed up to 80 ℃, then be incubated 30min, make and to wash the anion wool fiber.
The composite finishing agent of described anion is for adopting Japan to carry out composite getting with the Iorina powder that spins company's exploitation and the anionic finishing agent Kayacera of Nippon Kayaku Colors company greatly, and composite mass ratio is 1:5; Described hydrophilic softener is the 856D of permanent safe chemical industry.
The anion burst size of the anion wool the washed fiber that makes is 〉=3000/cm 3, wash 10 times after the anion burst size be 〉=2000/cm 3, fiber tangles with the felting degree as not being worse than 3-4 level (wool famous special product standard: IB-2) after the washing.
Embodiment 3
The wool pre-treatment:
Carding → scouring of wool → degreasing → bleaching;
Described wool-cleaning technology is processed 50min for adopting neutral scouring washing agent 40g/L and neutral salt glauber salt 12g/L 55 ℃ of temperature.Described neutral scouring washing agent is the w-90 of blue or green upper chemical industry.
Described degreasing process is processed 35min for adopting degreasing agent 17g/L and glauber salt 9g/L 55 ℃ of temperature.Described degreasing agent is the TB2706 of Threebond.
Described bleaching process is processed 35min for adopting hydrogen peroxide 25g/L, sodium metasilicate 9g/L and bleeding agent 6g/L 55 ℃ of temperature.Described bleeding agent is Rapid Panetrant T.
Wool shrinkproof is processed:
Adopt shrink-resistant agent and bleeding agent 55 ℃ of temperature, process 35min; Described shrink-resistant agent is 1600 of permanent safe chemical industry, and described bleeding agent is the JFC of permanent safe chemical industry;
The preparation of anion wool fiber:
Add the composite finishing agent of anion 55 ℃ of conditions, and add simultaneously hydrophilic softener, adjust pH value to 6, be warmed up to 75 ℃, then be incubated 30min, make and to wash the anion wool fiber.
The composite finishing agent of described anion is for adopting Japan to carry out composite getting with the Iorina powder that spins company's exploitation and the anionic finishing agent Kayacera of Nippon Kayaku Colors company greatly, and composite mass ratio is 1:4; Described hydrophilic softener is the 856D of permanent safe chemical industry.
The anion burst size of the anion wool the washed fiber that makes is 〉=3000/cm 3, wash 10 times after the anion burst size be 〉=2000/cm 3, fiber tangles with the felting degree as not being worse than 3-4 level (wool famous special product standard: IB-2) after the washing.
More than show and described basic principle of the present invention and principal character and advantage of the present invention.The technical staff of the industry should understand; the present invention is not restricted to the described embodiments; that describes in above-described embodiment and the specification just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications; these changes and improvements all fall in the claimed scope of the invention, and the claimed scope of the present invention is defined by appending claims and equivalent thereof.

Claims (12)

1. the preparation method that can wash the anion wool fiber is characterized in that it comprises the steps:
(1) wool pre-treatment: carding → scouring of wool → degreasing → bleaching;
(2) wool shrinkproof is processed: adopt shrink-resistant agent and bleeding agent at temperature 50-60 ℃, process 30-40min;
(3) preparation of anion wool fiber: add the composite finishing agent of anion 50-60 ℃ of condition, and add simultaneously hydrophilic softener, adjust the pH value to 5-7, be warmed up to 70-80 ℃, then be incubated 30min, make and to wash the anion wool fiber.
2. the preparation method who washes the anion wool fiber as claimed in claim 1 is characterized in that, described wool-cleaning technology is processed 40-60min for adopting neutral scouring washing agent 30-50g/L and neutral salt glauber salt 10-15g/L at temperature 50-60 ℃.
3. the preparation method who washes the anion wool fiber as claimed in claim 2 is characterized in that, described neutral scouring washing agent is the w-90 of blue or green upper chemical industry.
4. the preparation method who washes the anion wool fiber as claimed in claim 1 is characterized in that, described degreasing process is processed 30-40min for adopting degreasing agent 15-20g/L and glauber salt 8-10g/L at temperature 50-60 ℃.
5. the preparation method who washes the anion wool fiber as claimed in claim 4 is characterized in that, described degreasing agent is the TB2706 of Threebond.
6. the preparation method who washes the anion wool fiber as claimed in claim 1 is characterized in that, described bleaching process is processed 30-40min for adopting hydrogen peroxide 20-30g/L, sodium metasilicate 8-10g/L and bleeding agent 5-8g/L at temperature 50-60 ℃.
7. the preparation method who washes the anion wool fiber as claimed in claim 6 is characterized in that, described bleeding agent is Rapid Panetrant T.
8. the preparation method who washes the anion wool fiber as claimed in claim 1 is characterized in that, described shrink-resistant agent is 1600 of permanent safe chemical industry, and described bleeding agent is the JFC of permanent safe chemical industry.
9. the preparation method who washes the anion wool fiber as claimed in claim 1, it is characterized in that, the composite finishing agent of described anion is for adopting Japan to carry out composite getting with the Iorina powder that spins company's exploitation and the anionic finishing agent Kayacera of Nippon Kayaku Colors company greatly, and composite mass ratio is 1:3-5.
10. the preparation method who washes the anion wool fiber as claimed in claim 1 is characterized in that, described hydrophilic softener is the 856D of permanent safe chemical industry.
11. the preparation method who washes the anion wool fiber as claimed in claim 1 is characterized in that, described anion burst size of washing the anion wool fiber is 〉=3000/cm 3, wash 10 times after the anion burst size be 〉=2000/cm 3, fiber tangles with the felting degree as not being worse than 3-4 level (wool famous special product standard: IB-2) after the washing.
12. can wash the application of anion wool fiber in home textile product for one kind, it is characterized in that, described wash the anion wool fiber can be used for the preparation can wash the anion wool quilt.
CN201210530021.5A 2012-12-10 2012-12-10 A kind ofly wash the preparation method of anion wool fiber and the application in home textile product thereof Active CN102995388B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103382638A (en) * 2013-07-01 2013-11-06 上海水星家用纺织品股份有限公司 Preparation method of anion down feather material and applications thereof in home-textile products
CN104746335A (en) * 2013-12-31 2015-07-01 上海水星家用纺织品股份有限公司 Preparation method and application of wool fibers with anti-worm, antibacterial and anti-mite functions
CN106618010A (en) * 2016-12-29 2017-05-10 郑州德惠纺织科技有限公司 Degradable milk fiber quilt containing negative ions and preparation method of milk fiber quilt
CN106724474A (en) * 2016-12-29 2017-05-31 郑州德惠纺织科技有限公司 Containing anion and washable fibre and soya quilt and preparation method thereof
CN106811959A (en) * 2017-01-17 2017-06-09 常熟市新光毛条处理有限公司 A kind of anion finishing technique of Australia's wool top
CN110791953A (en) * 2019-11-15 2020-02-14 安徽京威纺织服饰有限公司 Production process of anion far infrared anti-ultraviolet woolen sweater
CN111139641A (en) * 2019-12-31 2020-05-12 张家港保税区宇联羊毛工业有限公司 Preparation method of wool tops capable of being comprehensively and easily nursed and product of wool tops

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2160292Y (en) * 1993-04-21 1994-04-06 山东省颜陵毛纺织厂 wool quilt
CN101294355A (en) * 2007-04-23 2008-10-29 陈磊 Multifunctional negative ion fibre, textile
CN101463556A (en) * 2007-12-17 2009-06-24 福建凤竹纺织科技股份有限公司 Negative ion knitting fabric and technique for producing the same
CN101509188A (en) * 2009-03-06 2009-08-19 东华大学 Milled finishing agent with excitated negative oxygen ion, preparation method and uses thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2160292Y (en) * 1993-04-21 1994-04-06 山东省颜陵毛纺织厂 wool quilt
CN101294355A (en) * 2007-04-23 2008-10-29 陈磊 Multifunctional negative ion fibre, textile
CN101463556A (en) * 2007-12-17 2009-06-24 福建凤竹纺织科技股份有限公司 Negative ion knitting fabric and technique for producing the same
CN101509188A (en) * 2009-03-06 2009-08-19 东华大学 Milled finishing agent with excitated negative oxygen ion, preparation method and uses thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103382638A (en) * 2013-07-01 2013-11-06 上海水星家用纺织品股份有限公司 Preparation method of anion down feather material and applications thereof in home-textile products
CN104746335A (en) * 2013-12-31 2015-07-01 上海水星家用纺织品股份有限公司 Preparation method and application of wool fibers with anti-worm, antibacterial and anti-mite functions
CN106618010A (en) * 2016-12-29 2017-05-10 郑州德惠纺织科技有限公司 Degradable milk fiber quilt containing negative ions and preparation method of milk fiber quilt
CN106724474A (en) * 2016-12-29 2017-05-31 郑州德惠纺织科技有限公司 Containing anion and washable fibre and soya quilt and preparation method thereof
CN106811959A (en) * 2017-01-17 2017-06-09 常熟市新光毛条处理有限公司 A kind of anion finishing technique of Australia's wool top
CN110791953A (en) * 2019-11-15 2020-02-14 安徽京威纺织服饰有限公司 Production process of anion far infrared anti-ultraviolet woolen sweater
CN111139641A (en) * 2019-12-31 2020-05-12 张家港保税区宇联羊毛工业有限公司 Preparation method of wool tops capable of being comprehensively and easily nursed and product of wool tops

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