CN103741247A - Anti-solarization fishing net - Google Patents
Anti-solarization fishing net Download PDFInfo
- Publication number
- CN103741247A CN103741247A CN201310670770.2A CN201310670770A CN103741247A CN 103741247 A CN103741247 A CN 103741247A CN 201310670770 A CN201310670770 A CN 201310670770A CN 103741247 A CN103741247 A CN 103741247A
- Authority
- CN
- China
- Prior art keywords
- fishing net
- solarization
- raw material
- polystyrene
- isopropyl imidazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 239000004014 plasticizer Substances 0.000 claims abstract description 10
- FUOZJYASZOSONT-UHFFFAOYSA-N 2-propan-2-yl-1h-imidazole Chemical compound CC(C)C1=NC=CN1 FUOZJYASZOSONT-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004793 Polystyrene Substances 0.000 claims abstract description 7
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002223 polystyrene Polymers 0.000 claims abstract description 7
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 claims abstract description 4
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 claims abstract description 4
- 238000012986 modification Methods 0.000 claims description 9
- 230000004048 modification Effects 0.000 claims description 9
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims description 6
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- -1 dioctyl ester Chemical class 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 4
- 229950002083 octabenzone Drugs 0.000 claims description 4
- 238000009987 spinning Methods 0.000 claims description 4
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 3
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims description 3
- 239000001293 FEMA 3089 Substances 0.000 claims description 3
- 235000019483 Peanut oil Nutrition 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001993 dienes Chemical class 0.000 claims description 3
- 229940044949 eucalyptus oil Drugs 0.000 claims description 3
- 239000010642 eucalyptus oil Substances 0.000 claims description 3
- 238000002454 metastable transfer emission spectrometry Methods 0.000 claims description 3
- 239000000312 peanut oil Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000004513 sizing Methods 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 206010025482 malaise Diseases 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
Abstract
The invention discloses an anti-solarization fishing net which comprises the following raw materials by weight: 91-100 parts of ultrahigh molecular weight polyethylene, 6-10 parts of polystyrene, 1-2 parts of 2-isopropyl imidazole, 0.1-0.2 part of ethylene dimethacrylate, 0.7-1 part of 2-hydroxy-4-n-octyloxy benzophenone, and 4-5 parts of modified plasticizer. The fishing net produced in the invention is added with 2-isopropyl imidazole and 2-hydroxy-4-n-octyloxy benzophenone, which greatly improves the anti-solarization performance of the fishing net, and prolongs the service life.
Description
Technical field
The present invention relates generally to a kind of fishing net, relates in particular to a kind of anti-Japanese solarization fishing net.
Background technology
Modern fishing net mainly adopts polyethylene, the raw materials such as nylon are processed, wherein polythene fishing net, to adopt polythene material through fusion plastification, spinning, plying is twisted thread and is made into, use Yu Haiyang trawlnet, purse seine, wind resistance sea net cage etc., there is longer life cycle, higher catching rate, but the mechanical property of polyethylene itself is general, TENSILE STRENGTH is lower, creep resistance is bad, just cause the intensity of conventional polyethylene fishing net, anti-wear performance, at the bottom of toughness is unwell to Complex Sea and wind and waves environment fishing operation, reduced the service life of fishing gear, not only waste resource, also directly affect catch.
Summary of the invention
The object of the invention is just to provide a kind of anti-Japanese solarization fishing net.
The present invention is achieved by the following technical solutions:
A kind of anti-Japanese solarization fishing net, it is comprised of the raw material of following weight parts:
Ultra-high molecular weight polyethylene 91-100, polystyrene 6-10,2 isopropyl imidazole 1-2, Ethylene glycol dimethacrylate 0.1-0.2, Octabenzone 0.7-1, modification plasticizer 4-5;
Described modification plasticizer is comprised of the raw material of following weight parts: MTES 1-1.2, dioctyl ester 2-2.3, ATBC 1.2-1.4, peanut oil 2-2.3, turpentine oil 1-1.2, eucalyptus oil 0.3-0.4, poly-different diene 1.2-1.4, morpholine 0.2-0.3, antioxidant MB 1-1.2, methyl ethyl ketone peroxide 0.2-0.3, styrene 1.2-1.4, nano titanium oxide 0.2-0.3;
Above-mentioned methyl ethyl ketone peroxide is added drop-wise in other each mixtures of materials, and stirring reaction 60-90 minute, is warming up to 120-130 ℃, and stirring reaction 2-3 hour obtains described modification plasticizer.
A preparation method for anti-Japanese solarization fishing net, comprises the following steps:
Get above-mentioned polystyrene and mix with 2 isopropyl imidazole, add Ethylene glycol dimethacrylate, insulated and stirred 10-16 minute at 60-70 ℃, add the each raw material of residue, be cooled to normal temperature, by extruder, melt extrude, drawing-off, sizing, spinning, obtain described anti-Japanese solarization fishing net.
Advantage of the present invention is:
The fishing net that the present invention produces adds 2 isopropyl imidazole and Octabenzone, has improved greatly the anti-insolation performance of fishing net, has extended service life.
The specific embodiment
Embodiment 1
A kind of anti-Japanese solarization fishing net, it is characterized in that it by following weight parts (kilogram) raw material form:
Ultra-high molecular weight polyethylene 100, polystyrene 10,2 isopropyl imidazole 1, Ethylene glycol dimethacrylate 0.2, Octabenzone 0.7, modification plasticizer 4;
Described modification plasticizer is comprised of the raw material of following weight parts: MTES 1.2, dioctyl ester 2.3, ATBC 1.4, peanut oil 2.3, turpentine oil 1.2, eucalyptus oil 0.4, poly-different diene 1.4, morpholine 0.3, antioxidant MB 1-1.2, methyl ethyl ketone peroxide 0.3, styrene 1.4, nano titanium oxide 0.3;
Above-mentioned methyl ethyl ketone peroxide is added drop-wise in other each mixtures of materials, and stirring reaction 90 minutes, is warming up to 130 ℃, and stirring reaction 2 hours obtains described modification plasticizer.
A preparation method for anti-Japanese solarization fishing net, comprises the following steps:
Get above-mentioned polystyrene and mix with 2 isopropyl imidazole, add Ethylene glycol dimethacrylate, insulated and stirred 16 minutes at 70 ℃, add the each raw material of residue, be cooled to normal temperature, by extruder, melt extrude, drawing-off, sizing, spinning, obtain described anti-Japanese solarization fishing net.
Filament properties test: elongation at break 15.3%;
Anti-tensile degree (KG) 54.7;
Knotting strength (KG) 38.10.
Claims (2)
1. an anti-Japanese solarization fishing net, is characterized in that what it was comprised of the raw material of following weight parts:
Ultra-high molecular weight polyethylene 91-100, polystyrene 6-10,2 isopropyl imidazole 1-2, Ethylene glycol dimethacrylate 0.1-0.2, Octabenzone 0.7-1, modification plasticizer 4-5;
Described modification plasticizer is comprised of the raw material of following weight parts: MTES 1-1.2, dioctyl ester 2-2.3, ATBC 1.2-1.4, peanut oil 2-2.3, turpentine oil 1-1.2, eucalyptus oil 0.3-0.4, poly-different diene 1.2-1.4, morpholine 0.2-0.3, antioxidant MB 1-1.2, methyl ethyl ketone peroxide 0.2-0.3, styrene 1.2-1.4, nano titanium oxide 0.2-0.3;
Above-mentioned methyl ethyl ketone peroxide is added drop-wise in other each mixtures of materials, and stirring reaction 60-90 minute, is warming up to 120-130 ℃, and stirring reaction 2-3 hour obtains described modification plasticizer.
2. a preparation method for anti-Japanese solarization fishing net as claimed in claim 1, is characterized in that comprising the following steps:
Get above-mentioned polystyrene and mix with 2 isopropyl imidazole, add Ethylene glycol dimethacrylate, insulated and stirred 10-16 minute at 60-70 ℃, add the each raw material of residue, be cooled to normal temperature, by extruder, melt extrude, drawing-off, sizing, spinning, obtain described anti-Japanese solarization fishing net.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310670770.2A CN103741247A (en) | 2013-12-11 | 2013-12-11 | Anti-solarization fishing net |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310670770.2A CN103741247A (en) | 2013-12-11 | 2013-12-11 | Anti-solarization fishing net |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103741247A true CN103741247A (en) | 2014-04-23 |
Family
ID=50498308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310670770.2A Pending CN103741247A (en) | 2013-12-11 | 2013-12-11 | Anti-solarization fishing net |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103741247A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104775297A (en) * | 2015-03-20 | 2015-07-15 | 巢湖市荷花渔网有限公司 | High-quality and high-efficiency fishing net |
| CN104782593A (en) * | 2015-03-26 | 2015-07-22 | 巢湖市鼎盛渔具有限公司 | Wear-resisting and aging-resisting fishing net |
| CN104805529A (en) * | 2015-03-26 | 2015-07-29 | 巢湖市鼎盛渔具有限公司 | High-temperature-resistant fishing net |
| CN104805528A (en) * | 2015-03-26 | 2015-07-29 | 巢湖市鼎盛渔具有限公司 | Efficient fishing net |
| CN105295169A (en) * | 2015-10-29 | 2016-02-03 | 六安市沪渔网具有限公司 | Sunshine resistant fishing net |
| CN105385076A (en) * | 2015-11-14 | 2016-03-09 | 巢湖市荷花渔网有限公司 | Sunscreen fishing net and preparation method thereof |
| CN107099878A (en) * | 2017-05-13 | 2017-08-29 | 巢湖市翔宇渔具有限公司 | A kind of processing method for improving fishing net weatherability |
| WO2022156215A1 (en) * | 2021-01-20 | 2022-07-28 | 东华大学 | Spinning stock solution, and heat-resistant creep-resistant fiber and preparation method therefor |
-
2013
- 2013-12-11 CN CN201310670770.2A patent/CN103741247A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104775297A (en) * | 2015-03-20 | 2015-07-15 | 巢湖市荷花渔网有限公司 | High-quality and high-efficiency fishing net |
| CN104782593A (en) * | 2015-03-26 | 2015-07-22 | 巢湖市鼎盛渔具有限公司 | Wear-resisting and aging-resisting fishing net |
| CN104805529A (en) * | 2015-03-26 | 2015-07-29 | 巢湖市鼎盛渔具有限公司 | High-temperature-resistant fishing net |
| CN104805528A (en) * | 2015-03-26 | 2015-07-29 | 巢湖市鼎盛渔具有限公司 | Efficient fishing net |
| CN105295169A (en) * | 2015-10-29 | 2016-02-03 | 六安市沪渔网具有限公司 | Sunshine resistant fishing net |
| CN105385076A (en) * | 2015-11-14 | 2016-03-09 | 巢湖市荷花渔网有限公司 | Sunscreen fishing net and preparation method thereof |
| CN107099878A (en) * | 2017-05-13 | 2017-08-29 | 巢湖市翔宇渔具有限公司 | A kind of processing method for improving fishing net weatherability |
| WO2022156215A1 (en) * | 2021-01-20 | 2022-07-28 | 东华大学 | Spinning stock solution, and heat-resistant creep-resistant fiber and preparation method therefor |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140423 |
|
| WD01 | Invention patent application deemed withdrawn after publication |