CN103757731B - A kind of acid and alkali-resistance fishing net - Google Patents
A kind of acid and alkali-resistance fishing net Download PDFInfo
- Publication number
- CN103757731B CN103757731B CN201310669613.XA CN201310669613A CN103757731B CN 103757731 B CN103757731 B CN 103757731B CN 201310669613 A CN201310669613 A CN 201310669613A CN 103757731 B CN103757731 B CN 103757731B
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- Prior art keywords
- alkali
- fishing net
- acid
- raw material
- stirring reaction
- Prior art date
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- Expired - Fee Related
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- 239000002253 acid Substances 0.000 title claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 230000004048 modification Effects 0.000 claims abstract description 10
- 238000012986 modification Methods 0.000 claims abstract description 10
- 239000004014 plasticizer Substances 0.000 claims abstract description 10
- LVNLBBGBASVLLI-UHFFFAOYSA-N 3-triethoxysilylpropylurea Chemical compound CCO[Si](OCC)(OCC)CCCNC(N)=O LVNLBBGBASVLLI-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000092 linear low density polyethylene Polymers 0.000 claims abstract description 7
- 239000004707 linear low-density polyethylene Substances 0.000 claims abstract description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 claims abstract description 4
- NPAIMXWXWPJRES-UHFFFAOYSA-N butyltin(3+) Chemical compound CCCC[Sn+3] NPAIMXWXWPJRES-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 9
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- -1 dioctyl ester Chemical class 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 4
- 238000009987 spinning Methods 0.000 claims description 4
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 3
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims description 3
- 239000001293 FEMA 3089 Substances 0.000 claims description 3
- 235000019483 Peanut oil Nutrition 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001993 dienes Chemical class 0.000 claims description 3
- 229940044949 eucalyptus oil Drugs 0.000 claims description 3
- 239000010642 eucalyptus oil Substances 0.000 claims description 3
- 238000002454 metastable transfer emission spectrometry Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000000312 peanut oil Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000004513 sizing Methods 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 229920000573 polyethylene Polymers 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 206010025482 malaise Diseases 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of acid and alkali-resistance fishing net, it is made up of the raw material of following weight parts: ultra-high molecular weight polyethylene 92-100, linear low density polyethylene 5-7, Mono-n-butyltin 0.2-0.4, pentaerythrite 2-3, ureidopropyltriethoxysilane 1-2, modification plasticizer 3-4, the fishing net that the present invention produces has good toughness, tensile strength and weather resisteant, acid-alkali-corrosive-resisting is strong, to the strong adaptability of water body, can increase the service life.
Description
Technical field
The present invention relates generally to a kind of fishing net, particularly relates to a kind of acid and alkali-resistance fishing net.
Background technology
Modern fishing net mainly adopts polyethylene, the raw materials such as nylon are processed, wherein polythene fishing net, adopt polythene material through fusion plastification, spinning, plying is twisted thread and to be made into, use Yu Haiyang trawlnet, purse seine, wind resistance sea net cage etc., there is longer life cycle, higher catching rate, but the mechanical property of polyethylene itself is general, TENSILE STRENGTH is lower, creep resistance is bad, just cause the intensity of conventional polyethylene fishing net, anti-wear performance, toughness is unwell at the bottom of Complex Sea and wind and waves environment fishing operation, reduce the service life of fishing gear, not only waste resource, also directly affect catch.
Summary of the invention
The object of the invention is just to provide a kind of acid and alkali-resistance fishing net.
The present invention is achieved by the following technical solutions:
A kind of acid and alkali-resistance fishing net, it is made up of the raw material of following weight parts:
Ultra-high molecular weight polyethylene 92-100, linear low density polyethylene 5-7, Mono-n-butyltin 0.2-0.4, pentaerythrite 2-3, ureidopropyltriethoxysilane 1-2, modification plasticizer 3-4;
Described modification plasticizer is made up of the raw material of following weight parts: MTES 1-1.2, dioctyl ester 2-2.3, ATBC 1.2-1.4, peanut oil 2-2.3, turpentine oil 1-1.2, eucalyptus oil 0.3-0.4, poly-different diene 1.2-1.4, morpholine 0.2-0.3, antioxidant MB 1-1.2, methyl ethyl ketone peroxide 0.2-0.3, styrene 1.2-1.4, nano titanium oxide 0.2-0.3;
Be added drop-wise to by above-mentioned methyl ethyl ketone peroxide in other each mixtures of materials, stirring reaction 60-90 minute, is warming up to 120-130 DEG C, stirring reaction 2-3 hour, obtains described modification plasticizer.
A preparation method for acid and alkali-resistance fishing net, comprises the following steps:
The ureidopropyltriethoxysilane getting above-mentioned weight 10-15% mixes with linear low density polyethylene, stirring reaction 10-15 minute at 60-70 DEG C, add pentaerythrite, continue insulated and stirred 5-8 minute, be cooled to normal temperature, add each raw material of residue, melt extruded by extruder, drawing-off, sizing, spinning, obtain described acid and alkali-resistance fishing net.
Advantage of the present invention is:
The fishing net that the present invention produces has good toughness, tensile strength and weather resisteant, and acid-alkali-corrosive-resisting is strong, to the strong adaptability of water body, can increase the service life.
Detailed description of the invention
Embodiment 1
A kind of acid and alkali-resistance fishing net, is characterized in that what it was made up of the raw material of following weight parts (kilogram):
Ultra-high molecular weight polyethylene 100, linear low density polyethylene 7, Mono-n-butyltin 0.4, pentaerythrite 2, ureidopropyltriethoxysilane 2, modification plasticizer 4;
Described modification plasticizer is made up of the raw material of following weight parts: MTES 1.2, dioctyl ester 2.3, ATBC 1.4, peanut oil 2.3, turpentine oil 1.2, eucalyptus oil 0.4, poly-different diene 1.4, morpholine 0.3, antioxidant MB 1.2, methyl ethyl ketone peroxide 0.3, styrene 1.4, nano titanium oxide 0.3;
Be added drop-wise to by above-mentioned methyl ethyl ketone peroxide in other each mixtures of materials, stirring reaction 90 minutes, is warming up to 130 DEG C, and stirring reaction 2 hours obtains described modification plasticizer.
A preparation method for acid and alkali-resistance fishing net, comprises the following steps:
The ureidopropyltriethoxysilane getting above-mentioned weight 15% mixes with linear low density polyethylene, stirring reaction 15 minutes at 70 DEG C, add pentaerythrite, continue insulated and stirred 8 minutes, be cooled to normal temperature, add each raw material of residue, melt extruded by extruder, drawing-off, sizing, spinning, obtain described acid and alkali-resistance fishing net.
Filament properties is tested: elongation at break 16.7%;
Anti-tensile degree (KG) 55.3;
Knotting strength (KG) 38.31.
Claims (2)
1. an acid and alkali-resistance fishing net, is characterized in that what it was made up of the raw material of following weight parts:
Ultra-high molecular weight polyethylene 92-100, linear low density polyethylene 5-7, Mono-n-butyltin 0.2-0.4, pentaerythrite 2-3, ureidopropyltriethoxysilane 1-2, modification plasticizer 3-4;
Described modification plasticizer is made up of the raw material of following weight parts: MTES 1-1.2, dioctyl ester 2-2.3, ATBC 1.2-1.4, peanut oil 2-2.3, turpentine oil 1-1.2, eucalyptus oil 0.3-0.4, poly-different diene 1.2-1.4, morpholine 0.2-0.3, antioxidant MB 1-1.2, methyl ethyl ketone peroxide 0.2-0.3, styrene 1.2-1.4, nano titanium oxide 0.2-0.3;
Be added drop-wise to by above-mentioned methyl ethyl ketone peroxide in other each mixtures of materials, stirring reaction 60-90 minute, is warming up to 120-130 DEG C, stirring reaction 2-3 hour, obtains described modification plasticizer.
2. a preparation method for acid and alkali-resistance fishing net as claimed in claim 1, is characterized in that comprising the following steps:
The ureidopropyltriethoxysilane getting above-mentioned weight 10-15% mixes with linear low density polyethylene, stirring reaction 10-15 minute at 60-70 DEG C, add pentaerythrite, continue insulated and stirred 5-8 minute, be cooled to normal temperature, add each raw material of residue, melt extruded by extruder, drawing-off, sizing, spinning, obtain described acid and alkali-resistance fishing net.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310669613.XA CN103757731B (en) | 2013-12-11 | 2013-12-11 | A kind of acid and alkali-resistance fishing net |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310669613.XA CN103757731B (en) | 2013-12-11 | 2013-12-11 | A kind of acid and alkali-resistance fishing net |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103757731A CN103757731A (en) | 2014-04-30 |
| CN103757731B true CN103757731B (en) | 2016-03-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310669613.XA Expired - Fee Related CN103757731B (en) | 2013-12-11 | 2013-12-11 | A kind of acid and alkali-resistance fishing net |
Country Status (1)
| Country | Link |
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| CN (1) | CN103757731B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2949532A1 (en) * | 2014-05-22 | 2015-11-26 | Invista Technologies S.A R.L. | Polymers with modified surface properties and method of making the same |
| CN104562235A (en) * | 2014-06-30 | 2015-04-29 | 巢湖市鼎盛渔具有限公司 | Forming technology of fishing net threads suitable for fresh water |
| CN104782593A (en) * | 2015-03-26 | 2015-07-22 | 巢湖市鼎盛渔具有限公司 | Wear-resisting and aging-resisting fishing net |
| CN104805529A (en) * | 2015-03-26 | 2015-07-29 | 巢湖市鼎盛渔具有限公司 | High-temperature-resistant fishing net |
| CN105295170A (en) * | 2015-10-29 | 2016-02-03 | 六安市沪渔网具有限公司 | Fishing net |
| CN105386156A (en) * | 2015-11-13 | 2016-03-09 | 巢湖市强力渔业有限责任公司 | High-quality fishing net |
| CN105754187A (en) * | 2016-04-14 | 2016-07-13 | 巢湖市荷花渔网有限公司 | Acid-resistant alkali-resistant fishing net |
| CN107177076A (en) * | 2017-06-15 | 2017-09-19 | 巢湖市强力渔业有限责任公司 | A kind of anticorrosive wear-resistant fishing net |
| CN107034540A (en) * | 2017-06-15 | 2017-08-11 | 巢湖市强力渔业有限责任公司 | The preparation method that a kind of resistance to agricultural chemicals corrodes fishing net |
| CN107524003A (en) * | 2017-08-18 | 2017-12-29 | 巢湖市俊业渔具有限公司 | A kind of method for strengthening fishing net weatherability |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101230501A (en) * | 2008-02-26 | 2008-07-30 | 山东爱地高分子材料有限公司 | Method for preparing high-strength polyethylene fibre by employing blended melting of super high molecular weight polyethylene and low density polyethylene |
| CN102251303A (en) * | 2011-05-03 | 2011-11-23 | 鑫海绳网制造有限公司 | Method for preparing trimeric high-strength and high-toughness energy-saving fishing net |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4695291B2 (en) * | 2001-05-16 | 2011-06-08 | 有限会社よつあみ | Low elongation yarn |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101230501A (en) * | 2008-02-26 | 2008-07-30 | 山东爱地高分子材料有限公司 | Method for preparing high-strength polyethylene fibre by employing blended melting of super high molecular weight polyethylene and low density polyethylene |
| CN102251303A (en) * | 2011-05-03 | 2011-11-23 | 鑫海绳网制造有限公司 | Method for preparing trimeric high-strength and high-toughness energy-saving fishing net |
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| Publication number | Publication date |
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| CN103757731A (en) | 2014-04-30 |
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Granted publication date: 20160302 Termination date: 20211211 |
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