CN1072700C - 防水表面组合物及其制备方法和用途 - Google Patents
防水表面组合物及其制备方法和用途 Download PDFInfo
- Publication number
- CN1072700C CN1072700C CN96107924A CN96107924A CN1072700C CN 1072700 C CN1072700 C CN 1072700C CN 96107924 A CN96107924 A CN 96107924A CN 96107924 A CN96107924 A CN 96107924A CN 1072700 C CN1072700 C CN 1072700C
- Authority
- CN
- China
- Prior art keywords
- composition
- silane
- silica gel
- perfluoroalkylalkyls
- lane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011248 coating agent Substances 0.000 title claims description 8
- 238000000576 coating method Methods 0.000 title claims description 8
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229910000077 silane Inorganic materials 0.000 claims abstract description 51
- 239000000203 mixture Substances 0.000 claims abstract description 42
- -1 siloxanes Chemical class 0.000 claims abstract description 35
- 150000001875 compounds Chemical class 0.000 claims abstract description 18
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 9
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 6
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 claims description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- 239000011159 matrix material Substances 0.000 claims description 20
- 125000000217 alkyl group Chemical group 0.000 claims description 18
- 239000000741 silica gel Substances 0.000 claims description 15
- 229910002027 silica gel Inorganic materials 0.000 claims description 15
- OQOGEOLRYAOSKO-UHFFFAOYSA-N 1,1-dichloro-1-nitroethane Chemical compound CC(Cl)(Cl)[N+]([O-])=O OQOGEOLRYAOSKO-UHFFFAOYSA-N 0.000 claims description 14
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 150000002367 halogens Chemical group 0.000 claims description 8
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 claims description 8
- 239000005052 trichlorosilane Substances 0.000 claims description 8
- 125000004423 acyloxy group Chemical group 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 230000007062 hydrolysis Effects 0.000 claims description 6
- 238000006460 hydrolysis reaction Methods 0.000 claims description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 claims description 3
- 241000779819 Syncarpia glomulifera Species 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical group 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000003208 petroleum Substances 0.000 claims description 3
- 239000001739 pinus spp. Substances 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 229940036248 turpentine Drugs 0.000 claims description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical group CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- NWKBSEBOBPHMKL-UHFFFAOYSA-N dichloro(methyl)silane Chemical compound C[SiH](Cl)Cl NWKBSEBOBPHMKL-UHFFFAOYSA-N 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims description 2
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 claims 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims 2
- 229910052740 iodine Inorganic materials 0.000 claims 2
- 239000011630 iodine Chemical group 0.000 claims 2
- 239000005049 silicon tetrachloride Substances 0.000 claims 2
- 150000005826 halohydrocarbons Chemical class 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 17
- 239000011521 glass Substances 0.000 abstract description 11
- 239000000758 substrate Substances 0.000 abstract description 5
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 229920003023 plastic Polymers 0.000 abstract description 2
- 239000004033 plastic Substances 0.000 abstract description 2
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229920000620 organic polymer Polymers 0.000 abstract 1
- 230000002940 repellent Effects 0.000 abstract 1
- 239000005871 repellent Substances 0.000 abstract 1
- 150000004756 silanes Chemical class 0.000 abstract 1
- 229960001866 silicon dioxide Drugs 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- 239000005329 float glass Substances 0.000 description 6
- 229920001296 polysiloxane Chemical class 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 230000003068 static effect Effects 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- CJYDNDLQIIGSTH-UHFFFAOYSA-N 1-(3,5,7-trinitro-1,3,5,7-tetrazocan-1-yl)ethanone Chemical compound CC(=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 CJYDNDLQIIGSTH-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- CSDVUOAFSGSYNN-UHFFFAOYSA-N C(CCCCCCCCC)[Si](Cl)(Cl)Cl.[F] Chemical class C(CCCCCCCCC)[Si](Cl)(Cl)Cl.[F] CSDVUOAFSGSYNN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- MBIPLTWQROCVBC-UHFFFAOYSA-N FC(C(F)(F)F)([Si](Cl)(Cl)Cl)C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F Chemical compound FC(C(F)(F)F)([Si](Cl)(Cl)Cl)C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F MBIPLTWQROCVBC-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- SOGIFFQYRAXTDR-UHFFFAOYSA-N diethoxy(methyl)silane Chemical compound CCO[SiH](C)OCC SOGIFFQYRAXTDR-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- RVZRBWKZFJCCIB-UHFFFAOYSA-N perfluorotributylamine Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)N(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F RVZRBWKZFJCCIB-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- QHAHOIWVGZZELU-UHFFFAOYSA-N trichloro(trichlorosilyloxy)silane Chemical compound Cl[Si](Cl)(Cl)O[Si](Cl)(Cl)Cl QHAHOIWVGZZELU-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Surface Treatment Of Glass (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US46146495A | 1995-06-05 | 1995-06-05 | |
| US461,464 | 1995-06-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1141941A CN1141941A (zh) | 1997-02-05 |
| CN1072700C true CN1072700C (zh) | 2001-10-10 |
Family
ID=23832663
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96107924A Expired - Lifetime CN1072700C (zh) | 1995-06-05 | 1996-06-03 | 防水表面组合物及其制备方法和用途 |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPH08333545A (fr) |
| KR (1) | KR100194250B1 (fr) |
| CN (1) | CN1072700C (fr) |
| CA (1) | CA2175848C (fr) |
| TW (1) | TW415923B (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100471906C (zh) * | 2002-06-03 | 2009-03-25 | 3M创新有限公司 | 氟-硅烷-低聚物组合物 |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19731416C1 (de) * | 1997-07-22 | 1998-09-17 | Vetrotech Saint Gobain Int Ag | Brandschutzverglasung |
| GB0206930D0 (en) | 2002-03-23 | 2002-05-08 | Univ Durham | Method and apparatus for the formation of hydrophobic surfaces |
| JP2012097267A (ja) * | 2003-09-17 | 2012-05-24 | Kazufumi Ogawa | 撥水撥油性複合膜形成溶液とそれを用いた撥水撥油性複合膜の製造方法とその方法を用いて製造した撥水撥油性複合膜 |
| JP5343271B2 (ja) * | 2003-09-17 | 2013-11-13 | 小川 一文 | 撥水撥油防汚性ガラス板とその製造方法及びそれを用いた自動車と電磁調理器 |
| CN100396751C (zh) * | 2005-06-21 | 2008-06-25 | 广州市白云化工实业有限公司 | 一种有机硅氟防水剂及其制备方法 |
| US8286561B2 (en) | 2008-06-27 | 2012-10-16 | Ssw Holding Company, Inc. | Spill containing refrigerator shelf assembly |
| US11786036B2 (en) | 2008-06-27 | 2023-10-17 | Ssw Advanced Technologies, Llc | Spill containing refrigerator shelf assembly |
| AU2009302329B2 (en) | 2008-10-07 | 2015-10-29 | Ssw Advanced Technologies, Llc | Spill resistant surfaces having hydrophobic and oleophobic borders |
| ES2613885T3 (es) | 2009-11-04 | 2017-05-26 | Ssw Holding Company, Inc. | Superficies de aparatos de cocción que tienen un patrón de confinamiento de salpicaduras y procedimientos de fabricación de las mismas |
| JP5858441B2 (ja) | 2010-03-15 | 2016-02-10 | ロス テクノロジー コーポレーション．Ｒｏｓｓ Ｔｅｃｈｎｏｌｏｇｙ Ｃｏｒｐｏｒａｔｉｏｎ | プランジャーおよび疎水性表面を得るための方法 |
| JP2014512417A (ja) | 2011-02-21 | 2014-05-22 | ロス テクノロジー コーポレーション． | 低ｖｏｃ結合剤系を含む超疎水性および疎油性被覆物 |
| EP2791255B1 (fr) | 2011-12-15 | 2017-11-01 | Ross Technology Corporation | Composition et revêtement pour une performance superhydrophobe |
| EP2864430A4 (fr) | 2012-06-25 | 2016-04-13 | Ross Technology Corp | Revêtements élastomères ayant des propriétés hydrophobes et/ou oléophobes |
| CN104829641B (zh) * | 2015-05-12 | 2018-01-19 | 傅筠 | 一种含氟有机硅单体及其制备方法 |
| KR101912605B1 (ko) * | 2017-03-10 | 2018-10-30 | 경기대학교 산학협력단 | 초발수 입자 및 이를 포함하는 조성물 |
| CN108395115B (zh) * | 2018-02-01 | 2022-05-13 | 阿尔特汽车技术股份有限公司 | 汽车后视镜 |
| CN110981225A (zh) * | 2019-12-20 | 2020-04-10 | 苏州浩纳新材料科技有限公司 | 一种玻璃疏水防雨涂料及制备方法和应用方法 |
| CN111501354B (zh) * | 2020-05-23 | 2022-11-04 | 苏州大学 | 一种防油防污自清洁功能性织物及其制备方法 |
| CN111849225B (zh) * | 2020-08-03 | 2021-11-05 | 中铝瑞闽股份有限公司 | 一种铝合金板带用石墨烯/烷烃复合涂层及其制备方法 |
| CN113930155B (zh) * | 2021-11-18 | 2022-05-31 | 福耀玻璃工业集团股份有限公司 | 一种憎水涂液、玻璃及其制备方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6051103A (ja) * | 1983-08-30 | 1985-03-22 | Shin Etsu Chem Co Ltd | 防汚処理剤 |
| JPH0759699B2 (ja) * | 1987-10-05 | 1995-06-28 | ダイキン工業株式会社 | 撥水撥油剤組成物 |
| US5523161A (en) * | 1990-04-03 | 1996-06-04 | Ppg Industries, Inc. | Water repellent surface treatment with integrated primer |
| US5308705A (en) * | 1990-04-03 | 1994-05-03 | Ppg Industries, Inc. | Water repellent surface treatment |
| JPH04144940A (ja) * | 1990-10-05 | 1992-05-19 | Asahi Glass Co Ltd | 撥水撥油剤組成物 |
| JP2500149B2 (ja) * | 1991-01-23 | 1996-05-29 | 松下電器産業株式会社 | 撥水撥油性被膜及びその製造方法 |
| JP2555797B2 (ja) * | 1991-05-13 | 1996-11-20 | トヨタ自動車株式会社 | 撥水ガラス及びその製造方法 |
| JP3155025B2 (ja) * | 1991-05-17 | 2001-04-09 | 旭硝子株式会社 | 表面処理された建築・建装用物品および該物品の製造方法 |
| JP2874391B2 (ja) * | 1991-06-05 | 1999-03-24 | 日産自動車株式会社 | 撥水処理ガラスの製造方法 |
| JPH05170486A (ja) * | 1991-12-25 | 1993-07-09 | Central Glass Co Ltd | ガラス表面用撥水処理剤およびその撥水処理ガラス |
| JPH06293782A (ja) * | 1993-04-07 | 1994-10-21 | Mitsubishi Kasei Corp | コーティング組成物 |
| CA2175849C (fr) * | 1995-06-01 | 2003-07-15 | George B. Goodwin | Traitement d'hydrofugation assurant la non-mouillabilite d'une surface |
-
1996
- 1996-05-06 CA CA002175848A patent/CA2175848C/fr not_active Expired - Fee Related
- 1996-05-20 TW TW085105930A patent/TW415923B/zh not_active IP Right Cessation
- 1996-06-03 CN CN96107924A patent/CN1072700C/zh not_active Expired - Lifetime
- 1996-06-04 KR KR1019960019762A patent/KR100194250B1/ko not_active Expired - Fee Related
- 1996-06-04 JP JP8141488A patent/JPH08333545A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100471906C (zh) * | 2002-06-03 | 2009-03-25 | 3M创新有限公司 | 氟-硅烷-低聚物组合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1141941A (zh) | 1997-02-05 |
| CA2175848A1 (fr) | 1996-12-06 |
| KR970001503A (ko) | 1997-01-24 |
| CA2175848C (fr) | 2000-01-11 |
| TW415923B (en) | 2000-12-21 |
| JPH08333545A (ja) | 1996-12-17 |
| KR100194250B1 (ko) | 1999-06-15 |
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