CN108660586A - Wash resistant is without melting the fire-retardant curtain of drop and its processing method - Google Patents

Wash resistant is without melting the fire-retardant curtain of drop and its processing method Download PDF

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Publication number
CN108660586A
CN108660586A CN201810515088.9A CN201810515088A CN108660586A CN 108660586 A CN108660586 A CN 108660586A CN 201810515088 A CN201810515088 A CN 201810515088A CN 108660586 A CN108660586 A CN 108660586A
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flame
retardant
weight
parts
washing
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李利君
葛欣国
王新钢
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Sichuan Fire Research Institute of Ministry of Public Security
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Sichuan Fire Research Institute of Ministry of Public Security
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    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/06Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
    • D01F2/08Composition of the spinning solution or the bath
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/90Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
    • D01F6/905Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides of aromatic polyamides
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/443Heat-resistant, fireproof or flame-retardant yarns or threads
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01Natural vegetable fibres
    • D10B2201/02Cotton
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20Cellulose-derived artificial fibres
    • D10B2201/22Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24Viscose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Woven Fabrics (AREA)

Abstract

A kind of wash resistant is without the fire-retardant curtain of drop, including 10 20 parts by weight of 20 30 parts by weight of cotton fiber, 10 20 parts by weight of aramid fiber and flame retardant viscose fiber is melted, added with 0.2 0.3 parts by weight of fire retardant in the flame retardant viscose fiber spinning solution and cotton fiber.Without the fiber of drop is melted when raw material cotton used in this application, aramid fiber, viscose glue are all burnings, so the curtain being made from it is also without dissolved drip.In addition, aramid fiber has soft feel with anti-flaming viscose blend fabric, good bulkiness, drapability, sucting wet air permeability and higher strength, wearability, good cloth cover finish, color fastness and chance live charcoalization do not melt the good characteristics such as drop, can meet the quality requirement of curtain decorative fabric.

Description

耐洗涤无融滴阻燃幕布及其加工方法Washing-resistant non-melting drop flame-retardant curtain and its processing method

技术领域technical field

本发明涉及防火技术领域,具体涉及耐洗涤无融滴阻燃幕布及其加工方法。The invention relates to the technical field of fire protection, in particular to a washing-resistant and non-melting dripping flame-retardant curtain and a processing method thereof.

背景技术Background technique

随着我国经济和社会的迅速发展,人们对文化消费的需求不断提高,近年 来国内影剧院、歌舞娱乐场所的数量和规模迅速攀升。在影剧院及歌舞娱乐场 所中存在大量的可燃物质,如软质座椅、沙发、软包装饰材料、地毯、幕布等。With the rapid development of my country's economy and society, people's demand for cultural consumption continues to increase. In recent years, the number and scale of domestic theaters, singing and dancing entertainment venues have risen rapidly. There are a large number of combustible substances in theaters and places of singing and dancing entertainment, such as soft seats, sofas, soft package decoration materials, carpets, curtains, etc.

《建筑内部装修设计防火规范》(GB 50222)要求影剧院中使用的舞台幕布 的燃烧性能应达B1级。从材质来看,市售阻燃舞台幕布产品中涤纶、棉及涤棉 混纺织物所占比重较大,不同材质的产品燃烧性能区别较大。The "Code for Fire Protection Design of Building Interior Decoration" (GB 50222) requires that the combustion performance of stage curtains used in theaters should reach Class B1. From the perspective of materials, polyester, cotton and polyester-cotton blended fabrics account for a relatively large proportion of commercially available flame-retardant stage curtain products, and the combustion performance of products of different materials is quite different.

本申请主要针对国内外耐洗阻燃幕布研究及发展趋势,采用多种阻燃纤维 混纺的方式,研发耐洗涤、燃烧时无融滴的阻燃幕布,填补国内空白。This application is mainly aimed at the research and development trend of washable flame-retardant curtains at home and abroad, and uses a variety of flame-retardant fiber blending methods to develop a flame-retardant curtain that is washable and has no melting droplets when burning, filling the domestic gap.

发明内容Contents of the invention

本发明的目的在于提供一种耐洗涤无融滴阻燃幕布及其加工方法,解决现 有影剧院、歌舞娱乐场所幕布易燃、阻燃性差,对人的生命健康有极大地威胁 的问题。The purpose of the present invention is to provide a washing-resistant non-melting drop flame-retardant curtain and its processing method, which solves the problem that the existing theaters, singing and dancing entertainment venues are flammable and poor in flame retardancy, and have a great threat to human life and health.

为解决上述的技术问题,本发明采用以下技术方案:In order to solve the above-mentioned technical problems, the present invention adopts the following technical solutions:

一种耐洗涤无融滴阻燃幕布,包括棉纤维20-30重量份、芳纶纤维10-20重 量份和阻燃粘胶纤维10-20重量份,所述阻燃粘胶纤维纺丝液和棉纤维中均加有 阻燃剂0.2-0.3重量份。A washing-resistant flame-retardant curtain without melting drops, comprising 20-30 parts by weight of cotton fibers, 10-20 parts by weight of aramid fibers and 10-20 parts by weight of flame-retardant viscose fibers, the flame-retardant viscose fiber spinning solution 0.2-0.3 parts by weight of flame retardant are added to cotton fibers.

作为优选的,所述阻燃剂包括Sandflam 5060、氢氧化镁、氢氧化铝、氢氧 化锌、磷酸二氢铵、磷酸氢二胺和磷酸三胺中的一种或几种的混合物。Preferably, the flame retardant includes one or more of Sandflam 5060, magnesium hydroxide, aluminum hydroxide, zinc hydroxide, ammonium dihydrogen phosphate, diamine hydrogen phosphate and triamine phosphate.

作为优选的,所述芳纶纤维纺丝液中还包括加强剂0.1-0.2重量份,所述阻 燃粘胶纤维纺丝液中还包括加强剂0.2-0.25重量份。Preferably, the aramid fiber spinning solution further includes 0.1-0.2 parts by weight of a reinforcing agent, and the flame-retardant viscose spinning solution further includes 0.2-0.25 parts by weight of a reinforcing agent.

作为优选的,所述加强剂包括碳酸二甲酯0.5-1重量份和聚乙烯醇0.3-0.7 重量份。加强剂可以在很大程度上提高限位的耐磨和韧性,提高耐洗性能。Preferably, the strengthening agent includes 0.5-1 weight part of dimethyl carbonate and 0.3-0.7 weight part of polyvinyl alcohol. The strengthening agent can greatly improve the wear resistance and toughness of the limit, and improve the washing resistance.

一种耐洗涤无融滴阻燃幕布的加工方法,包括依次进行的混棉、梳棉、并 条、粗纱、细纱、定型、捻线、络筒、定型、整经及卷纬、织造,其中,所述 混棉是分别将棉与芳纶纤维混纺、棉与阻燃粘胶纤维混纺。A method for processing a washing-resistant flame-retardant curtain without melting and dripping, comprising sequentially performing cotton blending, carding, drawing, roving, spun yarn, shaping, twisting, winding, shaping, warping, weft winding, and weaving, wherein , the cotton blending is respectively blending cotton and aramid fiber, cotton and flame-retardant viscose fiber.

作为优选的,所述梳棉步骤的相对湿度为50-70%,并条步骤的相对湿度为 55-60%,粗纱步骤的相对湿度为50-55%,细纱步骤的相对湿度为45-50%。纺纱 时保持较高的相对湿度,可以避免静电积聚。As preferably, the relative humidity of the carding step is 50-70%, the relative humidity of the drawing step is 55-60%, the relative humidity of the roving step is 50-55%, and the relative humidity of the spun step is 45-50%. %. Maintaining a high relative humidity during spinning avoids static build-up.

作为优选的,所述芳纶纤维长度为50-60mm、细度为1.6-1.7dtex;阻燃粘 胶纤维长度为35-40mm、细度为1.6-1.7dtex。As preferably, the length of the aramid fiber is 50-60mm and the fineness is 1.6-1.7dtex; the length of the flame-retardant viscose fiber is 35-40mm and the fineness is 1.6-1.7dtex.

作为优选的,所述粗纱捻度为2-3捻/10cm,不宜太高。为此采用较小定量 和较小粗纱捻系数以降低细纱牵伸不匀。细纱捻系数适当加大,一般取设计公 制捻系数为383左右较合适。细纱采用大的后区牵伸隔距及小的后区牵伸倍数, 牵伸胶辊采用立达软胶辊以改善成纱条干,确保细纱质量。Preferably, the roving twist is 2-3 twists/10cm, which should not be too high. For this reason, a smaller basis weight and a smaller roving twist coefficient are used to reduce uneven drafting of the spun yarn. The twist coefficient of the spun yarn should be appropriately increased, and it is generally more appropriate to take the twist coefficient of the design metric system as about 383. The spun yarn adopts a large rear draft gauge and a small rear draft multiple, and the draft cot adopts Rieter soft cot to improve the evenness of the finished yarn and ensure the quality of the spun yarn.

作为优选的,所述定型步骤中,温度为80-90℃,定型时间为35-45min, 以避免芳纶纤维发生扭曲。Preferably, in the setting step, the temperature is 80-90° C., and the setting time is 35-45 minutes, so as to avoid twisting of the aramid fiber.

与现有技术相比,本发明的有益效果至少是如下之一:Compared with the prior art, the beneficial effects of the present invention are at least one of the following:

本申请中使用的原料:棉、芳纶、粘胶都是燃烧时无融滴的纤维,所以由 其制成的幕布也没有溶滴。Raw materials used in this application: cotton, aramid fiber, and viscose are all fibers without melting drops when burning, so the curtains made of them do not have melting drops.

芳纶与阻燃粘胶混纺织物具有柔软的手感,良好的蓬松性、悬垂性、吸湿 透气性和较高的强力、耐磨性,良好的布面光洁度、色牢度以及遇火炭化不融 滴等优良特性,可满足幕布装饰面料的质量要求。Aramid and flame-retardant viscose blended fabric has soft hand feeling, good bulkiness, drapability, moisture absorption and air permeability, high strength and wear resistance, good cloth surface finish, color fastness and inability to melt when exposed to fire. Excellent properties such as dripping can meet the quality requirements of curtain decorative fabrics.

开清棉工序成卷时加压罗拉需要较高压力,以防止棉卷撕裂,圈条器及喇 叭口等导条装置要保持光滑流畅,以减少摩擦。梳棉工序采用低速度、中分梳、 小牵伸、快转移工艺,以减轻对纤维的损伤和由于易起静电造成的缠绕现象, 减少棉结、杂质与短绒。During the opening and cleaning process, the pressurizing roller needs a higher pressure to prevent the cotton lap from tearing, and the coiler and bell mouth and other strip guide devices should be kept smooth and smooth to reduce friction. The carding process adopts low speed, medium carding, small draft, and fast transfer technology to reduce damage to fibers and entanglement caused by easy static electricity, and reduce neps, impurities and short fibers.

具体实施方式Detailed ways

为了使本发明的目的、技术方案及优点更加清楚明白,以下结合实施例, 对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以 解释本发明,并不用于限定本发明。In order to make the object, technical solution and advantages of the present invention clearer, the present invention will be further described in detail below in conjunction with the examples. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention.

实施例1:Example 1:

本实施例提供了一种耐洗涤无融滴阻燃幕布的加工方法和该方法得到的耐 洗涤无融滴阻燃幕布,耐洗涤无融滴阻燃幕布的加工方法包括:依次进行的混 棉、梳棉、并条、粗纱、细纱、定型、捻线、络筒、定型、整经及卷纬、织造, 其中:This embodiment provides a washing-resistant non-melting drop flame-retardant curtain processing method and the washing-resistant non-melting dripping flame-retardant curtain obtained by this method. , carding, drawing, roving, spun yarn, setting, twisting, winding, setting, warping and weft winding, weaving, of which:

所述混棉是分别将棉10重量份与芳纶纤维10重量份混纺作为经向、棉5 重量份与阻燃粘胶纤维10重量份混纺,所述芳纶纤维长度为50mm、细度为 1.6dtex;阻燃粘胶纤维长度为35mm、细度为1.6dtex;其中所述阻燃粘胶纤维 纺丝液和棉纤维中均加有阻燃剂0.2重量份和加强剂0.2重量份,所述芳纶限位 纺丝液中包括加强剂0.1重量份;所述阻燃剂为氢氧化镁、氢氧化铝的混合物; 所述加强剂包括碳酸二甲酯0.5重量份和聚乙烯醇0.3重量份;The cotton blending is to blend 10 parts by weight of cotton and 10 parts by weight of aramid fiber as the warp direction, 5 parts by weight of cotton and 10 parts by weight of flame-retardant viscose fiber, the length of the aramid fiber is 50mm, and the fineness is 1.6dtex; the flame-retardant viscose fiber length is 35mm, and the fineness is 1.6dtex; wherein the flame-retardant viscose fiber spinning solution and the cotton fiber are all added with 0.2 parts by weight of flame retardant and 0.2 parts by weight of reinforcing agent, so Include 0.1 weight part of strengthening agent in the above-mentioned aramid limit spinning solution; Described flame retardant is the mixture of magnesium hydroxide, aluminum hydroxide; Said strengthening agent comprises 0.5 weight part of dimethyl carbonate and 0.3 weight part of polyvinyl alcohol share;

所述梳棉步骤的相对湿度为50%,并条步骤的相对湿度为55%,粗纱步骤的 相对湿度为50%,纱捻度为2捻/10cm;细纱步骤的相对湿度为45%;The relative humidity of the carding step is 50%, the relative humidity of the drawing step is 55%, the relative humidity of the roving step is 50%, and the yarn twist is 2 twists/10cm; the relative humidity of the spun step is 45%;

所述定型步骤中,温度为80℃,定型时间为45min。In the setting step, the temperature is 80° C., and the setting time is 45 minutes.

其中未详细叙述的步骤可以按照常规方式进行即可,这里不在阐述。The steps not described in detail can be carried out in a conventional manner, and will not be described here.

实施例2:Example 2:

本实施例提供了一种耐洗涤无融滴阻燃幕布的加工方法和该方法得到的耐 洗涤无融滴阻燃幕布,耐洗涤无融滴阻燃幕布的加工方法包括:依次进行的混 棉、梳棉、并条、粗纱、细纱、定型、捻线、络筒、定型、整经及卷纬、织造, 其中:This embodiment provides a washing-resistant non-melting drop flame-retardant curtain processing method and the washing-resistant non-melting dripping flame-retardant curtain obtained by this method. , carding, drawing, roving, spun yarn, setting, twisting, winding, setting, warping and weft winding, weaving, of which:

所述混棉是分别将棉15重量份与芳纶纤维20重量份混纺、棉20重量份与 阻燃粘胶纤维20重量份混纺,所述芳纶纤维长度为60mm、细度为1.7dtex; 阻燃粘胶纤维长度为40mm、细度为1.7dtex;其中所述阻燃粘胶纤维纺丝液和 棉纤维中均加有阻燃剂0.3重量份和加强剂0.25重量份,所述芳纶限位纺丝液 中包括加强剂0.2重量份;所述阻燃剂包括氢氧化锌;所述加强剂包括碳酸二 甲酯1重量份和聚乙烯醇0.7重量份;The blended cotton is blended with 15 parts by weight of cotton and 20 parts by weight of aramid fiber, 20 parts by weight of cotton and 20 parts by weight of flame-retardant viscose fiber, the length of the aramid fiber is 60mm, and the fineness is 1.7dtex; The flame-retardant viscose fiber has a length of 40mm and a fineness of 1.7dtex; wherein the flame-retardant viscose fiber spinning solution and the cotton fiber are all added with 0.3 parts by weight of a flame retardant and 0.25 parts by weight of a reinforcing agent, and the aramid fiber 0.2 parts by weight of a strengthening agent is included in the limit spinning solution; the flame retardant includes zinc hydroxide; the strengthening agent includes 1 part by weight of dimethyl carbonate and 0.7 parts by weight of polyvinyl alcohol;

所述梳棉步骤的相对湿度为70%,并条步骤的相对湿度为60%,粗纱步骤的 相对湿度为55%,纱捻度为3捻/10cm;细纱步骤的相对湿度为50%;The relative humidity of the carding step is 70%, the relative humidity of the drawing step is 60%, the relative humidity of the roving step is 55%, and the yarn twist is 3 twists/10cm; the relative humidity of the spun step is 50%;

所述定型步骤中,温度为90℃,定型时间为45min。In the setting step, the temperature is 90° C., and the setting time is 45 minutes.

其中未详细叙述的步骤可以按照常规方式进行即可,这里不在阐述。The steps not described in detail can be carried out in a conventional manner, and will not be described here.

实施例3:Example 3:

本实施例提供了一种耐洗涤无融滴阻燃幕布的加工方法和该方法得到的耐 洗涤无融滴阻燃幕布,耐洗涤无融滴阻燃幕布的加工方法包括:依次进行的混 棉、梳棉、并条、粗纱、细纱、定型、捻线、络筒、定型、整经及卷纬、织造, 其中:This embodiment provides a washing-resistant non-melting drop flame-retardant curtain processing method and the washing-resistant non-melting dripping flame-retardant curtain obtained by this method. , carding, drawing, roving, spun yarn, setting, twisting, winding, setting, warping and weft winding, weaving, of which:

所述混棉是分别将棉13重量份与芳纶纤维15重量份混纺、棉10重量份与 阻燃粘胶纤维15重量份混纺,所述芳纶纤维长度为55mm、细度为1.65dtex; 阻燃粘胶纤维长度为37mm、细度为1.5dtex;其中所述阻燃粘胶纤维纺丝液和 棉纤维中均加有阻燃剂0.25重量份和加强剂0.23重量份,所述芳纶限位纺丝液 中包括加强剂0.15重量份;所述阻燃剂为磷酸二氢铵、磷酸氢二胺和磷酸三胺 的混合物;所述加强剂包括碳酸二甲酯0.8重量份和聚乙烯醇0.5重量份;The cotton blending is respectively blending 13 parts by weight of cotton with 15 parts by weight of aramid fiber, 10 parts by weight of cotton and 15 parts by weight of flame-retardant viscose fiber, the length of the aramid fiber is 55 mm, and the fineness is 1.65 dtex; The flame-retardant viscose fiber has a length of 37 mm and a fineness of 1.5 dtex; 0.25 parts by weight of a flame retardant and 0.23 parts by weight of a reinforcing agent are added to the spinning solution of the flame-retardant viscose fiber and the cotton fiber, and the aramid fiber 0.15 parts by weight of reinforcing agent are included in the limiting spinning solution; the flame retardant is a mixture of ammonium dihydrogen phosphate, diamine hydrogen phosphate and triamine phosphate; the reinforcing agent includes 0.8 parts by weight of dimethyl carbonate and polyethylene 0.5 parts by weight of alcohol;

所述梳棉步骤的相对湿度为60%,并条步骤的相对湿度为57%,粗纱步骤的 相对湿度为53%,纱捻度为2.5捻/10cm;细纱步骤的相对湿度为47%;The relative humidity of the carding step is 60%, the relative humidity of the drawing step is 57%, the relative humidity of the roving step is 53%, and the yarn twist is 2.5 twists/10cm; the relative humidity of the spun step is 47%;

所述定型步骤中,温度为85℃,定型时间为38min。In the setting step, the temperature is 85° C., and the setting time is 38 minutes.

其中未详细叙述的步骤可以按照常规方式进行即可,这里不在阐述。The steps not described in detail can be carried out in a conventional manner, and will not be described here.

实施例4:Example 4:

本实施例提供了一种耐洗涤无融滴阻燃幕布的加工方法和该方法得到的耐 洗涤无融滴阻燃幕布,耐洗涤无融滴阻燃幕布的加工方法包括:依次进行的混 棉、梳棉、并条、粗纱、细纱、定型、捻线、络筒、定型、整经及卷纬、织造, 其中:This embodiment provides a washing-resistant non-melting drop flame-retardant curtain processing method and the washing-resistant non-melting dripping flame-retardant curtain obtained by this method. , carding, drawing, roving, spun yarn, setting, twisting, winding, setting, warping and weft winding, weaving, of which:

所述混棉是分别将棉14重量份与芳纶纤维17重量份混纺、棉15重量份与 阻燃粘胶纤维18重量份混纺,所述芳纶纤维长度为58mm、细度为1.67dtex; 阻燃粘胶纤维长度为39mm、细度为1.68dtex;其中所述阻燃粘胶纤维纺丝液 和棉纤维中均加有阻燃剂0.27重量份和加强剂0.24重量份,所述芳纶限位纺丝 液中包括加强剂0.13重量份;所述阻燃剂包括Sandflam 5060和磷酸三胺的混 合物;所述加强剂包括碳酸二甲酯0.6重量份和聚乙烯醇0.6重量份;The cotton blending is respectively blending 14 parts by weight of cotton with 17 parts by weight of aramid fiber, 15 parts by weight of cotton and 18 parts by weight of flame-retardant viscose fiber, the length of the aramid fiber is 58mm, and the fineness is 1.67dtex; The flame-retardant viscose fiber has a length of 39 mm and a fineness of 1.68 dtex; wherein the flame-retardant viscose fiber spinning solution and the cotton fiber are all added with 0.27 parts by weight of a flame retardant and 0.24 parts by weight of a reinforcing agent, and the aramid fiber 0.13 parts by weight of strengthening agent are included in the limiting spinning solution; the flame retardant includes a mixture of Sandflam 5060 and triamine phosphate; the strengthening agent includes 0.6 parts by weight of dimethyl carbonate and 0.6 parts by weight of polyvinyl alcohol;

所述梳棉步骤的相对湿度为65%,并条步骤的相对湿度为58%,粗纱步骤的 相对湿度为53%,纱捻度为2.3捻/10cm;细纱步骤的相对湿度为48%;The relative humidity of the carding step is 65%, the relative humidity of the drawing step is 58%, the relative humidity of the roving step is 53%, and the yarn twist is 2.3 twists/10cm; the relative humidity of the spun step is 48%;

所述定型步骤中,温度为88℃,定型时间为42min。In the setting step, the temperature is 88° C., and the setting time is 42 minutes.

其中未详细叙述的步骤可以按照常规方式进行即可,这里不在阐述。The steps not described in detail can be carried out in a conventional manner, and will not be described here.

实施例5:Example 5:

本实施例提供了一种耐洗涤无融滴阻燃幕布的加工方法和该方法得到的耐 洗涤无融滴阻燃幕布,耐洗涤无融滴阻燃幕布的加工方法包括:依次进行的混 棉、梳棉、并条、粗纱、细纱、定型、捻线、络筒、定型、整经及卷纬、织造, 其中:This embodiment provides a washing-resistant non-melting drop flame-retardant curtain processing method and the washing-resistant non-melting dripping flame-retardant curtain obtained by this method. , carding, drawing, roving, spun yarn, setting, twisting, winding, setting, warping and weft winding, weaving, of which:

所述混棉是分别将棉13重量份与芳纶纤维15重量份混纺、棉10重量份与 阻燃粘胶纤维15重量份混纺,所述芳纶纤维长度为55mm、细度为1.65dtex; 阻燃粘胶纤维长度为37mm、细度为1.5dtex;其中所述阻燃粘胶纤维纺丝液和 棉纤维中均加有阻燃剂0.25重量份和加强剂0.23重量份,所述芳纶限位纺丝液 中包括加强剂0.15重量份;所述阻燃剂为Sandflam 5060;所述加强剂包括碳 酸二甲酯0.8重量份和聚乙烯醇0.5重量份;The blended cotton is blended with 13 parts by weight of cotton and 15 parts by weight of aramid fiber, 10 parts by weight of cotton and 15 parts by weight of flame-retardant viscose fiber, the length of the aramid fiber is 55 mm, and the fineness is 1.65 dtex; The flame-retardant viscose fiber has a length of 37 mm and a fineness of 1.5 dtex; wherein the flame-retardant viscose fiber spinning solution and the cotton fiber are all added with 0.25 parts by weight of a flame retardant and 0.23 parts by weight of a reinforcing agent, and the aramid fiber 0.15 parts by weight of strengthening agent are included in the limiting spinning solution; the flame retardant is Sandflam 5060; the strengthening agent includes 0.8 parts by weight of dimethyl carbonate and 0.5 parts by weight of polyvinyl alcohol;

所述梳棉步骤的相对湿度为60%,并条步骤的相对湿度为57%,粗纱步骤的 相对湿度为53%,纱捻度为2.5捻/10cm;细纱步骤的相对湿度为47%;The relative humidity of the carding step is 60%, the relative humidity of the drawing step is 57%, the relative humidity of the roving step is 53%, and the yarn twist is 2.5 twists/10cm; the relative humidity of the spun step is 47%;

所述定型步骤中,温度为85℃,定型时间为38min。In the setting step, the temperature is 85° C., and the setting time is 38 minutes.

其中未详细叙述的步骤可以按照常规方式进行即可,这里不在阐述。The steps not described in detail can be carried out in a conventional manner, and will not be described here.

对实施例1-5所得到的五种幕布的燃烧性能和耐洗性能进行测试,结果如下 表:The combustion performance and washability of five kinds of curtains obtained by embodiment 1-5 are tested, and the results are as follows:

上表中幕布的阻燃性主要归因于它们的结构特点,聚合物分子链主要由含 有杂环的芳族链区构成,2种纤维混合后,使其结构由于共振而稳定,熔融温度 提高,强度和刚度有所改善。The flame retardancy of the curtains in the above table is mainly due to their structural characteristics. The polymer molecular chain is mainly composed of aromatic chain regions containing heterocyclic rings. After the two kinds of fibers are mixed, the structure is stabilized due to resonance and the melting temperature is increased. , with improved strength and stiffness.

由于粘胶纺丝液中加入Sandflam 5060阻燃剂的作用,在高温下分解产生脱 水剂,使纤维脱水炭化,减少可燃性气体的产生,其阻燃性能更好一些。Due to the effect of adding Sandflam 5060 flame retardant to the viscose spinning solution, it decomposes at high temperature to produce a dehydrating agent, dehydrates and carbonizes the fibers, reduces the generation of flammable gases, and has better flame retardancy.

织物中2种纤维混合,使热裂解吸热量增加,从而降低温度,阻止燃烧蔓 延。The two kinds of fibers in the fabric are mixed to increase the heat absorption of pyrolysis, thereby reducing the temperature and preventing the spread of combustion.

织物中纤维燃烧时会释放不燃性气体或高密度蒸汽,前者稍微增加稀释了 氧和气态可燃性产物,并降低温度,致使燃烧终止,后者可以覆盖在可燃气体 上,使燃烧窒息。When the fibers in the fabric are burned, non-combustible gas or high-density steam will be released. The former slightly increases the dilution of oxygen and gaseous combustible products, and lowers the temperature, resulting in the termination of combustion. The latter can cover the combustible gas and suffocate the combustion.

由于本申请使用的原料棉、芳纶、粘胶都是燃烧时无融滴的纤维,所以由 其制成的幕布也没有溶滴。Because the raw material cotton, aramid fibers and viscose used in the present application are all fibers without melting drops when burning, so the curtain made of it does not have melting drops.

尽管这里参照本发明的多个解释性实施例对本发明进行了描述,但是,应 该理解,本领域技术人员可以设计出很多其他的修改和实施方式,这些修改和 实施方式将落在本申请公开的原则范围和精神之内。更具体地说,在本申请公 开和权利要求的范围内,可以对主题组合布局的组成部件和/或布局进行多种变 型和改进。除了对组成部件和/或布局进行的变形和改进外,对于本领域技术人 员来说,其他的用途也将是明显的。Although the invention has been described herein with reference to a number of illustrative embodiments thereof, it is to be understood that numerous other modifications and implementations can be devised by those skilled in the art which will fall within the scope of the disclosure disclosed in this application. within the scope and spirit of the principles. More specifically, within the scope of the disclosure and claims of the present application, various modifications and improvements can be made to the components and/or layout of the subject combination layout. In addition to modifications and modifications to the component parts and/or layout, other uses will also be apparent to those skilled in the art.

Claims (9)

1.一种耐洗涤无融滴阻燃幕布,其特征在于:包括棉纤维20-30重量份、芳纶纤维10-20重量份和阻燃粘胶纤维10-20重量份,所述阻燃粘胶纤维纺丝液和棉纤维中均加有阻燃剂0.2-0.3重量份。1. A washing-resistant flame-retardant curtain without melting drops, characterized in that: it comprises 20-30 parts by weight of cotton fiber, 10-20 parts by weight of aramid fiber and 10-20 parts by weight of flame-retardant viscose fiber, and the flame-retardant 0.2-0.3 parts by weight of the flame retardant are added to the viscose fiber spinning liquid and the cotton fibers. 2.根据权利要求1所述的耐洗涤无融滴阻燃幕布,其特征在于,所述阻燃剂包括Sandflam 5060、氢氧化镁、氢氧化铝、氢氧化锌、磷酸二氢铵、磷酸氢二胺和磷酸三胺中的一种或几种的混合物。2. The washing-resistant and drip-free flame-retardant curtain according to claim 1, wherein the flame retardant includes Sandflam 5060, magnesium hydroxide, aluminum hydroxide, zinc hydroxide, ammonium dihydrogen phosphate, hydrogen phosphate One or more mixtures of diamine and triamine phosphate. 3.根据权利要求1所述的耐洗涤无融滴阻燃幕布,其特征在于,所述芳纶纤维纺丝液中还包括加强剂0.1-0.2重量份,所述阻燃粘胶纤维纺丝液中还包括加强剂0.2-0.25重量份。3. The washing-resistant and drip-free flame-retardant curtain according to claim 1, characterized in that, the aramid fiber spinning solution also includes 0.1-0.2 parts by weight of a reinforcing agent, and the flame-retardant viscose fiber spinning The liquid also includes 0.2-0.25 parts by weight of a strengthening agent. 4.根据权利要求3所述的耐洗涤无融滴阻燃幕布,其特征在于,所述加强剂包括碳酸二甲酯0.5-1重量份和聚乙烯醇0.3-0.7重量份。4 . The washing-resistant and non-melting drop flame retardant curtain according to claim 3 , wherein the strengthening agent comprises 0.5-1 part by weight of dimethyl carbonate and 0.3-0.7 part by weight of polyvinyl alcohol. 5.一种耐洗涤无融滴阻燃幕布的加工方法,其特征在于,包括依次进行的混棉、梳棉、并条、粗纱、细纱、定型、捻线、络筒、定型、整经及卷纬、织造,其中,所述混棉是分别将棉与芳纶纤维混纺、棉与阻燃粘胶纤维混纺。5. A processing method for washing-resistant flame-retardant curtain without melting drops, characterized in that it comprises successively cotton blending, carding, drawing, roving, spun yarn, shaping, twisting, winding, shaping, warping and Weft crimping and weaving, wherein the cotton blending is blending cotton and aramid fiber, cotton and flame-retardant viscose fiber respectively. 6.根据权利要求5所述的耐洗涤无融滴阻燃幕布的加工方法,其特征在于,所述梳棉步骤的相对湿度为50-70%,并条步骤的相对湿度为55-60%,粗纱步骤的相对湿度为50-55%,细纱步骤的相对湿度为45-50%。6. The washing-resistant and non-melting dripping flame-retardant curtain according to claim 5, wherein the relative humidity of the carding step is 50-70%, and the relative humidity of the drawing step is 55-60%. , the relative humidity of the roving step is 50-55%, and the relative humidity of the spun step is 45-50%. 7.根据权利要求5所述的耐洗涤无融滴阻燃幕布的加工方法,其特征在于,所述芳纶纤维长度为50-60mm、细度为1.6-1.7dtex;阻燃粘胶纤维长度为35-40mm、细度为1.6-1.7dtex。7. The washing-resistant and drip-free flame-retardant curtain according to claim 5, wherein the length of the aramid fiber is 50-60mm and the fineness is 1.6-1.7dtex; the length of the flame-retardant viscose fiber is It is 35-40mm and the fineness is 1.6-1.7dtex. 8.根据权利要求5所述的耐洗涤无融滴阻燃幕布的加工方法,其特征在于,所述粗纱捻度为2-3捻/10cm。8. The method for processing the washing-resistant and non-melting dripping flame-retardant curtain according to claim 5, characterized in that, the twist of the roving is 2-3 twists/10cm. 9.根据权利要求5所述的耐洗涤无融滴阻燃幕布的加工方法,其特征在于,所述定型步骤中,温度为80-90℃,定型时间为35-45min。9. The method for processing the washing-resistant and non-melting dripping flame-retardant curtain according to claim 5, characterized in that, in the setting step, the temperature is 80-90°C, and the setting time is 35-45 minutes.
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Application publication date: 20181016