CR20210453A - PESTICIDAS DE AZOLES BICÍCLICOS SUSTITUIDOS CON HETEROCICLOS (Divisional 2016-0127) - Google Patents

PESTICIDAS DE AZOLES BICÍCLICOS SUSTITUIDOS CON HETEROCICLOS (Divisional 2016-0127)

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Publication number
CR20210453A
CR20210453A CR20210453A CR20210453A CR20210453A CR 20210453 A CR20210453 A CR 20210453A CR 20210453 A CR20210453 A CR 20210453A CR 20210453 A CR20210453 A CR 20210453A CR 20210453 A CR20210453 A CR 20210453A
Authority
CR
Costa Rica
Prior art keywords
sup
heterocycle
substituted bicyclic
bicyclic azole
azole pesticides
Prior art date
Application number
CR20210453A
Other languages
English (en)
Inventor
Wenming Zhang
David Alan Clark
Breena Gloriana Fraga
Original Assignee
Fmc Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fmc Corp filed Critical Fmc Corp
Publication of CR20210453A publication Critical patent/CR20210453A/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D513/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00
    • C07D513/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for in groups C07D463/00, C07D477/00 or C07D499/00 - C07D507/00 in which the condensed system contains two hetero rings
    • C07D513/04—Ortho-condensed systems
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A01N43/52—1,3-Diazoles; Hydrogenated 1,3-diazoles condensed with carbocyclic rings, e.g. benzimidazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P7/00—Arthropodicides
    • A01P7/04—Insecticides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/14—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D407/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00
    • C07D407/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
    • C07D417/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
    • C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
    • C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
    • C07D471/04—Ortho-condensed systems
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Toxicology (AREA)
  • Insects & Arthropods (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Soil Sciences (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

La presente invención está dirigida a compuestos de la Fórmula <strong>1 </strong>(que incluyen todos los isómeros geométricos y estereoisómeros), <em>N</em>-óxidos y sales de estos, y composiciones que los contienen y su uso para controlar plagas de invertebrados: <img src="data:image/png;base64,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 (***)
CR20210453A 2013-09-13 2014-09-09 PESTICIDAS DE AZOLES BICÍCLICOS SUSTITUIDOS CON HETEROCICLOS (Divisional 2016-0127) CR20210453A (es)

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