CS207451B2 - Method of making the crystal copolymere - Google Patents

Method of making the crystal copolymere Download PDF

Info

Publication number: CS207451B2
Authority: CS; Czechoslovakia
Prior art keywords: propylene; ethylene; titanium tetrachloride; alpha; weight
Prior art date: 1976-04-19

Application number

CS772603A

Other languages

Czech (cs)

English (en)

Inventor

Takeshi Suzuki

Hiromasa Chiba

Original Assignee

Chisso Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-04-19

Filing date

1977-04-19

Publication date

1981-07-31

1977-04-19 Application filed by Chisso Corp filed Critical Chisso Corp

1981-07-31 Publication of CS207451B2 publication Critical patent/CS207451B2/cs

Links

229920001577 copolymer Polymers 0.000 title claims description 54
238000004519 manufacturing process Methods 0.000 title abstract description 10
239000013078 crystal Substances 0.000 title 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 54
239000005977 Ethylene Substances 0.000 claims abstract description 53
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 51
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 47
238000006116 polymerization reaction Methods 0.000 claims abstract description 46
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 37
239000000203 mixture Substances 0.000 claims abstract description 36
239000003054 catalyst Substances 0.000 claims abstract description 33
239000004711 α-olefin Substances 0.000 claims abstract description 33
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 31
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 23
238000007334 copolymerization reaction Methods 0.000 claims abstract description 23
239000007795 chemical reaction product Substances 0.000 claims abstract description 13
238000002156 mixing Methods 0.000 claims abstract description 13
150000001875 compounds Chemical class 0.000 claims abstract description 10
239000012442 inert solvent Substances 0.000 claims abstract description 7
150000004820 halides Chemical class 0.000 claims abstract description 6
238000000034 method Methods 0.000 claims description 32
-1 aliphatic glycol ethers Chemical class 0.000 claims description 22
239000000047 product Substances 0.000 claims description 12
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
125000001931 aliphatic group Chemical group 0.000 claims description 11
239000001257 hydrogen Substances 0.000 claims description 11
229910052739 hydrogen Inorganic materials 0.000 claims description 11
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 5
239000007789 gas Substances 0.000 claims description 5
239000002904 solvent Substances 0.000 claims description 5
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
238000002360 preparation method Methods 0.000 claims description 4
150000003512 tertiary amines Chemical class 0.000 claims description 4
150000004837 alkyl aryl thioethers Chemical class 0.000 claims description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
150000003335 secondary amines Chemical class 0.000 claims description 3
159000000032 aromatic acids Chemical class 0.000 claims description 2
150000003003 phosphines Chemical class 0.000 claims 1
230000000704 physical effect Effects 0.000 abstract description 27
229910003074 TiCl4 Inorganic materials 0.000 abstract description 4
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 abstract description 3
238000003801 milling Methods 0.000 abstract description 2
229920005606 polypropylene copolymer Polymers 0.000 abstract 1
229920000642 polymer Polymers 0.000 description 39
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 32
230000000052 comparative effect Effects 0.000 description 21
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
239000000243 solution Substances 0.000 description 15
239000000178 monomer Substances 0.000 description 11
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
239000004743 Polypropylene Substances 0.000 description 8
SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 8
229920001155 polypropylene Polymers 0.000 description 8
229910010165 TiCu Inorganic materials 0.000 description 7
230000000694 effects Effects 0.000 description 7
QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 6
230000001965 increasing effect Effects 0.000 description 6
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 5
230000004913 activation Effects 0.000 description 4
239000012071 phase Substances 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
230000003213 activating effect Effects 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
239000007791 liquid phase Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
150000002894 organic compounds Chemical class 0.000 description 3
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 3
238000003756 stirring Methods 0.000 description 3
238000003466 welding Methods 0.000 description 3
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
QQQCWVDPMPFUGF-ZDUSSCGKSA-N alpinetin Chemical compound C1([C@H]2OC=3C=C(O)C=C(C=3C(=O)C2)OC)=CC=CC=C1 QQQCWVDPMPFUGF-ZDUSSCGKSA-N 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 2
238000000227 grinding Methods 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
230000001788 irregular Effects 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000008213 purified water Substances 0.000 description 2
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 1
AOPDRZXCEAKHHW-UHFFFAOYSA-N 1-pentoxypentane Chemical compound CCCCCOCCCCC AOPDRZXCEAKHHW-UHFFFAOYSA-N 0.000 description 1
HYDWALOBQJFOMS-UHFFFAOYSA-N 3,6,9,12,15-pentaoxaheptadecane Chemical compound CCOCCOCCOCCOCCOCC HYDWALOBQJFOMS-UHFFFAOYSA-N 0.000 description 1
DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 1
229920006257 Heat-shrinkable film Polymers 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002313 adhesive film Substances 0.000 description 1
150000007824 aliphatic compounds Chemical class 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
VRAIHTAYLFXSJJ-UHFFFAOYSA-N alumane Chemical compound [AlH3].[AlH3] VRAIHTAYLFXSJJ-UHFFFAOYSA-N 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
229920001585 atactic polymer Polymers 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
238000000071 blow moulding Methods 0.000 description 1
HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
239000001273 butane Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
101150047356 dec-1 gene Proteins 0.000 description 1
238000007865 diluting Methods 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
239000011888 foil Substances 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical group 0.000 description 1
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229940095102 methyl benzoate Drugs 0.000 description 1
238000000465 moulding Methods 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
125000001741 organic sulfur group Chemical group 0.000 description 1
239000012785 packaging film Substances 0.000 description 1
229920006280 packaging film Polymers 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920005629 polypropylene homopolymer Polymers 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
239000001294 propane Substances 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
230000003068 static effect Effects 0.000 description 1
239000010959 steel Substances 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000010936 titanium Substances 0.000 description 1
BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/916—Interpolymer from at least three ethylenically unsaturated monoolefinic hydrocarbon monomers

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)

CS772603A 1976-04-19 1977-04-19 Method of making the crystal copolymere CS207451B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP51044315A JPS607645B2 (ja)	1976-04-19	1976-04-19	共重合体ポリプロピレン用触媒の重合前活性化による該共重合体の製造法

Publications (1)

Publication Number	Publication Date
CS207451B2 true CS207451B2 (en)	1981-07-31

Family

ID=12688044

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS772603A CS207451B2 (en)	1976-04-19	1977-04-19	Method of making the crystal copolymere

Country Status (4)

Country	Link
US (1)	US4304890A (ru)
JP (1)	JPS607645B2 (ru)
CS (1)	CS207451B2 (ru)
SU (1)	SU784785A3 (ru)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS55115416A (en) *	1979-02-27	1980-09-05	Nippon Oil Co Ltd	Manufacture of copolymer
JPS55145713A (en) *	1979-05-01	1980-11-13	Mitsubishi Petrochem Co Ltd	Crystalline copolymer of propylene and utilization thereof
JPS6024805B2 (ja) *	1979-09-05	1985-06-14	日石三菱株式会社	共重合体の製法
JPS6042807B2 (ja) *	1980-04-11	1985-09-25	チッソ株式会社	エチレンプロピレンα−オレフイン三元共重合体の製造方法
JPS5759902A (en) *	1980-09-29	1982-04-10	Chisso Corp	Preparation of alpha-olefinic polymer
JPS5774311A (en) *	1980-10-29	1982-05-10	Mitsui Toatsu Chem Inc	Production of terpolymer
JPS5774312A (en) *	1980-10-29	1982-05-10	Mitsui Toatsu Chem Inc	Production of erpolymer
JPS5777533A (en) *	1980-10-31	1982-05-14	Toyobo Co Ltd	Heat-shrinkable film
JPS5865734A (ja) *	1981-10-14	1983-04-19	Kanegafuchi Chem Ind Co Ltd	ポリプロピレン系樹脂発泡粒子およびその製造法
US4394304A (en) *	1982-01-29	1983-07-19	Massachusetts Institute Of Technology	Electrically conducting polymer blends
FI68632C (fi) *	1983-06-22	1985-10-10	Neste Oy	Foerfarande foer framstaellning av sampolymerer av eten och langkedjade alfa-olefiner
WO1986005794A1 (en) *	1985-04-01	1986-10-09	Uss Engineers And Consultants, Inc.	Terpolymer production
EP0282929B2 (en) *	1987-03-14	1997-10-22	Mitsubishi Kasei Corporation	Method for producing a propylene-alpha-olefin block copolymer
DE19506286A1 (de) *	1995-02-23	1996-08-29	Basf Ag	Statistische Copolymerisate des Propylens für Schaumstoffe
DE19543292A1 (de) *	1995-11-21	1997-05-22	Basf Ag	Copolymerisate des Propylens mit anderen C¶2¶-C¶1¶¶0¶-Alk-1-enen
DE19545499A1 (de) *	1995-12-06	1997-06-12	Basf Ag	Verbesserte statistische Propylencopolymerisate
ZA974798B (en) *	1996-05-31	1998-11-30	Sastech Pty Ltd	Termpolymerization
DE19827328A1 (de) *	1998-06-19	1999-12-23	Targor Gmbh	Propen-Terpolymere mit geringem extrahierbarem Anteil
ATE528327T1 (de) *	1998-10-27	2011-10-15	Westlake Longview Corp	Verfahren zur polymerisierung von olefine.
EP1886806B1 (en) *	2006-07-10	2010-11-10	Borealis Technology Oy	Biaxially oriented polypropylene film
DE602006004987D1 (de) *	2006-07-10	2009-03-12	Borealis Tech Oy	Elektrischer Isolierfilm
DE602006002512D1 (de) *	2006-07-10	2008-10-09	Borealis Tech Oy	Kurzkettig verzweigtes Polypropylen
EP1967547A1 (en) *	2006-08-25	2008-09-10	Borealis Technology OY	Extrusion coated substrate
EP1941997B1 (en) †	2006-12-18	2009-05-27	Borealis Technology Oy	Terpolymer with high melting point
EP2788388A1 (en) *	2011-12-05	2014-10-15	Basell Poliolefine Italia S.r.l.	Propylene terpolymers
JP6070279B2 (ja) *	2013-03-04	2017-02-01	セイコーエプソン株式会社	記録装置
JP6192029B2 (ja)	2013-12-09	2017-09-06	バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ	多層金属蒸着フィルム

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL203032A (ru)	1954-12-24
US3530107A (en) *	1968-11-06	1970-09-22	Mitsui Toatsu Chemicals	Modified catalyst system and process for production of polymers of 1-olefins
US3669948A (en) *	1970-09-04	1972-06-13	Chisso Corp	Method for producing poly{60 -olefins
NL7107362A (ru) *	1971-05-28	1972-11-30
DE2352980C3 (de) *	1973-10-23	1980-03-13	Chemische Werke Huels Ag, 4370 Marl	Verfahren zur Herstellung von kristallinen Propen-Äthen-Buten-1-Terpolymeren
JPS5434714B2 (ru) *	1975-03-11	1979-10-29
JPS5212799A (en) *	1975-07-19	1977-01-31	Fujitsu Ltd	Automatic audiometer masking system

1976
- 1976-04-19 JP JP51044315A patent/JPS607645B2/ja not_active Expired
1977
- 1977-04-19 CS CS772603A patent/CS207451B2/cs unknown
- 1977-04-19 SU SU772470316A patent/SU784785A3/ru active
1980
- 1980-07-08 US US06/166,832 patent/US4304890A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
JPS607645B2 (ja)	1985-02-26
JPS52127994A (en)	1977-10-27
US4304890A (en)	1981-12-08
SU784785A3 (ru)	1980-11-30

Publication	Publication Date	Title
CS207451B2 (en)	1981-07-31	Method of making the crystal copolymere
EP0151883B1 (en)	1989-05-24	Crystalline propylene polymer composition
US4675247A (en)	1987-06-23	Laminated polypropylene film
US5521251A (en)	1996-05-28	Propylene random copolymer composition
US4670529A (en)	1987-06-02	Packaging shrink film
DE2952579A1 (de)	1980-07-17	Verfahren zur herstellung eines propylencopolymeren
US4297445A (en)	1981-10-27	Continuous production of olefin block copolymers
JP3290293B2 (ja)	2002-06-10	ポリプロピレン樹脂および延伸フィルム
JPH0673132A (ja)	1994-03-15	ポリプロピレンランダム共重合体及びそのフィルム
JPH09309984A (ja)	1997-12-02	変性ポリエチレン耐衝撃共重合体組成物
JPH0368890B2 (ru)	1991-10-30
JP4748827B2 (ja)	2011-08-17	ストレッチフィルム用軟質フィルム
JP2001011259A (ja)	2001-01-16	ポリプロピレン樹脂組成物
JPH0812828A (ja)	1996-01-16	積層延伸フィルム用ポリプロピレン組成物及び積層延伸フィルム
JPS623864B2 (ru)	1987-01-27
JPH0114247B2 (ru)	1989-03-10
KR820000602B1 (ko)	1982-04-16	공중합 전에 활성화된 촉매를 사용하여 프로피렌 공중합체를 제조하는 방법
JP2533321B2 (ja)	1996-09-11	ポリプロピレン積層フィルム
JPS6340809B2 (ru)	1988-08-12
JPS646212B2 (ru)	1989-02-02
JPH0339092B2 (ru)	1991-06-12
JPS63112612A (ja)	1988-05-17	プロピレンブロック共重合体
JPH07166005A (ja)	1995-06-27	プロピレンランダム共重合体組成物
JPH0339089B2 (ru)	1991-06-12
JPH064684B2 (ja)	1994-01-19	結晶性ポリプロピレン