CS214764B2 - Method of making the polymeres of cyclodextrine with polyvinylalcool capable of forming the inclusive complexes and prepared in the form of beads,foils,fibres or blocks - Google Patents

Method of making the polymeres of cyclodextrine with polyvinylalcool capable of forming the inclusive complexes and prepared in the form of beads,foils,fibres or blocks Download PDF

Info

Publication number: CS214764B2
Authority: CS; Czechoslovakia
Prior art keywords: cyclodextrin; polyvinyl alcohol; polymer; prepared; polymers
Prior art date: 1978-07-13

Application number

CS794890A

Other languages

Czech (cs)

English (en)

Inventor

Jozsef Szejtli

Eva Fenyvesi

Sandor Zoltan

Bela Zsadon

Ferenc Toedoes

Original Assignee

Chinoin Gyogyszer Es Vegyeszet

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-07-13

Filing date

1979-07-12

Publication date

1982-05-28

1979-07-12 Application filed by Chinoin Gyogyszer Es Vegyeszet filed Critical Chinoin Gyogyszer Es Vegyeszet

1982-05-28 Publication of CS214764B2 publication Critical patent/CS214764B2/cs

Links

229920000858 Cyclodextrin Polymers 0.000 title claims abstract description 83
229920000642 polymer Polymers 0.000 title claims abstract description 57
HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 title claims abstract description 51
239000011324 bead Substances 0.000 title claims description 20
238000004519 manufacturing process Methods 0.000 title claims description 5
239000011888 foil Substances 0.000 title 1
229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 43
239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 42
239000000203 mixture Substances 0.000 claims abstract description 28
229940097362 cyclodextrins Drugs 0.000 claims abstract description 16
229920002689 polyvinyl acetate Polymers 0.000 claims abstract description 10
239000011118 polyvinyl acetate Substances 0.000 claims abstract description 10
150000001720 carbohydrates Chemical class 0.000 claims abstract description 8
238000004132 cross linking Methods 0.000 claims abstract description 5
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 36
238000000034 method Methods 0.000 claims description 16
239000000835 fiber Substances 0.000 claims description 13
238000006243 chemical reaction Methods 0.000 claims description 9
239000003431 cross linking reagent Substances 0.000 claims description 7
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 6
239000004721 Polyphenylene oxide Substances 0.000 claims description 4
239000010408 film Substances 0.000 claims description 4
229920000570 polyether Polymers 0.000 claims description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
229920001577 copolymer Polymers 0.000 claims description 2
238000002360 preparation method Methods 0.000 abstract description 7
229920002554 vinyl polymer Polymers 0.000 abstract description 2
230000008878 coupling Effects 0.000 abstract 1
238000010168 coupling process Methods 0.000 abstract 1
238000005859 coupling reaction Methods 0.000 abstract 1
239000000376 reactant Substances 0.000 abstract 1
239000000243 solution Substances 0.000 description 30
239000000047 product Substances 0.000 description 23
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 22
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 21
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
239000002245 particle Substances 0.000 description 14
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 10
239000007864 aqueous solution Substances 0.000 description 9
WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 description 8
229960004853 betadex Drugs 0.000 description 8
150000001875 compounds Chemical class 0.000 description 8
239000001116 FEMA 4028 Substances 0.000 description 7
235000011175 beta-cyclodextrine Nutrition 0.000 description 7
235000014633 carbohydrates Nutrition 0.000 description 6
IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 6
238000003756 stirring Methods 0.000 description 6
238000010521 absorption reaction Methods 0.000 description 5
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
QIVBCDIJIAJPQS-VIFPVBQESA-N L-tryptophane Chemical compound C1=CC=C2C(C[C@H](N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-VIFPVBQESA-N 0.000 description 4
QIVBCDIJIAJPQS-UHFFFAOYSA-N Tryptophan Natural products C1=CC=C2C(CC(N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-UHFFFAOYSA-N 0.000 description 4
229920005989 resin Polymers 0.000 description 4
239000011347 resin Substances 0.000 description 4
238000009987 spinning Methods 0.000 description 4
229920001450 Alpha-Cyclodextrin Polymers 0.000 description 3
QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 3
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical class [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
235000004279 alanine Nutrition 0.000 description 3
239000012670 alkaline solution Substances 0.000 description 3
239000012429 reaction media Substances 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
-1 sheets Substances 0.000 description 3
239000000779 smoke Substances 0.000 description 3
JJWFIVDAMOFNPS-QRPNPIFTSA-N (2s)-2-amino-3-(4-hydroxyphenyl)propanoic acid;hydrochloride Chemical compound Cl.OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 JJWFIVDAMOFNPS-QRPNPIFTSA-N 0.000 description 2
229920001353 Dextrin Polymers 0.000 description 2
239000004375 Dextrin Substances 0.000 description 2
239000004593 Epoxy Substances 0.000 description 2
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
229940043377 alpha-cyclodextrin Drugs 0.000 description 2
235000001014 amino acid Nutrition 0.000 description 2
229940024606 amino acid Drugs 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
238000012512 characterization method Methods 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
238000004587 chromatography analysis Methods 0.000 description 2
235000019504 cigarettes Nutrition 0.000 description 2
230000000536 complexating effect Effects 0.000 description 2
235000019425 dextrin Nutrition 0.000 description 2
239000002612 dispersion medium Substances 0.000 description 2
238000009826 distribution Methods 0.000 description 2
238000010828 elution Methods 0.000 description 2
238000001914 filtration Methods 0.000 description 2
GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 description 2
229940080345 gamma-cyclodextrin Drugs 0.000 description 2
239000007789 gas Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000002798 polar solvent Substances 0.000 description 2
229920006254 polymer film Polymers 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
229910052938 sodium sulfate Inorganic materials 0.000 description 2
235000011152 sodium sulphate Nutrition 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
230000008961 swelling Effects 0.000 description 2
229920003169 water-soluble polymer Polymers 0.000 description 2
SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 1
239000004475 Arginine Substances 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
125000002353 D-glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
239000004471 Glycine Substances 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
PMMYEEVYMWASQN-DMTCNVIQSA-N Hydroxyproline Chemical compound O[C@H]1CN[C@H](C(O)=O)C1 PMMYEEVYMWASQN-DMTCNVIQSA-N 0.000 description 1
XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 1
ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 description 1
ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 description 1
AGPKZVBTJJNPAG-WHFBIAKZSA-N L-isoleucine Chemical compound CC[C@H](C)[C@H](N)C(O)=O AGPKZVBTJJNPAG-WHFBIAKZSA-N 0.000 description 1
ROHFNLRQFUQHCH-YFKPBYRVSA-N L-leucine Chemical compound CC(C)C[C@H](N)C(O)=O ROHFNLRQFUQHCH-YFKPBYRVSA-N 0.000 description 1
KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 description 1
COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 description 1
AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 description 1
KZSNJWFQEVHDMF-BYPYZUCNSA-N L-valine Chemical compound CC(C)[C@H](N)C(O)=O KZSNJWFQEVHDMF-BYPYZUCNSA-N 0.000 description 1
ROHFNLRQFUQHCH-UHFFFAOYSA-N Leucine Natural products CC(C)CC(N)C(O)=O ROHFNLRQFUQHCH-UHFFFAOYSA-N 0.000 description 1
KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
239000004472 Lysine Substances 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Natural products OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 description 1
241001104043 Syringa Species 0.000 description 1
235000004338 Syringa vulgaris Nutrition 0.000 description 1
AYFVYJQAPQTCCC-UHFFFAOYSA-N Threonine Natural products CC(O)C(N)C(O)=O AYFVYJQAPQTCCC-UHFFFAOYSA-N 0.000 description 1
239000004473 Threonine Substances 0.000 description 1
KZSNJWFQEVHDMF-UHFFFAOYSA-N Valine Natural products CC(C)C(N)C(O)=O KZSNJWFQEVHDMF-UHFFFAOYSA-N 0.000 description 1
HFHDHCJBZVLPGP-RWMJIURBSA-N alpha-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO HFHDHCJBZVLPGP-RWMJIURBSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
235000003704 aspartic acid Nutrition 0.000 description 1
OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000003610 charcoal Substances 0.000 description 1
238000004440 column chromatography Methods 0.000 description 1
238000010668 complexation reaction Methods 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
235000018417 cysteine Nutrition 0.000 description 1
XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
PMMYEEVYMWASQN-UHFFFAOYSA-N dl-hydroxyproline Natural products OC1C[NH2+]C(C([O-])=O)C1 PMMYEEVYMWASQN-UHFFFAOYSA-N 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
239000003344 environmental pollutant Substances 0.000 description 1
125000003700 epoxy group Chemical group 0.000 description 1
235000013922 glutamic acid Nutrition 0.000 description 1
239000004220 glutamic acid Substances 0.000 description 1
HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
229960002591 hydroxyproline Drugs 0.000 description 1
238000011534 incubation Methods 0.000 description 1
239000010842 industrial wastewater Substances 0.000 description 1
AGPKZVBTJJNPAG-UHFFFAOYSA-N isoleucine Natural products CCC(C)C(N)C(O)=O AGPKZVBTJJNPAG-UHFFFAOYSA-N 0.000 description 1
229960000310 isoleucine Drugs 0.000 description 1
229920002521 macromolecule Polymers 0.000 description 1
229930182817 methionine Natural products 0.000 description 1
244000005700 microbiome Species 0.000 description 1
238000007431 microscopic evaluation Methods 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229960002715 nicotine Drugs 0.000 description 1
SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
231100000719 pollutant Toxicity 0.000 description 1
229920002401 polyacrylamide Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920005594 polymer fiber Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
238000004445 quantitative analysis Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000013049 sediment Substances 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000012265 solid product Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
FGMPLJWBKKVCDB-UHFFFAOYSA-N trans-L-hydroxy-proline Natural products ON1CCCC1C(O)=O FGMPLJWBKKVCDB-UHFFFAOYSA-N 0.000 description 1
NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
239000004474 valine Substances 0.000 description 1
239000002351 wastewater Substances 0.000 description 1
238000004065 wastewater treatment Methods 0.000 description 1
WHGYBXFWUBPSRW-FEYSZYNQSA-N β-dextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)C(O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FEYSZYNQSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0009—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid alpha-D-Glucans, e.g. polydextrose, alternan, glycogen; (alpha-1,4)(alpha-1,6)-D-Glucans; (alpha-1,3)(alpha-1,4)-D-Glucans, e.g. isolichenan or nigeran; (alpha-1,4)-D-Glucans; (alpha-1,3)-D-Glucans, e.g. pseudonigeran; Derivatives thereof
- C08B37/0012—Cyclodextrin [CD], e.g. cycle with 6 units (alpha), with 7 units (beta) and with 8 units (gamma), large-ring cyclodextrin or cycloamylose with 9 units or more; Derivatives thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
- C08L5/16—Cyclodextrin; Derivatives thereof

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Life Sciences & Earth Sciences (AREA)
Organic Chemistry (AREA)
Polymers & Plastics (AREA)
Medicinal Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Biochemistry (AREA)
Molecular Biology (AREA)
General Health & Medical Sciences (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Processes Of Treating Macromolecular Substances (AREA)
Compositions Of Macromolecular Compounds (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)
Medicinal Preparation (AREA)
Artificial Filaments (AREA)
Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Nonwoven Fabrics (AREA)

CS794890A 1978-07-13 1979-07-12 Method of making the polymeres of cyclodextrine with polyvinylalcool capable of forming the inclusive complexes and prepared in the form of beads,foils,fibres or blocks CS214764B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
HU78CI1845A HU177419B (en)	1978-07-13	1978-07-13	Process for preparing threedimensional,retentive polymers consisting of cyclodextrin and polyvinylalcohol units,capable of forming inclusion complexes in the form of bead,fibre or mainly block

Publications (1)

Publication Number	Publication Date
CS214764B2 true CS214764B2 (en)	1982-05-28

Family

ID=10994703

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS794890A CS214764B2 (en)	1978-07-13	1979-07-12	Method of making the polymeres of cyclodextrine with polyvinylalcool capable of forming the inclusive complexes and prepared in the form of beads,foils,fibres or blocks

Country Status (17)

Country	Link
US (1)	US4274985A (da)
JP (1)	JPS5820962B2 (da)
AT (1)	AT369402B (da)
BE (1)	BE877653A (da)
CA (1)	CA1124928A (da)
CH (1)	CH644386A5 (da)
CS (1)	CS214764B2 (da)
DD (1)	DD145108A1 (da)
DE (1)	DE2927733C2 (da)
DK (1)	DK166028C (da)
FI (1)	FI65444C (da)
FR (1)	FR2430954A1 (da)
GB (1)	GB2030574B (da)
HU (1)	HU177419B (da)
NO (1)	NO153967C (da)
SE (1)	SE446453B (da)
SU (1)	SU1227118A3 (da)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4371673A (en) *	1980-07-21	1983-02-01	The United States Of America As Represented By The Secretary Of The Department Of Health And Human Services	Water soluble forms of retinoids
HU182217B (en) *	1980-10-17	1983-12-28	Chinoin Gyogyszer Es Vegyeszet	Process for producing inclusive complexes of cyclodextrines and strong inorganic oxyacids
HU189534B (en) *	1981-09-09	1986-07-28	Chinoin Rt.,Hu	Process for producing new tablets containing cyclodextrin polymer as desintegrator
US4426292A (en)	1982-02-19	1984-01-17	Exxon Research And Engineering Co.	Process for selective separation of molecular species from mixtures thereof using cyclodextrins
HU190841B (en) *	1983-02-04	1986-11-28	Chinoin Gyogyszer Es Vegyeszeti Termekek Gyara Rt,Hu	Process for the production of cyclodextrin polymers swelling in water quickly and to a high extent
JPH072771B2 (ja) *	1984-06-27	1995-01-18	ナシヨナル・スタ−チ・アンド・ケミカル・コ−ポレイシヨン	グルコシド側鎖を有する合成重合体の製造方法
US4726905A (en) *	1986-04-30	1988-02-23	American Maize-Products Company	Method for removing polychlorinated biphenyl compounds from water
US4808232A (en) *	1986-12-08	1989-02-28	American Maize-Products Company	Separation and purification of cyclodextrins
HU201782B (en) *	1987-06-08	1990-12-28	Chinoin Gyogyszer Es Vegyeszet	Process for producing cyclodextrine-polymere iodine inclusion complex of controlled iodine release and powder containing them as active component
US4774329A (en) *	1987-08-04	1988-09-27	American Maize-Products Company	Controlled release agent for cetylpyridinium chloride
MY106598A (en) *	1988-08-31	1995-06-30	Australian Commercial Res & Development Ltd	Compositions and methods for drug delivery and chromatography.
US5075432A (en) *	1989-08-11	1991-12-24	Edward Vanzo	Spherical cyclodextrin polymer beads
DE4009840A1 (de) *	1990-03-27	1991-10-02	Consortium Elektrochem Ind	Cyclodextrin-polymerisate und verfahren zu deren herstellung
JPH0425505A (ja) *	1990-05-21	1992-01-29	Toppan Printing Co Ltd	シクロデキストリンポリマー及びシクロデキストリン膜の製造方法
CA2066633A1 (en) *	1990-11-30	1992-05-31	Masanobu Yoshinaga	Processes for producing cyclodextrin derivatives and polymers containing immobilizing cyclodextrin therein
JPH06165988A (ja) *	1992-08-24	1994-06-14	J Shii S:Kk	塗料スラッジ回収が容易な静電凝集器付水洗式塗装ブース
US5487998A (en) *	1993-01-06	1996-01-30	The United States Of America As Represented By The Secreatry Of The Department Of Health And Human Services	Trapping of aflatoxins and phytoestrogens
US5492947A (en) *	1994-06-23	1996-02-20	Aspen Research Corporation	Barrier material comprising a thermoplastic and a compatible cyclodextrin derivative
US5928745A (en) *	1994-06-23	1999-07-27	Cellresin Technologies, Llc	Thermoplastic fuel tank having reduced fuel vapor emissions
US5985772A (en) *	1994-06-23	1999-11-16	Cellresin Technologies, Llc	Packaging system comprising cellulosic web with a permeant barrier or contaminant trap
US5776842A (en) *	1994-06-23	1998-07-07	Cellresin Technologies, Llc	Cellulosic web with a contaminant barrier or trap
US5882565A (en) *	1995-12-11	1999-03-16	Cellresin Technologies, Llc	Barrier material comprising a thermoplastic and a compatible cyclodextrin derivative
DE19612768A1 (de) *	1996-03-29	1997-10-02	Basf Ag	Cyclodextringruppen enthaltende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung
US6527887B1 (en)	2002-01-18	2003-03-04	Mach I, Inc.	Polymeric cyclodextrin nitrate esters
RU2217521C2 (ru) *	2002-02-08	2003-11-27	Стадничук Александр Викторович	Литая износостойкая сталь для деталей горно-обогатительного производства
US7807823B2 (en) *	2004-02-05	2010-10-05	Millipore Corporation	Method of forming polysaccharide structures
WO2005077529A1 (en) *	2004-02-05	2005-08-25	Millipore Corporation	Porous adsorptive or chromatographic media
WO2005078016A1 (en)	2004-02-05	2005-08-25	Millipore Corporation	Room temperature stable agarose solutions
US7959979B2 (en) *	2004-02-05	2011-06-14	Millipore Corporation	Method of forming coated structures
WO2005077528A1 (en) *	2004-02-05	2005-08-25	Millipore Corporation	Porous adsorptive or chromatographic media
EP1761283A2 (en) *	2004-06-07	2007-03-14	California Institute Of Technology	Biodegradable drug-polymer delivery system
US9433922B2 (en) *	2007-08-14	2016-09-06	Emd Millipore Corporation	Media for membrane ion exchange chromatography based on polymeric primary amines, sorption device containing that media, and chromatography scheme and purification method using the same
US20090130738A1 (en) *	2007-11-19	2009-05-21	Mikhail Kozlov	Media for membrane ion exchange chromatography
WO2012120905A1 (ja) *	2011-03-09	2012-09-13	国立大学法人北海道大学	架橋型金属有機構造体および有機物架橋体、およびそれらの製造方法
WO2020142716A1 (en)	2019-01-03	2020-07-09	Sens Research Foundation, Inc.	Cyclodextrin dimers, compositions thereof, and uses thereof
CN116732645A (zh) *	2023-07-25	2023-09-12	南方寝饰科技有限公司	一种生态环保生物降解纤维及其制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
SE358894B (da) *	1961-10-25	1973-08-13	Pharmacia Ab
CH445129A (fr) *	1964-04-29	1967-10-15	Nestle Sa	Procédé pour la préparation de composés d'inclusion à poids moléculaire élevé
GB1244990A (en) *	1968-12-03	1971-09-02	Avebe Coop Verkoop Prod	Cyclodextrin derivatives

1978
- 1978-07-13 HU HU78CI1845A patent/HU177419B/hu not_active IP Right Cessation
1979
- 1979-07-06 AT AT0471279A patent/AT369402B/de not_active IP Right Cessation
- 1979-07-09 US US06/055,536 patent/US4274985A/en not_active Expired - Lifetime
- 1979-07-10 GB GB7923950A patent/GB2030574B/en not_active Expired
- 1979-07-10 DE DE2927733A patent/DE2927733C2/de not_active Expired
- 1979-07-11 FI FI792180A patent/FI65444C/fi not_active IP Right Cessation
- 1979-07-11 FR FR7918012A patent/FR2430954A1/fr active Granted
- 1979-07-12 BE BE0/196261A patent/BE877653A/xx not_active IP Right Cessation
- 1979-07-12 CH CH652179A patent/CH644386A5/de not_active IP Right Cessation
- 1979-07-12 DK DK293379A patent/DK166028C/da not_active IP Right Cessation
- 1979-07-12 SU SU792788604A patent/SU1227118A3/ru active
- 1979-07-12 NO NO792322A patent/NO153967C/no unknown
- 1979-07-12 CS CS794890A patent/CS214764B2/cs unknown
- 1979-07-12 DD DD79214293A patent/DD145108A1/de not_active IP Right Cessation
- 1979-07-12 SE SE7906088A patent/SE446453B/sv not_active IP Right Cessation
- 1979-07-13 CA CA331,763A patent/CA1124928A/en not_active Expired
- 1979-07-13 JP JP54088357A patent/JPS5820962B2/ja not_active Expired

Also Published As

Publication number	Publication date
DD145108A1 (de)	1980-11-19
SU1227118A3 (ru)	1986-04-23
BE877653A (fr)	1979-11-05
CH644386A5 (de)	1984-07-31
FI65444B (fi)	1984-01-31
DK166028B (da)	1993-03-01
GB2030574A (en)	1980-04-10
ATA471279A (de)	1982-05-15
NO153967B (no)	1986-03-17
DK166028C (da)	1993-07-12
CA1124928A (en)	1982-06-01
JPS5820962B2 (ja)	1983-04-26
NO153967C (no)	1986-06-25
FR2430954A1 (fr)	1980-02-08
JPS5513796A (en)	1980-01-30
SE7906088L (sv)	1980-01-14
US4274985A (en)	1981-06-23
FR2430954B1 (da)	1984-08-17
GB2030574B (en)	1983-03-23
SE446453B (sv)	1986-09-15
AT369402B (de)	1982-12-27
FI65444C (fi)	1984-05-10
HU177419B (en)	1981-10-28
DE2927733A1 (de)	1980-01-31
NO792322L (no)	1980-01-15
DK293379A (da)	1980-01-14
FI792180A7 (fi)	1980-01-14
DE2927733C2 (de)	1986-03-27

Publication	Publication Date	Title
CS214764B2 (en)	1982-05-28	Method of making the polymeres of cyclodextrine with polyvinylalcool capable of forming the inclusive complexes and prepared in the form of beads,foils,fibres or blocks
Crini et al.	1998	Sorption of aromatic compounds in water using insoluble cyclodextrin polymers
US3420788A (en)	1969-01-07	Inclusion resins of cyclodextrin and methods of use
Ziegler-Borowska et al.	2016	Effect of side substituents on thermal stability of the modified chitosan and its nanocomposites with magnetite
EP0013181B1 (en)	1982-10-13	Chitin derivative, material comprising said derivative and process for the preparation thereof
US8092682B2 (en)	2012-01-10	Matrix for separation of polyethers and method of separation
EP0121468A2 (fr)	1984-10-10	Procédé de fractionnement du plasma
CA2616867A1 (en)	2007-02-15	Process for cross-linking cellulose ester membranes
Crini et al.	1998	Macroporous polyamines containing cyclodextrin: synthesis, characterization, and sorption properties
CN118344507A (zh)	2024-07-16	一种环糊精金属有机骨架聚合物材料的制备方法
US5527902A (en)	1996-06-18	Bead-shaped cellulose products for separating and carrier materials and their manufacture
JP6253059B2 (ja)	2017-12-27	エンドトキシン吸着材
CN1352199A (zh)	2002-06-05	水体净化吸附剂聚环糊精的制备方法
CN106866900A (zh)	2017-06-20	一种光响应表面分子印迹材料及其制备方法和应用
JP2543081B2 (ja)	1996-10-16	シクロデキストリンの固定化方法
WO1989009643A1 (en)	1989-10-19	Novel crosslinked cellulose chromatography media
Legros et al.	2008	Self-organization of water soluble and amphiphile crosslinked carboxymethylpullulan
JPH06145204A (ja)	1994-05-24	エーテル化シクロデキストリンポリマー
Mathur et al.	1992	Guaran: A novel polysaccharide for racemate resolution
JP2862386B2 (ja)	1999-03-03	微小架橋セルロース粒子の製造法
Otta et al.	1982	Cyclodextrin polymers as specific sorbents
US20150251157A1 (en)	2015-09-10	Superhydroxylated adsorbents and uses thereof
CN116731273A (zh)	2023-09-12	一种Cr(III)离子印迹材料的制备方法
CN121003979A (zh)	2025-11-25	一种具有多官能团的复合材料及其制备方法和应用
JPH052105B2 (da)	1993-01-11