CS216991A3 - Thermoplastic material based on vinyl aromatic graft copolymer and polyamide - Google Patents

Thermoplastic material based on vinyl aromatic graft copolymer and polyamide Download PDF

Info

Publication number: CS216991A3
Authority: CS; Czechoslovakia
Prior art keywords: monomer; ethylenically unsaturated; thermoplastic composition; composition according; vinylaromatic
Prior art date: 1990-07-12

Application number

CS912169A

Other languages

Czech (cs)

English (en)

Inventor

Dario Ghidoni

Gian Claudio Fasulo

Anna Grazia Rossi

Luigi Bonetti

Italo Borghi

Original Assignee

Montedipe Srl

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-07-12

Filing date

1991-07-12

Publication date

1992-02-19

1991-07-12 Application filed by Montedipe Srl filed Critical Montedipe Srl

1992-02-19 Publication of CS216991A3 publication Critical patent/CS216991A3/cs

Links

229920000578 graft copolymer Polymers 0.000 title claims abstract description 17
229920002647 polyamide Polymers 0.000 title claims description 11
239000004952 Polyamide Substances 0.000 title claims description 10
229920002554 vinyl polymer Polymers 0.000 title claims description 6
239000012815 thermoplastic material Substances 0.000 title description 2
239000000178 monomer Substances 0.000 claims abstract description 68
239000000203 mixture Substances 0.000 claims abstract description 33
229920001169 thermoplastic Polymers 0.000 claims abstract description 19
239000004416 thermosoftening plastic Substances 0.000 claims abstract description 19
229920006122 polyamide resin Polymers 0.000 claims abstract description 13
229920001577 copolymer Polymers 0.000 claims description 33
229920001971 elastomer Polymers 0.000 claims description 17
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 15
239000000806 elastomer Substances 0.000 claims description 12
150000008064 anhydrides Chemical class 0.000 claims description 9
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 8
229920006285 olefinic elastomer Polymers 0.000 claims description 8
150000001408 amides Chemical class 0.000 claims description 7
125000004432 carbon atom Chemical group C* 0.000 claims description 7
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
125000000217 alkyl group Chemical group 0.000 claims description 6
125000002843 carboxylic acid group Chemical group 0.000 claims description 6
150000002148 esters Chemical class 0.000 claims description 6
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 6
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
229920002292 Nylon 6 Polymers 0.000 claims description 5
150000001336 alkenes Chemical class 0.000 claims description 5
125000003118 aryl group Chemical group 0.000 claims description 5
150000001993 dienes Chemical class 0.000 claims description 5
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 5
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 3
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 3
239000001530 fumaric acid Substances 0.000 claims description 3
229910052740 iodine Inorganic materials 0.000 claims description 3
239000011630 iodine Substances 0.000 claims description 3
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
239000011976 maleic acid Substances 0.000 claims description 3
239000000049 pigment Substances 0.000 claims description 3
239000003381 stabilizer Substances 0.000 claims description 3
239000002216 antistatic agent Substances 0.000 claims description 2
150000001735 carboxylic acids Chemical class 0.000 claims description 2
239000003063 flame retardant Substances 0.000 claims description 2
239000003365 glass fiber Substances 0.000 claims description 2
125000005843 halogen group Chemical group 0.000 claims description 2
YURNCBVQZBJDAJ-UHFFFAOYSA-N heptenoic acid group Chemical group C(C=CCCCC)(=O)O YURNCBVQZBJDAJ-UHFFFAOYSA-N 0.000 claims description 2
239000011256 inorganic filler Substances 0.000 claims description 2
229910003475 inorganic filler Inorganic materials 0.000 claims description 2
239000000314 lubricant Substances 0.000 claims description 2
239000004014 plasticizer Substances 0.000 claims description 2
239000002253 acid Substances 0.000 claims 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
239000000654 additive Substances 0.000 claims 1
239000000975 dye Substances 0.000 claims 1
150000002825 nitriles Chemical class 0.000 claims 1
YIYBQIKDCADOSF-UHFFFAOYSA-N pentenoic acid group Chemical group C(C=CCC)(=O)O YIYBQIKDCADOSF-UHFFFAOYSA-N 0.000 claims 1
230000009261 transgenic effect Effects 0.000 claims 1
-1 tert-butylperoxyisopropyl Chemical group 0.000 description 11
238000006116 polymerization reaction Methods 0.000 description 10
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 9
239000002904 solvent Substances 0.000 description 9
150000002978 peroxides Chemical class 0.000 description 8
238000002156 mixing Methods 0.000 description 7
229920001778 nylon Polymers 0.000 description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
239000004677 Nylon Substances 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
239000003999 initiator Substances 0.000 description 6
238000000034 method Methods 0.000 description 5
229920005989 resin Polymers 0.000 description 5
239000011347 resin Substances 0.000 description 5
239000005060 rubber Substances 0.000 description 5
239000000243 solution Substances 0.000 description 5
239000010409 thin film Substances 0.000 description 5
229920002943 EPDM rubber Polymers 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
239000000758 substrate Substances 0.000 description 4
229920002302 Nylon 6,6 Polymers 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
238000010559 graft polymerization reaction Methods 0.000 description 3
239000000463 material Substances 0.000 description 3
239000002245 particle Substances 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
230000008569 process Effects 0.000 description 3
230000035945 sensitivity Effects 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
OJOWICOBYCXEKR-UHFFFAOYSA-N 5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=CC)CC1C=C2 OJOWICOBYCXEKR-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
239000008187 granular material Substances 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
229920006012 semi-aromatic polyamide Polymers 0.000 description 2
OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 1
KDGNCLDCOVTOCS-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy propan-2-yl carbonate Chemical compound CC(C)OC(=O)OOC(C)(C)C KDGNCLDCOVTOCS-UHFFFAOYSA-N 0.000 description 1
AUHKVLIZXLBQSR-UHFFFAOYSA-N 1,2-dichloro-3-(1,2,2-trichloroethenyl)benzene Chemical compound ClC(Cl)=C(Cl)C1=CC=CC(Cl)=C1Cl AUHKVLIZXLBQSR-UHFFFAOYSA-N 0.000 description 1
XPXMCUKPGZUFGR-UHFFFAOYSA-N 1-chloro-2-(1,2,2-trichloroethenyl)benzene Chemical compound ClC(Cl)=C(Cl)C1=CC=CC=C1Cl XPXMCUKPGZUFGR-UHFFFAOYSA-N 0.000 description 1
NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
XKMDZVINHIFHLY-UHFFFAOYSA-N 1-ethenyl-3,5-dimethylbenzene Chemical compound CC1=CC(C)=CC(C=C)=C1 XKMDZVINHIFHLY-UHFFFAOYSA-N 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical compound ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 1
XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
KRDXTHSSNCTAGY-UHFFFAOYSA-N 2-cyclohexylpyrrolidine Chemical compound C1CCNC1C1CCCCC1 KRDXTHSSNCTAGY-UHFFFAOYSA-N 0.000 description 1
DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
229920000571 Nylon 11 Polymers 0.000 description 1
229920000299 Nylon 12 Polymers 0.000 description 1
229920001007 Nylon 4 Polymers 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
239000012963 UV stabilizer Substances 0.000 description 1
230000009471 action Effects 0.000 description 1
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid group Chemical group C(CCCCC(=O)O)(=O)O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
238000013019 agitation Methods 0.000 description 1
229920003231 aliphatic polyamide Polymers 0.000 description 1
DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
235000020661 alpha-linolenic acid Nutrition 0.000 description 1
150000001412 amines Chemical group 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000007872 degassing Methods 0.000 description 1
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
239000012933 diacyl peroxide Substances 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
230000009477 glass transition Effects 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical group OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
150000003951 lactams Chemical group 0.000 description 1
235000020778 linoleic acid Nutrition 0.000 description 1
OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
229960004488 linolenic acid Drugs 0.000 description 1
KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
238000000691 measurement method Methods 0.000 description 1
230000000877 morphologic effect Effects 0.000 description 1
JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
NQPDZGIKBAWPEJ-UHFFFAOYSA-N pentanoic acid group Chemical group C(CCCC)(=O)O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
150000004978 peroxycarbonates Chemical class 0.000 description 1
239000006069 physical mixture Substances 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
238000006068 polycondensation reaction Methods 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
QROGIFZRVHSFLM-UHFFFAOYSA-N prop-1-enylbenzene Chemical class CC=CC1=CC=CC=C1 QROGIFZRVHSFLM-UHFFFAOYSA-N 0.000 description 1
239000007870 radical polymerization initiator Substances 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 description 1
GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
JZFHXRUVMKEOFG-UHFFFAOYSA-N tert-butyl dodecaneperoxoate Chemical compound CCCCCCCCCCCC(=O)OOC(C)(C)C JZFHXRUVMKEOFG-UHFFFAOYSA-N 0.000 description 1
238000003856 thermoforming Methods 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
- C08L5/06—Pectin; Derivatives thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Graft Or Block Polymers (AREA)
Organic Insulating Materials (AREA)
Laminated Bodies (AREA)
Fertilizers (AREA)
Processing Of Solid Wastes (AREA)

CS912169A 1990-07-12 1991-07-12 Thermoplastic material based on vinyl aromatic graft copolymer and polyamide CS216991A3 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT02092190A IT1246980B (it)	1990-07-12	1990-07-12	Composizioni termoplastiche a base di un copolimero graffato vinil aromatico e di una poliammide

Publications (1)

Publication Number	Publication Date
CS216991A3 true CS216991A3 (en)	1992-02-19

Family

ID=11174108

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS912169A CS216991A3 (en)	1990-07-12	1991-07-12	Thermoplastic material based on vinyl aromatic graft copolymer and polyamide

Country Status (11)

Country	Link
US (1)	US5304597A (de)
EP (1)	EP0471973B1 (de)
JP (1)	JPH04226560A (de)
KR (1)	KR920002682A (de)
AT (1)	ATE143401T1 (de)
CA (1)	CA2046756A1 (de)
CS (1)	CS216991A3 (de)
DE (1)	DE69122335T2 (de)
HU (1)	HU912342D0 (de)
IT (1)	IT1246980B (de)
NO (1)	NO912723L (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5274044A (en) *	1992-07-28	1993-12-28	General Electric Company	Graft copolymers containing (thioaromatic) alkyl acrylate rubber substrates
US7169853B2 (en) *	1997-10-23	2007-01-30	University Of Florida Research Foundation, Inc.	Polyamide graft copolymers
DE10259500A1 (de) *	2002-12-19	2004-07-01	Bayer Ag	Pfropfpolymerisate auf Basis von Ethylen-α-Olefin-Kautschuken und Verfahren zu ihrer Herstellung
US20050234172A1 (en) *	2004-04-19	2005-10-20	Fina Technology, Inc.	Random copolymer-impact copolymer blend
CN111560167B (zh) *	2020-06-08	2021-04-23	北京化工大学	一种抗紫外聚酰胺色母粒及功能纤维的制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4584344A (en) *	1980-11-03	1986-04-22	Monsanto Company	Tough thermoplastic nylon compositions
CA1299791C (en) *	1986-10-30	1992-04-28	Mitsui Chemicals Inc.	Thermoplastic resin composition
JP2541292B2 (ja) *	1988-08-23	1996-10-09	住友化学工業株式会社	耐衝撃性ポリアミド樹脂組成物の製造法

1990
- 1990-07-12 IT IT02092190A patent/IT1246980B/it active IP Right Grant
1991
- 1991-07-11 HU HU912342A patent/HU912342D0/hu unknown
- 1991-07-11 CA CA002046756A patent/CA2046756A1/en not_active Abandoned
- 1991-07-11 JP JP3170266A patent/JPH04226560A/ja active Pending
- 1991-07-11 EP EP91111577A patent/EP0471973B1/de not_active Expired - Lifetime
- 1991-07-11 DE DE69122335T patent/DE69122335T2/de not_active Expired - Fee Related
- 1991-07-11 AT AT91111577T patent/ATE143401T1/de not_active IP Right Cessation
- 1991-07-11 NO NO91912723A patent/NO912723L/no unknown
- 1991-07-12 CS CS912169A patent/CS216991A3/cs unknown
- 1991-07-12 KR KR1019910011933A patent/KR920002682A/ko not_active Withdrawn
1993
- 1993-07-08 US US08/087,469 patent/US5304597A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
CA2046756A1 (en)	1992-01-13
DE69122335T2 (de)	1997-02-06
HU912342D0 (en)	1991-12-30
NO912723D0 (no)	1991-07-11
IT9020921A0 (it)	1990-07-12
ATE143401T1 (de)	1996-10-15
EP0471973B1 (de)	1996-09-25
EP0471973A3 (en)	1993-01-07
US5304597A (en)	1994-04-19
JPH04226560A (ja)	1992-08-17
NO912723L (no)	1992-01-13
EP0471973A2 (de)	1992-02-26
KR920002682A (ko)	1992-02-28
IT9020921A1 (it)	1992-01-12
IT1246980B (it)	1994-12-12
DE69122335D1 (de)	1996-10-31

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KR960014557B1 (ko)	1996-10-16	변형 스티렌계 중합체, 이를 함유하는 조성물 및 그 제조방법
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JPS644529B2 (de)	1989-01-26
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JPH0971702A (ja)	1997-03-18	耐熱性熱可塑性樹脂組成物
CA1339040C (en)	1997-04-01	Grafted block copolymers and process for the preparation thereof