CS25992A3 - Process for reducing hexane obtained from ethylene co-polymers - Google Patents

Process for reducing hexane obtained from ethylene co-polymers Download PDF

Info

Publication number: CS25992A3
Authority: CS; Czechoslovakia
Prior art keywords: ethylene; catalyst; preparation; compound; copolymers according
Prior art date: 1991-01-30

Application number

CS92259A

Other languages

Czech (cs)

English (en)

Inventor

David Nicholas Ing Edwards

Kiu Hee Ing Lee

Alfred Ing Mendelsohn

Richard Gregg Shaw

Burkhard Eric Wagner

Original Assignee

Union Carbide Chem Plastic

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-01-30

Filing date

1992-01-29

Publication date

1992-08-12

1992-01-29 Application filed by Union Carbide Chem Plastic filed Critical Union Carbide Chem Plastic

1992-08-12 Publication of CS25992A3 publication Critical patent/CS25992A3/cs

Links

VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 title claims description 68
238000000034 method Methods 0.000 title claims description 30
229920001038 ethylene copolymer Polymers 0.000 title claims description 27
230000008569 process Effects 0.000 title claims description 26
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 59
239000003054 catalyst Substances 0.000 claims description 56
239000002245 particle Substances 0.000 claims description 53
150000001875 compounds Chemical class 0.000 claims description 33
239000000377 silicon dioxide Substances 0.000 claims description 29
239000012190 activator Substances 0.000 claims description 25
238000002360 preparation method Methods 0.000 claims description 18
150000003609 titanium compounds Chemical class 0.000 claims description 15
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 14
239000005977 Ethylene Substances 0.000 claims description 14
150000002681 magnesium compounds Chemical class 0.000 claims description 13
235000012239 silicon dioxide Nutrition 0.000 claims description 12
238000009826 distribution Methods 0.000 claims description 9
238000004519 manufacturing process Methods 0.000 claims description 9
230000002829 reductive effect Effects 0.000 claims description 7
239000004711 α-olefin Substances 0.000 claims description 7
229910052799 carbon Inorganic materials 0.000 claims description 6
239000011347 resin Substances 0.000 claims description 5
229920005989 resin Polymers 0.000 claims description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
150000001336 alkenes Chemical class 0.000 claims description 2
239000003795 chemical substances by application Substances 0.000 claims description 2
208000019901 Anxiety disease Diseases 0.000 claims 1
239000007792 gaseous phase Substances 0.000 claims 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
230000000379 polymerizing effect Effects 0.000 claims 1
125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims 1
239000000203 mixture Substances 0.000 description 57
239000007789 gas Substances 0.000 description 44
239000002243 precursor Substances 0.000 description 41
229920001577 copolymer Polymers 0.000 description 28
229920000642 polymer Polymers 0.000 description 27
238000006116 polymerization reaction Methods 0.000 description 24
239000010936 titanium Substances 0.000 description 23
238000006243 chemical reaction Methods 0.000 description 20
239000000047 product Substances 0.000 description 18
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 12
239000000178 monomer Substances 0.000 description 11
239000000243 solution Substances 0.000 description 11
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 10
230000004913 activation Effects 0.000 description 10
229910052719 titanium Inorganic materials 0.000 description 10
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 8
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
239000012530 fluid Substances 0.000 description 8
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 8
239000000463 material Substances 0.000 description 8
239000002904 solvent Substances 0.000 description 8
238000005243 fluidization Methods 0.000 description 7
239000000126 substance Substances 0.000 description 7
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
150000001338 aliphatic hydrocarbons Chemical group 0.000 description 6
-1 aromatic carboxylic acids Chemical class 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 6
239000001257 hydrogen Substances 0.000 description 6
229910052739 hydrogen Inorganic materials 0.000 description 6
239000011777 magnesium Substances 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 5
238000001035 drying Methods 0.000 description 5
229930195733 hydrocarbon Natural products 0.000 description 5
150000002430 hydrocarbons Chemical class 0.000 description 5
239000000155 melt Substances 0.000 description 5
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
229910052786 argon Inorganic materials 0.000 description 4
239000012876 carrier material Substances 0.000 description 4
229910052681 coesite Inorganic materials 0.000 description 4
229910052906 cristobalite Inorganic materials 0.000 description 4
239000003085 diluting agent Substances 0.000 description 4
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 4
238000004090 dissolution Methods 0.000 description 4
239000011261 inert gas Substances 0.000 description 4
238000002347 injection Methods 0.000 description 4
239000007924 injection Substances 0.000 description 4
239000011148 porous material Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
229910052682 stishovite Inorganic materials 0.000 description 4
238000012546 transfer Methods 0.000 description 4
229910052905 tridymite Inorganic materials 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
125000005234 alkyl aluminium group Chemical group 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000000284 extract Substances 0.000 description 3
230000036961 partial effect Effects 0.000 description 3
239000000843 powder Substances 0.000 description 3
238000005245 sintering Methods 0.000 description 3
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
150000003752 zinc compounds Chemical class 0.000 description 3
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
238000002835 absorbance Methods 0.000 description 2
230000009471 action Effects 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
125000005907 alkyl ester group Chemical group 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
239000012986 chain transfer agent Substances 0.000 description 2
230000008859 change Effects 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
238000002425 crystallisation Methods 0.000 description 2
230000008025 crystallization Effects 0.000 description 2
150000004292 cyclic ethers Chemical class 0.000 description 2
238000011161 development Methods 0.000 description 2
238000000605 extraction Methods 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
229910001629 magnesium chloride Inorganic materials 0.000 description 2
238000005259 measurement Methods 0.000 description 2
TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
238000002156 mixing Methods 0.000 description 2
238000005192 partition Methods 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
238000001556 precipitation Methods 0.000 description 2
238000000926 separation method Methods 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
239000000725 suspension Substances 0.000 description 2
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
238000009827 uniform distribution Methods 0.000 description 2
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical compound CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 description 1
ONIKNECPXCLUHT-UHFFFAOYSA-N 2-chlorobenzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1Cl ONIKNECPXCLUHT-UHFFFAOYSA-N 0.000 description 1
DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
229910004298 SiO 2 Inorganic materials 0.000 description 1
NIJJYAXOARWZEE-UHFFFAOYSA-N Valproic acid Chemical compound CCCC(C(O)=O)CCC NIJJYAXOARWZEE-UHFFFAOYSA-N 0.000 description 1
150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
150000005215 alkyl ethers Chemical class 0.000 description 1
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
238000003556 assay Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
238000007664 blowing Methods 0.000 description 1
238000009835 boiling Methods 0.000 description 1
238000004364 calculation method Methods 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000012159 carrier gas Substances 0.000 description 1
238000003889 chemical engineering Methods 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000001514 detection method Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
239000012467 final product Substances 0.000 description 1
125000001153 fluoro group Chemical group F* 0.000 description 1
239000011888 foil Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
238000012685 gas phase polymerization Methods 0.000 description 1
238000005227 gel permeation chromatography Methods 0.000 description 1
239000008187 granular material Substances 0.000 description 1
230000017525 heat dissipation Effects 0.000 description 1
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
238000007654 immersion Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
238000002955 isolation Methods 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 1
229910001623 magnesium bromide Inorganic materials 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
239000002480 mineral oil Substances 0.000 description 1
235000010446 mineral oil Nutrition 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
239000003380 propellant Substances 0.000 description 1
238000010926 purge Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000004064 recycling Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000010992 reflux Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
239000013049 sediment Substances 0.000 description 1
238000005029 sieve analysis Methods 0.000 description 1
229910052814 silicon oxide Inorganic materials 0.000 description 1
239000002002 slurry Substances 0.000 description 1
238000009987 spinning Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000010998 test method Methods 0.000 description 1
229950011008 tetrachloroethylene Drugs 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
238000013022 venting Methods 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
238000005406 washing Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CS92259A 1991-01-30 1992-01-29 Process for reducing hexane obtained from ethylene co-polymers CS25992A3 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US64780091A	1991-01-30	1991-01-30

Publications (1)

Publication Number	Publication Date
CS25992A3 true CS25992A3 (en)	1992-08-12

Family

ID=24598316

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS92259A CS25992A3 (en)	1991-01-30	1992-01-29	Process for reducing hexane obtained from ethylene co-polymers

Country Status (15)

Country	Link
EP (1)	EP0499093A3 (no)
JP (1)	JPH05155938A (no)
KR (1)	KR920014836A (no)
CN (1)	CN1064870A (no)
AR (1)	AR245736A1 (no)
AU (1)	AU1051592A (no)
BR (1)	BR9200278A (no)
CA (1)	CA2060249A1 (no)
CS (1)	CS25992A3 (no)
FI (1)	FI920405L (no)
HU (1)	HU9200271D0 (no)
NO (1)	NO920384L (no)
PL (1)	PL293331A1 (no)
PT (1)	PT100069A (no)
ZA (1)	ZA92619B (no)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6533988B2 (en)	1995-05-02	2003-03-18	Borealis Technology Oy	Rotational moulding process of ethylene polymers or copolymers having a controlled particle size and morphology
SG97919A1 (en)	1999-08-31	2003-08-20	Sumitomo Chemical Co	Ethylene-alpha-olefin copolymer and polyethylene composition
CN1194993C (zh)	2002-06-06	2005-03-30	中国石油化工股份有限公司	用于乙烯聚合的固体催化剂组分及其催化剂
SG121873A1 (en) *	2004-03-18	2006-05-26	China Petroleum & Chemical	A catalyst for ethylene polymerization, a process for preparing the same and use thereof
US20060281879A1 (en)	2005-06-13	2006-12-14	Univation Technologies, Llc	Catalyst compositions comprising small silica support materials and methods of use in polymerization reactions
US20070049711A1 (en)	2005-09-01	2007-03-01	Chi-I Kuo	Catalyst compositions comprising support materials having an improved particle-size distribution
EP3013870B1 (en) *	2013-06-24	2023-10-25	Saudi Basic Industries Corporation	Process for making a blow molded article based on high density polyethylene prepared with titanated chromium-based catalysts
CN104926971B (zh) *	2014-03-18	2017-03-29	中国石油化工股份有限公司	一种烯烃聚合固体催化剂及制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4405495A (en) *	1980-06-30	1983-09-20	Union Carbide Corporation	Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization
US4398005A (en) *	1981-01-23	1983-08-09	Gulf Research & Development Company	Novel polymerization catalyst and process for using same to polymerize olefins

1992
- 1992-01-29 EP EP19920101466 patent/EP0499093A3/en not_active Withdrawn
- 1992-01-29 AU AU10515/92A patent/AU1051592A/en not_active Abandoned
- 1992-01-29 NO NO92920384A patent/NO920384L/no unknown
- 1992-01-29 HU HU9200271A patent/HU9200271D0/hu unknown
- 1992-01-29 PT PT100069A patent/PT100069A/pt not_active Application Discontinuation
- 1992-01-29 CA CA002060249A patent/CA2060249A1/en not_active Abandoned
- 1992-01-29 BR BR929200278A patent/BR9200278A/pt unknown
- 1992-01-29 CN CN92101449A patent/CN1064870A/zh active Pending
- 1992-01-29 ZA ZA92619A patent/ZA92619B/xx unknown
- 1992-01-29 AR AR92321701A patent/AR245736A1/es active
- 1992-01-29 CS CS92259A patent/CS25992A3/cs unknown
- 1992-01-29 FI FI920405A patent/FI920405L/fi not_active Application Discontinuation
- 1992-01-29 KR KR1019920001267A patent/KR920014836A/ko not_active Withdrawn
- 1992-01-29 JP JP4036932A patent/JPH05155938A/ja not_active Withdrawn
- 1992-01-30 PL PL29333192A patent/PL293331A1/xx unknown

Also Published As

Publication number	Publication date
EP0499093A3 (en)	1992-09-23
PL293331A1 (en)	1993-08-09
ZA92619B (en)	1992-10-28
FI920405A0 (fi)	1992-01-29
FI920405A7 (fi)	1992-07-31
CN1064870A (zh)	1992-09-30
PT100069A (pt)	1993-05-31
EP0499093A2 (en)	1992-08-19
HU9200271D0 (en)	1992-05-28
NO920384D0 (no)	1992-01-29
CA2060249A1 (en)	1992-07-31
AU1051592A (en)	1992-08-06
NO920384L (no)	1992-07-31
FI920405L (fi)	1992-07-31
JPH05155938A (ja)	1993-06-22
BR9200278A (pt)	1992-10-06
AR245736A1 (es)	1994-02-28
KR920014836A (ko)	1992-08-25

Publication	Publication Date	Title
CA1190214A (en)	1985-07-09	Polymerization catalyst, process for preparing, and use for ethylene polymerization
EP0004645B1 (en)	1984-12-19	Low pressure preparation of ethylene copolymers in fluid bed reactor
FI70418C (fi)	1986-09-19	Katalytiskt foerfarande foer polymerisation av etylen samt en foerblandning foer den enligt foerfarandet anvaenda katalysatorn
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