CS268812B2 - Method of olefins polymerization - Google Patents

Method of olefins polymerization Download PDF

Info

Publication number: CS268812B2
Authority: CS; Czechoslovakia
Prior art keywords: component; carbon atoms; solid product; cir; solid
Prior art date: 1985-03-14

Application number

CS861747A

Other languages

Czech (cs)

English (en)

Other versions

CS174786A2 (en

Inventor

Masato Harada

Makoto Iijima

Noriaki Saito

Original Assignee

Chisso Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-03-14

Filing date

1986-03-13

Publication date

1990-04-11

1986-03-13 Application filed by Chisso Corp filed Critical Chisso Corp

1989-08-14 Publication of CS174786A2 publication Critical patent/CS174786A2/cs

1990-04-11 Publication of CS268812B2 publication Critical patent/CS268812B2/cs

Links

150000001336 alkenes Chemical class 0.000 title claims abstract description 10
238000006116 polymerization reaction Methods 0.000 title claims description 27
238000000034 method Methods 0.000 title abstract description 26
-1 orthotitanic acid ester Chemical class 0.000 claims abstract description 70
239000012265 solid product Substances 0.000 claims abstract description 60
239000003054 catalyst Substances 0.000 claims abstract description 26
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 24
229930195733 hydrocarbon Natural products 0.000 claims abstract description 24
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 24
150000002148 esters Chemical class 0.000 claims abstract description 20
239000002904 solvent Substances 0.000 claims abstract description 16
238000002156 mixing Methods 0.000 claims abstract description 15
239000011949 solid catalyst Substances 0.000 claims abstract description 11
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
125000001931 aliphatic group Chemical group 0.000 claims abstract description 7
229920006395 saturated elastomer Polymers 0.000 claims abstract description 4
229910052720 vanadium Inorganic materials 0.000 claims abstract description 4
125000004432 carbon atom Chemical group C* 0.000 claims description 47
229920000642 polymer Polymers 0.000 claims description 37
239000000047 product Substances 0.000 claims description 19
239000010936 titanium Substances 0.000 claims description 17
125000000217 alkyl group Chemical group 0.000 claims description 16
239000004743 Polypropylene Substances 0.000 claims description 15
229920001155 polypropylene Polymers 0.000 claims description 15
238000012360 testing method Methods 0.000 claims description 14
239000000460 chlorine Substances 0.000 claims description 13
229910052801 chlorine Inorganic materials 0.000 claims description 13
125000001309 chloro group Chemical group Cl* 0.000 claims description 13
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 12
238000004519 manufacturing process Methods 0.000 claims description 11
229910052719 titanium Inorganic materials 0.000 claims description 11
150000005840 aryl radicals Chemical class 0.000 claims description 10
230000000052 comparative effect Effects 0.000 claims description 8
125000000753 cycloalkyl group Chemical group 0.000 claims description 6
239000011777 magnesium Substances 0.000 claims description 6
229910052749 magnesium Inorganic materials 0.000 claims description 6
229910052710 silicon Inorganic materials 0.000 claims description 6
239000010703 silicon Substances 0.000 claims description 6
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
229910052782 aluminium Inorganic materials 0.000 claims description 4
239000000843 powder Substances 0.000 claims description 4
125000004429 atom Chemical group 0.000 claims description 2
229910052799 carbon Inorganic materials 0.000 claims description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 2
229910052794 bromium Chemical group 0.000 claims 2
150000001924 cycloalkanes Chemical class 0.000 claims 1
125000002370 organoaluminium group Chemical group 0.000 claims 1
150000001875 compounds Chemical class 0.000 abstract description 31
229920000098 polyolefin Polymers 0.000 abstract description 23
238000006243 chemical reaction Methods 0.000 abstract description 18
150000003377 silicon compounds Chemical class 0.000 abstract description 16
239000002253 acid Substances 0.000 abstract description 4
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
230000000379 polymerizing effect Effects 0.000 abstract 1
150000003608 titanium Chemical class 0.000 abstract 1
125000005287 vanadyl group Chemical group 0.000 abstract 1
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 33
239000002245 particle Substances 0.000 description 26
239000000203 mixture Substances 0.000 description 24
239000007787 solid Substances 0.000 description 16
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 13
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 12
239000000725 suspension Substances 0.000 description 9
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 8
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 8
238000003756 stirring Methods 0.000 description 8
239000007795 chemical reaction product Substances 0.000 description 7
239000007789 gas Substances 0.000 description 7
FHUODBDRWMIBQP-UHFFFAOYSA-N Ethyl p-anisate Chemical compound CCOC(=O)C1=CC=C(OC)C=C1 FHUODBDRWMIBQP-UHFFFAOYSA-N 0.000 description 6
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 6
229920001577 copolymer Polymers 0.000 description 6
MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 6
239000012456 homogeneous solution Substances 0.000 description 6
JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 6
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 6
238000005406 washing Methods 0.000 description 6
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
238000009826 distribution Methods 0.000 description 5
238000012685 gas phase polymerization Methods 0.000 description 5
230000009965 odorless effect Effects 0.000 description 5
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 5
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
PQLAYKMGZDUDLQ-UHFFFAOYSA-K aluminium bromide Chemical compound Br[Al](Br)Br PQLAYKMGZDUDLQ-UHFFFAOYSA-K 0.000 description 4
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
238000000605 extraction Methods 0.000 description 4
239000003350 kerosene Substances 0.000 description 4
239000007788 liquid Substances 0.000 description 4
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 4
BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 4
239000005049 silicon tetrachloride Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
239000004711 α-olefin Substances 0.000 description 4
CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
239000012298 atmosphere Substances 0.000 description 3
YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 description 3
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 3
238000005469 granulation Methods 0.000 description 3
230000003179 granulation Effects 0.000 description 3
239000000463 material Substances 0.000 description 3
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
230000035484 reaction time Effects 0.000 description 3
229930195734 saturated hydrocarbon Natural products 0.000 description 3
CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 3
NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 2
UBOXGVDOUJQMTN-UHFFFAOYSA-N 1,1,2-trichloroethane Chemical compound ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 2
RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
WOFPPJOZXUTRAU-UHFFFAOYSA-N 2-Ethyl-1-hexanol Natural products CCCCC(O)CCC WOFPPJOZXUTRAU-UHFFFAOYSA-N 0.000 description 2
FZXRXKLUIMKDEL-UHFFFAOYSA-N 2-Methylpropyl propanoate Chemical compound CCC(=O)OCC(C)C FZXRXKLUIMKDEL-UHFFFAOYSA-N 0.000 description 2
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
238000003915 air pollution Methods 0.000 description 2
238000009835 boiling Methods 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 description 2
AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
238000001035 drying Methods 0.000 description 2
RSIHJDGMBDPTIM-UHFFFAOYSA-N ethoxy(trimethyl)silane Chemical compound CCO[Si](C)(C)C RSIHJDGMBDPTIM-UHFFFAOYSA-N 0.000 description 2
FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 2
230000005484 gravity Effects 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
POPACFLNWGUDSR-UHFFFAOYSA-N methoxy(trimethyl)silane Chemical compound CO[Si](C)(C)C POPACFLNWGUDSR-UHFFFAOYSA-N 0.000 description 2
QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
150000002899 organoaluminium compounds Chemical class 0.000 description 2
239000012071 phase Substances 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
AIFMYMZGQVTROK-UHFFFAOYSA-N silicon tetrabromide Chemical compound Br[Si](Br)(Br)Br AIFMYMZGQVTROK-UHFFFAOYSA-N 0.000 description 2
238000007711 solidification Methods 0.000 description 2
230000008023 solidification Effects 0.000 description 2
239000012798 spherical particle Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
HUZZQXYTKNNCOU-UHFFFAOYSA-N triethyl(methoxy)silane Chemical compound CC[Si](CC)(CC)OC HUZZQXYTKNNCOU-UHFFFAOYSA-N 0.000 description 2
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
JAGYXYUAYDLKNO-GGWOSOGESA-N (2e,5e)-hepta-2,5-diene Chemical compound C\C=C\C\C=C\C JAGYXYUAYDLKNO-GGWOSOGESA-N 0.000 description 1
YKYIFUROKBDHCY-ONEGZZNKSA-N (e)-4-ethoxy-1,1,1-trifluorobut-3-en-2-one Chemical group CCO\C=C\C(=O)C(F)(F)F YKYIFUROKBDHCY-ONEGZZNKSA-N 0.000 description 1
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
SPZCXVPOFSVCFS-UHFFFAOYSA-N 1,2-dichloroethane;tetrachloromethane Chemical compound ClCCCl.ClC(Cl)(Cl)Cl SPZCXVPOFSVCFS-UHFFFAOYSA-N 0.000 description 1
YIWGJFPJRAEKMK-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yl)-3-methyl-8-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carbonyl]-1,3,8-triazaspiro[4.5]decane-2,4-dione Chemical compound CN1C(=O)N(c2ccc3n[nH]nc3c2)C2(CCN(CC2)C(=O)c2cnc(NCc3cccc(OC(F)(F)F)c3)nc2)C1=O YIWGJFPJRAEKMK-UHFFFAOYSA-N 0.000 description 1
HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
KTXWGMUMDPYXNN-UHFFFAOYSA-N 2-ethylhexan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCC(CC)C[O-].CCCCC(CC)C[O-].CCCCC(CC)C[O-].CCCCC(CC)C[O-] KTXWGMUMDPYXNN-UHFFFAOYSA-N 0.000 description 1
KVMAQXBSRFDBSI-UHFFFAOYSA-N 2-methoxyethoxy(dimethyl)silane Chemical compound COCCO[SiH](C)C KVMAQXBSRFDBSI-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
ZQVKTHRQIXSMGY-UHFFFAOYSA-M 4-ethylbenzoate Chemical compound CCC1=CC=C(C([O-])=O)C=C1 ZQVKTHRQIXSMGY-UHFFFAOYSA-M 0.000 description 1
101000623895 Bos taurus Mucin-15 Proteins 0.000 description 1
RMUHMURYGITZFI-UHFFFAOYSA-K CCCCO[Ti](Br)(Br)Br Chemical compound CCCCO[Ti](Br)(Br)Br RMUHMURYGITZFI-UHFFFAOYSA-K 0.000 description 1
SMRBVBHMRPWMNX-UHFFFAOYSA-M CCO[Ti](Br)(OCC)OCC Chemical compound CCO[Ti](Br)(OCC)OCC SMRBVBHMRPWMNX-UHFFFAOYSA-M 0.000 description 1
NTWOIGOPFDMZAE-UHFFFAOYSA-M CCO[Ti](Cl)(OCC)OCC Chemical compound CCO[Ti](Cl)(OCC)OCC NTWOIGOPFDMZAE-UHFFFAOYSA-M 0.000 description 1
YPYHKBILABGYMK-UHFFFAOYSA-K C[O-].[Cl-].[Cl-].[Cl-].[V+4] Chemical compound C[O-].[Cl-].[Cl-].[Cl-].[V+4] YPYHKBILABGYMK-UHFFFAOYSA-K 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
241001436793 Meru Species 0.000 description 1
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
229910006293 Si—N—O Inorganic materials 0.000 description 1
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 description 1
229910021552 Vanadium(IV) chloride Inorganic materials 0.000 description 1
BBXQECAADFELLQ-UHFFFAOYSA-L [Br-].C(C)O[V+2](OCC)OCC.[Br-] Chemical compound [Br-].C(C)O[V+2](OCC)OCC.[Br-] BBXQECAADFELLQ-UHFFFAOYSA-L 0.000 description 1
TUVACOWGCLLPBM-UHFFFAOYSA-L [Br-].[Br-].C(C)O[V+2]OCC Chemical compound [Br-].[Br-].C(C)O[V+2]OCC TUVACOWGCLLPBM-UHFFFAOYSA-L 0.000 description 1
CJWANOYUFBSCHS-UHFFFAOYSA-L [Br-].[Br-].CCO[Ti+2]OCC Chemical compound [Br-].[Br-].CCO[Ti+2]OCC CJWANOYUFBSCHS-UHFFFAOYSA-L 0.000 description 1
RWIHNAXETZYVLX-UHFFFAOYSA-K [Br-].[Br-].[Br-].C(C)O[V+3] Chemical compound [Br-].[Br-].[Br-].C(C)O[V+3] RWIHNAXETZYVLX-UHFFFAOYSA-K 0.000 description 1
UDROSRLVOUGOBB-UHFFFAOYSA-L [Cl-].C(C)O[V+2](OCC)OCC.[Cl-] Chemical compound [Cl-].C(C)O[V+2](OCC)OCC.[Cl-] UDROSRLVOUGOBB-UHFFFAOYSA-L 0.000 description 1
QSMLJCIHMPUAQG-UHFFFAOYSA-L [Cl-].[Cl-].CCCO[Ti+2]OCCC Chemical compound [Cl-].[Cl-].CCCO[Ti+2]OCCC QSMLJCIHMPUAQG-UHFFFAOYSA-L 0.000 description 1
FJRLGAXBJJJBNP-UHFFFAOYSA-L [Cl-].[Cl-].CCO[V++]OCC Chemical compound [Cl-].[Cl-].CCO[V++]OCC FJRLGAXBJJJBNP-UHFFFAOYSA-L 0.000 description 1
FSQYIVHUQMXNET-UHFFFAOYSA-L [Cl-].[Cl-].CO[V+2]OC Chemical compound [Cl-].[Cl-].CO[V+2]OC FSQYIVHUQMXNET-UHFFFAOYSA-L 0.000 description 1
XQHQKPNUNKDJOU-UHFFFAOYSA-K [Cl-].[Cl-].[Cl-].CCCCCCO[Ti+3] Chemical compound [Cl-].[Cl-].[Cl-].CCCCCCO[Ti+3] XQHQKPNUNKDJOU-UHFFFAOYSA-K 0.000 description 1
GKQZBJMXIUKBGB-UHFFFAOYSA-K [Cl-].[Cl-].[Cl-].CCCO[Ti+3] Chemical compound [Cl-].[Cl-].[Cl-].CCCO[Ti+3] GKQZBJMXIUKBGB-UHFFFAOYSA-K 0.000 description 1
FVDJHRVKTKBNFV-UHFFFAOYSA-K [O-]CC.[Cl-].[Cl-].[Cl-].[V+4] Chemical compound [O-]CC.[Cl-].[Cl-].[Cl-].[V+4] FVDJHRVKTKBNFV-UHFFFAOYSA-K 0.000 description 1
HIVIJGFXNOOEAS-UHFFFAOYSA-K [O-]CCCC.[Cl-].[Cl-].[Cl-].[V+4] Chemical compound [O-]CCCC.[Cl-].[Cl-].[Cl-].[V+4] HIVIJGFXNOOEAS-UHFFFAOYSA-K 0.000 description 1
KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
238000005275 alloying Methods 0.000 description 1
RMRFFCXPLWYOOY-UHFFFAOYSA-N allyl radical Chemical compound [CH2]C=C RMRFFCXPLWYOOY-UHFFFAOYSA-N 0.000 description 1
229920006125 amorphous polymer Polymers 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
DULCUDSUACXJJC-UHFFFAOYSA-N benzeneacetic acid ethyl ester Natural products CCOC(=O)CC1=CC=CC=C1 DULCUDSUACXJJC-UHFFFAOYSA-N 0.000 description 1
AOKMFXQCRBQJOP-UHFFFAOYSA-N benzyl trimethylsilyl ether Chemical compound C[Si](C)(C)OCC1=CC=CC=C1 AOKMFXQCRBQJOP-UHFFFAOYSA-N 0.000 description 1
CPLASELWOOUNGW-UHFFFAOYSA-N benzyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)CC1=CC=CC=C1 CPLASELWOOUNGW-UHFFFAOYSA-N 0.000 description 1
GQVVQDJHRQBZNG-UHFFFAOYSA-N benzyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CC1=CC=CC=C1 GQVVQDJHRQBZNG-UHFFFAOYSA-N 0.000 description 1
GSKAIYAPIGRGRZ-UHFFFAOYSA-N benzyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)CC1=CC=CC=C1 GSKAIYAPIGRGRZ-UHFFFAOYSA-N 0.000 description 1
LGSNSXWSNMARLH-UHFFFAOYSA-N butan-1-ol titanium Chemical compound C(CCC)O.[Ti].C(CCC)O LGSNSXWSNMARLH-UHFFFAOYSA-N 0.000 description 1
APKYUQFPWXLNFH-UHFFFAOYSA-M butan-1-olate titanium(4+) chloride Chemical compound [Cl-].CCCCO[Ti+](OCCCC)OCCCC APKYUQFPWXLNFH-UHFFFAOYSA-M 0.000 description 1
DEFMLLQRTVNBOF-UHFFFAOYSA-K butan-1-olate;trichlorotitanium(1+) Chemical compound [Cl-].[Cl-].[Cl-].CCCCO[Ti+3] DEFMLLQRTVNBOF-UHFFFAOYSA-K 0.000 description 1
239000001273 butane Substances 0.000 description 1
OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
XGZGKDQVCBHSGI-UHFFFAOYSA-N butyl(triethoxy)silane Chemical compound CCCC[Si](OCC)(OCC)OCC XGZGKDQVCBHSGI-UHFFFAOYSA-N 0.000 description 1
SXPLZNMUBFBFIA-UHFFFAOYSA-N butyl(trimethoxy)silane Chemical compound CCCC[Si](OC)(OC)OC SXPLZNMUBFBFIA-UHFFFAOYSA-N 0.000 description 1
SHOVVTSKTTYFGP-UHFFFAOYSA-L butylaluminum(2+);dichloride Chemical compound CCCC[Al](Cl)Cl SHOVVTSKTTYFGP-UHFFFAOYSA-L 0.000 description 1
150000001733 carboxylic acid esters Chemical class 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
GJDATTLXPMXFQF-UHFFFAOYSA-M chloro(dicyclohexyl)alumane Chemical compound [Cl-].C1CCCCC1[Al+]C1CCCCC1 GJDATTLXPMXFQF-UHFFFAOYSA-M 0.000 description 1
ISFMCQATCMRFPY-UHFFFAOYSA-M chloro(diphenyl)alumane Chemical compound [Cl-].C=1C=CC=CC=1[Al+]C1=CC=CC=C1 ISFMCQATCMRFPY-UHFFFAOYSA-M 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
RYDAFAXZTLPDEJ-UHFFFAOYSA-N cyclopropylmethoxy(dimethyl)silane Chemical compound C[SiH](OCC1CC1)C RYDAFAXZTLPDEJ-UHFFFAOYSA-N 0.000 description 1
VJRUISVXILMZSL-UHFFFAOYSA-M dibutylalumanylium;chloride Chemical compound CCCC[Al](Cl)CCCC VJRUISVXILMZSL-UHFFFAOYSA-M 0.000 description 1
125000003963 dichloro group Chemical group Cl* 0.000 description 1
KWHPGQVFPWGFMG-UHFFFAOYSA-N diethoxy-ethyl-methoxysilane Chemical compound CCO[Si](CC)(OC)OCC KWHPGQVFPWGFMG-UHFFFAOYSA-N 0.000 description 1
MNFGEHQPOWJJBH-UHFFFAOYSA-N diethoxy-methyl-phenylsilane Chemical compound CCO[Si](C)(OCC)C1=CC=CC=C1 MNFGEHQPOWJJBH-UHFFFAOYSA-N 0.000 description 1
VSYLGGHSEIWGJV-UHFFFAOYSA-N diethyl(dimethoxy)silane Chemical compound CC[Si](CC)(OC)OC VSYLGGHSEIWGJV-UHFFFAOYSA-N 0.000 description 1
XRMDNKCCJBREJR-UHFFFAOYSA-N diethyl-methoxy-methylsilane Chemical compound CC[Si](C)(CC)OC XRMDNKCCJBREJR-UHFFFAOYSA-N 0.000 description 1
238000007865 diluting Methods 0.000 description 1
JBGFFDWOMCOPIV-UHFFFAOYSA-N dimethoxy(prop-1-enyl)silane Chemical compound CO[SiH](OC)C=CC JBGFFDWOMCOPIV-UHFFFAOYSA-N 0.000 description 1
CVQVSVBUMVSJES-UHFFFAOYSA-N dimethoxy-methyl-phenylsilane Chemical group CO[Si](C)(OC)C1=CC=CC=C1 CVQVSVBUMVSJES-UHFFFAOYSA-N 0.000 description 1
KSPUBJZRDZWSPU-UHFFFAOYSA-N dimethyl-bis(phenylmethoxy)silane Chemical compound C=1C=CC=CC=1CO[Si](C)(C)OCC1=CC=CC=C1 KSPUBJZRDZWSPU-UHFFFAOYSA-N 0.000 description 1
JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
DBIUYPYENULRPV-UHFFFAOYSA-N diphenyl(2-phenylethoxy)silane Chemical compound C1(=CC=CC=C1)[SiH](OCCC1=CC=CC=C1)C1=CC=CC=C1 DBIUYPYENULRPV-UHFFFAOYSA-N 0.000 description 1
ZMXPNWBFRPIZFV-UHFFFAOYSA-M dipropylalumanylium;chloride Chemical compound [Cl-].CCC[Al+]CCC ZMXPNWBFRPIZFV-UHFFFAOYSA-M 0.000 description 1
210000005069 ears Anatomy 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000003912 environmental pollution Methods 0.000 description 1
UHSDHNXHBQDMMH-UHFFFAOYSA-L ethanolate;titanium(4+);dichloride Chemical compound CCO[Ti](Cl)(Cl)OCC UHSDHNXHBQDMMH-UHFFFAOYSA-L 0.000 description 1
FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
DFJDZTPFNSXNAX-UHFFFAOYSA-N ethoxy(triethyl)silane Chemical compound CCO[Si](CC)(CC)CC DFJDZTPFNSXNAX-UHFFFAOYSA-N 0.000 description 1
WPJVMPQSTHTWKF-UHFFFAOYSA-N ethoxy-dimethoxy-methylsilane Chemical compound CCO[Si](C)(OC)OC WPJVMPQSTHTWKF-UHFFFAOYSA-N 0.000 description 1
RAQWTXJGPUSSID-UHFFFAOYSA-N ethoxy-ethyl-dimethoxysilane Chemical compound CCO[Si](CC)(OC)OC RAQWTXJGPUSSID-UHFFFAOYSA-N 0.000 description 1
HTSRFYSEWIPFNI-UHFFFAOYSA-N ethyl-dimethoxy-methylsilane Chemical compound CC[Si](C)(OC)OC HTSRFYSEWIPFNI-UHFFFAOYSA-N 0.000 description 1
SUHRFYWSDBWMFS-UHFFFAOYSA-N ethyl-methoxy-dimethylsilane Chemical compound CC[Si](C)(C)OC SUHRFYWSDBWMFS-UHFFFAOYSA-N 0.000 description 1
IHKDRIREOZWRQU-UHFFFAOYSA-N ethyl-methyl-phenoxy-phenylsilane Chemical compound C=1C=CC=CC=1[Si](C)(CC)OC1=CC=CC=C1 IHKDRIREOZWRQU-UHFFFAOYSA-N 0.000 description 1
SNICGNCQFDTQKP-UHFFFAOYSA-N ethyl-methyl-phenylmethoxysilane Chemical compound C[SiH](OCC1=CC=CC=C1)CC SNICGNCQFDTQKP-UHFFFAOYSA-N 0.000 description 1
GVCFCTGXJJBELQ-UHFFFAOYSA-N ethyl-tris(phenylmethoxy)silane Chemical compound C=1C=CC=CC=1CO[Si](OCC=1C=CC=CC=1)(CC)OCC1=CC=CC=C1 GVCFCTGXJJBELQ-UHFFFAOYSA-N 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
229940011051 isopropyl acetate Drugs 0.000 description 1
GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
230000007774 longterm Effects 0.000 description 1
OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 1
229910001623 magnesium bromide Inorganic materials 0.000 description 1
238000000691 measurement method Methods 0.000 description 1
QZCOACXZLDQHLQ-UHFFFAOYSA-M methanolate titanium(4+) chloride Chemical compound [Cl-].[Ti+4].[O-]C.[O-]C.[O-]C QZCOACXZLDQHLQ-UHFFFAOYSA-M 0.000 description 1
229940095102 methyl benzoate Drugs 0.000 description 1
DDIZAANNODHTRB-UHFFFAOYSA-N methyl p-anisate Chemical compound COC(=O)C1=CC=C(OC)C=C1 DDIZAANNODHTRB-UHFFFAOYSA-N 0.000 description 1
PAARSARXSVEONG-UHFFFAOYSA-N methyl-bis[(5-methyl-2-propan-2-ylcyclohexyl)oxy]-phenylsilane Chemical group CC(C)C1CCC(C)CC1O[Si](C)(C=1C=CC=CC=1)OC1C(C(C)C)CCC(C)C1 PAARSARXSVEONG-UHFFFAOYSA-N 0.000 description 1
GEIHDEVWPDTQIM-UHFFFAOYSA-N methyl-tris(phenylmethoxy)silane Chemical compound C=1C=CC=CC=1CO[Si](OCC=1C=CC=CC=1)(C)OCC1=CC=CC=C1 GEIHDEVWPDTQIM-UHFFFAOYSA-N 0.000 description 1
238000003801 milling Methods 0.000 description 1
239000003607 modifier Substances 0.000 description 1
239000000178 monomer Substances 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
BNZYBNYNPXKWCM-UHFFFAOYSA-N phenyl 4-methoxybenzoate Chemical compound C1=CC(OC)=CC=C1C(=O)OC1=CC=CC=C1 BNZYBNYNPXKWCM-UHFFFAOYSA-N 0.000 description 1
229940049953 phenylacetate Drugs 0.000 description 1
WLJVXDMOQOGPHL-UHFFFAOYSA-N phenylacetic acid Chemical compound OC(=O)CC1=CC=CC=C1 WLJVXDMOQOGPHL-UHFFFAOYSA-N 0.000 description 1
MCSINKKTEDDPNK-UHFFFAOYSA-N propyl propionate Chemical compound CCCOC(=O)CC MCSINKKTEDDPNK-UHFFFAOYSA-N 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
238000011160 research Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
150000005846 sugar alcohols Polymers 0.000 description 1
UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 1
VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 1
SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
ZIYNWDQDHKSRCE-UHFFFAOYSA-N tricyclohexylalumane Chemical compound C1CCCCC1[Al](C1CCCCC1)C1CCCCC1 ZIYNWDQDHKSRCE-UHFFFAOYSA-N 0.000 description 1
PYLGJXLKFZZEBJ-UHFFFAOYSA-N tricyclopentylalumane Chemical compound C1CCCC1[Al](C1CCCC1)C1CCCC1 PYLGJXLKFZZEBJ-UHFFFAOYSA-N 0.000 description 1
DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 description 1
150000003682 vanadium compounds Chemical class 0.000 description 1
JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 description 1
239000008096 xylene Substances 0.000 description 1
150000003738 xylenes Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/68—Vanadium, niobium, tantalum or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

CS861747A 1985-03-14 1986-03-13 Method of olefins polymerization CS268812B2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP60051507A JPH0617400B2 (ja)	1985-03-14	1985-03-14	オレフインの重合方法

Publications (2)

Publication Number	Publication Date
CS174786A2 CS174786A2 (en)	1989-08-14
CS268812B2 true CS268812B2 (en)	1990-04-11

Family

ID=12888908

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS861747A CS268812B2 (en)	1985-03-14	1986-03-13	Method of olefins polymerization

Country Status (4)

Country	Link
US (1)	US4831091A (ja)
JP (1)	JPH0617400B2 (ja)
KR (1)	KR910004496B1 (ja)
CS (1)	CS268812B2 (ja)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4999356A (en) *	1987-08-07	1991-03-12	Hoechst-Roussel Pharmaceuticals, Inc.	1-phenyl-3-(1-piperazinyl)-1H-indazoles
US4990478A (en) *	1989-09-21	1991-02-05	Amoco Corporation	Silane-modified supported polyolefin catalyst to produce a broadened molecular weight distribution product
EP0578470B1 (en) *	1992-07-06	1998-10-07	Nippon Oil Co. Ltd.	Process for preparing polyolefins
US6863177B2 (en)	1996-05-13	2005-03-08	Matsushita Electric Industrial Co., Ltd.	Electrically conductive propylene resin composition and part-housing container
JP3688078B2 (ja) *	1996-11-20	2005-08-24	三井化学株式会社	オレフィン重合用触媒、予備重合触媒、オレフィンの重合方法
US20020045190A1 (en) *	2000-07-11	2002-04-18	Wilson Robert B.	Encoding methods using up-converting phosphors for high-throughput screening of catalysts
KR100543429B1 (ko) *	2002-12-11	2006-01-20	삼성토탈 주식회사	초고분자량 폴리에틸렌 중합용 촉매 및 이를 이용한초고분자량 폴리에틸렌의 제조방법

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4187196A (en) *	1971-06-25	1980-02-05	Montedison S.P.A.	Process for the stereoregular polymerization of alpha-olefins
JPS5883006A (ja) *	1981-11-13	1983-05-18	Mitsui Petrochem Ind Ltd	オレフインの重合方法
IT1190683B (it) *	1982-02-12	1988-02-24	Montedison Spa	Componenti e catalizzatori per la polimerizzazione di olefine
IT1190681B (it) *	1982-02-12	1988-02-24	Montedison Spa	Componenti e catalizzatori per la polimerizzazione di olefine
JPH0730128B2 (ja) *	1984-10-04	1995-04-05	チッソ株式会社	オレフィン重合用固体触媒成分の製造法

1985
- 1985-03-14 JP JP60051507A patent/JPH0617400B2/ja not_active Expired - Lifetime
1986
- 1986-02-28 KR KR1019860001409A patent/KR910004496B1/ko not_active Expired
- 1986-03-13 CS CS861747A patent/CS268812B2/cs unknown
1988
- 1988-08-01 US US07/226,729 patent/US4831091A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
KR910004496B1 (ko)	1991-07-05
JPH0617400B2 (ja)	1994-03-09
KR860007293A (ko)	1986-10-10
US4831091A (en)	1989-05-16
CS174786A2 (en)	1989-08-14
JPS61209207A (ja)	1986-09-17

Publication	Publication Date	Title
EP0856013B1 (en)	2000-07-19	Morphology-controlled olefin polymerization catalyst formed from an emulsion
WO2006096621A2 (en)	2006-09-14	Propylene polymer catalyst donor component
WO2006110234A2 (en)	2006-10-19	Propylene polymer catalyst donor component
US7019097B2 (en)	2006-03-28	Process for the (co)polymerization of ethylene
CN1177868C (zh)	2004-12-01	镁/钛烷氧基配合物以及由此制得的聚合催化剂
JPH072791B2 (ja)	1995-01-18	オレフイン重合体製造法
JPS62104810A (ja)	1987-05-15	オレフイン重合体の製造方法
CS268812B2 (en)	1990-04-11	Method of olefins polymerization
JP2952695B2 (ja)	1999-09-27	立体規則性ポリオレフィンの製造方法
JPH0655787B2 (ja)	1994-07-27	ポリオレフイン製造法
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