CS4691A2 - Catalyst's component and catalyst for olefins polymerization - Google Patents

Catalyst's component and catalyst for olefins polymerization Download PDF

Info

Publication number: CS4691A2
Authority: CS; Czechoslovakia
Prior art keywords: olefin polymerization; polymerization catalyst; butyl; catalyst component; formula
Prior art date: 1990-01-10

Application number

CS9146A

Other languages

Czech (cs)

English (en)

Inventor

Giampiero Dr Morini

Enrico Albizzati

Umberto Dr Giannini

Luisa Barino

Raimondo Scordamaglia

Elisabetta Dr Barbassa

Original Assignee

Himont Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-01-10

Filing date

1991-01-10

Publication date

1991-09-15

1991-01-10 Application filed by Himont Inc filed Critical Himont Inc

1991-09-15 Publication of CS4691A2 publication Critical patent/CS4691A2/cs

Links

239000003054 catalyst Substances 0.000 title claims description 37
150000001336 alkenes Chemical class 0.000 title claims description 18
238000006116 polymerization reaction Methods 0.000 title claims description 13
-1 titanium halide Chemical class 0.000 claims description 46
238000006243 chemical reaction Methods 0.000 claims description 15
239000011777 magnesium Substances 0.000 claims description 15
150000003961 organosilicon compounds Chemical class 0.000 claims description 15
229910052749 magnesium Inorganic materials 0.000 claims description 14
150000001875 compounds Chemical class 0.000 claims description 12
125000000217 alkyl group Chemical group 0.000 claims description 10
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 10
239000007787 solid Substances 0.000 claims description 10
125000003118 aryl group Chemical group 0.000 claims description 9
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 8
239000002685 polymerization catalyst Substances 0.000 claims description 8
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 7
238000000605 extraction Methods 0.000 claims description 6
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
239000010936 titanium Substances 0.000 claims description 6
125000000753 cycloalkyl group Chemical group 0.000 claims description 5
229910052719 titanium Inorganic materials 0.000 claims description 5
125000002877 alkyl aryl group Chemical group 0.000 claims description 4
125000003710 aryl alkyl group Chemical group 0.000 claims description 4
229910001629 magnesium chloride Inorganic materials 0.000 claims description 4
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 3
229910052736 halogen Inorganic materials 0.000 claims description 3
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 3
XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 3
125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 claims description 3
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
229910052698 phosphorus Inorganic materials 0.000 claims description 3
229910052717 sulfur Inorganic materials 0.000 claims description 3
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 3
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
229910052760 oxygen Inorganic materials 0.000 claims description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 2
150000002367 halogens Chemical class 0.000 claims 2
125000001183 hydrocarbyl group Chemical group 0.000 claims 2
125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 claims 1
229910052757 nitrogen Inorganic materials 0.000 claims 1
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 18
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 16
238000000034 method Methods 0.000 description 12
229920000642 polymer Polymers 0.000 description 11
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 11
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 11
239000004215 Carbon black (E152) Substances 0.000 description 7
229930195733 hydrocarbon Natural products 0.000 description 7
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
150000002430 hydrocarbons Chemical class 0.000 description 6
229910052739 hydrogen Inorganic materials 0.000 description 6
125000004432 carbon atom Chemical group C* 0.000 description 5
150000002148 esters Chemical class 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
239000000203 mixture Substances 0.000 description 5
239000011347 resin Substances 0.000 description 5
229920005989 resin Polymers 0.000 description 5
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
239000005977 Ethylene Substances 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000000178 monomer Substances 0.000 description 4
239000012265 solid product Substances 0.000 description 4
230000000707 stereoselective effect Effects 0.000 description 4
239000000126 substance Substances 0.000 description 4
150000003609 titanium compounds Chemical class 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
125000005234 alkyl aluminium group Chemical group 0.000 description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
239000000706 filtrate Substances 0.000 description 3
238000001914 filtration Methods 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000000047 product Substances 0.000 description 3
239000011949 solid catalyst Substances 0.000 description 3
239000007790 solid phase Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
ARGRHMLWRBWKBG-UHFFFAOYSA-N C(C)(C)(C)C1=CC=C(C=C1)[SiH2]C(OC)(OC)OC Chemical compound C(C)(C)(C)C1=CC=C(C=C1)[SiH2]C(OC)(OC)OC ARGRHMLWRBWKBG-UHFFFAOYSA-N 0.000 description 2
101000809257 Homo sapiens Ubiquitin carboxyl-terminal hydrolase 4 Proteins 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
229910003074 TiCl4 Inorganic materials 0.000 description 2
102100038463 Ubiquitin carboxyl-terminal hydrolase 4 Human genes 0.000 description 2
238000002441 X-ray diffraction Methods 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000003426 co-catalyst Substances 0.000 description 2
CPAYFVMIEQWZQG-UHFFFAOYSA-N dimethoxymethyl(diphenyl)silane Chemical compound C1(=CC=CC=C1)[SiH](C(OC)OC)C1=CC=CC=C1 CPAYFVMIEQWZQG-UHFFFAOYSA-N 0.000 description 2
IFLCOMFNZPJCFT-UHFFFAOYSA-N dimethoxymethyl-(2-ethylhexyl)-methylsilane Chemical compound CCCCC(CC)C[SiH](C)C(OC)OC IFLCOMFNZPJCFT-UHFFFAOYSA-N 0.000 description 2
XYYQWMDBQFSCPB-UHFFFAOYSA-N dimethoxymethylsilane Chemical compound COC([SiH3])OC XYYQWMDBQFSCPB-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000007789 gas Substances 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
229910052809 inorganic oxide Inorganic materials 0.000 description 2
150000002681 magnesium compounds Chemical class 0.000 description 2
UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 description 2
DTQCCXZWJWTXJK-UHFFFAOYSA-N phenyl(trimethoxymethyl)silane Chemical compound C1(=CC=CC=C1)[SiH2]C(OC)(OC)OC DTQCCXZWJWTXJK-UHFFFAOYSA-N 0.000 description 2
230000005855 radiation Effects 0.000 description 2
229910000077 silane Inorganic materials 0.000 description 2
150000004756 silanes Chemical class 0.000 description 2
238000001228 spectrum Methods 0.000 description 2
239000012798 spherical particle Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
239000000725 suspension Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
239000004711 α-olefin Substances 0.000 description 2
HMXOXVTXBLUMRA-UHFFFAOYSA-N (4-chlorophenyl)-(trimethoxymethyl)silane Chemical compound ClC1=CC=C(C=C1)[SiH2]C(OC)(OC)OC HMXOXVTXBLUMRA-UHFFFAOYSA-N 0.000 description 1
NMDOITPNLAVEFG-UHFFFAOYSA-N 1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalen-1-yl(trimethoxymethyl)silane Chemical compound C1(CCCC2CCCCC12)[SiH2]C(OC)(OC)OC NMDOITPNLAVEFG-UHFFFAOYSA-N 0.000 description 1
XTIGGAHUZJWQMD-UHFFFAOYSA-N 1-chloro-2-methoxyethane Chemical compound COCCCl XTIGGAHUZJWQMD-UHFFFAOYSA-N 0.000 description 1
QZKJLZAKZSKUBX-UHFFFAOYSA-N 2-ethylhexyl(trimethoxymethyl)silane Chemical compound C(C)C(C[SiH2]C(OC)(OC)OC)CCCC QZKJLZAKZSKUBX-UHFFFAOYSA-N 0.000 description 1
XGUYBRSOIPIWLW-UHFFFAOYSA-N 2-methylpropyl(trimethoxymethyl)silane Chemical compound C(C(C)C)[SiH2]C(OC)(OC)OC XGUYBRSOIPIWLW-UHFFFAOYSA-N 0.000 description 1
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
XWFRXZRWMDOLIP-UHFFFAOYSA-N C(C(C)C)[SiH](C(OCC)OCC)CC(C)C Chemical compound C(C(C)C)[SiH](C(OCC)OCC)CC(C)C XWFRXZRWMDOLIP-UHFFFAOYSA-N 0.000 description 1
YJUQAFMOFUCNGZ-UHFFFAOYSA-N C(C)(C)[SiH](C(OCC)OCC)C(C)C Chemical compound C(C)(C)[SiH](C(OCC)OCC)C(C)C YJUQAFMOFUCNGZ-UHFFFAOYSA-N 0.000 description 1
RFKFYFTUHRFUKQ-UHFFFAOYSA-N C(C)OC([SiH](C)C)OCC Chemical compound C(C)OC([SiH](C)C)OCC RFKFYFTUHRFUKQ-UHFFFAOYSA-N 0.000 description 1
VSPRYFWDJSXQQO-UHFFFAOYSA-N C(C)[SiH](C(OC)OC)CC Chemical compound C(C)[SiH](C(OC)OC)CC VSPRYFWDJSXQQO-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
241000252233 Cyprinus carpio Species 0.000 description 1
DAPNEKIAGKFAPV-UHFFFAOYSA-N FC1=CC=C(C=C1)[SiH2]C(OC)(OC)OC Chemical compound FC1=CC=C(C=C1)[SiH2]C(OC)(OC)OC DAPNEKIAGKFAPV-UHFFFAOYSA-N 0.000 description 1
239000007818 Grignard reagent Substances 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
229910010068 TiCl2 Inorganic materials 0.000 description 1
LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 1
238000002083 X-ray spectrum Methods 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
150000007860 aryl ester derivatives Chemical class 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
FICXCYXCWUFNLW-UHFFFAOYSA-N benzyl-(dimethoxymethyl)-phenylsilane Chemical compound C1(=CC=CC=C1)[SiH](C(OC)OC)CC1=CC=CC=C1 FICXCYXCWUFNLW-UHFFFAOYSA-N 0.000 description 1
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
YPHYBCUUGZYASI-UHFFFAOYSA-N bis(2-methylpropoxy)methyl-bis(2-methylpropyl)silane Chemical compound C(C(C)C)[SiH](C(OCC(C)C)OCC(C)C)CC(C)C YPHYBCUUGZYASI-UHFFFAOYSA-N 0.000 description 1
NCEJQINTSWFWPH-UHFFFAOYSA-N bis(cyclohexylmethyl)-dimethoxysilane Chemical compound C1CCCCC1C[Si](OC)(OC)CC1CCCCC1 NCEJQINTSWFWPH-UHFFFAOYSA-N 0.000 description 1
FOYPLZRACIXBKK-UHFFFAOYSA-N butyl(trimethoxymethyl)silane Chemical compound C(CCC)[SiH2]C(OC)(OC)OC FOYPLZRACIXBKK-UHFFFAOYSA-N 0.000 description 1
OOSZILWKTQCRSZ-UHFFFAOYSA-N butyl-dimethoxy-methylsilane Chemical compound CCCC[Si](C)(OC)OC OOSZILWKTQCRSZ-UHFFFAOYSA-N 0.000 description 1
150000001733 carboxylic acid esters Chemical class 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
ALQVXXYBGQAIIJ-UHFFFAOYSA-N cyclohexyl(trimethoxymethyl)silane Chemical compound C1(CCCCC1)[SiH2]C(OC)(OC)OC ALQVXXYBGQAIIJ-UHFFFAOYSA-N 0.000 description 1
125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
ASXJJAJXJLFIHE-UHFFFAOYSA-N cyclohexylmethyl-(dimethoxymethyl)-methylsilane Chemical compound COC(OC)[SiH](C)CC1CCCCC1 ASXJJAJXJLFIHE-UHFFFAOYSA-N 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
NTVQPRPSHSXAPK-UHFFFAOYSA-N diethoxymethyl(diethyl)silane Chemical compound C(C)[SiH](C(OCC)OCC)CC NTVQPRPSHSXAPK-UHFFFAOYSA-N 0.000 description 1
MHJIKFAIIPAQSP-UHFFFAOYSA-N diethoxymethyl(dipropyl)silane Chemical compound C(CC)[SiH](C(OCC)OCC)CCC MHJIKFAIIPAQSP-UHFFFAOYSA-N 0.000 description 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical group CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 1
KTBFSTHWSBRFFU-UHFFFAOYSA-N dimethoxymethyl(dimethyl)silane Chemical compound C[SiH](C(OC)OC)C KTBFSTHWSBRFFU-UHFFFAOYSA-N 0.000 description 1
YMKVOFXDBSXMIH-UHFFFAOYSA-N dimethoxymethyl(dipropyl)silane Chemical compound C(CC)[SiH](C(OC)OC)CCC YMKVOFXDBSXMIH-UHFFFAOYSA-N 0.000 description 1
XGKZPLJBOXWVTL-UHFFFAOYSA-N dimethoxymethyl-(2-methylpropyl)-propan-2-ylsilane Chemical compound C(C(C)C)[SiH](C(OC)OC)C(C)C XGKZPLJBOXWVTL-UHFFFAOYSA-N 0.000 description 1
FXFXQVBZYXSFAQ-UHFFFAOYSA-N dimethoxymethyl-bis(2,2-dimethylpropyl)silane Chemical compound C(C(C)(C)C)[SiH](C(OC)OC)CC(C)(C)C FXFXQVBZYXSFAQ-UHFFFAOYSA-N 0.000 description 1
MMAOLTRXBAMUBO-UHFFFAOYSA-N dimethoxymethyl-bis(2-methylpropyl)silane Chemical compound C(C(C)C)[SiH](C(OC)OC)CC(C)C MMAOLTRXBAMUBO-UHFFFAOYSA-N 0.000 description 1
DOOFHDXRBGGNDG-UHFFFAOYSA-N dimethoxymethyl-bis(4-methylphenyl)silane Chemical compound CC1=CC=C(C=C1)[SiH](C(OC)OC)C1=CC=C(C=C1)C DOOFHDXRBGGNDG-UHFFFAOYSA-N 0.000 description 1
DSTGZGWZGLBMRS-UHFFFAOYSA-N dimethoxymethyl-methyl-phenylsilane Chemical compound C[SiH](C(OC)OC)C1=CC=CC=C1 DSTGZGWZGLBMRS-UHFFFAOYSA-N 0.000 description 1
ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical class C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical group C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 description 1
230000008034 disappearance Effects 0.000 description 1
IAQAVXKRQSHUNL-UHFFFAOYSA-N ditert-butyl(dimethoxymethyl)silane Chemical compound C(C)(C)(C)[SiH](C(OC)OC)C(C)(C)C IAQAVXKRQSHUNL-UHFFFAOYSA-N 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
YCNSGSUGQPDYTK-UHFFFAOYSA-N ethyl phenyl carbonate Chemical compound CCOC(=O)OC1=CC=CC=C1 YCNSGSUGQPDYTK-UHFFFAOYSA-N 0.000 description 1
238000007429 general method Methods 0.000 description 1
GVVPGTZRZFNKDS-JXMROGBWSA-N geranyl diphosphate Chemical compound CC(C)=CCC\C(C)=C\CO[P@](O)(=O)OP(O)(O)=O GVVPGTZRZFNKDS-JXMROGBWSA-N 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000004795 grignard reagents Chemical class 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
150000002596 lactones Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
HZZOEADXZLYIHG-UHFFFAOYSA-N magnesiomagnesium Chemical compound [Mg][Mg] HZZOEADXZLYIHG-UHFFFAOYSA-N 0.000 description 1
YZQBYALVHAANGI-UHFFFAOYSA-N magnesium;dihypochlorite Chemical compound [Mg+2].Cl[O-].Cl[O-] YZQBYALVHAANGI-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
ZHCUAVYLSFVRFU-UHFFFAOYSA-N methyl(propan-2-yl)silicon Chemical compound C[Si]C(C)C ZHCUAVYLSFVRFU-UHFFFAOYSA-N 0.000 description 1
BCOLJLYGWZEIEA-UHFFFAOYSA-N methyl(trimethoxymethyl)silane Chemical compound C[SiH2]C(OC)(OC)OC BCOLJLYGWZEIEA-UHFFFAOYSA-N 0.000 description 1
239000004005 microsphere Substances 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
239000012071 phase Substances 0.000 description 1
125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
125000004437 phosphorous atom Chemical group 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
125000005498 phthalate group Chemical class 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
150000003377 silicon compounds Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000005049 silicon tetrachloride Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000001384 succinic acid Substances 0.000 description 1
125000004646 sulfenyl group Chemical group S(*)* 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
125000004434 sulfur atom Chemical group 0.000 description 1
KGXMVURFZUILPA-UHFFFAOYSA-N tert-butyl(trimethoxymethyl)silane Chemical compound C(C)(C)(C)[SiH2]C(OC)(OC)OC KGXMVURFZUILPA-UHFFFAOYSA-N 0.000 description 1
MGEONZHNKLHMRA-UHFFFAOYSA-N tert-butyl-cyclohexyl-(dimethoxymethyl)silane Chemical compound C1(CCCCC1)[SiH](C(OC)OC)C(C)(C)C MGEONZHNKLHMRA-UHFFFAOYSA-N 0.000 description 1
125000001544 thienyl group Chemical group 0.000 description 1
ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
TUQLLQQWSNWKCF-UHFFFAOYSA-N trimethoxymethylsilane Chemical compound COC([SiH3])(OC)OC TUQLLQQWSNWKCF-UHFFFAOYSA-N 0.000 description 1
ZDVDCWGJCRZBHK-UHFFFAOYSA-N trimethyl(naphthalen-1-ylmethyl)silane Chemical compound C1=CC=C2C(C[Si](C)(C)C)=CC=CC2=C1 ZDVDCWGJCRZBHK-UHFFFAOYSA-N 0.000 description 1
238000001665 trituration Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

CS9146A 1990-01-10 1991-01-10 Catalyst's component and catalyst for olefins polymerization CS4691A2 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT19039A IT1241062B (it)	1990-01-10	1990-01-10	Componenti e catalizzatori per la polimerizzazione di olefine

Publications (1)

Publication Number	Publication Date
CS4691A2 true CS4691A2 (en)	1991-09-15

Family

ID=11154036

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS9146A CS4691A2 (en)	1990-01-10	1991-01-10	Catalyst's component and catalyst for olefins polymerization

Country Status (23)

Country	Link
US (1)	US5106807A (ja)
EP (2)	EP0671417B1 (ja)
JP (1)	JP2962841B2 (ja)
KR (1)	KR910014404A (ja)
CN (1)	CN1027643C (ja)
AR (1)	AR244712A1 (ja)
AU (1)	AU628245B2 (ja)
BR (1)	BR9100088A (ja)
CA (1)	CA2033808A1 (ja)
CS (1)	CS4691A2 (ja)
DE (2)	DE69125959T2 (ja)
FI (1)	FI910137L (ja)
HU (1)	HUT60293A (ja)
IL (1)	IL96870A0 (ja)
IT (1)	IT1241062B (ja)
MX (1)	MX24042A (ja)
NO (1)	NO910097L (ja)
PH (1)	PH27589A (ja)
PL (1)	PL288637A1 (ja)
PT (1)	PT96460A (ja)
RO (1)	RO107125B1 (ja)
YU (1)	YU1591A (ja)
ZA (1)	ZA9152B (ja)

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1990
- 1990-01-10 IT IT19039A patent/IT1241062B/it active IP Right Grant
- 1990-12-28 MX MX24042A patent/MX24042A/es unknown
1991
- 1991-01-02 IL IL96870A patent/IL96870A0/xx unknown
- 1991-01-02 PH PH41810A patent/PH27589A/en unknown
- 1991-01-03 ZA ZA9152A patent/ZA9152B/xx unknown
- 1991-01-04 US US07/638,289 patent/US5106807A/en not_active Expired - Lifetime
- 1991-01-04 AU AU68660/91A patent/AU628245B2/en not_active Ceased
- 1991-01-08 CA CA002033808A patent/CA2033808A1/en not_active Abandoned
- 1991-01-08 AR AR91318800A patent/AR244712A1/es active
- 1991-01-09 HU HU9156A patent/HUT60293A/hu unknown
- 1991-01-09 NO NO91910097A patent/NO910097L/no unknown
- 1991-01-09 PL PL28863791A patent/PL288637A1/xx unknown
- 1991-01-10 BR BR919100088A patent/BR9100088A/pt unknown
- 1991-01-10 DE DE69125959T patent/DE69125959T2/de not_active Expired - Fee Related
- 1991-01-10 DE DE69114309T patent/DE69114309T2/de not_active Expired - Fee Related
- 1991-01-10 KR KR1019910000278A patent/KR910014404A/ko not_active Withdrawn
- 1991-01-10 FI FI910137A patent/FI910137L/fi not_active Application Discontinuation
- 1991-01-10 EP EP95106653A patent/EP0671417B1/en not_active Expired - Lifetime
- 1991-01-10 PT PT96460A patent/PT96460A/pt not_active Application Discontinuation
- 1991-01-10 RO RO146712A patent/RO107125B1/ro unknown
- 1991-01-10 JP JP3012887A patent/JP2962841B2/ja not_active Expired - Fee Related
- 1991-01-10 CS CS9146A patent/CS4691A2/cs unknown
- 1991-01-10 CN CN91100086A patent/CN1027643C/zh not_active Expired - Fee Related
- 1991-01-10 EP EP91100270A patent/EP0437263B1/en not_active Expired - Lifetime
- 1991-01-18 YU YU1591A patent/YU1591A/sh unknown

Also Published As

Publication number	Publication date
IL96870A0 (en)	1992-03-29
EP0437263A1 (en)	1991-07-17
FI910137A7 (fi)	1991-07-11
NO910097L (no)	1991-07-11
US5106807A (en)	1992-04-21
DE69114309T2 (de)	1996-05-02
JPH0625332A (ja)	1994-02-01
CN1053241A (zh)	1991-07-24
MX24042A (es)	1994-03-31
IT9019039A1 (it)	1991-07-11
FI910137L (fi)	1991-07-11
CN1027643C (zh)	1995-02-15
EP0671417A3 (en)	1995-11-22
DE69125959D1 (de)	1997-06-05
IT9019039A0 (it)	1990-01-10
RO107125B1 (ro)	1993-09-30
AU628245B2 (en)	1992-09-10
AR244712A1 (es)	1993-11-30
ZA9152B (en)	1991-10-30
DE69125959T2 (de)	1997-12-18
KR910014404A (ko)	1991-08-31
NO910097D0 (no)	1991-01-09
EP0437263B1 (en)	1995-11-08
JP2962841B2 (ja)	1999-10-12
HU910056D0 (en)	1991-08-28
PL288637A1 (en)	1992-02-10
PT96460A (pt)	1991-10-15
HUT60293A (en)	1992-08-28
EP0671417B1 (en)	1997-05-02
BR9100088A (pt)	1991-10-22
YU1591A (sh)	1994-05-10
CA2033808A1 (en)	1991-07-11
PH27589A (en)	1993-08-18
FI910137A0 (fi)	1991-01-10
DE69114309D1 (de)	1995-12-14
IT1241062B (it)	1993-12-29
AU6866091A (en)	1991-07-11
EP0671417A2 (en)	1995-09-13

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CS4691A2 (en)	1991-09-15	Catalyst's component and catalyst for olefins polymerization
US7009015B2 (en)	2006-03-07	Alpha-olefin polymerization catalyst system which contains an aromatic silane compound
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KR20000068056A (ko)	2000-11-25	올레핀 중합용 성분 및 촉매
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CS226436B2 (en)	1984-03-19	Method of preparing catalysts of stereoregular alpha-olefin polymerization
HUP0104266A2 (hu)	2002-03-28	Komponensek és katalizátorok olefinek polimerizálására
JPS61130312A (ja)	1986-06-18	エチレン重合用触媒成分の製造法
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EP0010746B1 (en)	1984-03-21	Catalyst components and catalysts for the polymerization of olefins; the use thereof
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JPH0717695B2 (ja)	1995-03-01	オレフイン重合用触媒担体の製造法
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