DD154991A5 - Mercaptoorganopolysiloxanmassen aus einem mercaptoorganopolysiloxan,einem aliphatisch ungesaettigten polydorganosiloxan und einem metallsalz einer carbonsaeure - Google Patents
Mercaptoorganopolysiloxanmassen aus einem mercaptoorganopolysiloxan,einem aliphatisch ungesaettigten polydorganosiloxan und einem metallsalz einer carbonsaeure Download PDFInfo
- Publication number
- DD154991A5 DD154991A5 DD80225682A DD22568280A DD154991A5 DD 154991 A5 DD154991 A5 DD 154991A5 DD 80225682 A DD80225682 A DD 80225682A DD 22568280 A DD22568280 A DD 22568280A DD 154991 A5 DD154991 A5 DD 154991A5
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- units
- formula
- sio
- octanoate
- mercaptoorganopolysiloxane
- Prior art date
Links
- 150000003839 salts Chemical class 0.000 title claims abstract description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title 1
- 239000002253 acid Substances 0.000 title 1
- 229910052799 carbon Inorganic materials 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 66
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000001735 carboxylic acids Chemical class 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 8
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 6
- 239000011572 manganese Substances 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 5
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 4
- -1 dimethylsiloxane units Chemical group 0.000 claims description 39
- ORTRPLABQKAPKJ-UHFFFAOYSA-K iron(3+);octanoate Chemical compound [Fe+3].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O ORTRPLABQKAPKJ-UHFFFAOYSA-K 0.000 claims description 14
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- SGLXWMAOOWXVAM-UHFFFAOYSA-L manganese(2+);octanoate Chemical compound [Mn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O SGLXWMAOOWXVAM-UHFFFAOYSA-L 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 239000011593 sulfur Substances 0.000 claims description 5
- DVTHIMLUHWEZOM-UHFFFAOYSA-L nickel(2+);octanoate Chemical compound [Ni+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O DVTHIMLUHWEZOM-UHFFFAOYSA-L 0.000 claims description 4
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims description 3
- 230000000903 blocking effect Effects 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 2
- 150000001734 carboxylic acid salts Chemical class 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 abstract description 9
- 239000000806 elastomer Substances 0.000 abstract description 9
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 7
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 150000002815 nickel Chemical class 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 description 20
- 239000000463 material Substances 0.000 description 19
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 235000010446 mineral oil Nutrition 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical class [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 229910021485 fumed silica Inorganic materials 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 229910017464 nitrogen compound Inorganic materials 0.000 description 2
- 150000002830 nitrogen compounds Chemical class 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical group CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 description 1
- HQFBDBUXEMTDCW-UHFFFAOYSA-N 3,4-dihydro-2H-silol-1-yl-methyl-silyloxysilane Chemical compound [SiH3]O[SiH](C)[Si]1=CCCC1 HQFBDBUXEMTDCW-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229910020175 SiOH Inorganic materials 0.000 description 1
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical group C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002669 linoleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 125000001038 naphthoyl group Chemical group C1(=CC=CC2=CC=CC=C12)C(=O)* 0.000 description 1
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 1
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- IALUUOKJPBOFJL-UHFFFAOYSA-N potassium oxidosilane Chemical compound [K+].[SiH3][O-] IALUUOKJPBOFJL-UHFFFAOYSA-N 0.000 description 1
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- BWSZXUOMATYHHI-UHFFFAOYSA-N tert-butyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(C)(C)C BWSZXUOMATYHHI-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Dental Prosthetics (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/099,257 US4284539A (en) | 1979-12-03 | 1979-12-03 | Compositions including mercaptoorganopolysiloxanes, aliphatically unsaturated polydiorganosiloxanes and carboxylic acid salts of metals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD154991A5 true DD154991A5 (de) | 1982-05-05 |
Family
ID=22273960
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD80225682A DD154991A5 (de) | 1979-12-03 | 1980-12-03 | Mercaptoorganopolysiloxanmassen aus einem mercaptoorganopolysiloxan,einem aliphatisch ungesaettigten polydorganosiloxan und einem metallsalz einer carbonsaeure |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4284539A (es) |
| EP (1) | EP0030098B1 (es) |
| JP (1) | JPS603421B2 (es) |
| KR (1) | KR840000526B1 (es) |
| BR (1) | BR8008955A (es) |
| CA (1) | CA1151791A (es) |
| DD (1) | DD154991A5 (es) |
| DE (1) | DE3068249D1 (es) |
| ES (1) | ES497372A0 (es) |
| WO (1) | WO1981001570A1 (es) |
| ZA (1) | ZA807297B (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4526954A (en) * | 1983-12-28 | 1985-07-02 | Union Carbide Corporation | Organosiloxane polymers and compositions containing same curable upon exposure to gaseous oxygen |
| ES2082128T3 (es) * | 1990-03-23 | 1996-03-16 | Ici Plc | Polimeros. |
| JP2511729B2 (ja) * | 1990-10-16 | 1996-07-03 | 信越化学工業株式会社 | シリコ―ングリ―スのクリ―プ防止方法及びそれに適した光硬化性シリコ―ングリ―ス組成物 |
| US5543443A (en) * | 1992-01-27 | 1996-08-06 | The Procter & Gamble Company | Denture stabilizing compositions |
| FR2743565B1 (fr) * | 1996-01-11 | 1998-02-20 | Rhone Poulenc Chimie | Utilisation d'une association de composes silicones comme agent de couplage dans les compositions d'elastomeres chargees de silice |
| CN100569804C (zh) | 2004-11-18 | 2009-12-16 | 禾逊专业化学公司 | 超薄硫醇-烯涂层 |
| US8044111B2 (en) | 2007-11-30 | 2011-10-25 | Novartis Ag | Actinically-crosslinkable silicone-containing block copolymers |
| AU2011282603B2 (en) | 2010-07-30 | 2014-01-30 | Novartis Ag | Amphiphilic polysiloxane prepolymers and uses thereof |
| US8967888B2 (en) | 2012-04-25 | 2015-03-03 | Tyco Electronics Raychem Bvba | Dry silicone gels and their methods of making using thiol-ene chemistry |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3287291A (en) * | 1962-07-12 | 1966-11-22 | Union Carbide Corp | Diorganosiloxanes cured with an alkoxy end-blocked silyl tetraformal |
| US3445419A (en) * | 1966-01-21 | 1969-05-20 | Dow Corning | Room temperature vulcanizable silicones |
| DE2008426A1 (es) | 1969-02-27 | 1970-09-10 | ||
| US3655713A (en) * | 1970-07-13 | 1972-04-11 | Dow Corning | Silacyclopentane thiols and thiolates |
| US3816282A (en) * | 1971-04-15 | 1974-06-11 | Gen Electric | Radiation induced polymerization of polysiloxanes |
| US4064027A (en) * | 1973-09-28 | 1977-12-20 | Dow Corning Corporation | UV curable composition |
| US3873499A (en) * | 1973-11-29 | 1975-03-25 | Dow Corning | Fast curing mercaptoalkyl vinyl siloxane resins |
| US4039505A (en) * | 1976-03-03 | 1977-08-02 | Dow Corning Corporation | Siloxane elastomers containing sulfur and method of preparation |
| US4066603A (en) * | 1976-03-03 | 1978-01-03 | Dow Corning Corporation | Sulfur containing silicone elastomer and method of preparation |
| US4039504A (en) * | 1976-03-03 | 1977-08-02 | Dow Corning Corporation | Mercaptosiloxane elastomer and method of preparation |
| JPS5355362A (en) * | 1976-10-29 | 1978-05-19 | Shin Etsu Chem Co Ltd | Organopolysiloxane composition |
| US4070329A (en) * | 1977-01-03 | 1978-01-24 | Dow Corning Corporation | Siloxane elastomer prepared from mercaptoorg anopolysiloxanes |
| US4070328A (en) * | 1977-01-03 | 1978-01-24 | Dow Corning Corporation | Mercaptoorganopolysiloxanes cured to elastomers with peroxides and nitrogen compounds |
-
1979
- 1979-12-03 US US06/099,257 patent/US4284539A/en not_active Expired - Lifetime
-
1980
- 1980-11-03 JP JP56500183A patent/JPS603421B2/ja not_active Expired
- 1980-11-03 BR BR8008955A patent/BR8008955A/pt unknown
- 1980-11-03 WO PCT/US1980/001481 patent/WO1981001570A1/en not_active Ceased
- 1980-11-07 CA CA000364232A patent/CA1151791A/en not_active Expired
- 1980-11-18 DE DE8080304121T patent/DE3068249D1/de not_active Expired
- 1980-11-18 EP EP80304121A patent/EP0030098B1/en not_active Expired
- 1980-11-21 ZA ZA00807297A patent/ZA807297B/xx unknown
- 1980-12-02 ES ES497372A patent/ES497372A0/es active Granted
- 1980-12-03 DD DD80225682A patent/DD154991A5/de unknown
- 1980-12-03 KR KR1019800004613A patent/KR840000526B1/ko not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS603421B2 (ja) | 1985-01-28 |
| WO1981001570A1 (en) | 1981-06-11 |
| ES8302044A1 (es) | 1983-01-01 |
| DE3068249D1 (en) | 1984-07-19 |
| BR8008955A (pt) | 1981-10-20 |
| US4284539A (en) | 1981-08-18 |
| ES497372A0 (es) | 1983-01-01 |
| ZA807297B (en) | 1981-11-25 |
| CA1151791A (en) | 1983-08-09 |
| EP0030098A1 (en) | 1981-06-10 |
| EP0030098B1 (en) | 1984-06-13 |
| KR830004369A (ko) | 1983-07-09 |
| JPS56501603A (es) | 1981-11-05 |
| KR840000526B1 (ko) | 1984-04-17 |
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