DD251275A5 - Als akarizid wirksame zusammensetzungen - Google Patents

Als akarizid wirksame zusammensetzungen Download PDF

Info

Publication number: DD251275A5
Authority: DD; German Democratic Republic
Prior art keywords: group; phenyl; carbon atoms; propyl; formula
Prior art date: 1985-04-16

Application number

DD86289077A

Other languages

German (de)

English (en)

Inventor

Peter J West

Russell G Hunt

Duncan A Gates

Original Assignee

��@��Kk��

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-04-16

Filing date

1986-04-14

Publication date

1987-11-11

1986-04-14 Application filed by ��@��Kk�� filed Critical ��@��Kk��

1987-11-11 Publication of DD251275A5 publication Critical patent/DD251275A5/de

Links

239000000203 mixture Substances 0.000 title claims abstract description 25
239000000642 acaricide Substances 0.000 title claims abstract description 6
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 26
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 17
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 13
239000001257 hydrogen Substances 0.000 claims abstract description 13
150000004867 thiadiazoles Chemical class 0.000 claims abstract description 13
235000013601 eggs Nutrition 0.000 claims abstract description 12
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims abstract description 10
230000000895 acaricidal effect Effects 0.000 claims abstract description 10
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 8
229910052760 oxygen Inorganic materials 0.000 claims abstract description 8
239000001301 oxygen Substances 0.000 claims abstract description 8
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 4
125000004414 alkyl thio group Chemical group 0.000 claims abstract description 4
229910052717 sulfur Chemical group 0.000 claims abstract description 4
239000011593 sulfur Chemical group 0.000 claims abstract description 4
125000000547 substituted alkyl group Chemical group 0.000 claims abstract description 3
125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 3
-1 η-butyl Chemical group 0.000 claims description 41
238000000034 method Methods 0.000 claims description 14
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 10
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 8
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 8
125000000217 alkyl group Chemical group 0.000 claims description 7
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 7
239000004094 surface-active agent Substances 0.000 claims description 5
125000004705 ethylthio group Chemical group C(C)S* 0.000 claims description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
125000003342 alkenyl group Chemical group 0.000 claims description 3
125000000304 alkynyl group Chemical group 0.000 claims description 3
125000000753 cycloalkyl group Chemical group 0.000 claims description 3
125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims description 3
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 3
125000003118 aryl group Chemical group 0.000 claims description 2
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 claims description 2
238000003898 horticulture Methods 0.000 abstract description 3
150000001875 compounds Chemical class 0.000 description 33
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 13
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
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XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
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238000006243 chemical reaction Methods 0.000 description 9
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WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
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VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
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150000001412 amines Chemical class 0.000 description 4
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UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
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KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
229920001732 Lignosulfonate Polymers 0.000 description 2
SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 2
244000046052 Phaseolus vulgaris Species 0.000 description 2
235000010627 Phaseolus vulgaris Nutrition 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
241000344246 Tetranychus cinnabarinus Species 0.000 description 2
241001454293 Tetranychus urticae Species 0.000 description 2
150000008055 alkyl aryl sulfonates Chemical class 0.000 description 2
238000009835 boiling Methods 0.000 description 2
235000013339 cereals Nutrition 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
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239000012442 inert solvent Substances 0.000 description 2
229910052943 magnesium sulfate Inorganic materials 0.000 description 2
235000019341 magnesium sulphate Nutrition 0.000 description 2
229920001983 poloxamer Polymers 0.000 description 2
239000003380 propellant Substances 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000002689 soil Substances 0.000 description 2
239000000600 sorbitol Substances 0.000 description 2
150000003871 sulfonates Chemical class 0.000 description 2
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
LXOFYPKXCSULTL-UHFFFAOYSA-N 2,4,7,9-tetramethyldec-5-yne-4,7-diol Chemical compound CC(C)CC(C)(O)C#CC(C)(O)CC(C)C LXOFYPKXCSULTL-UHFFFAOYSA-N 0.000 description 1
CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
ULXJDHHDIRHRFH-UHFFFAOYSA-N 3-[(3-propyl-1,2,4-thiadiazol-5-yl)oxy]aniline Chemical compound CCCC1=NSC(OC=2C=C(N)C=CC=2)=N1 ULXJDHHDIRHRFH-UHFFFAOYSA-N 0.000 description 1
OFPRLCSYRJMYLN-UHFFFAOYSA-N 5-(3-isocyanatophenoxy)-3-propyl-1,2,4-thiadiazole Chemical compound CCCC1=NSC(OC=2C=C(C=CC=2)N=C=O)=N1 OFPRLCSYRJMYLN-UHFFFAOYSA-N 0.000 description 1
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
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241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
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235000008534 Capsicum annuum var annuum Nutrition 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
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229920000742 Cotton Polymers 0.000 description 1
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239000004338 Dichlorodifluoromethane Substances 0.000 description 1
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DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
206010061217 Infestation Diseases 0.000 description 1
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ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
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125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
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PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
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229920002554 vinyl polymer Polymers 0.000 description 1
239000000230 xanthan gum Substances 0.000 description 1
229920001285 xanthan gum Polymers 0.000 description 1
229940082509 xanthan gum Drugs 0.000 description 1
235000010493 xanthan gum Nutrition 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
- C07D285/01—Five-membered rings
- C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
- C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
- C07D285/08—1,2,4-Thiadiazoles; Hydrogenated 1,2,4-thiadiazoles
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/20—N-Aryl derivatives thereof
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/22—O-Aryl or S-Aryl esters thereof

Landscapes

Life Sciences & Earth Sciences (AREA)
Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Pest Control & Pesticides (AREA)
Plant Pathology (AREA)
Agronomy & Crop Science (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
General Health & Medical Sciences (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

DD86289077A 1985-04-16 1986-04-14 Als akarizid wirksame zusammensetzungen DD251275A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB858509752A GB8509752D0 (en)	1985-04-16	1985-04-16	Acaricides

Publications (1)

Publication Number	Publication Date
DD251275A5 true DD251275A5 (de)	1987-11-11

Family

ID=10577744

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD86289077A DD251275A5 (de)	1985-04-16	1986-04-14	Als akarizid wirksame zusammensetzungen

Country Status (15)

Country	Link
US (1)	US4692457A (pt)
EP (1)	EP0200334A3 (pt)
JP (1)	JPS61267563A (pt)
KR (1)	KR860008154A (pt)
CN (1)	CN86102451A (pt)
AU (1)	AU577940B2 (pt)
BR (1)	BR8601668A (pt)
DD (1)	DD251275A5 (pt)
DK (1)	DK168586A (pt)
GB (1)	GB8509752D0 (pt)
GR (1)	GR860979B (pt)
HU (1)	HUT41401A (pt)
SU (1)	SU1450744A3 (pt)
ZA (1)	ZA862767B (pt)
ZW (1)	ZW8886A1 (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US7273879B2 (en) *	2002-01-17	2007-09-25	Sumitomo Chemical Company, Limited	Thiadiazole compounds and use thereof
EP1574505B1 (en) *	2002-11-08	2008-07-16	Sumitomo Chemical Company, Limited	1,2,4-thiadiazole compounds and use thereof
US7371746B2 (en) *	2003-10-15	2008-05-13	Sumitomo Chemical Company Limited	1,2,4-Thiadiazole compounds and pests controlling composition containing the same
CN103214474B (zh) *	2013-05-02	2016-04-27	南开大学	一类含4,5-二氢噻唑醇酸酯的5-甲基-1,2,3-噻二唑衍生物及其制备方法和用途

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CH550538A (de) *	1971-08-31	1974-06-28	Ciba Geigy Ag	Handelsfaehiges mittel zur bekaempfung von schaedlichen mikroorganismen.
DE3431272A1 (de) *	1984-08-25	1986-03-06	Bayer Ag, 5090 Leverkusen	Substituierte phenylharnstoffe

1985
- 1985-04-16 GB GB858509752A patent/GB8509752D0/en active Pending
1986
- 1986-03-20 EP EP86302066A patent/EP0200334A3/en not_active Withdrawn
- 1986-04-12 CN CN198686102451A patent/CN86102451A/zh active Pending
- 1986-04-14 GR GR860979A patent/GR860979B/el unknown
- 1986-04-14 DD DD86289077A patent/DD251275A5/de unknown
- 1986-04-14 DK DK168586A patent/DK168586A/da not_active IP Right Cessation
- 1986-04-14 BR BR8601668A patent/BR8601668A/pt unknown
- 1986-04-14 ZA ZA862767A patent/ZA862767B/xx unknown
- 1986-04-15 US US06/852,181 patent/US4692457A/en not_active Expired - Fee Related
- 1986-04-15 SU SU864027329A patent/SU1450744A3/ru active
- 1986-04-15 JP JP61085231A patent/JPS61267563A/ja active Pending
- 1986-04-15 HU HU861576A patent/HUT41401A/hu unknown
- 1986-04-16 AU AU56156/86A patent/AU577940B2/en not_active Ceased
- 1986-04-16 ZW ZW88/86A patent/ZW8886A1/xx unknown
- 1986-04-16 KR KR1019860002901A patent/KR860008154A/ko not_active Withdrawn

Also Published As

Publication number	Publication date
JPS61267563A (ja)	1986-11-27
EP0200334A3 (en)	1987-09-30
DK168586A (da)	1986-10-17
GB8509752D0 (en)	1985-05-22
ZA862767B (en)	1987-01-28
AU577940B2 (en)	1988-10-06
US4692457A (en)	1987-09-08
EP0200334A2 (en)	1986-11-05
CN86102451A (zh)	1986-11-26
DK168586D0 (da)	1986-04-14
AU5615686A (en)	1986-12-18
HUT41401A (en)	1987-04-28
KR860008154A (ko)	1986-11-12
SU1450744A3 (ru)	1989-01-07
BR8601668A (pt)	1986-12-16
ZW8886A1 (en)	1986-11-19
GR860979B (en)	1986-08-07

Publication	Publication Date	Title
DE3788629T2 (de)	1994-04-28	Neue malonsäurederivate und zusammensetzungen, die sie enthalten, zur verzögerung des pflanzenwachstums.
DE2406475C2 (de)	1983-04-28	5-Acetamido-2,4-dimethyltrifluormethansulfonanilid und dessen landwirtschaftlich geeignete Salze, Verfahren zur Herstellung dieser Verbindungen und diese Verbindungen enthaltende Mittel
DE2654314C2 (pt)	1987-06-25
US3084096A (en)	1963-04-02	Indanyl n-methyl carbamate
DE2744169A1 (de)	1978-04-06	N-eckige klammer auf 4-(subst.- benzyloxy)-phenyl eckige klammer zu -n'- methyl-n'-methoxyharnstoffe, verfahren zu ihrer herstellung und ihre verwendung als herbizide
DE2101938C2 (de)	1983-05-11	3-[2-Chlor-4-(3,3-dimethylureido)-phenyl]-5-tert.-butyl-1,3,4-oxadiazolon-(2), seine Herstellung und herbicide Zusammensetzungen, die es enthalten
DE2619303A1 (de)	1976-11-18	Neue schwefelhaltige bisformamidine, verfahren zu ihrer herstellung und verwendung derselben sowie diese enthaltende land-, garten- und forstwirtschaftliche chemikalien
CH628017A5 (de)	1982-02-15	Verfahren zur herstellung der neuen verbindung n-(4-benzyloxyphenyl)-n'-methyl-n'-methoxyharnstoff.
DD149935A5 (de)	1981-08-05	Verfahren zur herstellung von racemen oder optisch aktivem 2-(propargyloxyimino)-1,7,7-trimethylbicyclo(2,2,1)heptan
DE2554866A1 (de)	1976-06-16	Fungizide zusammensetzung
DD251275A5 (de)	1987-11-11	Als akarizid wirksame zusammensetzungen
DE2436957A1 (de)	1975-02-27	Carbaminsaeure-derivate
CH632997A5 (en)	1982-11-15	Plant growth regulator
DE1953422C3 (de)	1975-03-27	Fungicides Mittel für Landwirtschaft und Gartenbau
DE2125997A1 (de)	1971-12-09	Neue Phosphonamidothioate
DE2511897C2 (de)	1985-10-10	2,6-Dinitroaniline, Verfahren zu ihrer Herstellung und diese enthaltende herbizide Mittel
DE2624094A1 (de)	1976-12-02	N-carbamoyl-n-phenylaminosaeure-derivate, verfahren zu ihrer herstellung und herbizide mittel
EP0023539B1 (de)	1983-01-12	3-(N-1,3,4-Thiadiazolyl-2)-amino-alkyl-acrylsäurealkylester, Verfahren zu ihrer Herstellung und ihre Verwendung als Pflanzenbakterizide
CH628210A5 (en)	1982-02-26	Herbicidal preparation
DD236868A5 (de)	1986-06-25	Mittel zum protahieren der wirkungsdauer und zur erhoehung der selektivitaet von herbiziden zusammensetzungen
DE2061051B2 (de)	1980-01-03	Thiocarbamidsäureester, Verfahren zu ihrer Herstellung und Mittel, die diese Thiocarbamidsäureester als Wirkstoff erhalten
EP0016731B1 (de)	1983-02-16	Meta-Cyanoalkoxy-Phenylharnstoffe mit herbizider Wirkung, deren Herstellung und sie enthaltende Mittel
DE2548898A1 (de)	1976-05-06	Benzothiazolderivate, verfahren zu ihrer herstellung und ihre verwendung als herbizide
EP0092632B1 (de)	1985-09-04	Neue Benzonitrilderivate, Verfahren zu ihrer Herstellung und herbicide Mittel
DE1801279C (de)	1971-09-09	2 Methyl 5 sek bzw tert butyl phenyl N methylcarbamat und ihre Verwen dung als Insektizide