DD260702A5 - Verfahren zur polymerisation von halogenvinyl-monomeren in waessriger suspension - Google Patents

Verfahren zur polymerisation von halogenvinyl-monomeren in waessriger suspension Download PDF

Info

Publication number: DD260702A5
Authority: DD; German Democratic Republic
Prior art keywords: polymerization; reactor; acid; solution; salt
Prior art date: 1986-05-16

Application number

DD87302821A

Other languages

German (de)

English (en)

Inventor

Giovanni P Crose

Angelo C Arnaldi

Giovanni Benussi

Graziano Vidotto

Original Assignee

��@��@��@�K@�K@�Kk��

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-05-16

Filing date

1987-05-15

Publication date

1988-10-05

1987-05-15 Application filed by ��@��@��@�K@�K@�Kk�� filed Critical ��@��@��@�K@�K@�Kk��

1988-10-05 Publication of DD260702A5 publication Critical patent/DD260702A5/de

Links

239000000178 monomer Substances 0.000 title claims abstract description 20
238000000034 method Methods 0.000 title claims description 20
230000000379 polymerizing effect Effects 0.000 title claims description 6
229920002554 vinyl polymer Polymers 0.000 title abstract description 3
229910052736 halogen Inorganic materials 0.000 title abstract 2
-1 HALOGEN VINYL Chemical class 0.000 title description 10
239000000725 suspension Substances 0.000 title description 3
238000006116 polymerization reaction Methods 0.000 claims abstract description 27
150000003839 salts Chemical class 0.000 claims abstract description 18
239000000375 suspending agent Substances 0.000 claims abstract description 8
239000003999 initiator Substances 0.000 claims abstract description 6
239000006185 dispersion Substances 0.000 claims abstract description 5
239000002184 metal Substances 0.000 claims abstract description 4
150000003254 radicals Chemical class 0.000 claims abstract 2
230000008569 process Effects 0.000 claims description 10
239000002253 acid Substances 0.000 claims description 5
239000007900 aqueous suspension Substances 0.000 claims description 5
125000000129 anionic group Chemical group 0.000 claims description 3
125000000896 monocarboxylic acid group Chemical group 0.000 claims description 2
206010039509 Scab Diseases 0.000 abstract description 12
230000015572 biosynthetic process Effects 0.000 abstract description 7
125000002091 cationic group Chemical group 0.000 abstract description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract description 3
239000000654 additive Substances 0.000 abstract description 2
150000002367 halogens Chemical class 0.000 abstract description 2
229910052757 nitrogen Inorganic materials 0.000 abstract description 2
230000008021 deposition Effects 0.000 abstract 1
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 23
239000000243 solution Substances 0.000 description 22
QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 17
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 16
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 14
229920001577 copolymer Polymers 0.000 description 12
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 11
238000013459 approach Methods 0.000 description 11
JBIJLHTVPXGSAM-UHFFFAOYSA-N 2-naphthylamine Chemical compound C1=CC=CC2=CC(N)=CC=C21 JBIJLHTVPXGSAM-UHFFFAOYSA-N 0.000 description 10
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
229920000642 polymer Polymers 0.000 description 9
239000002904 solvent Substances 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
235000011037 adipic acid Nutrition 0.000 description 7
239000001361 adipic acid Substances 0.000 description 7
239000000203 mixture Substances 0.000 description 7
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 6
125000004432 carbon atom Chemical group C* 0.000 description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
239000000975 dye Substances 0.000 description 5
230000007062 hydrolysis Effects 0.000 description 5
238000006460 hydrolysis reaction Methods 0.000 description 5
239000000126 substance Substances 0.000 description 5
KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 description 4
UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 4
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 4
SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 4
GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 4
NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 4
KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 4
KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 4
RDOWQLZANAYVLL-UHFFFAOYSA-N phenanthridine Chemical compound C1=CC=C2C3=CC=CC=C3C=NC2=C1 RDOWQLZANAYVLL-UHFFFAOYSA-N 0.000 description 4
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 3
PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 3
229910000831 Steel Inorganic materials 0.000 description 3
238000004140 cleaning Methods 0.000 description 3
235000019441 ethanol Nutrition 0.000 description 3
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
230000004048 modification Effects 0.000 description 3
238000012986 modification Methods 0.000 description 3
239000003505 polymerization initiator Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000010959 steel Substances 0.000 description 3
BAXOFTOLAUCFNW-UHFFFAOYSA-N 1H-indazole Chemical compound C1=CC=C2C=NNC2=C1 BAXOFTOLAUCFNW-UHFFFAOYSA-N 0.000 description 2
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 2
HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical compound [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
125000002877 alkyl aryl group Chemical group 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
125000000751 azo group Chemical group [*]N=N[*] 0.000 description 2
239000001913 cellulose Substances 0.000 description 2
229920002678 cellulose Polymers 0.000 description 2
229920003086 cellulose ether Polymers 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
125000000753 cycloalkyl group Chemical group 0.000 description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 2
RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
150000002976 peresters Chemical class 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
238000000746 purification Methods 0.000 description 2
PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 2
CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
230000009467 reduction Effects 0.000 description 2
239000001587 sorbitan monostearate Substances 0.000 description 2
235000011076 sorbitan monostearate Nutrition 0.000 description 2
229940035048 sorbitan monostearate Drugs 0.000 description 2
238000005507 spraying Methods 0.000 description 2
PCJGHYSTCBLKIA-UHFFFAOYSA-N (1-acetylcyclohexyl)sulfonyloxy 1-acetylcyclohexane-1-sulfonate Chemical compound C1CCCCC1(C(C)=O)S(=O)(=O)OOS(=O)(=O)C1(C(=O)C)CCCCC1 PCJGHYSTCBLKIA-UHFFFAOYSA-N 0.000 description 1
ZVBFXRWQTYTMRU-UHFFFAOYSA-N (1-butylcyclohexyl) carboxyoxy carbonate Chemical compound OC(=O)OOC(=O)OC1(CCCC)CCCCC1 ZVBFXRWQTYTMRU-UHFFFAOYSA-N 0.000 description 1
CBYABTHXYJJUTO-UHFFFAOYSA-N (1-tert-butylcyclohexyl) carboxyoxy carbonate Chemical compound OC(=O)OOC(=O)OC1(C(C)(C)C)CCCCC1 CBYABTHXYJJUTO-UHFFFAOYSA-N 0.000 description 1
LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 1
TZJQCUDHKUWEFU-UHFFFAOYSA-N 2,2-dimethylpentanenitrile Chemical compound CCCC(C)(C)C#N TZJQCUDHKUWEFU-UHFFFAOYSA-N 0.000 description 1
VEPOHXYIFQMVHW-XOZOLZJESA-N 2,3-dihydroxybutanedioic acid (2S,3S)-3,4-dimethyl-2-phenylmorpholine Chemical compound OC(C(O)C(O)=O)C(O)=O.C[C@H]1[C@@H](OCCN1C)c1ccccc1 VEPOHXYIFQMVHW-XOZOLZJESA-N 0.000 description 1
VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
108010010803 Gelatin Proteins 0.000 description 1
235000000177 Indigofera tinctoria Nutrition 0.000 description 1
239000005639 Lauric acid Substances 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
150000007514 bases Chemical class 0.000 description 1
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
FPRSIFBSNOCHLZ-UHFFFAOYSA-N carboxyoxy propan-2-yl carbonate Chemical class CC(C)OC(=O)OOC(O)=O FPRSIFBSNOCHLZ-UHFFFAOYSA-N 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
239000008273 gelatin Substances 0.000 description 1
229920000159 gelatin Polymers 0.000 description 1
235000019322 gelatine Nutrition 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
229940097275 indigo Drugs 0.000 description 1
COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000002609 medium Substances 0.000 description 1
150000005002 naphthylamines Chemical class 0.000 description 1
229920005615 natural polymer Polymers 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
239000001005 nitro dye Substances 0.000 description 1
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
150000002832 nitroso derivatives Chemical class 0.000 description 1
231100000989 no adverse effect Toxicity 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
150000002897 organic nitrogen compounds Chemical class 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
150000002898 organic sulfur compounds Chemical class 0.000 description 1
RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
230000002265 prevention Effects 0.000 description 1
239000000047 product Substances 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
150000004053 quinones Chemical class 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
238000004544 sputter deposition Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
239000000988 sulfur dye Substances 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
239000001017 thiazole dye Substances 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
238000009736 wetting Methods 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
- C08F2/004—Scale prevention in a polymerisation reactor or its auxiliary parts by a prior coating on the reactor walls

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

DD87302821A 1986-05-16 1987-05-15 Verfahren zur polymerisation von halogenvinyl-monomeren in waessriger suspension DD260702A5 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT20470/86A IT1190641B (it)	1986-05-16	1986-05-16	Procedimento per la polimerizzazione in sospensione acquosa di monomeri vinilici contenenti alogeno

Publications (1)

Publication Number	Publication Date
DD260702A5 true DD260702A5 (de)	1988-10-05

Family

ID=11167430

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD87302821A DD260702A5 (de)	1986-05-16	1987-05-15	Verfahren zur polymerisation von halogenvinyl-monomeren in waessriger suspension

Country Status (11)

Country	Link
BE (1)	BE1000425A5 (cs)
BG (1)	BG46748A3 (cs)
CS (1)	CS276393B6 (cs)
DD (1)	DD260702A5 (cs)
EG (1)	EG18374A (cs)
ES (1)	ES2006486A6 (cs)
FR (1)	FR2598710B1 (cs)
GB (1)	GB2190604B (cs)
IT (1)	IT1190641B (cs)
PL (1)	PL155094B1 (cs)
YU (1)	YU46202B (cs)

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE91560C (cs) *	1970-05-07
CA1077197A (en) *	1975-03-24	1980-05-06	Kazuhiko Kurimoto	Method for bulk polymerization of vinyl chloride
JPS5213592A (en) *	1975-07-23	1977-02-01	Shin Etsu Chem Co Ltd	Polymerization of vinyl chloride
JPS5223187A (en) *	1975-08-14	1977-02-21	Shin Etsu Chem Co Ltd	Process for polymerizing vinyl monomers
GB1578805A (en) *	1976-07-21	1980-11-12	Ici Australia Ltd	Vinyl halide polymerisation process and reactor and coating composition
GR64894B (en) *	1977-01-25	1980-06-07	Shinetsu Chemical Co	Method for the polymerization of a vinyl menomer
US4220743A (en) *	1977-03-08	1980-09-02	Ici Australia Limited	Process for aqueous dispersion polymerization of vinyl halide monomers in coated reactor
US4255470A (en) *	1977-07-15	1981-03-10	The B. F. Goodrich Company	Process for preventing polymer buildup in a polymerization reactor

1986
- 1986-05-16 IT IT20470/86A patent/IT1190641B/it active
1987
- 1987-05-11 GB GB8711095A patent/GB2190604B/en not_active Expired - Lifetime
- 1987-05-14 BE BE8700534A patent/BE1000425A5/fr not_active IP Right Cessation
- 1987-05-14 BG BG079754A patent/BG46748A3/xx unknown
- 1987-05-14 EG EG277/87A patent/EG18374A/xx active
- 1987-05-15 PL PL1987265715A patent/PL155094B1/pl unknown
- 1987-05-15 YU YU87387A patent/YU46202B/sh unknown
- 1987-05-15 ES ES8701686A patent/ES2006486A6/es not_active Expired
- 1987-05-15 DD DD87302821A patent/DD260702A5/de not_active IP Right Cessation
- 1987-05-15 CS CS873541A patent/CS276393B6/cs unknown
- 1987-05-15 FR FR878706850A patent/FR2598710B1/fr not_active Expired - Lifetime

Also Published As

Publication number	Publication date
IT8620470A1 (it)	1987-11-16
IT8620470A0 (it)	1986-05-16
PL265715A1 (en)	1988-07-21
GB2190604B (en)	1990-05-30
FR2598710A1 (fr)	1987-11-20
IT1190641B (it)	1988-02-16
EG18374A (en)	1992-10-30
BG46748A3 (en)	1990-02-15
GB8711095D0 (en)	1987-06-17
PL155094B1 (en)	1991-10-31
GB2190604A (en)	1987-11-25
YU46202B (sh)	1993-05-28
YU87387A (en)	1988-04-30
CS354187A3 (en)	1992-01-15
BE1000425A5 (fr)	1988-12-06
CS276393B6 (en)	1992-05-13
FR2598710B1 (fr)	1991-05-24
ES2006486A6 (es)	1989-05-01

Legal Events

Date	Code	Title	Description
1996-06-20	ENJ	Ceased due to non-payment of renewal fee

Publication	Publication Date	Title
DE2165239A1 (de)	1972-07-27	Verfahren zur Herstellung von Fluorelastomer-Terpolymeren
DE2357869C2 (de)	1986-10-16	Verfahren zur Herstellung von Vinylchloridpolymeren
DE2834939A1 (de)	1979-02-22	Dispersionsstabilisator fuer die suspensionspolymerisation von vinylverbindungen
DE2518260A1 (de)	1976-03-04	Verbesserte suspensionspolymerisation von vinylchloridmonomeren bzw. gemischen davon mit anderen vinylmonomeren
US3959235A (en)	1976-05-25	Method of polymerizing vinyl chloride
DE3019390A1 (de)	1980-12-04	Verfahren zur unterdrueckung der bildung von polymerkrusten
EP0152115B1 (de)	1989-02-08	Verfahren zur Herstellung von Polymerisaten ethylenisch ungesättigter Verbindungen
DE2757065C2 (de)	1982-03-11	Verfahren zur Polymerisation von Vinylchlorid, allein oder zusammen mit anderen Vinylhalogeniden oder anderen mit Vinylchlorid copolymerisierbaren Comonomeren, in wäßriger Dispersion und Reaktionsgefäß zu dessen Durchführung
DE2555568C2 (de)	1982-11-25	Verfahren zur Suspensionspolymerisation von Vinylchlorid
DE2538148C2 (de)	1984-04-05	Verfahren zur Verhinderung der Anreicherung eines Polymerisats auf den inneren Oberflächen eines Polymerisationsgefäßes während der Polymerisation in wäßriger Dispersion
EP0003035B1 (de)	1982-03-24	Verfahren zur Herstellung von Vinylchlorid-Polymerisaten sowie Polymerisationsgefäss zur Ausführung des Verfahrens
DD260702A5 (de)	1988-10-05	Verfahren zur polymerisation von halogenvinyl-monomeren in waessriger suspension
DE68919163T2 (de)	1995-03-09	Verfahren zur Unterdrückung der Bildung von Polymerkrusten.
EP0019198A1 (de)	1980-11-26	Verfahren zur Herstellung von Vinylchlorid-Polymerisaten, Mittel zur Beschichtung von Polymerisationsgefässen sowie das damit beschichtete Polymerisationsgefäss
DE2632468C2 (cs)	1989-04-20
DE2637582A1 (de)	1977-03-03	Verfahren zur herstellung von vinylchloridpolymeren
US4374966A (en)	1983-02-22	Process for the manufacture of vinyl chloride polymers by coating polymerization vessels
DE3019389A1 (de)	1980-12-04	Verfahren zur unterdrueckung der bildung von polymerkrusten
DE2437044B2 (de)	1979-05-23	Verfahren zur Herstellung von Polymerisaten und Copolymerisaten des Vinylchlorids durch Suspensionspolymerisation
EP0019197A1 (de)	1980-11-26	Verfahren zur Herstellung von Vinylchlorid-Polymerisaten, Mittel zur Beschichtung von Polymerisationsgefässen sowie das damit beschichtete Polymerisationsgefäss
EP0081777A2 (de)	1983-06-22	Verfahren zur Herstellung von Vinylchlorid-Polymerisaten
DD231363A5 (de)	1985-12-24	Verfahren zur polymerisation von vinychlorid
DE3039543A1 (de)	1981-09-10	Verfahren zur herstellung von pvc-harzen
DE69808541T2 (de)	2003-07-10	Verfahren zur Herstellung von Polymeren ausgehend von N-Vinylacetamid-Monomeren
DE2313277A1 (de)	1974-09-19	Verfahren zur polymerisation von vinylchlorid