DK1603979T3 - Begroningshæmmende malingsammensætning - Google Patents
Begroningshæmmende malingsammensætning Download PDFInfo
- Publication number
- DK1603979T3 DK1603979T3 DK04720227.0T DK04720227T DK1603979T3 DK 1603979 T3 DK1603979 T3 DK 1603979T3 DK 04720227 T DK04720227 T DK 04720227T DK 1603979 T3 DK1603979 T3 DK 1603979T3
- Authority
- DK
- Denmark
- Prior art keywords
- parts
- monomer
- group
- meth
- acrylate
- Prior art date
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- LDHNBZQNIWUKEG-UHFFFAOYSA-L zinc;2-fluoroacetate Chemical compound [Zn+2].[O-]C(=O)CF.[O-]C(=O)CF LDHNBZQNIWUKEG-UHFFFAOYSA-L 0.000 description 1
- FIHFSAQQCBNMHR-UHFFFAOYSA-L zinc;2-nitrobenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1[N+]([O-])=O.[O-]C(=O)C1=CC=CC=C1[N+]([O-])=O FIHFSAQQCBNMHR-UHFFFAOYSA-L 0.000 description 1
- NZBPBKKXMQWABX-UHFFFAOYSA-L zinc;2-nitronaphthalene-1-carboxylate Chemical compound [Zn+2].C1=CC=C2C(C(=O)[O-])=C([N+]([O-])=O)C=CC2=C1.C1=CC=C2C(C(=O)[O-])=C([N+]([O-])=O)C=CC2=C1 NZBPBKKXMQWABX-UHFFFAOYSA-L 0.000 description 1
- NVKSAUAQUPYOPO-UHFFFAOYSA-L zinc;decanoate Chemical compound [Zn+2].CCCCCCCCCC([O-])=O.CCCCCCCCCC([O-])=O NVKSAUAQUPYOPO-UHFFFAOYSA-L 0.000 description 1
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 1
- GJAPSKMAVXDBIU-UHFFFAOYSA-L zinc;hexadecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O GJAPSKMAVXDBIU-UHFFFAOYSA-L 0.000 description 1
- PKJOUIVGCFHFTK-UHFFFAOYSA-L zinc;hexanoate Chemical compound [Zn+2].CCCCCC([O-])=O.CCCCCC([O-])=O PKJOUIVGCFHFTK-UHFFFAOYSA-L 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 description 1
- XDWXRAYGALQIFG-UHFFFAOYSA-L zinc;propanoate Chemical compound [Zn+2].CCC([O-])=O.CCC([O-])=O XDWXRAYGALQIFG-UHFFFAOYSA-L 0.000 description 1
- WNZNEKPFXJXMSK-UHFFFAOYSA-L zinc;quinoline-2-carboxylate Chemical compound [Zn+2].C1=CC=CC2=NC(C(=O)[O-])=CC=C21.C1=CC=CC2=NC(C(=O)[O-])=CC=C21 WNZNEKPFXJXMSK-UHFFFAOYSA-L 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1637—Macromolecular compounds
- C09D5/165—Macromolecular compounds containing hydrolysable groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Claims (13)
1. Begroningshæmmende malingsammensætning omfattende en copolymer opnået ved polymerisering afen monomerblanding omfattende siliciumindeholdende polymeriserbar monomer (a) med to (meth)acryl endegrupper og metalatom-indeholdende polymeriserbar monomer (c) med bivalent metalatom, hvor copolymeren indeholder et bivalent metalatom, hvor monomer (a) er monomer (ai) vist med den følgende formel (I): CH2=C(R1)-CO-0-(CkH2k-0-)i-CmH2m-(-SiR2R3-0-)n-SiR4R5-CoH2o-(-0-CPH2p-)q-0-C0-C(R6) = CH2 (I) hvor hver af R1 og R6 uafhængigt betegner et hydrogenatom eller en methylgruppe; hver af k og p betegner et helt tal på 2 til 5; hver af I og q betegner 0 til 50; hver af m og o betegner et helt tal på 2 til 5; n betegner 3 til 80; hver af R2, R3 R4, og R5 uafhængigt betegner en alkylgruppe, en alkoxygruppe, en phenylgruppe, en substitueret phenylgruppe, en phenoxygruppe, eller en substitueret phenoxygruppe, eller hvor monomer (a) er monomer (a2) vist med den følgende formel (II): CH2 = C(R11)-C0-0-(Ck’H2k-0-)|-Cm’H2m-Si(-(-0SiR12R13-)r-0SiR14R15R16)2-0Si(-(-0SiR17R18-)s-0SiR19R20R21)2-Co,H2o-(-0-Cp,H2p,-)q,-O-CO-C(R22)=CH2 (II) hvor hver af R11 og R22 uafhængigt betegner et hydrogenatom eller en methylgruppe; hver af k' og p' betegner et helt tal på 2 til 5; hver af 1' og q' betegner 0 til 50; hver af m' og o' betegner et helt tal på 2 til 5; hver af r og s betegner 0 til 20; hver af R12, R13, R14, R15, R16, R17, R18, R19, R20, og R21 uafhængigt betegner en alkylgruppe.
2. Den begroningshæmmende malingsammensætning ifølge krav 1, hvor en mængde af monomer (a) i monomerblandingen er indenfor området på 0,1 til 30 vægtprocent, og en mængde af det bivalente metalatom i copolymeren er indenfor området på 1 til 25 vægtprocent.
3. Den begroningshæmmende malingsammensætning ifølge et hvilket som helst af kravene 1 eller 2, hvor copolymeren opnås ved polymerisering af monomerblandingen yderligere omfattende silicium-indeholdende polymeriserbar monomer (b) med én (meth)acryl endegruppe.
4. Den begroningshæmmende malingsammensætning ifølge krav 3, hvor monomer (b) omfatter monomer (bi) vist med den følgende formel (III): CH2=C(R41)-C0-0-(CuH2u-0-)v-CwH2w-(-SiR42R43-0-)x-SiR44R45R46 (III) hvor R41 betegner et hydrogenatom eller en methylgruppe; u betegner et helt tal på 2 til 5; v betegner 0 til 50; w betegner et helt tal på 2 til 5; x betegner 3 til 80; hver af R42, R43, R44, R45, og R46 uafhængigt betegner en alkylgruppe, en alkoxygruppe, en phenylgruppe, en substitueret phenylgruppe, en phenoxy-gruppe, eller en substitueret phenoxygruppe.
5. Den begroningshæmmende malingsammensætning ifølge krav 3, hvor monomer (b) omfatter monomer (b2) vist med den følgende formel (IV): CH2=C(R51)-C0-0-(Cu’H2u'-0-)v-Cw’H2w-Si(-0SiR52R53R54)3 (IV) hvor R51 betegner et hydrogenatom eller en methylgruppe; u1 betegner et helt tal på 2 til 5; ν' betegner 0 til 50; w' betegner et helt tal på 2 til 5; hver af R52, R53, og R54 betegner en alkylgruppe, R55 (der betegner -(-0-SiR56R57-)y-0SiR58R59R60 hvor y betegner et helt tal på 0 til 20; hver af R56, R57, R58, R59, og R60 uafhængigt betegner en alkylgruppe), og R61 (der betegner -R62-(-OC2H4)y-OR63 hvor y' betegner et helt tal på 1 til 20; hver af R62 og R63 uafhængigt betegner en alkylgruppe).
6. Den begroningshæmmende malingsammensætning ifølge et hvilket som helst af kravene 3 eller 4, hvor mængden af den silicium-indeholdende polymeriserbare monomer (a) og den silicium-indeholdende polymeriserbare monomer (b) i monomerblandingen er indenfor området på 1 til 60 vægtprocent.
7. Den begroningshæmmende malingsammensætning ifølge krav 1, hvor monomer (c) omfatter én eller flere slags monomerer valgt fra metal-atom-indeholdende polymeriserbar monomer (ci) med to umættede grupper og metalatom-indeholdende polymeriserbar monomer (C2) vist med den følgende formel (V): CH2=C(R71)-C0-0-M-R72 (V) hvor R71 betegner et hydrogenatom eller en methylgruppe; M betegner Mg, Zn, or Cu; og R72 betegner en organisk syregruppe eller en alkoholgruppe.
8. Begroningshæmmende malingsammensætning omfattende en copolymer opnået ved polymerisering afen monomerblanding omfattende siliciumindeholdende polymeriserbar monomer (b) med én (meth)acryl endegruppe, og metalatom-indeholdende polymeriserbar monomer (ci) med to umættede grupper og med metalatom valgt fra Mg, Zn, og Cu, hvor monomer (b) omfatter monomer (bi) vist med den følgende formel (III): CH2=C(R4)-C0-0-(CuH2u-0-)v-CwH2w-(-SiR42R43-0-)x-SiR44R45R46 (III) hvor R41 betegner et hydrogenatom eller en methylgruppe; u betegner et helt tal på 2 til 5; v betegner 0 til 50; w betegner et helt tal på 2 til 5; x betegner 3 til 80; hver af R42, R43, R44, R45, og R46 uafhængigt betegner en alkylgruppe, en alkoxygruppe, en phenylgruppe, en substitueret phenylgruppe, en pnenoxygruppe, eller en substitueret phenoxygruppe, eller hvor monomer (b) omfatter monomer (b2) vist med den følgende formel (IV): CH2=C(R51)-C0-0-(Cu-H2u-0-)v-CwH2w'-Si(-0SiR52R53R54)3 (IV) hvor R51 betegner et hydrogenatom eller en methylgruppe; u' betegner et helt tal på 2 til 5; ν' betegner O til 50; w' betegner et helt tal på 2 til 5; hver af R52, R53, og R54 uafhængigt betegner en alkylgruppe, R55 (der betegner -(-0-SiR56R57-)y-OSiR58R59R60 hvor y betegner et helt tal på 0 til 20; hver af R56, R57, R58, R59, og R60 uafhængigt betegner en alkylgruppe), og R61 (der betegner -R62-(-OC2H4)y-OR63 hvor y' betegner et helt tal på 1 til 20; hver af R62 og R63 uafhængigt betegner en alkylgruppe).
9. Den begroningshæmmende malingsammensætning ifølge krav 8, hvor en mængde af den silicium-indeholdende polymeriserbare monomer (b) i monomerblandingen er indenfor området på 1 til 60 vægtprocent, og en mængde af den metalatom-indeholdende polymeriserbare monomer (ci) er indenfor området på 1 til 50 vægtprocent.
10. Den begroningshæmmende malingsammensætning ifølge krav 8, hvor copolymeren opnås ved polymerisering af monomerblandingen yderligere omfattende metalatom-indeholdende polymeriserbar monomer (C2) vist med den følgende formel (V): CH2=C(R71)-C0-0-M-R72 (V) hvor R71 betegner et hydrogenatom eller en methylgruppe; M betegner Mg, Zn, eller Cu; og R72 betegner en organisk syregruppe eller en alkoholgruppe.
11. Den begroningshæmmende malingsammensætning ifølge krav 10, i hvilken forholdet (mol) af den metalatom-indeholdende polymeriserbare monomer (ci) og den metalatom-indeholdende polymeriserbare monomer (C2) i monomerblandingen ((C2)/(ci)) er indenfor området på 20/80 til 80/20.
12. Den begroningshæmmende malingsammensætning ifølge krav 10, hvor mængden af den metalatom-indeholdende polymeriserbare monomer (ci) og den metalatom-indeholdende polymeriserbare monomer (C2) i monomerblandingen er indenfor området på 1 til 50 vægtprocent.
13. Fremgangsmåde til forebyggelse af vedhæftning af marin organisme og/eller tang på en overflade omfattende: påføre den begroningshæmmende malingsammensætning ifølge krav 1 eller 8 til en overflade med behov derfor.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003069916 | 2003-03-14 | ||
| JP2003087957 | 2003-03-27 | ||
| JP2004002078A JP4154344B2 (ja) | 2003-03-14 | 2004-01-07 | 塗料組成物及び共重合体 |
| JP2004002079A JP4154345B2 (ja) | 2003-03-27 | 2004-01-07 | 塗料組成物及び共重合体 |
| PCT/JP2004/003376 WO2004081121A1 (en) | 2003-03-14 | 2004-03-12 | Antifouling paint composition |
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| DK1603979T3 true DK1603979T3 (da) | 2016-09-05 |
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| DK04720227.0T DK1603979T3 (da) | 2003-03-14 | 2004-03-12 | Begroningshæmmende malingsammensætning |
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| EP (1) | EP1603979B1 (da) |
| KR (1) | KR101003602B1 (da) |
| DK (1) | DK1603979T3 (da) |
| NO (1) | NO334529B1 (da) |
| TW (1) | TWI303654B (da) |
| WO (1) | WO2004081121A1 (da) |
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| CN101675126B (zh) * | 2007-05-01 | 2014-07-30 | 阿克佐诺贝尔国际涂料股份有限公司 | 基于可固化聚有机硅氧烷聚氧化烯共聚物的防污涂料组合物 |
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| CN102575126B (zh) * | 2009-10-13 | 2014-08-20 | 日本油漆船舶涂料公司 | 防污涂料组合物以及防污涂膜、复合涂膜和水中结构物 |
| JP5415551B2 (ja) * | 2009-10-13 | 2014-02-12 | 日本ペイントマリン株式会社 | 防汚塗料組成物、ならびに防汚塗膜、複合塗膜および水中構造物 |
| WO2011074620A1 (ja) | 2009-12-18 | 2011-06-23 | 中国塗料株式会社 | 金属架橋型オルガノポリシロキサンチオブロックビニル共重合体および該金属架橋型共重合体を含有する防汚塗料組成物 |
| CN107513300A (zh) * | 2010-04-06 | 2017-12-26 | 三菱化学株式会社 | 防污涂料组合物、防污涂膜的制造方法及防污涂膜 |
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| SG11201908632RA (en) | 2017-03-29 | 2019-10-30 | Mitsubishi Chem Corp | (meth)acrylic copolymer, method for producing same, resin composition and antifouling paint composition |
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| JPH07108958B2 (ja) * | 1993-09-01 | 1995-11-22 | 日本ペイント株式会社 | 撥水型防汚塗料組成物 |
| JPH08259645A (ja) | 1995-03-28 | 1996-10-08 | Hitachi Chem Co Ltd | グラフト共重合体、その製造法及び塗料 |
| JP3247058B2 (ja) * | 1996-12-06 | 2002-01-15 | 日立造船株式会社 | 破壊装置 |
| JPH10168350A (ja) * | 1996-12-10 | 1998-06-23 | Mitsubishi Rayon Co Ltd | 防汚性塗料組成物 |
| DK2009069T3 (da) * | 1997-05-20 | 2013-04-22 | Mitsubishi Rayon Co | Begroningshindrende malingssammensætning |
| JPH11166152A (ja) * | 1997-12-05 | 1999-06-22 | Nof Corp | 水中防汚被覆剤 |
| JP4573929B2 (ja) | 1999-09-06 | 2010-11-04 | 中国塗料株式会社 | ポリシロキサン−アクリル樹脂ブロック共重合体組成物、防汚剤組成物、防汚塗膜、防汚処理基材、並びに基材の防汚処理方法 |
| JP4647060B2 (ja) * | 2000-05-12 | 2011-03-09 | 中国塗料株式会社 | 防汚塗料組成物、防汚塗膜、該防汚塗膜で被覆された船舶または水中構造物ならびに船舶外板または水中構造物の防汚方法 |
| JP3483524B2 (ja) | 2000-06-28 | 2004-01-06 | 三菱レイヨン株式会社 | 金属含有樹脂組成物および防汚性塗料組成物 |
| JP2002294159A (ja) * | 2001-03-30 | 2002-10-09 | Kansai Paint Co Ltd | 防汚性塗膜形成性塗料組成物 |
-
2004
- 2004-03-03 TW TW93105486A patent/TWI303654B/zh not_active IP Right Cessation
- 2004-03-12 WO PCT/JP2004/003376 patent/WO2004081121A1/en not_active Ceased
- 2004-03-12 US US10/548,638 patent/US7928175B2/en active Active
- 2004-03-12 DK DK04720227.0T patent/DK1603979T3/da active
- 2004-03-12 EP EP04720227.0A patent/EP1603979B1/en not_active Expired - Lifetime
- 2004-03-12 KR KR1020057017092A patent/KR101003602B1/ko not_active Expired - Fee Related
-
2005
- 2005-10-11 NO NO20054666A patent/NO334529B1/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| TW200508338A (en) | 2005-03-01 |
| EP1603979A1 (en) | 2005-12-14 |
| NO20054666L (no) | 2005-12-14 |
| NO334529B1 (no) | 2014-03-31 |
| EP1603979B1 (en) | 2016-06-29 |
| EP1603979A4 (en) | 2006-04-05 |
| WO2004081121A1 (en) | 2004-09-23 |
| US20060258772A1 (en) | 2006-11-16 |
| KR101003602B1 (ko) | 2010-12-23 |
| US7928175B2 (en) | 2011-04-19 |
| TWI303654B (en) | 2008-12-01 |
| KR20050118677A (ko) | 2005-12-19 |
| NO20054666D0 (no) | 2005-10-11 |
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