ECSP10010006A - Derivado de oxopirazina y herbicida - Google Patents
Derivado de oxopirazina y herbicidaInfo
- Publication number
- ECSP10010006A ECSP10010006A EC2010010006A ECSP10010006A ECSP10010006A EC SP10010006 A ECSP10010006 A EC SP10010006A EC 2010010006 A EC2010010006 A EC 2010010006A EC SP10010006 A ECSP10010006 A EC SP10010006A EC SP10010006 A ECSP10010006 A EC SP10010006A
- Authority
- EC
- Ecuador
- Prior art keywords
- derivative
- salt
- atom
- oxopirazine
- herbicide
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/04—Ortho-condensed systems
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P13/00—Drugs for disorders of the urinary system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
- C07D241/36—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems
- C07D241/38—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems with only hydrogen or carbon atoms directly attached to the ring nitrogen atoms
- C07D241/40—Benzopyrazines
- C07D241/44—Benzopyrazines with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Pharmacology & Pharmacy (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Medicinal Chemistry (AREA)
- Public Health (AREA)
- Urology & Nephrology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
Se describe un derivado de oxopirazina que tiene excelente actividad herbicida, exhibiendo al mismo tiempo alta seguridad para cosechas útiles, o una sal del mismo. También se describe un herbicida que contiene dicho derivado de oxipirazina o una sal del mismo. Se describe de manera específica un derivado de oxipirazina representado por la fórmula general [I] que se encuentra más adelante o una sal del mismo. También se describe en forma específica un herbicida que contiene cualesquiera de los compuestos. (En la fórmula X1 representa un átomo de oxígeno o un átomo de azufre; X2 representa CH o N(O)m; en donde m representa un entero de 0 ó 1; R1 representa un átomo de hidrógeno; un grupo C1-C12 alquilo o similar; R2 es un átomo de halógeno, un grupo ciano o similar; R3 representa un grupo hidroxilo; un átomo de halógeno o similar; A1 representa C(R4R5); A2 representa C(R6R7) o C=O; A3 representa (CR8R9); y R4-R9 cada uno representan un átomo de hidrógeno o un grupo alquilo).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007201387 | 2007-08-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ECSP10010006A true ECSP10010006A (es) | 2010-04-30 |
Family
ID=40304083
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EC2010010006A ECSP10010006A (es) | 2007-08-01 | 2010-03-01 | Derivado de oxopirazina y herbicida |
Country Status (30)
| Country | Link |
|---|---|
| US (2) | US8389523B2 (es) |
| EP (1) | EP2174934B1 (es) |
| JP (1) | JP5291624B2 (es) |
| KR (1) | KR101546819B1 (es) |
| CN (1) | CN101778832B (es) |
| AP (1) | AP2513A (es) |
| AR (1) | AR067763A1 (es) |
| AU (1) | AU2008283629B2 (es) |
| BR (1) | BRPI0813863B1 (es) |
| CA (1) | CA2694882C (es) |
| CO (1) | CO6160266A2 (es) |
| CR (1) | CR11184A (es) |
| CU (1) | CU23926B1 (es) |
| DO (1) | DOP2010000044A (es) |
| EA (1) | EA017807B1 (es) |
| EC (1) | ECSP10010006A (es) |
| ES (1) | ES2389320T3 (es) |
| HN (1) | HN2010000208A (es) |
| IL (1) | IL202378A (es) |
| MX (1) | MX2010001240A (es) |
| MY (1) | MY153045A (es) |
| NI (1) | NI201000018A (es) |
| NZ (1) | NZ582426A (es) |
| PL (1) | PL2174934T3 (es) |
| PT (1) | PT2174934E (es) |
| SV (1) | SV2010003470A (es) |
| TW (1) | TWI430749B (es) |
| UA (1) | UA100242C2 (es) |
| WO (1) | WO2009016841A1 (es) |
| ZA (1) | ZA200908210B (es) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2389442A4 (en) | 2009-01-22 | 2012-07-04 | Syngenta Participations Ag | MUTED HYDROXYLPHENYLPYRUVATE DIOXYGENASE POLYPEPTIDES AND METHOD OF THEIR USE |
| EP2394995B1 (en) * | 2009-02-03 | 2014-01-15 | Kumiai Chemical Industry CO., LTD. | Ring-fused 2-pyridone derivatives and herbicides |
| CA2771588C (en) | 2009-09-09 | 2018-07-31 | E I Du Pont De Nemours And Company | Herbicidal pyrimidone derivatives |
| CN102971302B (zh) | 2010-06-29 | 2015-11-25 | Fmc公司 | 6-酰基-1,2,4-三嗪-3,5-二酮衍生物及除草剂 |
| TWI549943B (zh) * | 2011-03-09 | 2016-09-21 | 杜邦股份有限公司 | 除草之含側氧與磺酸基(sulfono)雙氮雜環 |
| JP5927007B2 (ja) | 2011-04-11 | 2016-05-25 | 石原産業株式会社 | 除草組成物 |
| JP5875924B2 (ja) | 2011-04-14 | 2016-03-02 | 石原産業株式会社 | 除草組成物 |
| TW201247631A (en) * | 2011-04-28 | 2012-12-01 | Du Pont | Herbicidal pyrazinones |
| JP6389610B2 (ja) * | 2011-10-14 | 2018-09-12 | クミアイ化学工業株式会社 | 除草剤組成物 |
| US9550724B2 (en) | 2011-12-14 | 2017-01-24 | Ihara Chemical Industry Co., Ltd. | Diphenylamine compounds and production method thereof |
| ES2682893T3 (es) | 2012-03-09 | 2018-09-24 | Ishihara Sangyo Kaisha, Ltd. | Composición herbicida |
| GB201205654D0 (en) * | 2012-03-29 | 2012-05-16 | Syngenta Ltd | Herbicidal compounds |
| IN2014KN02601A (es) | 2012-04-24 | 2015-05-08 | Vertex Pharma | |
| WO2014086737A1 (de) * | 2012-12-06 | 2014-06-12 | Bayer Cropscience Ag | Kondensierte 2-pyridon-3-carboxamide und ihre verwendung als herbizide |
| JP6029995B2 (ja) * | 2013-02-04 | 2016-11-24 | クミアイ化学工業株式会社 | 除草剤組成物 |
| SMT202100687T1 (it) | 2013-03-12 | 2022-01-10 | Vertex Pharma | Inibitori della dna-pk |
| CN103271040B (zh) * | 2013-06-05 | 2015-03-11 | 江苏龙灯化学有限公司 | 一种协同除草组合物 |
| ES2705342T3 (es) | 2013-10-17 | 2019-03-22 | Vertex Pharma | Co-cristales de (S)-N-metil-8-(1-((2'-metil-[4,5'-bipirimidin]-6-il)amino)propan-2-il)quinolin-4-carboxamida y derivados deuterados de la misma como inhibidores de DNA-PK |
| JP5944597B2 (ja) * | 2014-06-16 | 2016-07-05 | イハラケミカル工業株式会社 | トリケトン化合物の製造方法 |
| KR101866271B1 (ko) * | 2015-06-01 | 2018-07-23 | 한국화학연구원 | 벤조일사이클로헥산다이온 화합물 및 이 화합물을 포함하는 제초제 |
| BR112018004779A8 (pt) | 2015-09-11 | 2022-08-09 | Bayer Cropscience Lp | Variantes de hppd e métodos de uso |
| CA3246612A1 (en) | 2016-07-08 | 2025-10-27 | Kumiai Chemical Industry Co., Ltd. | Herbicidal composition comprising an oxopyrazine compound |
| EP3518931A4 (en) | 2016-09-27 | 2020-05-13 | Vertex Pharmaceuticals Incorporated | METHOD FOR TREATING CANCER WITH A COMBINATION OF DNA-DAMAGING SUBSTANCES AND DNA-PK INHIBITORS |
| GB201618266D0 (en) * | 2016-10-28 | 2016-12-14 | Syngenta Participations Ag | Improvements in or relating to organic compounds |
| US11180770B2 (en) | 2017-03-07 | 2021-11-23 | BASF Agricultural Solutions Seed US LLC | HPPD variants and methods of use |
| AU2020214760B2 (en) | 2019-01-31 | 2021-10-21 | Kumiai Chemical Industry Co., Ltd. | Methods for producing nitroso compound and quinoxaline compound |
| US12240843B2 (en) | 2019-07-18 | 2025-03-04 | Qingdao Kingagroot Chemical Compound Co., Ltd. | Substituted 1,2,4-triazolo[4,3-a]pyridine derivative and preparation method, herbicidal composition and application thereof |
| CN110835321B (zh) * | 2019-11-28 | 2020-11-24 | 东北农业大学 | 一种含有喹喔啉结构的三酮类化合物、制备方法及其应用 |
| WO2023222834A1 (en) | 2022-05-20 | 2023-11-23 | Syngenta Crop Protection Ag | Herbicidal compositions |
| WO2025176774A1 (de) | 2024-02-22 | 2025-08-28 | Bayer Aktiengesellschaft | Herbizide zusammensetzungen |
| WO2025216304A1 (ja) * | 2024-04-12 | 2025-10-16 | クミアイ化学工業株式会社 | ジクロロメタン溶媒又はエーテル溶媒を用いたニトロソ化合物及びキノキサリン化合物の製造方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1408675A (en) * | 1973-03-16 | 1975-10-01 | Allen & Hanburys Ltd | Amides derived from quinoxaline |
| US4181724A (en) * | 1978-09-11 | 1980-01-01 | The Upjohn Company | Quinoxalinone compounds useful for expanding the lumina or air passages in mammals |
| JPH0678319B2 (ja) * | 1986-03-11 | 1994-10-05 | 東ソー株式会社 | キノキサリノン誘導体 |
| CA1340284C (en) | 1987-03-19 | 1998-12-22 | Zeneca Inc. | Herbicidal substituted cyclic diones |
| JP2638253B2 (ja) | 1990-04-20 | 1997-08-06 | 株式会社バイオセンサー研究所 | ビタミンｄ類定量用試薬およびその製法 |
| JPH0529853A (ja) * | 1991-07-22 | 1993-02-05 | Toshiba Corp | 直線性補正回路 |
| JP3098808B2 (ja) * | 1991-07-23 | 2000-10-16 | 株式会社日立製作所 | 半導体装置 |
| JP2000080085A (ja) * | 1997-09-01 | 2000-03-21 | Kyorin Pharmaceut Co Ltd | ６，７−非対称ジ置換キノキサリンカルボン酸誘導体とその付加塩及びそれらの製造方法 |
| AU744540B2 (en) | 1997-09-01 | 2002-02-28 | Kyorin Pharmaceutical Co. Ltd. | 6,7-asymmetrically disubstituted quinoxalinecarboxylic acid derivatives, addition salts thereof, and processes for the preparation of both |
| JPH11236375A (ja) * | 1997-12-03 | 1999-08-31 | Taisho Pharmaceut Co Ltd | １，２−ジヒドロ−２−オキソキノリン誘導体 |
| DE69826034T2 (de) * | 1997-12-03 | 2005-09-08 | Taisho Pharmaceutical Co., Ltd. | 1,2-dihydro-2-oxochinolin-derivate |
| SE0302324D0 (sv) * | 2003-08-28 | 2003-08-28 | Astrazeneca Ab | Novel compounds |
| JP5029583B2 (ja) | 2008-11-26 | 2012-09-19 | アイシン・エィ・ダブリュ株式会社 | 走行案内装置、走行案内方法及びコンピュータプログラム |
-
2008
- 2008-07-31 WO PCT/JP2008/002055 patent/WO2009016841A1/ja not_active Ceased
- 2008-07-31 AU AU2008283629A patent/AU2008283629B2/en active Active
- 2008-07-31 US US12/671,411 patent/US8389523B2/en active Active
- 2008-07-31 PT PT08790319T patent/PT2174934E/pt unknown
- 2008-07-31 AR ARP080103331A patent/AR067763A1/es active IP Right Grant
- 2008-07-31 UA UAA201000814A patent/UA100242C2/uk unknown
- 2008-07-31 EP EP08790319A patent/EP2174934B1/en active Active
- 2008-07-31 KR KR1020097027146A patent/KR101546819B1/ko active Active
- 2008-07-31 MY MYPI20100274 patent/MY153045A/en unknown
- 2008-07-31 ES ES08790319T patent/ES2389320T3/es active Active
- 2008-07-31 NZ NZ582426A patent/NZ582426A/en unknown
- 2008-07-31 CA CA2694882A patent/CA2694882C/en active Active
- 2008-07-31 CN CN200880100263.2A patent/CN101778832B/zh active Active
- 2008-07-31 PL PL08790319T patent/PL2174934T3/pl unknown
- 2008-07-31 MX MX2010001240A patent/MX2010001240A/es active IP Right Grant
- 2008-07-31 JP JP2009525287A patent/JP5291624B2/ja active Active
- 2008-07-31 AP AP2009005066A patent/AP2513A/xx active
- 2008-07-31 EA EA201070202A patent/EA017807B1/ru not_active IP Right Cessation
- 2008-07-31 BR BRPI0813863A patent/BRPI0813863B1/pt active IP Right Grant
- 2008-08-01 TW TW097129187A patent/TWI430749B/zh active
-
2009
- 2009-11-20 ZA ZA2009/08210A patent/ZA200908210B/en unknown
- 2009-11-26 IL IL202378A patent/IL202378A/en active IP Right Grant
-
2010
- 2010-01-04 CR CR11184A patent/CR11184A/es unknown
- 2010-01-25 NI NI201000018A patent/NI201000018A/es unknown
- 2010-01-29 DO DO2010000044A patent/DOP2010000044A/es unknown
- 2010-02-01 HN HN2010000208A patent/HN2010000208A/es unknown
- 2010-02-01 CO CO10010108A patent/CO6160266A2/es unknown
- 2010-02-01 CU CU2010000021A patent/CU23926B1/es active IP Right Grant
- 2010-02-01 SV SV2010003470A patent/SV2010003470A/es not_active Application Discontinuation
- 2010-03-01 EC EC2010010006A patent/ECSP10010006A/es unknown
-
2013
- 2013-01-17 US US13/743,574 patent/US8648075B2/en active Active
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