EP0116510A1 - Verfahren zum Fixieren von Färbungen mit Direkt- oder Reaktivfarbstoffen auf Cellulosefasern - Google Patents

Verfahren zum Fixieren von Färbungen mit Direkt- oder Reaktivfarbstoffen auf Cellulosefasern Download PDF

Info

Publication number
EP0116510A1
EP0116510A1 EP84420023A EP84420023A EP0116510A1 EP 0116510 A1 EP0116510 A1 EP 0116510A1 EP 84420023 A EP84420023 A EP 84420023A EP 84420023 A EP84420023 A EP 84420023A EP 0116510 A1 EP0116510 A1 EP 0116510A1
Authority
EP
European Patent Office
Prior art keywords
fixing
dyes
dyes according
zirconium
carried out
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP84420023A
Other languages
English (en)
French (fr)
Other versions
EP0116510B1 (de
Inventor
Jean Balland
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Manufacture de Produits Chimiques Protex SARL
Original Assignee
Manufacture de Produits Chimiques Protex SARL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Manufacture de Produits Chimiques Protex SARL filed Critical Manufacture de Produits Chimiques Protex SARL
Priority to AT84420023T priority Critical patent/ATE28674T1/de
Publication of EP0116510A1 publication Critical patent/EP0116510A1/de
Application granted granted Critical
Publication of EP0116510B1 publication Critical patent/EP0116510B1/de
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/10—After-treatment with compounds containing metal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/916—Natural fiber dyeing
    • Y10S8/918—Cellulose textile

Definitions

  • the present invention relates to a process for fixing dyes produced with direct and reactive dyes on cellulosic fibers.
  • the application of a fixing agent is carried out after dyeing according to the conventional methods of application carried out or by exhaustion in a long bath, or continuously or semi-continuously.
  • the application of a fixing agent can also be carried out during a finishing operation, particularly during treatments carried out using thermosetting resins intended to modify the physical characteristics of an article.
  • a strengthening of the fixing power of the fixatives introduced resulting in an improvement in the solidity of the colors produced.
  • the improvement manifests with direct and reactive dyes.
  • the conditions of the present invention make it possible to improve wet solidities, such as, for example, solidities in washing, in water, in sweat, etc.
  • the present invention therefore relates to a process for fixing dyes produced in direct or reactive dyes on cellulosic fibers, according to which a zirconium salt is added to conventional fixatives.
  • fixatives are those usually used to improve the solidities of direct or reactive dyes, for example the condensation products of formaldehyde with the compounds comprising in their molecule at least one amino group, such as the condensation products of formaldehyde with guanidine, the aminotriazine, aminoguanidine, dicyandiamidine biguanidine and dicyanodiamide.
  • the zirconium salt is zirconium oxychloride.
  • the fixing method according to the invention is, in the case of reactive dyes, advantageously carried out directly after dyeing, without an intermediate washing operation.
  • the resins used are those currently known and used to achieve the permanent finishing of cellulosic articles, such as resins based on urea-formaldehyde, melamine-formaldehyde, glyoxal-carbamate, etc.
  • the quantity of fixative used can vary according to the requirements of the article under consideration, this quantity possibly being between 0.1 and 50% relative to the weight of the fiber, and preferably between 1 and 5% by compared to fiber.
  • the amount of zirconium salt is also introduced according to the desired results may be varied between 95% and with respect to the q uan- tity scavenger introduced, and is preferably between 20 and 40%.
  • the dyeing of the cellulosic fibers is carried out according to conventional dyeing methods, currently known; fixing is carried out after dyeing according to the impregnation and drying processes
  • a previously bleached and hydrophilized cotton fabric is dyed with a direct dye, the reference to the Color Index is Blue Direct 78.
  • Dyeing is carried out by exhaustion according to the conventional process at a temperature of 95 ° C in the presence of sodium chloride.
  • the impregnation is carried out at a temperature of 20 ° C., the quantity of bath absorbed is expressed between the rollers of a scarf so as to retain 80% of the impregnation bath relative to the weight of the fiber, then dried immediately the material impregnated on the oar for 2 minutes at the temperature of 120 ° C.
  • a second sample is treated under identical conditions, after adding 2 g per liter of ziconium oxychloride in the previous impregnation bath.
  • the fixing is carried out using a fixing agent resulting from the condensation of biguanidine with formaldehyde.
  • a previously bleached and hydrophilized cotton fabric is dyed using a reactive dye, the reference to the Color Index is Blue Reactive 3.
  • Dyeing is carried out according to the so-called conventional Pad-Therm process (padding-heat treatment).
  • the impregnation is carried out at a temperature of 20 ° C., the sample is then expressed between the rolls of a scarf so as to retain 80% of the impregnation bath relative to the weight of the fiber, then dried on a ream for 2 minutes at 120 ° C.
  • a previously bleached and hydrophilized cotton fabric is dyed using a reactive dye, the reference to the Color Index is Reactive Blue 137.
  • Dyeing is carried out using the conventional Pad Steam process (padding, spraying).
  • the washing fastness test at 60 ° C and 95 ° C also shows a higher resistance of the color having been treated in the presence of zirconium.
  • Determining the nervousness of the articles obtained also makes it possible to highlight an improvement of the order of 15% in the nervousness of the fiber on the samples made in the presence of zirconium salts.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
EP84420023A 1983-02-11 1984-02-08 Verfahren zum Fixieren von Färbungen mit Direkt- oder Reaktivfarbstoffen auf Cellulosefasern Expired EP0116510B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT84420023T ATE28674T1 (de) 1983-02-11 1984-02-08 Verfahren zum fixieren von faerbungen mit direkt- oder reaktivfarbstoffen auf cellulosefasern.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8302873 1983-02-11
FR8302873A FR2540902B1 (fr) 1983-02-11 1983-02-11 Procede de fixation des teintures realisees en colorants directs et reactifs sur fibres cellulosiques

Publications (2)

Publication Number Publication Date
EP0116510A1 true EP0116510A1 (de) 1984-08-22
EP0116510B1 EP0116510B1 (de) 1987-07-29

Family

ID=9286159

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84420023A Expired EP0116510B1 (de) 1983-02-11 1984-02-08 Verfahren zum Fixieren von Färbungen mit Direkt- oder Reaktivfarbstoffen auf Cellulosefasern

Country Status (6)

Country Link
US (1) US4547196A (de)
EP (1) EP0116510B1 (de)
JP (1) JPS59157387A (de)
AT (1) ATE28674T1 (de)
DE (1) DE3465120D1 (de)
FR (1) FR2540902B1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0294081A3 (en) * 1987-06-04 1989-10-18 Milliken Research Corporation Process for pattern dyeing of textile materials

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5207800A (en) * 1991-10-07 1993-05-04 Burlington Chemical Co., Inc. Low toxicity, biodegradable salt substitute for dyeing textiles: magnesium acetate in direct or reactive dyeing of cotton

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR826631A (fr) * 1936-09-17 1938-04-06 Ste Ind Chim Bale Procédé pour l'amélioration de produits industriels, produits améliorés, bains et préparations pour l'amélioration de ces produits
FR1286054A (fr) * 1960-02-05 1962-03-02 Sun Chemical Corp Composition pour le traitement de textiles cellulosiques
BE665387A (de) * 1964-06-20 1965-10-01
FR2476670A1 (fr) * 1980-02-22 1981-08-28 Sandoz Sa Produit, composition et procede pour ameliorer les solidites au mouille des colorants substantifs sur fibres cellulosiques

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2650152A (en) * 1951-07-21 1953-08-25 American Cyanamid Co Printing assistants for vat colors comprising zirconium salts
FR1086380A (fr) * 1953-07-10 1955-02-11 Teintureries Laval Procédé de traitement de tissus
US3429647A (en) * 1965-01-06 1969-02-25 Monsanto Co Method of preventing jute staining
CH260068D (de) * 1967-03-02
FR1593912A (de) * 1968-12-02 1970-06-01
FR2073223A6 (en) * 1969-07-04 1971-10-01 Givaudan Sarl Azoic pigment dyestuff - contg zirconyl chloride - and benzoic acid esp for cotton
NL8104330A (nl) * 1980-09-24 1982-04-16 Sandoz Ag Werkwijze voor het wasecht maken van cellulose-bevattend textiel en daarbij te gebruiken stoffen.
CH673195B5 (de) * 1981-05-14 1990-08-31 Sandoz Ag
CH669081GA3 (de) * 1981-05-14 1989-02-28
US4436524A (en) * 1981-05-16 1984-03-13 Sandoz Ltd. After treating composition for direct or reactive dyeings on cellulose
NL8202475A (nl) * 1981-06-22 1983-01-17 Sandoz Ag Verbeteringen aan of met betrekking tot organische verbindingen.
CH669705GA3 (de) * 1982-08-30 1989-04-14

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR826631A (fr) * 1936-09-17 1938-04-06 Ste Ind Chim Bale Procédé pour l'amélioration de produits industriels, produits améliorés, bains et préparations pour l'amélioration de ces produits
FR1286054A (fr) * 1960-02-05 1962-03-02 Sun Chemical Corp Composition pour le traitement de textiles cellulosiques
BE665387A (de) * 1964-06-20 1965-10-01
FR2476670A1 (fr) * 1980-02-22 1981-08-28 Sandoz Sa Produit, composition et procede pour ameliorer les solidites au mouille des colorants substantifs sur fibres cellulosiques

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0294081A3 (en) * 1987-06-04 1989-10-18 Milliken Research Corporation Process for pattern dyeing of textile materials

Also Published As

Publication number Publication date
EP0116510B1 (de) 1987-07-29
FR2540902A1 (fr) 1984-08-17
ATE28674T1 (de) 1987-08-15
JPS59157387A (ja) 1984-09-06
US4547196A (en) 1985-10-15
FR2540902B1 (fr) 1986-05-16
DE3465120D1 (en) 1987-09-03

Similar Documents

Publication Publication Date Title
BE897597A (fr) Procede pour ameliorer les solidites des colorants ou azurants optiques usr un substrat constitue de fibres de polyamide ou de fibres contenant des groupes hydroxy
EP0116510B1 (de) Verfahren zum Fixieren von Färbungen mit Direkt- oder Reaktivfarbstoffen auf Cellulosefasern
BE1001934A3 (fr) Procede de teinture de substrats mixtes.
FR2512855A1 (fr) Procede de teinture a la continue de substrats cellulosiques
Choi One-bath dyeing and nonformaldehyde durable press finishing of cotton using dialdehyde and a monochlorotriazinyl reactive dye
AU609460B2 (en) Dyeing and printing fibres
WO2000014324A1 (en) Method of dyeing cotton/wool blends
Mohtashim et al. Investigations into the sequential application of crease resist finish, tannin and cationic reactant to improve the resistance of sulphur dyes to oxidation
FR2552791A1 (fr) Procede de teinture de substrats textiles comprenant de la laine
CN1151327C (zh) 纤维素纤维的处理工艺
JPS6220317B2 (de)
JPS61194282A (ja) カチオン化セルロ−ズ系繊維の処理方法
US2297701A (en) Process of dyeing animal fibers
FR2542340A1 (fr) Procede de teinture de substrats a base de melanges de polyacrylonitrile et de cellulose
FR2571071A1 (fr) Procede de post-traitement des fibres textiles.
FR2746808A1 (fr) Agent et procede d'amelioration de la solidite au frottement de teintures ou d'impressions
FR2795103A1 (fr) Procede de demontage du fixateur de teinture a partir d'un article textile cellulosique teint ou imprime avec un colorant reactif ou direct et fixe
US3310361A (en) Process for the production of multi-colored woolen goods
JPH0742660B2 (ja) セルロ−ス系繊維を含む繊維材料染色物の後処理法
FR2748281A1 (fr) Amelioration de la solidite au chlore de teintures et impressions sur fibres ou tissus cellulosiques realisees avec des colorants reactifs
US3326629A (en) Fastness properties of dyeings and prints obtained with sulfur dyes
AU6068499A (en) Method of dyeing cotton/wool blends
FR2684395A1 (fr) Nouveau procede de teinture par foulardage-vaporisage.
BE890422A (fr) Produit, composition et procede pour ameliorer les solidites des colorants substantifs sur fibres cellulosiques
FR2616816A1 (fr) Procede de traitement de fibres cellulosiques eventuellement melangees avec des fibres synthetiques, procede de teinture d'un article polyester-coton et produits teints obtenus

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Designated state(s): AT BE CH DE GB IT LI LU NL SE

17P Request for examination filed

Effective date: 19850416

17Q First examination report despatched

Effective date: 19860414

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE GB IT LI LU NL SE

REF Corresponds to:

Ref document number: 28674

Country of ref document: AT

Date of ref document: 19870815

Kind code of ref document: T

ITF It: translation for a ep patent filed
REF Corresponds to:

Ref document number: 3465120

Country of ref document: DE

Date of ref document: 19870903

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Effective date: 19880208

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Effective date: 19880209

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19880229

Ref country code: LI

Effective date: 19880229

Ref country code: CH

Effective date: 19880229

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
BERE Be: lapsed

Owner name: MANUFACTURE DE PRODUITS CHIMIQUES PROTEX

Effective date: 19880228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19880901

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee
REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19881122

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Effective date: 19890228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Effective date: 19891101

EUG Se: european patent has lapsed

Ref document number: 84420023.8

Effective date: 19880927