EP0237804A2 - Ölzusammensetzung für Transmission mit Handbetrieb - Google Patents

Ölzusammensetzung für Transmission mit Handbetrieb Download PDF

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Publication number
EP0237804A2
EP0237804A2 EP87102143A EP87102143A EP0237804A2 EP 0237804 A2 EP0237804 A2 EP 0237804A2 EP 87102143 A EP87102143 A EP 87102143A EP 87102143 A EP87102143 A EP 87102143A EP 0237804 A2 EP0237804 A2 EP 0237804A2
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EP
European Patent Office
Prior art keywords
group
oil
weight
parts
oil composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP87102143A
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English (en)
French (fr)
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EP0237804A3 (de
Inventor
Yuji Ikemoto
Osamu Iizuka
Toru Aoki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eneos Corp
Original Assignee
Nippon Oil Corp
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Publication date
Application filed by Nippon Oil Corp filed Critical Nippon Oil Corp
Publication of EP0237804A2 publication Critical patent/EP0237804A2/de
Publication of EP0237804A3 publication Critical patent/EP0237804A3/de
Withdrawn legal-status Critical Current

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    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/042Metal salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/065Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds containing sulfur
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/042Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for automatic transmissions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/044Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for manual transmissions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C10N2040/046Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for traction drives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/08Hydraulic fluids, e.g. brake-fluids

Definitions

  • the present invention relates to an oil composition for manual transmissions which is used to lubricate manual transmissions [manual transmissions of FR (Front engine, Rear drive) automobiles and manual transaxle of FF (Front engine, Front drive) automobiles] of automobiles which include passenger cars, trucks, large-sized cars such as buses, and tractors.
  • manual transmissions of FR (Front engine, Rear drive) automobiles and manual transaxle of FF (Front engine, Front drive) automobiles of automobiles which include passenger cars, trucks, large-sized cars such as buses, and tractors.
  • gear clashing As a feeling of ride on passenger cars and large-sized cars is investigated and improved, much attention has been paid to "gear clashing" and “sticking” which take place in shifting gear by a manual transmission, which troubles have not been considered so far.
  • the gear clashing generally occurs in a car which is running for a long distance, and in particular, it is often generated in the case that engine brakes are applied by shifting down abruptly at the time of a high-speed running, so as to reduce a speed of the car. If the gear clashing occurs in such a state, a gear change will not be performed smoothly, with the result that serious accidents will happen on occasion.
  • the sticking is also called “double gearing" and is a phenomenon which tends to occur in shifting gear at a low-speed running or at idling, and when the car is in the state of the sticking, the operation of a gear change is felt to be very heavy.
  • the friction between the synchronizer rings and the gear cones is naturally connected closely with a used lubricating oil.
  • the present inventors have extensively studied with the intention of solving these problems by using a new lubricating oil, and they have found that the occurrence of the sticking can be prevented by lowering a static coefficient of friction or a dynamic coefficient of friction under low-speed conditions and that the occurrence of the gear clashing can be inhibited by heightening a dynamic frinction coefficient under high-speed conditions.
  • an epochal lubricating oil has been developed which satisfies the above requirements and which has all properties such as an extreme pressure character and a stability against oxidation that the oil for manual transmissions should possess.
  • the present invention is directed to an oil composition for manual transmissions in which (A) 80 to 90 parts by weight of a base oil having a viscosity of 1 to 50 cSt at 100°C is blended with, as essential ingredients, (B) 0.2 to 5 parts by weight of a sulfurized oil or a sulfurized ester, (C) 0.1 to 5 parts by weight of phosphorous ester, (D) 0.2 to 5 parts by weight of zinc dithiophosphate, and (E) 2 to 5 parts by weight of a metallic detergent.
  • A 80 to 90 parts by weight of a base oil having a viscosity of 1 to 50 cSt at 100°C is blended with, as essential ingredients, (B) 0.2 to 5 parts by weight of a sulfurized oil or a sulfurized ester, (C) 0.1 to 5 parts by weight of phosphorous ester, (D) 0.2 to 5 parts by weight of zinc dithiophosphate, and (E) 2 to 5 parts by weight of a metallic detergent.
  • a base oil (A) is a lubricating oil fraction of a mineral oil series, a synthesized lubricating oil or a mixture thereof.
  • the synthesized lubricating oils include poly- ⁇ -olefins, olefin polymers, carboxylates of monovalent or polyvalent alcohols, polyethers, silicones, polyglycols, silicates, alkyl aromatic compounds, carbonates and hydrocarbon halides. Viscosities of these base oils at 100°C are within the range of 1 to 50 cSt, preferably 4 to 18 cSt.
  • Sulfurized oils and the sulfurized esters each of which is the essential ingredient (B) include sulfurized animal and vegetable oils as well as sulfurized fatty acid esters of synthesized oils.
  • An amount of an ingredient (B) to be blended is within the range of 0.2 to 5 parts by weight, preferably 1 to 3 parts by weight.
  • a phosphorous ester which is an essential ingredient (C) is a compound represented by the following general formula: (RO)aP(OH)b wherein a is a value of 1 to 3, preferably 2; b is a value of 0 to 2, preferably 1; and R is an alkyl group, an aryl group, an alkylaryl group having 3 to 25 carbon atoms, or a mixture thereof.
  • phosphorous esters examples include laurylhydrogen phosphite and oleylhydrogen phosphite.
  • An amount of the phosphorous ester to be blended is within the range of 0.1 to 5 parts by weight, preferably 0.5 to 2 parts by weight.
  • a zinc dithiophosphate which is an essential ingredient (D) is a compound represented by the following general formula: wherein R is an alkyl group, an aryl group, an alkylaryl group having 3 to 25 carbon atoms, or a mixture thereof.
  • zinc dithiophosphates examples include zinc diisopropyldithiophosphate, zinc di-2-ethylhexyldi­thiophosphate and zinc dinonylphenyldithiophosphate.
  • An amount of the zinc dithiophosphate to be blended is within the range of 0.2 to 5 parts by weight, preferably 0.5 to 3 parts by weight.
  • Metallic detergents each of which is an essential ingredient (E) include sulfonates, phenates, salicylates and phosphonates, and examples of the metals for them include Ca, Ba, Mg and Na.
  • An amount of the metallic detergent to be blended is within the range of 0.2 to 5 parts by weight, preferably 0.5 to 4 parts by weight.
  • a phenol series or an amine series anti­oxidant a rust preventive, a pour point depressant such as a polymethacrylate and a viscosity index improver which are all used usually in the lubricating oil.
  • a pour point depressant such as a polymethacrylate
  • a viscosity index improver which are all used usually in the lubricating oil.
  • compositions I to IV were prepared, in the following proportions, from ingredients which correspond to essential ingredients (A) to (E) in the order of top to bottom of each composition. Values in the following compositions represent amounts of the respective ingredients in terms of "part by weight”.
  • High-speed conditions (1) At an input revolutional speed of 4,000 rpm at a lever-pressing load of 4 kgf and at an oil temperature of 70°C, a gear change cycle of passing through neutral and four gear positions was repeaded 50,000 times, and the friction coefficient at this point of time was measured.
  • compositions I to IV of the present invention have the excellent properties that the dynamic frinction coefficients under the high-speed conditions (1) are high and the dynamic frinction coefficients under the low-speed conditions (2) are low, and it can thus be appreciated that the composi­tions of the present invention are desirable as the oils for manual transmissions.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)
EP87102143A 1986-02-19 1987-02-16 Ölzusammensetzung für Transmission mit Handbetrieb Withdrawn EP0237804A3 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP34182/86 1986-02-19
JP61034182A JPS62192495A (ja) 1986-02-19 1986-02-19 手動変速機油組成物

Publications (2)

Publication Number Publication Date
EP0237804A2 true EP0237804A2 (de) 1987-09-23
EP0237804A3 EP0237804A3 (de) 1988-07-20

Family

ID=12407056

Family Applications (1)

Application Number Title Priority Date Filing Date
EP87102143A Withdrawn EP0237804A3 (de) 1986-02-19 1987-02-16 Ölzusammensetzung für Transmission mit Handbetrieb

Country Status (2)

Country Link
EP (1) EP0237804A3 (de)
JP (1) JPS62192495A (de)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0335702A3 (de) * 1988-03-31 1989-12-13 Ethyl Petroleum Additives, Inc. Schmierölzusammensetzung
EP0501527A1 (de) * 1987-01-30 1992-09-02 The Lubrizol Corporation Getriebeschmiermittelzusammensetzung
EP0578435A1 (de) * 1992-07-09 1994-01-12 Ethyl Petroleum Additives Limited Modifizierung der Reibung synthetischer Getriebeöle
US5767044A (en) * 1993-08-20 1998-06-16 The Lubrizol Corporation Lubricating compositions with improved thermal stability and limited slip performance
WO2002016533A3 (en) * 2000-08-22 2002-09-12 Lubrizol Corp Extended drain manual transmission lubricants and concentrates
US6482778B2 (en) * 1999-08-11 2002-11-19 Ethyl Corporation Zinc and phosphorus containing transmission fluids having enhanced performance capabilities
EP2565257A4 (de) * 2010-04-27 2013-10-16 Hannal Inc Feuerfestes hydrauliköl
EP3135750A1 (de) * 2015-08-26 2017-03-01 Infineum International Limited Schmierölzusammensetzungen
WO2020260650A1 (fr) * 2019-06-28 2020-12-30 Total Marketing Services Composition lubrifiante pour prévenir la corrosion et/ou la tribocorrosion des pièces métalliques dans un moteur

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3508785B2 (ja) * 1994-12-13 2004-03-22 出光興産株式会社 ギヤ用潤滑油組成物
WO2005118758A1 (ja) * 2004-06-01 2005-12-15 Nippon Oil Corporation 手動変速機用潤滑油組成物
JP4768234B2 (ja) * 2004-06-01 2011-09-07 東燃ゼネラル石油株式会社 自動車用駆動系潤滑油組成物
JP5393192B2 (ja) * 2009-02-24 2014-01-22 Jx日鉱日石エネルギー株式会社 ギヤ用潤滑油組成物
US9181511B2 (en) * 2009-04-01 2015-11-10 Infineum International Limited Lubricating oil composition
CN114317075B (zh) * 2021-12-03 2023-04-11 广东红日星实业有限公司 一种切削液及其制备方法和应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1235896A (en) * 1968-05-24 1971-06-16 Mobil Oil Corp Multifunctional fluid
JPS4945769A (en) * 1972-09-04 1974-05-01 Seiko Instr & Electronics Udedokeikeesu no kozo
US3899432A (en) * 1974-06-03 1975-08-12 Chevron Res All-purpose lubricating oil composition with anti-chatter characteristics for wet disc brakes
JPS54149705A (en) * 1978-05-16 1979-11-24 Fuji Kouyu Kk Lubricant composition for internal combustion engine
US4181619A (en) * 1978-10-30 1980-01-01 Mobil Oil Corporation Antiwear composition
JPS6084394A (ja) * 1983-09-19 1985-05-13 Idemitsu Kosan Co Ltd 疲労寿命改良潤滑剤

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0501527A1 (de) * 1987-01-30 1992-09-02 The Lubrizol Corporation Getriebeschmiermittelzusammensetzung
US5523005A (en) * 1987-01-30 1996-06-04 The Lubrizol Corporation Gear lubricant composition
EP0335702A3 (de) * 1988-03-31 1989-12-13 Ethyl Petroleum Additives, Inc. Schmierölzusammensetzung
EP0578435A1 (de) * 1992-07-09 1994-01-12 Ethyl Petroleum Additives Limited Modifizierung der Reibung synthetischer Getriebeöle
US5767044A (en) * 1993-08-20 1998-06-16 The Lubrizol Corporation Lubricating compositions with improved thermal stability and limited slip performance
US6482778B2 (en) * 1999-08-11 2002-11-19 Ethyl Corporation Zinc and phosphorus containing transmission fluids having enhanced performance capabilities
WO2002016533A3 (en) * 2000-08-22 2002-09-12 Lubrizol Corp Extended drain manual transmission lubricants and concentrates
US6503872B1 (en) * 2000-08-22 2003-01-07 The Lubrizol Corporation Extended drain manual transmission lubricants and concentrates
AU2001286646B2 (en) * 2000-08-22 2006-03-30 The Lubrizol Corporation Extended drain manual transmission lubricants and concentrates
EP2565257A4 (de) * 2010-04-27 2013-10-16 Hannal Inc Feuerfestes hydrauliköl
EP3135750A1 (de) * 2015-08-26 2017-03-01 Infineum International Limited Schmierölzusammensetzungen
KR20170026224A (ko) * 2015-08-26 2017-03-08 인피늄 인터내셔날 리미티드 윤활유 조성물
US11136523B2 (en) 2015-08-26 2021-10-05 Infineum International Limited Lubricating oil compositions
WO2020260650A1 (fr) * 2019-06-28 2020-12-30 Total Marketing Services Composition lubrifiante pour prévenir la corrosion et/ou la tribocorrosion des pièces métalliques dans un moteur
FR3097875A1 (fr) * 2019-06-28 2021-01-01 Total Marketing Services Composition lubrifiante pour prévenir la corrosion et/ou la tribocorrosion des pièces métalliques dans un moteur

Also Published As

Publication number Publication date
JPS62192495A (ja) 1987-08-24
EP0237804A3 (de) 1988-07-20

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