EP0466512A1 - Procédé d'opérer un moteur à combustion interne - Google Patents

Procédé d'opérer un moteur à combustion interne Download PDF

Info

Publication number
EP0466512A1
EP0466512A1 EP91306360A EP91306360A EP0466512A1 EP 0466512 A1 EP0466512 A1 EP 0466512A1 EP 91306360 A EP91306360 A EP 91306360A EP 91306360 A EP91306360 A EP 91306360A EP 0466512 A1 EP0466512 A1 EP 0466512A1
Authority
EP
European Patent Office
Prior art keywords
gasoline
amount
hydrocarbons
manganese tricarbonyl
fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP91306360A
Other languages
German (de)
English (en)
Other versions
EP0466512B1 (fr
EP0466512B2 (fr
Inventor
Thomas Albert Leeper
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ethyl Corp
Original Assignee
Ethyl Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=24203896&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0466512(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ethyl Corp filed Critical Ethyl Corp
Publication of EP0466512A1 publication Critical patent/EP0466512A1/fr
Publication of EP0466512B1 publication Critical patent/EP0466512B1/fr
Application granted granted Critical
Publication of EP0466512B2 publication Critical patent/EP0466512B2/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/023Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/305Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/04Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/10Use of additives to fuels or fires for particular purposes for improving the octane number

Definitions

  • the gasoline base stock blends with which the cyclopentadienyl manganese tricarbonyl additive is blended pursuant to this invention will generally contain 40-90 volume % of saturates, up to 30 (and preferably less than 10 and more preferably less than 5) volume % olefins, and up to 45 volume % aromatics.
  • Preferred gasoline base stock blends for use in the practice of this invention are those containing no more than 40% by volume of aromatics, more preferably no more than 30% by volume of aromatics, still more preferably no more than 28% by volume of aromatics, and most preferably no more than 25% by volume of aromatics.
  • the overall fuel blend will contain no more than 1% by volume and most preferably no more than 0.8% by volume of benzene.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
EP91306360A 1990-07-13 1991-07-12 Utilisation d'au moins un composé du type cyclopentadiényl-manganèse-tricarbonyle dans un carburant formulé sans plomb. Expired - Lifetime EP0466512B2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US55209090A 1990-07-13 1990-07-13
US552090 1990-07-13

Publications (3)

Publication Number Publication Date
EP0466512A1 true EP0466512A1 (fr) 1992-01-15
EP0466512B1 EP0466512B1 (fr) 1994-06-29
EP0466512B2 EP0466512B2 (fr) 2003-07-02

Family

ID=24203896

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91306360A Expired - Lifetime EP0466512B2 (fr) 1990-07-13 1991-07-12 Utilisation d'au moins un composé du type cyclopentadiényl-manganèse-tricarbonyle dans un carburant formulé sans plomb.

Country Status (6)

Country Link
EP (1) EP0466512B2 (fr)
JP (1) JP3112990B2 (fr)
AU (1) AU651116B2 (fr)
CA (1) CA2045706C (fr)
DE (1) DE69102683T3 (fr)
ES (1) ES2055964T5 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0529942A1 (fr) * 1991-08-23 1993-03-03 Ethyl Corporation Un procédé pour réduire les émissions d'un four d'affinage
US5551957A (en) * 1992-05-06 1996-09-03 Ethyl Corporation Compostions for control of induction system deposits
US6629407B2 (en) 2000-12-12 2003-10-07 Ethyl Corporation Lean burn emissions system protectant composition and method
CN108699460A (zh) * 2016-01-13 2018-10-23 雅富顿化学公司 用于改进航空燃料燃烧的方法和组合物

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6242147B1 (en) 1997-09-03 2001-06-05 Minolta Co., Ltd. Negatively chargeable toner and developing device using thereof
US6971337B2 (en) 2002-10-16 2005-12-06 Ethyl Corporation Emissions control system for diesel fuel combustion after treatment system
US7101493B2 (en) 2003-08-28 2006-09-05 Afton Chemical Corporation Method and composition for suppressing coal dust
US7332001B2 (en) 2003-10-02 2008-02-19 Afton Chemical Corporation Method of enhancing the operation of diesel fuel combustion systems
US20050091913A1 (en) * 2003-10-29 2005-05-05 Aradi Allen A. Method for reducing combustion chamber deposit flaking
US7276094B2 (en) 2003-11-25 2007-10-02 Ethyl Petroleum Additives, Inc. Mixed metal catalyst additive and method for use in hydrocarbonaceous fuel combustion system
US7111591B2 (en) 2003-12-10 2006-09-26 Afton Chemical Corporation Method of improving the operation of combustion particulate filters
US8852298B2 (en) 2006-06-29 2014-10-07 Afton Chemical Corporation Fuel composition containing iron and manganese to reduce spark plug fouling
US8852299B2 (en) 2006-06-30 2014-10-07 Afton Chemical Corporation Fuel composition
US8715373B2 (en) 2007-07-10 2014-05-06 Afton Chemical Corporation Fuel composition comprising a nitrogen-containing compound
JP5773220B2 (ja) * 2012-08-07 2015-09-02 トヨタ自動車株式会社 排ガスセンサ
JP5787180B2 (ja) * 2012-08-07 2015-09-30 トヨタ自動車株式会社 排ガスセンサ

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2818417A (en) * 1955-07-11 1957-12-31 Ethyl Corp Cyclomatic compounds
GB1145930A (en) * 1967-12-22 1969-03-19 Exxon Research Engineering Co Liquid fuel composition
WO1987001384A1 (fr) * 1985-08-28 1987-03-12 Orr William C Composition de carburant sans plomb

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3127351A (en) * 1964-03-31 Xxvii
US4437436A (en) * 1982-10-04 1984-03-20 Shell Oil Company Antiknock additive compositions and unleaded gasoline containing same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2818417A (en) * 1955-07-11 1957-12-31 Ethyl Corp Cyclomatic compounds
GB1145930A (en) * 1967-12-22 1969-03-19 Exxon Research Engineering Co Liquid fuel composition
WO1987001384A1 (fr) * 1985-08-28 1987-03-12 Orr William C Composition de carburant sans plomb

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
OIL AND GAS JOURNAL. April 9, 1990, TULSA US pages 43 - 48; UNZELMAN: 'REFORMULATED GASOLINES WILL CHALLENGE PRODUCT-QUALITY MAINTENANCE ' *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0529942A1 (fr) * 1991-08-23 1993-03-03 Ethyl Corporation Un procédé pour réduire les émissions d'un four d'affinage
AU663876B2 (en) * 1991-08-23 1995-10-26 Afton Chemical Intangibles Llc Gasoline engine fuels of enhanced properties
US5551957A (en) * 1992-05-06 1996-09-03 Ethyl Corporation Compostions for control of induction system deposits
US6629407B2 (en) 2000-12-12 2003-10-07 Ethyl Corporation Lean burn emissions system protectant composition and method
CN108699460A (zh) * 2016-01-13 2018-10-23 雅富顿化学公司 用于改进航空燃料燃烧的方法和组合物
EP3402864A4 (fr) * 2016-01-13 2019-07-24 Afton Chemical Corporation Procédé et composition d'amélioration de la combustion de carburants pour aviation

Also Published As

Publication number Publication date
ES2055964T3 (es) 1994-09-01
EP0466512B1 (fr) 1994-06-29
CA2045706C (fr) 2002-09-17
CA2045706A1 (fr) 1992-01-14
AU8016691A (en) 1992-01-16
JP3112990B2 (ja) 2000-11-27
ES2055964T5 (es) 2003-12-16
JPH04226597A (ja) 1992-08-17
DE69102683D1 (de) 1994-08-04
DE69102683T2 (de) 1994-10-20
AU651116B2 (en) 1994-07-14
EP0466512B2 (fr) 2003-07-02
DE69102683T3 (de) 2004-04-08

Similar Documents

Publication Publication Date Title
US5599357A (en) Method of operating a refinery to reduce atmospheric pollution
EP0466512B1 (fr) Procédé d'opérer un moteur à combustion interne
US5113803A (en) Reduction of Nox emissions from gasoline engines
USH1305H (en) Reformulated gasolines and methods of producing reformulated gasolines
EP0466511B1 (fr) Carburants à propriétés augmentées
JPH09111260A (ja) 無鉛ガソリン
AU688433B2 (en) Reducing exhaust emissions from otto-cycle engines
CA2076302C (fr) Carburants a proprietes ameliorees
JP5173698B2 (ja) 無鉛高オクタン価ガソリン及び無鉛高オクタン価ガソリンの製造方法
Zweidinger et al. Identification of volatile hydrocarbons as mobile source tracers for fine-particulate organics
McGinty et al. A review of the effect of petrol composition on unregulated motor vehicle emissions with particular emphasis on non-catalyst vehicles
JP4429940B2 (ja) 無鉛ガソリン
JP3946276B2 (ja) ガソリン基材及び該基材を用いた無鉛ガソリン
Ufuk EFFECT OF OXYGENATE ADDITIVES INTO GASOLINE FOR IMPROVED FUEL PROPERTIES
JP2006328356A (ja) 無鉛高オクタン価ガソリン
JP5005989B2 (ja) 無鉛ガソリン
JP5117020B2 (ja) 無鉛ガソリン
JP5173696B2 (ja) 無鉛高オクタン価ガソリン及び無鉛高オクタン価ガソリンの製造方法
JP4974618B2 (ja) 無鉛ガソリン
Merritt et al. Developmental fuels emissions evaluation
Kalligeros et al. Impact of gasoline quality on engine performance and emissions
RICHARD Reformulated Gasolines, Refining Options
JPH0762361A (ja) ディーゼル燃料組成物

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): BE DE ES FR GB IT

17P Request for examination filed

Effective date: 19920629

17Q First examination report despatched

Effective date: 19921211

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): BE DE ES FR GB IT

ITF It: translation for a ep patent filed
REF Corresponds to:

Ref document number: 69102683

Country of ref document: DE

Date of ref document: 19940804

ET Fr: translation filed
REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2055964

Country of ref document: ES

Kind code of ref document: T3

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

26 Opposition filed

Opponent name: MR. BILL ORR

Effective date: 19950323

PLBF Reply of patent proprietor to notice(s) of opposition

Free format text: ORIGINAL CODE: EPIDOS OBSO

PLBQ Unpublished change to opponent data

Free format text: ORIGINAL CODE: EPIDOS OPPO

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

R26 Opposition filed (corrected)

Opponent name: MR. BILL ORR

Effective date: 19950323

PLAW Interlocutory decision in opposition

Free format text: ORIGINAL CODE: EPIDOS IDOP

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

APAE Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOS REFNO

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

APAE Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOS REFNO

REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

PLAW Interlocutory decision in opposition

Free format text: ORIGINAL CODE: EPIDOS IDOP

RTI2 Title (correction)

Free format text: THE USE OF AT LEAST ONE CYLOPENTADIENYLMANGANESE TRICARBONYL COMPOUND IN A FORMULATED LEAD FRE GASOLINE FUEL.

PUAH Patent maintained in amended form

Free format text: ORIGINAL CODE: 0009272

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT MAINTAINED AS AMENDED

27A Patent maintained in amended form

Effective date: 20030702

AK Designated contracting states

Designated state(s): BE DE ES FR GB IT

REG Reference to a national code

Ref country code: ES

Ref legal event code: DC2A

Date of ref document: 20030708

Kind code of ref document: T5

ET3 Fr: translation filed ** decision concerning opposition
APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO

REG Reference to a national code

Ref country code: GB

Ref legal event code: 732E

REG Reference to a national code

Ref country code: ES

Ref legal event code: PC2A

REG Reference to a national code

Ref country code: FR

Ref legal event code: TP

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20070726

Year of fee payment: 17

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20070831

Year of fee payment: 17

BECA Be: change of holder's address

Owner name: *AFTON CHEMICAL INTANGIBLES LLC330 SOUTH FOURTH ST

Effective date: 20060131

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20070727

Year of fee payment: 17

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20070730

Year of fee payment: 17

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20070717

Year of fee payment: 17

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20080712

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090203

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20090331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080712

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080712

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080731

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20080714

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080714

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20100728

Year of fee payment: 20

BE20 Be: patent expired

Owner name: *AFTON CHEMICAL INTANGIBLES LLC

Effective date: 20110712