EP0510048B1 - Preparation de filage contenant du polymere sous forme d'emulsions aqueuses ou de solutions aqueuses - Google Patents

Preparation de filage contenant du polymere sous forme d'emulsions aqueuses ou de solutions aqueuses Download PDF

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Publication number
EP0510048B1
EP0510048B1 EP91902137A EP91902137A EP0510048B1 EP 0510048 B1 EP0510048 B1 EP 0510048B1 EP 91902137 A EP91902137 A EP 91902137A EP 91902137 A EP91902137 A EP 91902137A EP 0510048 B1 EP0510048 B1 EP 0510048B1
Authority
EP
European Patent Office
Prior art keywords
water
soluble
aqueous
spinning
emulsions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP91902137A
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German (de)
English (en)
Other versions
EP0510048A1 (fr
EP0510048B2 (fr
Inventor
Ulrich Eicken
Raymond Mathis
Heidi Fiedler
Manfred Gorzinski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cognis IP Management GmbH
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
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Publication of EP0510048B1 publication Critical patent/EP0510048B1/fr
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Publication of EP0510048B2 publication Critical patent/EP0510048B2/fr
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2904—Staple length fiber
    • Y10T428/2907—Staple length fiber with coating or impregnation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2967—Synthetic resin or polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2964—Artificial fiber or filament
    • Y10T428/2967—Synthetic resin or polymer
    • Y10T428/2969—Polyamide, polyimide or polyester

Definitions

  • the invention relates to spin finishes in the form of aqueous emulsion or aqueous solutions containing water-soluble polymer compounds with weight average molecular weights greater than 10 6 , a process for reducing the spin-off of spin finishes from fiber surfaces and the use of certain water-soluble polymer compounds with weight average molecular weights greater than 10 6 in aqueous Emulsions or aqueous solutions of spin finishes to reduce the spin-off of spin finishes from fiber surfaces.
  • textile lubricants based on hydrocarbons, such as mineral oils and / or fatty acid esters and / or fats and / or oils, are the high molecular weight polymers of a-mono-olefins having 4 to 20 carbon atoms contain, have an improved adhesion to the fiber surface.
  • EP 261 415 and EP 127 293 known that the use of high molecular weight polyisobutenes as well as the use of copolymers containing as monomeric components butenes in combination with C 5 - include a-olefins, a decrease in the Abspritzens of winding oils - 20 effect during yarn processing.
  • the winding oils described in US 4,098,702 contain polymeric viscosity index improvers, for example polyisobutenes with molecular weights between 20,000 and 2,000,000, polyalkylstyrenes with molecular weights between 20,000 and 2,000,000 or polymethacrylates with molecular weights between 300,000 and 800,000, to improve the adhesion of the Spooling oils on the fiber surface.
  • polymeric viscosity index improvers for example polyisobutenes with molecular weights between 20,000 and 2,000,000, polyalkylstyrenes with molecular weights between 20,000 and 2,000,000 or polymethacrylates with molecular weights between 300,000 and 800,000, to improve the adhesion of the Spooling oils on the fiber surface.
  • the invention furthermore relates to the use of water-soluble polyalkylene oxides with weight average molecular weights greater than 10 6 , water-soluble polyacrylic and / or polymethacrylamides with weight average molecular weights greater than 10 6 and / or water-soluble copolymers of acrylic and / or methacrylamide and unsaturated carboxylic acids with 3 to 5 carbon atoms with weight average molecular weights greater than 10 6 in aqueous emulsions or aqueous solutions of spin finishes to reduce the spin-off of the spin finishes from fiber surfaces.
  • the content of water-soluble polymer compounds with weight average molecular weights greater than 10 6 in the aqueous emulsions or in the aqueous solutions of the spin finishes according to the invention is preferably between 0.0001 and 0.3% by weight, particularly preferably between 0.005 and 0.05% by weight. %.
  • Polyethylene oxides, polyacrylamides and / or copolymers of acrylamide and carboxylic acids with 3 to 5 carbon atoms are preferably used as water-soluble polymer compounds with weight average molecular weights greater than 10 6 .
  • Polyethylene oxides with weight average molecular weights greater than 10 6 are, for example, from Union Carbide as powder under the names Polyox R WSR301 and Polyox R WSR Coagulant and polyacrylamides with weight average molecular weights greater than 10 6, for example from Henkel KGaA under the name Ferrocryl R or from Stockhausen the name Praestol R.
  • Copolymers of acrylamide and unsaturated carboxylic acids with 3 to 5 carbon atoms, for example copolymers of acrylamide and acrylic acid with weight average molecular weights greater than 10 6, are available, for example, under the name Superfloc R (manufacturer: Cyanamid).
  • Polyethylene oxides are particularly preferably used as water-soluble polymer compounds with weight average molecular weights greater than 10 6 in spin finishes.
  • Suitable lubricants in spin finishes according to the invention are, for example, mineral oils, carboxylic acid esters, prepared from aliphatic carboxylic acids with 8 to 22 carbon atoms and straight and / or branched, optionally alkoxylated alkyl alcohols with 1 to 22 carbon atoms, for example isobutyl stearate, n-hexyl laurate, tallow fatty acid -2-ethylhexyl ester, coconut fatty acid triglycerides and / or trimethylolpropane tripelargonate, silicones, for example dimethylpolysiloxane and / or polyalkylene glycols, for example ethylene oxide / propylene oxide mixed polymers with average molecular weights between 600 and 6,000.
  • mineral oils for example, mineral oils, carboxylic acid esters, prepared from aliphatic carboxylic acids with 8 to 22 carbon atoms and straight and / or branched, optionally alkoxylated al
  • Anionic, cationic and / or antistatic agents come as anionic, cationic and / or nonionic surfactants into consideration, such as mono- and / or diglycerides such as glycerol mono- and / or dioleate, alkoxylated, preferably ethoxylated and / or propoxylated fats, oils, fatty alcohols having 8 to 22 carbon atoms and / or C 8 - 18 o Alkylphenols, for example Ri zinusöl ethoxylated with 10 to 40 moles of ethylene oxide (EO) and / or C, 6 - 18 fatty alcohols, alkoxylated with ethylene oxide and / or propylene, optionally alkoxylated C 8 - 22 remono- -Fettkla- and / or diethanolamides, for example, optionally ethoxylated oleic acid mono- and / or diethanolamide, tallow fatty acid mono- and / or diethanolamide
  • Sodium dioctyl sulfosuccinate and / or amine oxides for example dimethyldodecylamine oxide.
  • a smoothing agent can simultaneously act as an antistatic and / or as an emulsifier .
  • Emulsifiers, antistatic agents and / or wetting agents can be used in any mixing ratio to one another in the spin finishes according to the invention.
  • the spin finishes according to the invention can be pH regulators, for example aliphatic Ci-22 carboxylic acids and / or C 1-4 hydroxycarboxylic acids, such as acetic acid, glycolic acid and / or oleic acid, alkali metal hydroxides, such as potassium hydroxide and / or amines, such as triethanolamine, Thread closing agents, for example fatty acid sarcosides and / or copolymers with maleic anhydride and / or polyurethanes according to DE 38 30 468, contain bactericides and / or anti-corrosion agents.
  • pH regulators for example aliphatic Ci-22 carboxylic acids and / or C 1-4 hydroxycarboxylic acids, such as acetic acid, glycolic acid and / or oleic acid, alkali metal hydroxides, such as potassium hydroxide and / or amines, such as triethanolamine, Thread closing agents, for example fatty acid sarcosides and / or copolymers with male
  • Polymeric, aqueous spin finish emulsions or solutions are applied in a known manner immediately after the capillaries have emerged from the spinneret.
  • the preparations which have a temperature between 18 and 30 ° C, are applied with the help of application rollers or with metering pumps using suitable applicators.
  • the amount of active substance applied (oil coating) of the spin finish emulsions or spin finish solutions according to the invention is between 0.3 and 2.0% by weight, based on the weight of the thread bundle.
  • the bundles of threads are wound on spinning bobbins.
  • the thread bundles can consist, for example, of polyesters, polyamides, polyolefins and / or polyacrylics.
  • the spin finishes according to the invention adhere very well to fiber surfaces and are only spun off in very small quantities at the high thread speeds customary today.
  • the data in% mean% by weight.
  • aqueous emulsion was prepared from 150 g of the above-mentioned spin finish and 840 g of water, and 10 g of an aqueous 1% by weight Polyox R WSR301 solution were stirred into it at 20 ° C.
  • Polyester 167 dtex / 34 filaments
  • the polymer-containing spin finish emulsion which had a temperature of 20 ° C., was applied immediately after the capillaries emerged via a metering pump (oil coating: 1.5% by weight).
  • the amount sprayed off was collected and weighed. In comparison to the spin finish without the addition of polymer, a reduction in the amount sprayed off was achieved with the polymer-containing spin finish by 82%.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

La présente invention se rapporte à des préparations de filage sous forme d'émulsions aqueuses ou de solutions aqueuses contenant des composés de polymère hydrosolubles avec des moyennes de poids moléculaires supérieures à 106.

Claims (11)

1. Préparations de filage à base d'agents de lissage, d'agents émulsionnants, d'agents antistatiques et/ou d'agents mouillants, contenant des composés polymères sous forme d'émulsions aqueuses ou de solutions aqueuses, caractérisées en ce que celles-ci contiennent un ou plusieurs des composés polymères solubles dans l'eau suivants avec des moyennes pondérales de poids moléculaire, plus grandes que 106 : des poly(oxydes d'alcoylène) et/ou des polyacryl- et/ou polyméthacrylamides et/ou des copolymères à base d'acryl- et/ou de méthacrylamide et d'acides carboxyliques non saturés ayant de 3 à 5 atomes de carbone.
2. Préparations de filage selon la revendication 1, caractérisées en ce que les émulsions aqueuses ou les solutions aqueuses des préparations de filage renferment de 0,0001 à 0,3 % en poids, de préférence de 0,005 à 0,05 % en poids, de composés polymères solubles dans l'eau.
3. Préparations de filage selon l'une ou les deux revendications 1 à 2, caractérisées en ce que les émulsions aqueuses ou les solutions aqueuses des préparations de filage renferment des oxydes de polyéthylène solubles dans l'eau, des polyacrylamides solubles dans l'eau et/ou des copolymères solubles dans l'eau d'acrylamide et d'acides carboxyliques non saturés ayant de 3 à 5 atomes de carbone.
4. Préparations de filage selon l'une ou plusieurs des revendications 1 à 3, caractérisées en ce que les émulsions aqueuses ou les solutions aqueuses de préparations de filage renferment des poly(oxyde d'éthylène) solubles dans l'eau.
5. Procédé pour diminuer l'élimination des préparations de filage de surfaces de fibres, caractérisé en ce que directement après la sortie des capillaires de la buse de filage, on applique les préparations de filage qui renferment un ou plusieurs des composés polymères solubles dans l'eau suivants ayant des moyennes pondérales de poids moléculaire plus grandes que 106 :
- poly(oxydes d'alcoylène) et/ou polyacryl- et/ou polyméthacrylamides et/ou copolymères d'acryl- et/ou de méthacrylamide et d'acides carboxyliques non saturés ayant de 3 à 5 atomes de carbone.

sous forme d'émulsions aqueuses ou de solutions aqueuses sur le faisceau de fils.
6. Procédé selon la revendication 5, caractérisé en ce que les émulsions ou solutions aqueuses de préparations de filage qui renferment de 0,0001 à 0,3 % en poids, de préférence de 0,005 à 0,05 % en poids de composés polymères solubles dans l'eau sont appliquées sur le faisceau de fils.
7. Procédé selon l'une ou les deux revendications 5 ou 6, caractérisé en ce que les émulsions ou solutions de préparation de filage qui renferment des poly(oxydes d'éthylène) solubles dans l'eau, des polyacrylamides solubles dans l'eau et/ou des copolymères solubles dans l'eau d'acrylamide et d'acides carboxyliques non saturés ayant de 3 à 5 atomes de carbone, sont appliquées sur le faisceau de fils.
8. Procédé selon l'une ou plusieurs des revendications 5 à 7, caractérisé en ce que les émulsions ou solutions aqueuses de préparation de filage qui renferment des poly(oxydes d'éthylène) solubles dans l'eau, sont appliquées sur le faisceau de fils.
9. Utilisation de poly(oxydes d'acoylène) solubles dans l'eau ayant des moyennes pondérales de poids moléculaire plus grandes que 106 et/ou des polyacryl-, et/ou polyméthacrylamides solubles dans l'eau avec des moyennes pondérales de poids moléculaire plus grandes que 106 et/ou des copolymères solubles dans l'eau d'acryl- et/ou de méthacryl amide et d'acides carboxyliques non saturés ayant de 3 à 5 atomes de carbone, de poids moléculaires plus grands que 106, sous la forme d'émulsions aqueuses ou de solutions aqueuses de préparations de filage en vue de la diminution de l'élimination des préparations de filage, de surfaces de fibres.
10. Utilisation selon la revendication 9, caractérisée en ce que l'on utilise des poly(oxydes d'éthylène) solubles dans l'eau, des polyacrylamides solubles dans l'eau et/ou des copolymères solubles dans l'eau d'acrylamide et d'acides carboxyliques non saturés ayant de 3 à 5 atomes de carbone.
11. Utilisation selon l'une ou les deux revendications 9 à 10, caractérisée en ce que l'on utilise des poly(oxydes d'éthylène) solubles dans l'eau.
EP91902137A 1990-01-08 1990-12-21 Preparation de filage contenant du polymere sous forme d'emulsions aqueuses ou de solutions aqueuses Expired - Lifetime EP0510048B2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4000304A DE4000304A1 (de) 1990-01-08 1990-01-08 Polymerhaltige spinnpraeparationen in form waessriger emulsionen oder waessriger loesungen
DE4000304 1990-01-08
PCT/EP1990/002288 WO1991010717A1 (fr) 1990-01-08 1990-12-21 Preparation de filage contenant du polymere sous forme d'emulsions aqueuses ou de solutions aqueuses

Publications (3)

Publication Number Publication Date
EP0510048A1 EP0510048A1 (fr) 1992-10-28
EP0510048B1 true EP0510048B1 (fr) 1994-09-21
EP0510048B2 EP0510048B2 (fr) 1998-11-04

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ID=6397714

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EP91902137A Expired - Lifetime EP0510048B2 (fr) 1990-01-08 1990-12-21 Preparation de filage contenant du polymere sous forme d'emulsions aqueuses ou de solutions aqueuses

Country Status (4)

Country Link
US (2) US5382372A (fr)
EP (1) EP0510048B2 (fr)
DE (2) DE4000304A1 (fr)
WO (1) WO1991010717A1 (fr)

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US6491839B1 (en) 1999-05-07 2002-12-10 Cognis Corporation Process for making a textile finish composition having anti-sling properties
AU1211201A (en) * 1999-10-26 2001-06-06 Cognis Corporation Polymeric lubricant compositions, and methods for their use
US9309378B2 (en) 2009-06-19 2016-04-12 Exacto, Inc. Emulsion compositions comprising polyacrylamide copolymer and ethylene oxide—propylene oxide copolymer
US9307758B2 (en) 2009-06-19 2016-04-12 Exacto, Inc. Polyacrylamide based agricultural compositions
US9428630B2 (en) 2009-06-19 2016-08-30 Exacto, Inc. Water-in-oil polyacrylamide-based microemulsions and related methods
CN102912640B (zh) * 2012-10-25 2014-06-25 上虞市皇马化学有限公司 一种原油型涤纶工业丝油剂及其制备方法
CN103147168B (zh) * 2013-03-06 2017-06-16 常州市灵达化学品有限公司 一种纺丝油剂及制备方法
WO2014158175A1 (fr) * 2013-03-28 2014-10-02 Exacto, Inc. Compositions d'émulsion comprenant un copolymère de polyacylamide et un copolymère d'oxyde d'éthylène-oxyde de propylène
CA3132992A1 (fr) 2019-03-14 2020-09-17 Exacto, Inc. Microtreillis inverses transparents ou semi-transparents de polyacrylamide utilises en tant qu'agent de reduction de derive d'emulsion d'huile
CN114000229A (zh) * 2021-12-08 2022-02-01 江苏双江能源科技股份有限公司 一种涤纶dty油剂用抗飞溅剂及其制备方法
CN114517409A (zh) * 2022-03-25 2022-05-20 杭州临港化纤有限公司 一种丝线加弹油剂及其制备方法

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Also Published As

Publication number Publication date
DE59007287D1 (de) 1994-10-27
EP0510048A1 (fr) 1992-10-28
EP0510048B2 (fr) 1998-11-04
WO1991010717A1 (fr) 1991-07-25
US5490943A (en) 1996-02-13
DE4000304A1 (de) 1991-07-11
US5382372A (en) 1995-01-17

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