EP0890699B1 - Mit einem Kunstoffprofil versehenes Verglasungselement mit hohem Isoliervermögen - Google Patents

Mit einem Kunstoffprofil versehenes Verglasungselement mit hohem Isoliervermögen Download PDF

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Publication number
EP0890699B1
EP0890699B1 EP98400872A EP98400872A EP0890699B1 EP 0890699 B1 EP0890699 B1 EP 0890699B1 EP 98400872 A EP98400872 A EP 98400872A EP 98400872 A EP98400872 A EP 98400872A EP 0890699 B1 EP0890699 B1 EP 0890699B1
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EP
European Patent Office
Prior art keywords
glazed element
glazed
element according
profile
plastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP98400872A
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English (en)
French (fr)
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EP0890699A3 (de
EP0890699A2 (de
Inventor
Claude Morin
Yves Demars
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Gobain Glass France SAS
Original Assignee
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint Gobain Glass France SAS, Compagnie de Saint Gobain SA filed Critical Saint Gobain Glass France SAS
Publication of EP0890699A2 publication Critical patent/EP0890699A2/de
Publication of EP0890699A3 publication Critical patent/EP0890699A3/de
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Publication of EP0890699B1 publication Critical patent/EP0890699B1/de
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Classifications

    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47FSPECIAL FURNITURE, FITTINGS, OR ACCESSORIES FOR SHOPS, STOREHOUSES, BARS, RESTAURANTS OR THE LIKE; PAYING COUNTERS
    • A47F3/00Show cases or show cabinets
    • A47F3/04Show cases or show cabinets air-conditioned, refrigerated
    • A47F3/0404Cases or cabinets of the closed type
    • A47F3/0426Details
    • A47F3/0434Glass or transparent panels
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/663Elements for spacing panes
    • E06B3/66304Discrete spacing elements, e.g. for evacuated glazing units

Definitions

  • the invention relates to a glazed element with high insulating power provided with a plastic profile, in particular intended to be fixed on a structure carrier.
  • She is particularly interested in the fixing of glass element to high insulating power on a supporting structure by a technique of fixing said elements by their circumference using a peripheral frame material plastic.
  • the glazed elements thus fixed are glazing monolithic or laminated glazing.
  • such glazings because of their structure and their mechanical behavior, can easily be equipped with profiles at the periphery.
  • the usual techniques of injection deposition of a plastic profile on monolithic or laminated glazing have been widely described in many documents. These techniques have is the subject of many research and improvements. They are on time currently perfectly controlled and widely used.
  • these types glazing does not meet the criteria of acoustic and thermal comfort sought after in recent constructions.
  • Each of the substrates may be a unit glass plate or present a laminated structure.
  • the techniques conventional methods of depositing a peripheral plastic frame pose some problems. Indeed, such insulating glass units are not studied for withstand high pressure on the periphery, because of the nature of the joints sealing devices.
  • the application of high pressures such as, for example, for example, those required in the thermoplastic injection technique, would cause a crushing of the peripheral seal and therefore, as a consequence, a peripheral deformation of the glass sheets constituting the insulating glazing, deformation weakening the insulating glass and may even lead to bursting.
  • European Patent EP-B-236 211 discloses glazing having two glass sheets separated by a dehydrated air space. The Peripheral seal is obtained by reactive injection in situ under high pressure. To achieve this glazing, it is proposed a device comprising means of pulling each glass sheet of the glazing against a wall of the mold during the molding operation. In this way, the crushing of the joint device is deleted.
  • the usual insulating glazing units provide insulation thermal rating considered unsatisfactory for some applications.
  • he is known to produce glazing comprising three sheets of glass and one air blades can be replaced by a gas such as Krypton.
  • These glazings have significantly improved insulation properties but have a structure and mechanical behavior such that it is not easy for them to use, especially in montages type hung glazing.
  • the object of the invention is to provide an insulating glazing unit equipped with a frame plastic peripheral obviating the various disadvantages previously mentioned.
  • the invention thus relates to a glazed element with high insulating power composed of at least two sheets of glass between which a void has been realized, separated from each other by studs distributed over the entire surface and joined at their periphery by a mineral seal, this glazed element being such that at least part of its outer surface is covered by minus a molded plastic profile and preferably at least a portion of its periphery on at least one of its faces.
  • Patent Application EP-A-0 645 516 describes an insulating glazing unit consisting of two glass sheets separated from each other by a weak space in which the void has been realized.
  • the glass sheets are separated each other by studs distributed over the entire surface and joined to their peripheries by a mineral seal.
  • the structure of such a glazing has the advantage of giving it rigidity and holding equivalent to those of a monolithic glazing of thickness equal to the sum of the thicknesses glass sheets, that is to say the glass sheets behave as only one whose thickness is the sum of the two.
  • This type of glazing presents advantageously a small thickness for insulation properties thermal improvements.
  • the high glazed element insulating power because of its mechanical behavior, does not require supporting frames unlike conventional insulating glass units. So, the hanging such glazed elements can be realized by means of profiles in plastic material positioned on at least one face of said glazed element periphery and this without risk of degradation of the glazed element, in particular of the peripheral seal.
  • the plastic profile also covers the edge and / or both sides of the glazed element.
  • the contact surface between the glazed element and the material profile plastic is more important and the maintenance of the glazed element can be achieved mechanically and / or by gluing.
  • the plastic profile covers the entire periphery of the element.
  • this layout of the plastic profile greatly facilitates all handling operations, transport and installation on site. Indeed, she improves the protection of the glazing and more particularly its edges with the possibility of stacking windows on each other others without having to interpose shims, the glazed surfaces not being contact with each other because of the extra thickness of the profiles.
  • the part outer profile of plastic masking its own inner part and the peripheral sealing seal of the glazed element and being able to be tinted, or be painted to match the supporting structure on which the glazed element is intended to be fixed.
  • the overmolded plastic profile is a profile obtained by thermoplastic injection or by reactive injection.
  • the technique of overmolding by injection of an entourage around the periphery of a monolithic or laminated glazing has been described in many documents especially in patents EP-B-127 546 and EP-B-145 443.
  • the inventors have demonstrated that the application of such overmoulding techniques by injection on glazed elements according to the invention makes it possible to perform plastic profiles without the risk of degradation or bursting of the glazed element.
  • the mechanical strength of these glazed elements being equivalent to that of monolithic elements, it is possible to apply strong pressures on the edges of the glazed element unlike the insulating glass conventional.
  • this injection molding technique is used when the plastic profile covers at least one face and the song of the glazed element.
  • the overmolded plastic profile is an extruded profile.
  • "Extruded profile” means all types of profile prefabricated by extrusion which can be glued to the glazed element or extruded directly on the glazed element.
  • the extrusion deposition technique of a frame elastomer on monolithic or laminated glazing has been described in numerous documents, in particular in European patents EP-B-121 481 and EP-B-524 092. The inventors have shown that the use of such Conventional extrusion deposition techniques are not a problem with the glazed element according to the invention.
  • this technique of extrusion deposit is used when the plastic profile covers only one side of the glazed element.
  • the profile made of plastic, substantially in the plane of the glazed element, a part flange constituting an element of a fastener assembly.
  • the glazed element provided with such a profile can be easily attached to a bearing structure, for example, by bonding said overlying part to the supporting structure, by nailing through said overflowing part or by any other means known to those skilled in the art.
  • said portion protruding from the section of material plastic may constitute a means of centering the glazed element on the carrier structure, for example, when it consists of a set of cells inside which the glazed element is embedded.
  • the overflowing part said plastic profile has projecting areas such as legs, flanges, abutments, participating in the set-up, rigging and / or fixing said glazed element.
  • the plastic profile has a shape appropriate to the type of attachment envisaged for a type of application concerned such as, for example, a sealing lip at the level of the upper surface of the glazed element and a hooking tab at the level of the flanking portion of said profile for a flake-type mounting for the building roof.
  • the leg latching allows the glazed elements to be positioned level of the battens of the frame and the sealing lip then comes into contact with the upper glazed element which partially overlaps the said glazed element in order to thus achieve the sealing of the assembly at this level. overlap.
  • At least one insert is embedded in the plastic profile.
  • the presence of such inserts allows the attachment of the glazed element to a structure carrier, this fixing being able to be for example of the snap type or type screwing, or allows the attachment of glass elements together.
  • the glass sheets of the glazed element undergo a quenching treatment.
  • This quenching allows to reinforce the resistance of the glass sheets during the realization of the vacuum, as well as than the overall strength of the glazed element in its various applications.
  • At least one of the glass sheets comprises advantageously a low-emissive layer on its internal face, that is to say on the face in contact with the pads. This layer can contribute to thermal insulation function.
  • the invention also relates to the use of the predefined glazed element.
  • a first use concerns the constitution of roofs, the glazed elements serving as tiles or covering panels.
  • the constitution of roofing is carried out by fixing said glazed elements by nailing, screwing or stapling through the projecting portion of said sections of material plastic.
  • a second use relates to the constitution of building facades large areas.
  • This type of application makes it possible to produce facades of entirely made of glazed elements, some transparent playing the role of glazing-vision, the other opaque, generally acting spandrels.
  • Such facades have a minimum of surface discontinuity views from the outside.
  • a third use relates to the constitution of doors or walls of climatic chambers.
  • This type of application has the advantage of producing, for a small wall thickness, a very high thermal insulation for this kind of use, thermal insulation that can not be achieved with the conventional insulating glazing having an overall thickness meeting the criteria congestion and visibility.
  • the glazed element 1 with high insulating power consists of two sheets of glass 2 and 3 between which a vacuum 4 has been made, separated from one another by studs 5 distributed over the entire surface and joined at their periphery by a mineral seal 6.
  • the glass sheet 2 is coated on its face internal of a low emissive layer 7.
  • This layer is for example of the type of that described in French Patent No. 2,701,474 filed in the name of SAINT-GOBAIN GLAZING INTERNATIONAL.
  • the pads 5 have a thickness of 0.2 millimeter and a diameter of 0.4 millimeter. They are spread all over the surface of the glass sheets and are distant from each other by 30 millimeters.
  • the studs 5 are deposited on one of the glass sheets 2 and 3 after these have been coated with a low-emissive layer 7, for example by pyrolysis, then soaked. After depositing a string of glass frit at the periphery of the second glass sheet, the two glass sheets 2 and 3 are assembled and then heat treatment of the assembly for weld the two glass sheets 2 and 3, the sealing gasket 6 thus realizing the tightness of the whole.
  • We then realize the gap between two sheets of glass 2 and 3 by any means known to those skilled in the art, such as, for example, by the process described in the patent application French translation in the name of SAINT-GOBAIN VITRAGE under n ° 96/09 632.
  • the glazed element is then ready to be equipped with a plastic profile.
  • FIG. 1 represents the glazed element 1 whose four corners are covered with a section 8 made of plastic.
  • the profiles 8 allow the mechanical attachment of the assembly to a supporting structure, and this by attachment points 9. Other locations of the profiles 8 in matter plastic, that is to say other than located in the corners, are also possible.
  • FIG. 2 represents the glazed element 1 whose edge is illustrated by a dotted line 20 and whose entire periphery is covered with a profile 10 made of plastic
  • this profile 10 allows the mechanical attachment of the assembly to a bearing structure, and this by snap points 11. Points other than in the corners are also possible. The number of snap points will be determined based on the size of the element 1, the type of application envisaged and the desired aesthetics.
  • the profiles 8 and 10 will preferably be obtained either by injection thermoplastic or by reactive injection, or by extrusion.
  • Injection deposition techniques have been described in many documents. They consist, in a general way, in setting up on the edge of the element, a mold formed of two mold halves, which defines the molding cavity. After closing the mold, the molding cavity is filled with plastic material. When the plastic material presents the inside of the mold forms a profile no longer deforming, the mold is open and the element thus framed is removed from the mold.
  • the plastics material is a reaction mixture that expands into the cavity and forms a body porous mold with an envelope sealing.
  • thermoplastic injection deposition technique the cavity of the mold is filled with thermoplastic material melted under pressure relatively high.
  • extrusion deposition technique has also been described in many documents such as for example in the European patent EP-B-524 092. In general, it consists in using a robot that moves a extrusion nozzle at the periphery of the element in order to deposit a profile in plastic material according to a determined continuous trajectory or not, the nozzle extrusion being fed with plastic from an extruder for through a pressure hose.
  • extrusion deposition technique will be preferred when the profile is plastic material will only cover one face, this technique being more adapted to the surface deposit. Moreover, this technique does not require the production of molds adapted to each type of element.
  • an adhesion promoter deposited on the periphery of the glazed element it is advantageous to use, before the deposition of the plastic material, an adhesion promoter deposited on the periphery of the glazed element.
  • the choice of the priming composition as adhesion promoter depends on the nature of the profile.
  • This composition is, for example, type of that described in European patents EP 0 574 315 and EP 0 603 072, that is to say based on at least one silane and a composition capable of to form a layer with free hydroxyl groups.
  • This kind of composition gives good results for the profiles in thermoplastic such as those, for example, polyurethane.
  • FIG. 3 represents a first embodiment of the glazed element according to the invention.
  • the glazed element 1 is covered by a profile 12 made of plastic material on one of its faces, the profile 12 being positioned on the periphery of the glass sheet 3.
  • this section 12 has in its thickness a hole 13 which allows the insertion of a fastening element such as, for example, a screw-nut, this element of fastening for fastening the glazed element to a structure carrier through the profile 12.
  • a fastening element such as, for example, a screw-nut
  • FIG. 4 represents a second embodiment of the element glazed according to the invention.
  • the glazed element 1 is covered by a section 14 of plastic material on both sides and on its edge, that is to say the profile 14 is positioned on the entire edge of the glazed element 1.
  • this profile 14 has an extra thickness of material at the level of the edge of the glazed element, this part of the profile being pierced so that a fastening element such as, for example, a screw-nut, can be introduced for attachment to a supporting structure.
  • FIG. 5 represents a third embodiment of the element glazed according to the invention.
  • the glazed element 1 is covered by a plastic profile 16 on the entire edge of The glazed element 1.
  • this section 16 has an element female 17 of a latching system, this member 17 then cooperating with the corresponding male organ forming an integral part of the structure carrier.
  • the member 17 can also be the male organ of a system latching cooperating with the corresponding female member forming part integral of the supporting structure.
  • FIG. 6 represents a fourth embodiment of the element glazed according to the invention.
  • the glazed element 1 is covered by a plastic profile 18 on the entire edge of the glazed element 1.
  • the profile 18 is provided with a metal insert 19, one of which part is embedded in the plastic material, this insert 19 cooperating with a fastening means in order to allow the attachment of the glazed element 1 to a supporting structure.
  • the metal insert 19 may be, for example, a screw of which only the head is embedded in the profile 18.
  • FIG. 7 represents a fifth embodiment of the element glazed according to the invention.
  • the glazed element 1 is covered by a section 21 of plastic material on its entire edge.
  • this section 21 has substantially in the plane of the glazed element 1, an overflowing portion 22.
  • This overflowing portion 22 has at its end an appendage 23 in L that we will call leg and the profile 21 at the edge of the sheet overlap glass 2 has a lip 24 which we will call sealing lip.
  • This type of profile 21 is particularly suitable for the constitution of tiles mounted in shell, the bonding paste abutting on a batten of a frame and the section 21 is then nailed to the bed.
  • the lip 24 makes it possible to sealing between two glazed elements thus hung at the level of their horizontal overlap.

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  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Securing Of Glass Panes Or The Like (AREA)
  • Insulators (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Special Wing (AREA)
  • Electronic Switches (AREA)
  • Laminated Bodies (AREA)
  • Forklifts And Lifting Vehicles (AREA)
  • Inorganic Insulating Materials (AREA)
  • Glass Compositions (AREA)
  • Ceramic Capacitors (AREA)

Claims (15)

  1. Glaselement (1) mit hohem Dammvermögen, das sich aus mindestens zwei Glasscheiben (2, 3) zusammensetzt, zwischen welchen ein Vakuum (4) erzeugt worden ist und welche durch über die gesamte Fläche verteilte Stifte (5) voneinander getrennt und am Umfang durch eine anorganische Dichtung (6) verbunden sind, wobei wenigstens ein Teil der Außenfläche des Glaselements (1) mit mindestens einem aufgeformten Kunststoffprofil (8, 10, 12, 14, 16, 18, 21) bedeckt ist
  2. Glaselement nach Anspruch 1, dadurch gekennzeichnet, dass wenigstens ein Teil des Umfangs des Glaselements (1) auf wenigstens einer Seite mit mindestens einem Kunststoffprofil (8, 10, 12, 14, 16, 18, 21) bedeckt ist.
  3. Glaselement nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass das Kunststoffprofil (8, 10, 14, 16, 18, 21) die Kante des Glaselements (1) bedeckt.
  4. Glaselement nach Anspruch 2 oder 3, dadurch gekennzeichnet, dass das Kunststoffprofil (8, 10, 14, 16, 18, 21) beide Seiten des Glaselements (1) bedeckt.
  5. Glaselement nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass das aufgeformte Kunststoffprofil (8, 10, 12, 14, 16, 18, 21) ein Profil ist, das durch Thermoplast- oder Reaktionsspritzgießen erhalten worden ist.
  6. Glaselement nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass das aufgeformte Kunststoffprofil (8, 10, 12, 14, 16, 18, 21) ein extrudiertes Profil ist.
  7. Glaselement nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass das Kunststoffprofil (8, 10, 21) im Wesentlichen in der Ebene des Glaselements (1) einen überstehenden Teil (22) umfasst, der einen Bestandteil einer Befestigungseinheit bildet.
  8. Glaselement nach Anspruch 7, dadurch gekennzeichnet, dass der überstehenden Teil (22) des Kunststoffprofils (8, 10, 21) vorstehende Bereiche (23) wie Klemmen, nach außen umgebogene Ränder und Anschläge aufweist, die am Anbringen, Festklemmen und/oder Befestigen des Glaselements (1) beteiligt sind.
  9. Glaselement nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass mindestens ein Einsatz (19), der mit einem Befestigungsmittel zusammenwirkt, in das Kunststoffprofil (8, 10, 18) eingebettet ist.
  10. Glaselement nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass das Glaselement (1) aus vorgespannten Glasscheiben (2, 3) besteht.
  11. Glaselement nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass mindestens eine der Glasscheiben (2, 3) auf der mit den Stiften (5) in Berührung befindlichen Seite eine niedrig emittierende Schicht (7) besitzt.
  12. Verwendung des Glaselements nach einem der vorhergehenden Ansprüche zum Decken von Dächern.
  13. Verwendung des Glaselements nach Anspruch 12, dadurch gekennzeichnet, dass das Decken eines Daches durch Befestigung der Glaselemente durch Nageln, Verschrauben oder Klemmen durch den überstehenden Teil der Kuststoffprofile hindurch durchgeführt wird.
  14. Verwendung des Glaselements nach einem der Ansprüche 1 bis 11 zur Herstellung von Gebäudefassaden.
  15. Verwendung des Glaselements nach einem der Ansprüche 1 bis 11 zur Herstellung von Türen oder Wänden für einen klimatisierten Raum.
EP98400872A 1997-07-07 1998-04-09 Mit einem Kunstoffprofil versehenes Verglasungselement mit hohem Isoliervermögen Expired - Lifetime EP0890699B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9708585A FR2765614B3 (fr) 1997-07-07 1997-07-07 Element vitre a haut pouvoir isolant muni de profile en matiere plastique
FR9708585 1997-07-07

Publications (3)

Publication Number Publication Date
EP0890699A2 EP0890699A2 (de) 1999-01-13
EP0890699A3 EP0890699A3 (de) 1999-11-10
EP0890699B1 true EP0890699B1 (de) 2005-03-02

Family

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Family Applications (1)

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EP98400872A Expired - Lifetime EP0890699B1 (de) 1997-07-07 1998-04-09 Mit einem Kunstoffprofil versehenes Verglasungselement mit hohem Isoliervermögen

Country Status (11)

Country Link
US (1) US6216417B1 (de)
EP (1) EP0890699B1 (de)
JP (2) JPH1122327A (de)
AT (1) ATE290150T1 (de)
CA (1) CA2234297C (de)
DE (1) DE69829133T2 (de)
DK (1) DK0890699T3 (de)
ES (1) ES2236876T3 (de)
FR (1) FR2765614B3 (de)
PL (1) PL194640B1 (de)
PT (1) PT890699E (de)

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ES2593323T3 (es) * 2007-08-03 2016-12-07 Vkr Holding A/S Un método para fabricar un módulo de cristal y una ventana que comprende tal módulo de cristal
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EP2687669B1 (de) * 2007-08-03 2015-04-22 VKR Holding A/S Verfahren zum Befestigen einer Isoliergasscheibe an einem Fensterrahmen mittels eines Einsatzes im extrudierten Randstreifen
US8276498B1 (en) * 2007-08-08 2012-10-02 Composiflex Ballistic shield system
EP3299566B1 (de) 2009-02-03 2020-03-25 VKR Holding A/S Fenster mit einem flügelrahmen und mitteln zur verminderung von kondensation
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US10196851B2 (en) * 2015-01-29 2019-02-05 Schott Gemtron Corporation Encapsulated insulated glass unit
EP3563015B1 (de) * 2016-12-29 2023-08-02 VKR Holding A/S Zur installation an einen fensterrahmen angepasstes scheibenmodul und verfahren zur herstellung eines scheibenmoduls
DK179723B1 (en) * 2017-02-15 2019-04-12 Vkr Holding A/S A method for attaching a pane element to a sash and a pane module including a pane element
CN107675998B (zh) * 2017-10-25 2023-05-16 浙江艾希德新材料科技有限公司 一种防撞淋浴房玻璃门
FR3080402A1 (fr) * 2018-04-23 2019-10-25 Saint-Gobain Glass France Fenetre de batiment ou element de facade de batiment comprenant un vitrage mobile ou amovible
FR3080403A1 (fr) * 2018-04-23 2019-10-25 Saint-Gobain Glass France Fenetre de batiment ou element de facade de batiment
US12428902B2 (en) 2020-11-16 2025-09-30 Gemtron Corporation Encapsulated oven window pack

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Also Published As

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US6216417B1 (en) 2001-04-17
CA2234297C (fr) 2006-10-17
ATE290150T1 (de) 2005-03-15
PT890699E (pt) 2005-05-31
JP4546575B2 (ja) 2010-09-15
EP0890699A3 (de) 1999-11-10
DE69829133D1 (de) 2005-04-07
JPH1122327A (ja) 1999-01-26
DE69829133T2 (de) 2006-02-09
PL194640B1 (pl) 2007-06-29
PL325745A1 (en) 1999-01-18
CA2234297A1 (fr) 1999-01-07
FR2765614A1 (fr) 1999-01-08
DK0890699T3 (da) 2005-06-06
EP0890699A2 (de) 1999-01-13
FR2765614B3 (fr) 1999-08-06
ES2236876T3 (es) 2005-07-16
JP2010031644A (ja) 2010-02-12

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