EP1122086A1 - Film de couverture pour la protection d'imprimés et procédé pour sa préparation - Google Patents
Film de couverture pour la protection d'imprimés et procédé pour sa préparation Download PDFInfo
- Publication number
- EP1122086A1 EP1122086A1 EP00300874A EP00300874A EP1122086A1 EP 1122086 A1 EP1122086 A1 EP 1122086A1 EP 00300874 A EP00300874 A EP 00300874A EP 00300874 A EP00300874 A EP 00300874A EP 1122086 A1 EP1122086 A1 EP 1122086A1
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- EP
- European Patent Office
- Prior art keywords
- ethylene
- film
- copolymer resin
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000013039 cover film Substances 0.000 title claims abstract description 58
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 239000006185 dispersion Substances 0.000 claims abstract description 48
- 239000000758 substrate Substances 0.000 claims abstract description 30
- 239000004014 plasticizer Substances 0.000 claims abstract description 25
- 239000005977 Ethylene Substances 0.000 claims abstract description 24
- 239000000178 monomer Substances 0.000 claims abstract description 22
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 14
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 11
- 150000001993 dienes Chemical class 0.000 claims abstract description 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 10
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- 238000000576 coating method Methods 0.000 claims abstract description 7
- 239000004615 ingredient Substances 0.000 claims abstract description 7
- 150000001733 carboxylic acid esters Chemical class 0.000 claims abstract description 6
- 239000010408 film Substances 0.000 claims description 51
- -1 polyethylene terephthalate Polymers 0.000 claims description 49
- 229920005989 resin Polymers 0.000 claims description 47
- 239000011347 resin Substances 0.000 claims description 47
- 229920001577 copolymer Polymers 0.000 claims description 32
- VOWAEIGWURALJQ-UHFFFAOYSA-N Dicyclohexyl phthalate Chemical group C=1C=CC=C(C(=O)OC2CCCCC2)C=1C(=O)OC1CCCCC1 VOWAEIGWURALJQ-UHFFFAOYSA-N 0.000 claims description 30
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 28
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 28
- 229920006026 co-polymeric resin Polymers 0.000 claims description 20
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 19
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 19
- 229920003146 methacrylic ester copolymer Polymers 0.000 claims description 14
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 13
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 13
- 239000005026 oriented polypropylene Substances 0.000 claims description 13
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 13
- 235000007586 terpenes Nutrition 0.000 claims description 12
- 229920013716 polyethylene resin Polymers 0.000 claims description 11
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 9
- 239000010410 layer Substances 0.000 claims description 8
- 239000002356 single layer Substances 0.000 claims description 8
- 229920006228 ethylene acrylate copolymer Polymers 0.000 claims description 7
- KCXZNSGUUQJJTR-UHFFFAOYSA-N Di-n-hexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC KCXZNSGUUQJJTR-UHFFFAOYSA-N 0.000 claims description 6
- 150000003505 terpenes Chemical class 0.000 claims description 6
- XFDQLDNQZFOAFK-UHFFFAOYSA-N 2-benzoyloxyethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCOC(=O)C1=CC=CC=C1 XFDQLDNQZFOAFK-UHFFFAOYSA-N 0.000 claims description 3
- LUNMJRJMSXZSLC-UHFFFAOYSA-N 2-cyclopropylethanol Chemical compound OCCC1CC1 LUNMJRJMSXZSLC-UHFFFAOYSA-N 0.000 claims description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
- PJLLCGNQPWXWGL-UHFFFAOYSA-N [3-benzoyloxy-2-(benzoyloxymethyl)-2-methylpropyl] benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC(COC(=O)C=1C=CC=CC=1)(C)COC(=O)C1=CC=CC=C1 PJLLCGNQPWXWGL-UHFFFAOYSA-N 0.000 claims description 3
- VNGOYPQMJFJDLV-UHFFFAOYSA-N dimethyl benzene-1,3-dicarboxylate Chemical compound COC(=O)C1=CC=CC(C(=O)OC)=C1 VNGOYPQMJFJDLV-UHFFFAOYSA-N 0.000 claims description 3
- DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical compound C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 claims description 3
- 125000005456 glyceride group Chemical group 0.000 claims description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- SYDJVRWZOWPNNO-UHFFFAOYSA-N sucrose-benzoate Natural products OCC1OC(OC2(COC(=O)c3ccccc3)OC(CO)C(O)C2O)C(O)C(O)C1O SYDJVRWZOWPNNO-UHFFFAOYSA-N 0.000 claims description 3
- CBKMOPGKNJBDFA-UHFFFAOYSA-N tricyclohexyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound C1CCCCC1OC(=O)CC(C(=O)OC1CCCCC1)(O)CC(=O)OC1CCCCC1 CBKMOPGKNJBDFA-UHFFFAOYSA-N 0.000 claims description 3
- DKYVVNLWACXMDW-UHFFFAOYSA-N n-cyclohexyl-4-methylbenzenesulfonamide Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC1CCCCC1 DKYVVNLWACXMDW-UHFFFAOYSA-N 0.000 claims 2
- 238000000034 method Methods 0.000 abstract description 18
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 56
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 56
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 38
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 27
- 238000007720 emulsion polymerization reaction Methods 0.000 description 13
- 239000002245 particle Substances 0.000 description 13
- 239000004094 surface-active agent Substances 0.000 description 13
- 125000002298 terpene group Chemical group 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 4
- 239000004816 latex Substances 0.000 description 4
- 229920000126 latex Polymers 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 229920000159 gelatin Polymers 0.000 description 3
- 239000008273 gelatin Substances 0.000 description 3
- 235000019322 gelatine Nutrition 0.000 description 3
- 235000011852 gelatine desserts Nutrition 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- SOGAXMICEFXMKE-UHFFFAOYSA-N alpha-Methyl-n-butyl acrylate Natural products CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- WUXWWSDWRUVSNE-UHFFFAOYSA-N methyl propane-1-sulfonate;prop-2-enamide Chemical compound NC(=O)C=C.CCCS(=O)(=O)OC WUXWWSDWRUVSNE-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- UTSYWKJYFPPRAP-UHFFFAOYSA-N n-(butoxymethyl)prop-2-enamide Chemical compound CCCCOCNC(=O)C=C UTSYWKJYFPPRAP-UHFFFAOYSA-N 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0027—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers
Definitions
- This invention relates to a cover film employable for protection of a print and a method for production thereof. More specifically, this invention relates to a cover film to be attached on a print which is printed on a sheet of paper employable for printing conducted by employing a type of a printer which uses a water based ink or which is printed on a sheet of paper on which a film for expediting permeation of a water based ink into the paper and for causing clear printing thereon, is attached, for the purpose to project the print from a potential external hazard particularly caused by rain unavoidable, when the print is kept outdoors.
- the film available in the prior art for expediting permeation of the water based ink into the paper and for causing clear printing thereon is a film of a hydrophilic material such as polyvinyl alcohol, water soluble acrylic resin, water soluble polyester resin, aqueous urethane resin, gelatin, polyethylene oxide or the like.
- a typical film resistive against the influence of weather and/or climate and which is available in the prior art is a film of polyethylene terephthalate or oriented polypropylene which is coated a film of polyethylene resin, ethylene vinyl acetate copolymer resin, ethylene acrylic ester copolymer resin, ethylene methacrylic ester copolymer resin, ethylene acrylate copolymer resin, ethylene methacrylate copolymer resin, ethylene acrylate acrylic ester copolymer resin, ethylene methacrylate acrylic ester copolymer resin, ethylene acrylate methacrylic ester copolymer resin, ethylene acrylate methacrylic ester copolymer resin or ethylene methacrylate methacrylic ester copolymer resin.
- the cover film available in the prior art is, however, involved with the following drawbacks. Firstly, the cover film is inclined to be readily removed from the print which is produced by printing conducted on a sheet of paper which is coated with the foregoing film for expediting permeation of a water based ink into the paper and for causing clear printing thereon and which actually is made of a hydrophilic material, in a rather long period in which the print is kept outdoors. Secondly, the process to cover the print with the cover film must be conducted at a relatively high temperature for example 100° C.
- the first object of this invention is to provide a cover film employable for protection of a print which is printed on a sheet of paper employable for printing conducted by employing a type of a printer which uses a water based ink or which is printed on a sheet of paper on which a film for expediting permeation of a water based ink into the paper and for causing clear printing thereon is attached, for the purpose to protect the print from a potential external hazard particularly caused by rain unavoidable, when the print is kept outdoors, wherein the effects of the protection is durable for a long time and the cover film can be attached on a print at a relatively low temperature.
- the second object of this invention is to provide a method for producing the foregoing cover film.
- This invention is based on a concept to utilize the chemical property that a cover film produced by coating an aqueous dispersion containing 100 weight portion of a copolymer latex containing at least one ingredient of a group including ethylene, unsaturated carboxylic acid and unsaturated carboxylic ester, in addition to aliphatic conjugated diolefin monomer and vinyl monomer, 10 through 200 weight portion of a tackifier and 50 through 500 weight portion of a crystalline plasticizer, is effective to adhere the cover film itself to the film of a hydrophilic material such as polyvinyl alcohol, water soluble acrylic resin, water soluble polyester resin, aqueous urethane resin, gelatin, polyethylene oxide or the like, when the cover film is pressed toward the film of the hydrophilic material under a high temperature, because the copolymer latex, the tackifier and the crystalline plasticizer are melted together under a high temperature and the crystalline plasticizer plasticizes the copolymer latex and the tackifier,
- a cover film in accordance with this invention is a film produced by coating an aqueous dispersion containing 50 through 500 weight portion of at least one ingredient of a group including ethylene, unsaturated carboxylic acid and unsaturated carboxylic ester, in addition to aliphatic conjugated diolefin monomer and vinyl monomer, 10 through 500 weight portion of a tackifier and 50 through 500 weight portion of a crystalline plasticizer which is liquefied at a temperature of 40° C, on a substrate which actually is a single layer film or a plural layer film of polyethylene terephthalate or oriented polypropylene or on a substrate which actually is a single layer film or a plural layer film of polyethylene terephthalate or oriented polypropylene which is coated with a film of polyethylene resin, ethylene vinyl acetate copolymer resin, ethylene acrylic ester copolymer resin, ethylene methacrylic ester copolymer resin, ethylene acrylate copolymer resin, ethylene
- a method for producing a cover film in accordance with this invention is a step for coating an aqueous dispersion containing 50 through 500 weight portion of at least one ingredient of a group including ethylene, unsaturated carboxylic acid and unsaturated carboxylic ester, in addition to aliphatic conjugated diolefin monomer and vinyl monomer, 10 through 500 weight portion of a tackifier and 50 through 500 weight portion of a crystalline plasticizer which is liquefied at a temperature of 40° C, on a substrate which actually is a single layer film or a plural layer film of polyethylene terephthalate or oriented polypropylene or on a substrate which actually is a single layer film or a plural layer film of polyethylene terephthalate or oriented polypropylene which is coated with a film of polyethylene resin, ethylene vinyl acetate copolymer resin, ethylene acrylic ester copolymer resin, ethylene methacrylic ester copolymer resin, ethylene acrylate copoly
- tackifier available in the prior art can be employed for the foregoing purpose. It is needless to emphasize that the compatibility is good with the base resin. Rosin, the derivatives of rosin, terpene and the derivatives of terpene are preferable.
- Typical examples of the foregoing crystalline plasticizers are dicyclohexyl phthalate, diphenyl phthalate, dihexyl phthalate, dihydro aviethyl phthalate, dimethyl isophthalate, sucrose benzoate, ethyleneglycol dibenzoate, trimethylolethane tri-benzoate, glyceride tri-benzoate, pentaerythritol tetra-benzoate, sucrose octacetate, tri-cyclohexyl citrate and N-cyclohexyl p-toluenesulfonamide et al.
- Fig. 1 is a schematic drawing illustrating a process for attaching a cover film in accordance with one embodiment of this invention on the both surfaces of a print to be protected by the cover film of this invention.
- An emulsion polymerization process is employed to polymerize 10 weight % of butadiene, 10 weight % of methacrylic acid and 80 weight % of styrene to produce styrene butadiene methacrylate copolymer particles containing the styrene component, butadiene component and methacrylic acid componet in a ratio of 80 : 10 : 10.
- An aqueous dispersion containing 100 weight portion of the foregoing copolymer, 60 weight portion of a tackifier which actually is rosin estyer and 160 weight portion of crystalline plasticizer which actually is dicyclohexyl phthalate (for example, an aqueous dispersion containing dicyclohexyl phthalate, a surface active agent and a water soluble resin in a ratio of 100 : 3 : 3) is produced.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate. In this manner, a cover film in accordance with the first embodiment of this invention is produced.
- An emulsion polymerization process is employed to polymerize 10 weight % of butadiene, 10 weight % of methacrylic acid and 80 weight % of styrene to produce styrene butadiene methacrylate copolymer particles containing the styrene component, butadiene component and methacrylic acid componet in a ratio of 80 : 10 : 10.
- An aqueous dispersion containing 100 weight portion of the foregoing copolymer, 60 weight portion of a tackifier which actually is rosin estyer and 160 weight portion of crystalline plasticizer which actually is dicyclohexyl phthalate (for example, an aqueous dispersion containing dicyclohexyl phthalate, a surface active agent and a water soluble resin in a ratio of 100 : 3 : 3) is produced.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate coated with ethylene vinyl acetate copolymer. In this manner, a cover film in accordance with the second embodiment of this invention is produced.
- An emulsion polymerization process is employed to polymerize 10 weight % of butadiene, 10 weight % of methacrylic acid and 80 weight % of styrene to produce styrene butadiene methacrylate copolymer particles containing the styrene component, butadiene component and methacrylic acid componet in a ratio of 80 : 10 : 10.
- An aqueous dispersion containing 100 weight portion of the foregoing copolymer, 60 weight portion of a tackifier which actually is terpene and 100 weight portion of crystalline plasticizer which actually is dicyclohexyl phthalate (for example, an aqueous dispersion containing dicyclohexyl phthalate, a surface active agent and a water soluble resin in a ratio of 100 : 3 : 3) is produced.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate. In this manner, a cover film in accordance with the third embodiment of this invention is produced.
- An emulsion polymerization process is employed to polymerize 10 weight % of butadiene, 10 weight % of methacrylic acid and 80 weight % of styrene to produce styrene butadiene methacrylate copolymer particles containing the styrene component, butadiene component and methacrylic acid componet in a ratio of 80 : 10 : 10.
- An aqueous dispersion containing 100 weight portion of the foregoing copolymer, 60 weight portion of a tackifier which actually is terpene and 100 weight portion of crystalline plasticizer which actually is dicyclohexyl phthalate (for example, an aqueous dispersion containing dicyclohexyl phthalate, a surface active agent and a water soluble resin in a ratio of 100 : 3 : 3) is produced.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate coated with ethylene vinyl acetate copolymer. In this manner, a cover film in accordance with the fourth embodiment of this invention is produced.
- An emulsion polymerization process is employed to polymerize 10 weight % of butadiene, 10 weight % of methacrylic acid and 80 weight % of styrene to produce styrene butadiene methacrylate copolymer particles containing the styrene component, butadiene component and methacrylic acid componet in a ratio of 80 : 10 : 10.
- An aqueous dispersion containing 100 weight portion of the foregoing copolymer, 60 weight portion of a tackifier which actually is terpene and 160 weight portion of crystalline plasticizer which actually is dicyclohexyl phthalate (for example, an aqueous dispersion containing dicyclohexyl phthalate, a surface active agent and a water soluble resin in a ratio of 100 : 3 : 3) is produced.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate. In this manner, a cover film in accordance with the fifth embodiment of this invention is produced.
- An emulsion polymerization process is employed to polymerize 10 weight % of butadiene, 10 weight % of methacrylic acid and 80 weight % of styrene to produce styrene butadiene methacrylate copolymer particles containing the styrene component, butadiene component and methacrylic acid componet in a ratio of 80 : 10 : 10.
- An aqueous dispersion containing 100 weight portion of the foregoing copolymer, 60 weight portion of a tackifier which actually is terpene and 160 weight portion of crystalline plasticizer which actually is dicyclohexyl phthalate (for example, an aqueous dispersion containing dicyclohexyl phthalate, a surface active agent and a water soluble resin in a ratio of 100 : 3 : 3) is produced.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate coated with ethylene vinyl acetate copolymer. In this manner, a cover film in accordance with the sixth embodiment of this invention is produced.
- An aqueous dispersion is produced by dispersing dicyclohexyl phthalate in water at a temperature less than 50° C.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate coated with ethylene vinyl acetate copolymer.. In this manner, a cover film in accordance with the seventh embodiment of this invention is produced.
- An emulsion polymerization process is employed to polymerize 10 weight % of butadiene, 10 weight % of methacrylic acid and 80 weight % of styrene to produce styrene butadiene methacrylate copolymer particles containing the styrene component, butadiene component and methacrylic acid componet in a ratio of 80 : 10 : 10.
- An aqueous dispersion containing 100 weight portion of the foregoing copolymer, 100 weight portion of a tackifier which actually is rosin estyer and 100 weight portion of crystalline plasticizer which actually is dicyclohexyl phthalate (for example, an aqueous dispersion containing dicyclohexyl phthalate, a surface active agent and a water soluble resin in a ratio of 100 : 3 : 3) is produced.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate coated with ethylene vinyl acetate copolymer. In this manner, a cover film in accordance with the eighth embodiment of this invention is produced.
- An emulsion polymerization process is employed to polymerize 10 weight % of butadiene, 10 weight % of methacrylic acid and 80 weight % of styrene to produce styrene butadiene methacrylate copolymer particles containing the styrene component, butadiene component and methacrylic acid componet in a ratio of 80 : 10 : 10.
- An aqueous dispersion containing 100 weight portion of the foregoing copolymer, 60 weight portion of a tackifier which actually is rosin estyer and 100 weight portion of crystalline plasticizer which actually is dicyclohexyl phthalate (for example, an aqueous dispersion containing dicyclohexyl phthalate, a surface active agent and a water soluble resin in a ratio of 100 : 3 : 3) is produced.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate coated with ethylene vinyl acetate copolymer. In this manner, a cover film in accordance with the ninth embodiment of this invention is produced.
- An emulsion polymerization process is employed to polymerize 10 weight % of butadiene, 10 weight % of methacrylic acid and 80 weight % of styrene to produce styrene butadiene methacrylate copolymer particles containing the styrene component, butadiene component and methacrylic acid componet in a ratio of 80 : 10 : 10.
- An aqueous dispersion containing 100 weight portion of the foregoing copolymer, 2 weight portion of a tackifier which actually is rosin estyer and 100 weight portion of crystalline plasticizer which actually is dicyclohexyl phthalate (for example, an aqueous dispersion containing dicyclohexyl phthalate, a surface active agent and a water soluble resin in a ratio of 100 : 3 : 3) is produced.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate coated with ethylene vinyl acetate copolymer. In this manner, a cover film in accordance with the tenth embodiment of this invention is produced.
- An emulsion polymerization process is employed to polymerize 10 weight % of butadiene, 10 weight % of methacrylic acid and 80 weight % of styrene to produce styrene butadiene methacrylate copolymer particles containing the styrene component, butadiene component and methacrylic acid componet in a ratio of 80 : 10 : 10.
- An aqueous dispersion containing 50 weight portion of the foregoing copolymer, 100 weight portion of a tackifier which actually is rosin estyer and 100 weight portion of crystalline plasticizer which actually is dicyclohexyl phthalate (for example, an aqueous dispersion containing dicyclohexyl phthalate, a surface active agent and a water soluble resin in a ratio of 100 : 3 : 3) is produced.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate coated with ethylene vinyl acetate copolymer. In this manner, a cover film in accordance with the eleventh embodiment of this invention is produced.
- An emulsion polymerization process is employed to polymerize 10 weight % of butadiene, 10 weight % of methacrylic acid and 80 weight % of styrene to produce styrene butadiene methacrylate copolymer particles containing the styrene component, butadiene component and methacrylic acid componet in a ratio of 80 : 10 : 10.
- An aqueous dispersion containing 10 weight portion of the foregoing copolymer, 100 weight portion of a tackifier which actually is rosin estyer and 100 weight portion of crystalline plasticizer which actually is dicyclohexyl phthalate (for example, an aqueous dispersion containing dicyclohexyl phthalate, a surface active agent and a water soluble resin in a ratio of 100 : 3 : 3) is produced.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate coated with ethylene vinyl acetate copolymer. In this manner, a cover film in accordance with the twelfth embodiment of this invention is produced.
- An emulsion polymerization process is employed to polymerize 10 weight % of butadiene, 10 weight % of methacrylic acid and 80 weight % of styrene to produce styrene butadiene methacrylate copolymer particles containing the styrene component, butadiene component and methacrylic acid componet in a ratio of 80 : 10 : 10.
- An aqueous dispersion containing 10 weight portion of the foregoing copolymer, 100 weight portion of a tackifier which actually is terpene and 100 weight portion of crystalline plasticizer which actually is dicyclohexyl phthalate (for example, an aqueous dispersion containing dicyclohexyl phthalate, a surface active agent and a water soluble resin in a ratio of 100 : 3 : 3) is produced.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate coated with ethylene vinyl acetate copolymer. In this manner, a cover film in accordance with the thirteenth embodiment of this invention is produced.
- An emulsion polymerization process is employed to polymerize 10 weight % of butadiene, 10 weight % of methacrylic acid and 80 weight % of styrene to produce styrene butadiene methacrylate copolymer particles containing the styrene component, butadiene component and methacrylic acid componet in a ratio of 80 : 10 : 10.
- An aqueous dispersion containing 10 weight portion of the foregoing copolymer, 100 weight portion of a tackifier which actually is terpene phenol copolymer and 100 weight portion of crystalline plasticizer which actually is dicyclohexyl phthalate (for example, an aqueous dispersion containing dicyclohexyl phthalate, a surface active agent and a water soluble resin in a ratio of 100 : 3 : 3) is produced.
- a gravure coater is employed to coat the foregoing aqueous dispersion on a substrate of polyethylene terephthalate coated with ethylene vinyl acetate copolymer. In this manner, a cover film in accordance with the fourteenth embodiment of this invention is produced.
- letters and/or pictures (7) are printed on a film for expediting permeation of the water based ink into the paper and for causing clear printing thereon (2) coated on one surface of a sheet of paper (1) to produce a print (3).
- the film for expediting permeation of the water based ink into the paper and for causing clear printing thereon (2) is a film of a hydrophilic material such as polyvinyl alcohol, water soluble acrylic resin, water soluble polyester resin, aqueous urethane resin, gelatin, polyethylene oxide or the like.
- Two sheets of cover films (4) in accordance with the first through fourteenth embodiments of this invention are attached on the both surfaces of the print (3) at a low temperature of approximately 80° C.
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00300874A EP1122086A1 (fr) | 2000-02-04 | 2000-02-04 | Film de couverture pour la protection d'imprimés et procédé pour sa préparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP00300874A EP1122086A1 (fr) | 2000-02-04 | 2000-02-04 | Film de couverture pour la protection d'imprimés et procédé pour sa préparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1122086A1 true EP1122086A1 (fr) | 2001-08-08 |
Family
ID=8172680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP00300874A Withdrawn EP1122086A1 (fr) | 2000-02-04 | 2000-02-04 | Film de couverture pour la protection d'imprimés et procédé pour sa préparation |
Country Status (1)
| Country | Link |
|---|---|
| EP (1) | EP1122086A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1205809A3 (fr) * | 2000-11-13 | 2004-01-07 | Hewlett-Packard Company | Surcouche protectrice pour des images obtenues par jet d'encre, transfert thermique ou xérographie, et dispositifs pour l'application de la couche |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4427744A (en) * | 1982-08-19 | 1984-01-24 | H. B. Fuller Company | Heat-activated pressure sensitive adhesive for bonding label stock to plastic film, metal foil and the like |
| JPS62164777A (ja) * | 1986-01-14 | 1987-07-21 | Mitsubishi Paper Mills Ltd | 感熱性粘着組成物 |
| JPH01193381A (ja) * | 1988-01-27 | 1989-08-03 | Mitsubishi Paper Mills Ltd | 感熱性粘着組成物および感熱性粘着シート |
| US5252393A (en) * | 1987-06-25 | 1993-10-12 | Mitsubishi Paper Mills Ltd. | Thermal delayed-tack adhesive compositions and thermal delayed-tack adhesive sheets |
| JPH0657223A (ja) * | 1992-08-07 | 1994-03-01 | Toyo Ink Mfg Co Ltd | 感熱性ディレードタック型粘着剤 |
| JPH06100848A (ja) * | 1992-08-07 | 1994-04-12 | Toyo Ink Mfg Co Ltd | 感熱性ディレードタック型粘着剤および感熱性粘着シート |
| JPH06313163A (ja) * | 1993-03-05 | 1994-11-08 | Toppan Printing Co Ltd | 感熱性粘着組成物及び感熱性粘着シート |
| JPH0711229A (ja) * | 1993-06-25 | 1995-01-13 | Toyo Ink Mfg Co Ltd | 感熱性粘着剤および感熱性粘着シート |
| JPH07109444A (ja) * | 1993-10-15 | 1995-04-25 | Toyo Ink Mfg Co Ltd | 高速ラベラー用感熱性粘着シート |
| JPH08207426A (ja) * | 1995-01-31 | 1996-08-13 | Kimoto & Co Ltd | インクジェット記録用シート |
| JPH08231929A (ja) * | 1995-02-28 | 1996-09-10 | Toppan Printing Co Ltd | 粘着シート及びその剥離方法 |
-
2000
- 2000-02-04 EP EP00300874A patent/EP1122086A1/fr not_active Withdrawn
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4427744A (en) * | 1982-08-19 | 1984-01-24 | H. B. Fuller Company | Heat-activated pressure sensitive adhesive for bonding label stock to plastic film, metal foil and the like |
| JPS62164777A (ja) * | 1986-01-14 | 1987-07-21 | Mitsubishi Paper Mills Ltd | 感熱性粘着組成物 |
| US5252393A (en) * | 1987-06-25 | 1993-10-12 | Mitsubishi Paper Mills Ltd. | Thermal delayed-tack adhesive compositions and thermal delayed-tack adhesive sheets |
| JPH01193381A (ja) * | 1988-01-27 | 1989-08-03 | Mitsubishi Paper Mills Ltd | 感熱性粘着組成物および感熱性粘着シート |
| JPH0657223A (ja) * | 1992-08-07 | 1994-03-01 | Toyo Ink Mfg Co Ltd | 感熱性ディレードタック型粘着剤 |
| JPH06100848A (ja) * | 1992-08-07 | 1994-04-12 | Toyo Ink Mfg Co Ltd | 感熱性ディレードタック型粘着剤および感熱性粘着シート |
| JPH06313163A (ja) * | 1993-03-05 | 1994-11-08 | Toppan Printing Co Ltd | 感熱性粘着組成物及び感熱性粘着シート |
| JPH0711229A (ja) * | 1993-06-25 | 1995-01-13 | Toyo Ink Mfg Co Ltd | 感熱性粘着剤および感熱性粘着シート |
| JPH07109444A (ja) * | 1993-10-15 | 1995-04-25 | Toyo Ink Mfg Co Ltd | 高速ラベラー用感熱性粘着シート |
| JPH08207426A (ja) * | 1995-01-31 | 1996-08-13 | Kimoto & Co Ltd | インクジェット記録用シート |
| JPH08231929A (ja) * | 1995-02-28 | 1996-09-10 | Toppan Printing Co Ltd | 粘着シート及びその剥離方法 |
Non-Patent Citations (9)
| Title |
|---|
| DATABASE WPI Section Ch Week 198734, Derwent World Patents Index; Class A81, AN 1987-240165, XP002140451 * |
| DATABASE WPI Section Ch Week 198937, Derwent World Patents Index; Class A18, AN 1989-266930, XP002140452 * |
| DATABASE WPI Section Ch Week 199413, Derwent World Patents Index; Class A81, AN 1994-107039, XP002140458 * |
| DATABASE WPI Section Ch Week 199419, Derwent World Patents Index; Class A81, AN 1994-156854, XP002140457 * |
| DATABASE WPI Section Ch Week 199504, Derwent World Patents Index; Class A14, AN 1995-027817, XP002140456 * |
| DATABASE WPI Section Ch Week 199512, Derwent World Patents Index; Class A18, AN 1995-085674, XP002140459 * |
| DATABASE WPI Section Ch Week 199525, Derwent World Patents Index; Class A18, AN 1995-190932, XP002140455 * |
| DATABASE WPI Section Ch Week 199642, Derwent World Patents Index; Class A97, AN 1996-421053, XP002140454 * |
| DATABASE WPI Section Ch Week 199646, Derwent World Patents Index; Class A94, AN 1996-461559, XP002140453 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1205809A3 (fr) * | 2000-11-13 | 2004-01-07 | Hewlett-Packard Company | Surcouche protectrice pour des images obtenues par jet d'encre, transfert thermique ou xérographie, et dispositifs pour l'application de la couche |
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