EP1910090A2 - Abkratzbarer bedruckter textilträger und aus dem träger bestehendes kleidungsstück - Google Patents

Abkratzbarer bedruckter textilträger und aus dem träger bestehendes kleidungsstück

Info

Publication number
EP1910090A2
EP1910090A2 EP06794462A EP06794462A EP1910090A2 EP 1910090 A2 EP1910090 A2 EP 1910090A2 EP 06794462 A EP06794462 A EP 06794462A EP 06794462 A EP06794462 A EP 06794462A EP 1910090 A2 EP1910090 A2 EP 1910090A2
Authority
EP
European Patent Office
Prior art keywords
ink
support
printed
scratchable
textile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP06794462A
Other languages
English (en)
French (fr)
Inventor
Philippe Alzina
Guillaume Abou
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of EP1910090A2 publication Critical patent/EP1910090A2/de
Withdrawn legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/5214Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
    • D06P1/5228Polyalkenyl alcohols, e.g. PVA
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/004Dyeing with phototropic dyes; Obtaining camouflage effects
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/5214Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
    • D06P1/5235Polyalkenyl halides, e.g. PVC
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5264Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D06P1/5285Polyurethanes; Polyurea; Polyguanides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/001Special chemical aspects of printing textile materials
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/13Fugitive dyeing or stripping dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/13Fugitive dyeing or stripping dyes
    • D06P5/138Fugitive dyeing or stripping dyes fugitive dyeing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06QDECORATING TEXTILES
    • D06Q1/00Decorating textiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41PINDEXING SCHEME RELATING TO PRINTING, LINING MACHINES, TYPEWRITERS, AND TO STAMPS
    • B41P2200/00Printing processes
    • B41P2200/40Screen printing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/2481Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including layer of mechanically interengaged strands, strand-portions or strand-like strips

Definitions

  • the invention relates to a printed textile support, used in particular in the fields of communication, promotion on the one hand, fashion and sportswear on the other hand. More specifically, it relates to a printed textile support, on which is applied an ink which, after scratching, reveals the original impression. It also relates to a scratchable ink intended to be applied on a printed textile support.
  • the Applicant had the idea of making these printed textile supports scratch-resistant, so as to make them completely new products for an evolving market.
  • the printed textile support is a T-shirt, a sweatshirt, a polo shirt, a shirt, a sweater, an undergarment, and more broadly, any textile textile support likely to be printed.
  • the document US2002 / 0029713 describes a process for printing transferable scratch-off ink, business card in particular and more generally paper. It is incidentally referred to the possibility of using as a support, a woven or a nonwoven. No application example is given.
  • the transfer is a technique in which a layer of ink is printed on a film, then a layer of glue, then the film is returned and it is applied to the support to be printed.
  • the support is a textile support and the ink is a scratch-off ink
  • the final product can be expected to be unsatisfactory in two essential respects. The first is that scratching is not optimal since some of the ink may remain trapped in the glue. In addition, a certain proportion of glue should remain on the textile surface, even after washing. In other words, the textile supports thus obtained can not be applied to clothing.
  • the problem to be solved by the invention is to provide a woven or knitted fabric which does not have the disadvantages mentioned above and which consequently can be applied to clothing.
  • the subject of the invention is a printed woven or knitted textile support covered on all or part of the printed area with a scratch-off ink, said support being characterized in that the scratch-off ink is applied directly to all or part of the printed area, advantageously over the entire printed area.
  • Textile printing and paper printing can be carried out by similar techniques but with radically different inks, this being due to the nature of the medium.
  • the support of the invention is printed with a water or solvent ink.
  • the support of the invention is printed with a plastisol ink.
  • this plastisol ink is applied by screen printing.
  • plastisol inks ie inks containing PVC dispersed in one or more plasticizers, to which pigments are added.
  • PVC and plasticizers make it possible to fix the ink on the textile material.
  • these inks have the advantage of being resistant in time, both in terms of color and in terms of appearance.
  • the plastisol ink printed on a textile is not damaged by the passage through a washing machine.
  • the opacity of this ink makes it possible to print on dark substrates.
  • plastisols are inks easy to apply by screen printing. That's why nearly 80% of the consumer textile market, including T-shirts, uses plastisol inks.
  • the plastisols printed on the T-shirts must remain intact for obvious reasons of aesthetics, it that is to say without alterations after scraping by the nail of the scratchable ink.
  • plastisol inks are fragile and rough.
  • the scratchable ink is applied directly to all or part of the printed area and advantageously contains one or more water-soluble binders, pigments and mineral fillers.
  • This type of formulation makes it possible to have a sufficiently soft ink (presence of water-soluble binder) and sufficiently friable (presence of filler) to ensure effective scraping and to obtain a perfectly clean textile after washing.
  • the scrapable ink contains: between 40 and 70% by weight of water-soluble binder, between 5 and 10% by weight of pigments, between 20 and 30% by weight of mineral filler.
  • the water-soluble binder is chosen from the group comprising polyvinyl alcohol and polyquaternium.
  • the mineral filler is preferably calcium carbonate.
  • the ink further contains between 5 and 25% by weight of an aqueous acrylic-polyurethane dispersion.
  • the invention also relates to an article of clothing such as, for example, a t-shirt, sweatshirt, polo shirt, sweater, undergarment consisting of a woven or printed textile support covered on all or part of the printed area of a scratch-off ink.
  • the scratchable ink is applied directly, preferably by screen printing.
  • the invention also relates to the scratchable ink described above intended to be applied to a woven or knitted fabric.
  • It also relates to a method of manufacturing a scratch-resistant printed textile according to which: all or part of a textile is printed using an aqueous or solvent ink, or advantageously a plastisol ink, it is applied directly to all or part of said ink, a scratchable ink.
  • Figure 1 is a photograph of a medium printed with plastisol ink and covered with a scratch-off ink for paper.
  • Figure 2 is a photograph of the support of Figure 1 covered with a scratchable ink of the invention.
  • Example 1
  • An ink having the following composition (by weight) is prepared: polyvinyl alcohol aqueous dispersion: 50% acrylic polyurethane aqueous dispersion: 10% aqueous pigment dispersion: 8% surfactant: 3% calcium carbonate: 29%
  • This ink is applied to a T-shirt previously printed with plastisol ink.
  • the application of the scratchable ink is performed by screen printing. After scraping, the plastisol ink remains intact.
  • Figures 1 and 2 are photographs of T-shirts printed with plastisol ink.
  • the plastisol of Figure 1 is itself covered with a scratch-resistant paper ink.
  • the ink is integral with the printed medium and does not come off, even with a strong scraping action.
  • the ink of the invention (FIG. 2) is scratched off without damaging the support printed below.
  • the scratchable ink contains: - between 40 and 70% by weight of water-soluble binder, between 5 and 10% by weight of pigments,
  • the inorganic filler is calcium carbonate.
  • the ink further contains between 5 and 25% by weight of an aqueous acrylic-polyurethane dispersion.
  • Articles of apparel such as, for example, t-shirts, sweatshirts, polo shirts, shirts, sweaters, undergarments consisting of a woven or knitted textile backing covered over all or part of the printed area of a scratch-off ink .

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Details Of Garments (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
EP06794462A 2005-05-26 2006-05-26 Abkratzbarer bedruckter textilträger und aus dem träger bestehendes kleidungsstück Withdrawn EP1910090A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0551381A FR2886210B1 (fr) 2005-05-26 2005-05-26 Support textile imprime grattable
PCT/FR2006/050483 WO2006129037A2 (fr) 2005-05-26 2006-05-26 Support textile imprime grattable et article d'habillement constitue dudit support

Publications (1)

Publication Number Publication Date
EP1910090A2 true EP1910090A2 (de) 2008-04-16

Family

ID=36088291

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06794462A Withdrawn EP1910090A2 (de) 2005-05-26 2006-05-26 Abkratzbarer bedruckter textilträger und aus dem träger bestehendes kleidungsstück

Country Status (4)

Country Link
US (1) US20090100564A1 (de)
EP (1) EP1910090A2 (de)
FR (1) FR2886210B1 (de)
WO (1) WO2006129037A2 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8037545B2 (en) * 2007-03-16 2011-10-18 Branders.Com, Inc. Article and method including a temporary decoration
CN102719140B (zh) * 2012-06-12 2013-10-16 中山市中益油墨涂料有限公司 用于水性防伪油墨的调墨油及用其制备的水性防伪油墨

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE756694A (fr) * 1969-09-26 1971-03-25 Trentesaux Toulemonde Sa Supports provisoires utilisables en impression
FR2595987B1 (fr) * 1986-03-20 1990-12-21 Hautes Vosges Impressions Procede d'encrage pour caches grattables
US5972088A (en) * 1996-03-13 1999-10-26 Sun Chemical Corporation Water-based gravure printing ink
JP2001081382A (ja) * 1999-09-17 2001-03-27 Sakura Color Prod Corp スクラッチインキ組成物及びそれを用いた筆記具
US20020028321A1 (en) * 2000-05-11 2002-03-07 Feilen Michael A. Method of printing scratch-off material and resulting product
DE20009870U1 (de) * 2000-06-05 2001-01-11 Lerch, Christoph, Wien Flächestabiles textiles Bahnenmaterial insbesondere zur Vorlage an Ink-Jet-Druckverfahren
US6939627B2 (en) * 2000-07-13 2005-09-06 Dai Nippon Printing Co., Ltd. Scratch layer transfer sheet and method of producing scratch printing product

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2006129037A3 *

Also Published As

Publication number Publication date
WO2006129037A3 (fr) 2007-04-12
FR2886210B1 (fr) 2008-11-28
US20090100564A1 (en) 2009-04-23
FR2886210A1 (fr) 2006-12-01
WO2006129037A2 (fr) 2006-12-07

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