ES2001647A6 - Un generador de hidrogeno catalitico para uso con mezclas de metanol y oxigeno - Google Patents
Un generador de hidrogeno catalitico para uso con mezclas de metanol y oxigenoInfo
- Publication number
- ES2001647A6 ES2001647A6 ES8601598A ES8601598A ES2001647A6 ES 2001647 A6 ES2001647 A6 ES 2001647A6 ES 8601598 A ES8601598 A ES 8601598A ES 8601598 A ES8601598 A ES 8601598A ES 2001647 A6 ES2001647 A6 ES 2001647A6
- Authority
- ES
- Spain
- Prior art keywords
- methanol
- zone
- copper catalyst
- supported
- hydrogen generator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
UN GENERADOR DE HIDROGENO CATALITICO QUE GENERA HIDROGENO POR OXIDACION PARCIAL DEL METANOL POR OXIGENO (HABITUALMENTE SUMINISTRADO COMO AIRE) QUE COMPRENDE UN SISTEMA CATALIZADOR PERMEABLE A LOS GASES QUE TIENE UNA ZONA CORRIENTE ARRIBA (2) RELLENA CON UN CATALIZADOR DE COBRE SOPORTADO SOBRE UN SOPORTE REFRACTARIO (3) (POR EJEMPLO SILICE O SILICATO EN FORMA DE GRANULOS) Y UNA ZONA CORRIENTE ABAJO (4) RELLENA CON UNA MEZCLA DE UN CATALIZADOR DE COBRE SOBRE UN SOPORTE SIMILAR Y UN CATALIZADOR DE PLATINO O PALADIO SOPORTADO SOBRE UN SOPORTE REFRACTARIO SIMILAR (5B). SE CARGA UNA MEZCLA DE METANOL Y OXIGENO EN LA ZONA CORRIENTE ARRIBA Y PENETRA INICIALMENTE A TRAVES DE LA ZONA CORRIENTE ABAJO DONDE SE INICIA LA OXIDACION ESPONTANEA DEL METANOL ELEVANDOSE LA TEMPERATURA DEL SISTEMA A UN NIVEL AL QUE COMIENZA LA OXIDACION PARCIAL DE METANOL EN PRESENCIA DEL CATALIZADOR DE COBRE EN LA ZONA CORRIENTE ARRIBA (2), Y SE PRODUCE HIDROGENO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB858521953A GB8521953D0 (en) | 1985-09-04 | 1985-09-04 | Catalytic hydrogen generator |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2001647A6 true ES2001647A6 (es) | 1988-06-01 |
Family
ID=10584701
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES8601598A Expired ES2001647A6 (es) | 1985-09-04 | 1986-09-03 | Un generador de hidrogeno catalitico para uso con mezclas de metanol y oxigeno |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4789540A (es) |
| EP (1) | EP0217532B1 (es) |
| JP (1) | JPH0798641B2 (es) |
| AT (1) | ATE47705T1 (es) |
| AU (1) | AU580443B2 (es) |
| CA (1) | CA1290548C (es) |
| DE (1) | DE3666689D1 (es) |
| ES (1) | ES2001647A6 (es) |
| GB (1) | GB8521953D0 (es) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4946667A (en) * | 1985-06-10 | 1990-08-07 | Engelhard Corporation | Method of steam reforming methanol to hydrogen |
| FR2608144B1 (fr) * | 1986-12-16 | 1989-03-24 | Inst Francais Du Petrole | Procede de production d'hydrogene par reformage catalytique du methanol a la vapeur d'eau |
| JP2755804B2 (ja) * | 1990-08-27 | 1998-05-25 | 株式会社東芝 | 水素製造方法 |
| US5209906A (en) * | 1991-05-10 | 1993-05-11 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of National Defence | Modular isothermal reactor |
| US5271916A (en) * | 1991-07-08 | 1993-12-21 | General Motors Corporation | Device for staged carbon monoxide oxidation |
| US5316747A (en) * | 1992-10-09 | 1994-05-31 | Ballard Power Systems Inc. | Method and apparatus for the selective oxidation of carbon monoxide in a hydrogen-containing gas mixture |
| GB9412786D0 (en) * | 1994-06-24 | 1994-08-17 | Johnson Matthey Plc | Improved reformer |
| DE4423587C2 (de) * | 1994-07-06 | 1996-09-05 | Daimler Benz Ag | Vorrichtung zur Wasserstoffgewinnung mittels partieller Oxidation und/oder Wasserdampfreformierung von Methanol |
| WO1996026892A1 (fr) * | 1995-02-27 | 1996-09-06 | Aisin Seiki Kabushiki Kaisha | Generateur d'hydrogene |
| US5939025A (en) * | 1995-08-23 | 1999-08-17 | The University Of Chicago | Methanol partial oxidation reformer |
| US6245303B1 (en) | 1998-01-14 | 2001-06-12 | Arthur D. Little, Inc. | Reactor for producing hydrogen from hydrocarbon fuels |
| US6126908A (en) * | 1996-08-26 | 2000-10-03 | Arthur D. Little, Inc. | Method and apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide |
| US7066973B1 (en) | 1996-08-26 | 2006-06-27 | Nuvera Fuel Cells | Integrated reformer and shift reactor |
| DE19727841A1 (de) * | 1997-06-24 | 1999-01-07 | Fraunhofer Ges Forschung | Verfahren und Vorrichtung zur autothermen Reformierung von Kohlenwasserstoffen |
| DE19743673C2 (de) | 1997-10-02 | 2002-05-08 | Xcellsis Gmbh | Vorrichtung zur Wasserstofferzeugung aus Kohlenwasserstoffen und Verfahren zur Herstellung eines Katalysators |
| DE19755814C1 (de) * | 1997-12-16 | 1999-11-18 | Dbb Fuel Cell Engines Gmbh | Verfahren zum Betrieb einer Anlage zur Wasserdampfreformierung eines Kohlenwasserstoffs |
| GB9806198D0 (en) | 1998-03-24 | 1998-05-20 | Johnson Matthey Plc | Ctalytic generation of hydrogen |
| GB9806199D0 (en) | 1998-03-24 | 1998-05-20 | Johnson Matthey Plc | Catalytic generation of hydrogen |
| DE19822691A1 (de) | 1998-05-20 | 1999-11-25 | Volkswagen Ag | Brennstoffzellensystem und Verfahren zum Erzeugen elektrischer Energie mittels eines Brennstoffzellensystems |
| DE19822689A1 (de) | 1998-05-20 | 1999-11-25 | Volkswagen Ag | Brennstoffzellensystem und Verfahren zum Erzeugen elektrischer Energie mittels eines Brennstoffzellensystems |
| DE19827879C1 (de) * | 1998-06-23 | 2000-04-13 | Dbb Fuel Cell Engines Gmbh | Wasserdampfreformierungsreaktor, insbesondere mit autothermer Prozeßführung |
| ES2359884T3 (es) | 1998-07-08 | 2011-05-27 | Toyota Jidosha Kabushiki Kaisha | Aparato para la reforma de combustibles. |
| DE19836289A1 (de) * | 1998-08-11 | 2000-02-17 | Opel Adam Ag | Reformer |
| DE19847987C2 (de) * | 1998-10-17 | 2001-06-13 | Xcellsis Gmbh | Verfahren zur Herstellung einer Vorrichtung zur Wasserstofferzeugung und Vorrichtung zur Wasserstofferzeugung |
| US6986797B1 (en) | 1999-05-03 | 2006-01-17 | Nuvera Fuel Cells Inc. | Auxiliary reactor for a hydrocarbon reforming system |
| US6641625B1 (en) | 1999-05-03 | 2003-11-04 | Nuvera Fuel Cells, Inc. | Integrated hydrocarbon reforming system and controls |
| US6746650B1 (en) * | 1999-06-14 | 2004-06-08 | Utc Fuel Cells, Llc | Compact, light weight methanol fuel gas autothermal reformer assembly |
| DE19928100A1 (de) * | 1999-06-19 | 2001-01-11 | Daimler Chrysler Ag | Verfahren zur Bestimmung des Zustandes von Katalysatoren |
| DE60028391T2 (de) | 1999-08-31 | 2007-05-10 | Shell Internationale Research Maatschappij B.V. | Katalytisches oxidationsverfahren mit durchflussregelsystem |
| DE19944185A1 (de) | 1999-09-15 | 2001-03-29 | Xcellsis Gmbh | Vorrichtung zur Durchführung einer heterogen katalysierten Reaktion und Verfahren zu deren Herstellung |
| DE19947312A1 (de) * | 1999-10-01 | 2001-04-05 | Volkswagen Ag | Kraftstoffreformer und Verfahren zum Reformieren |
| DE10023409A1 (de) * | 2000-05-12 | 2001-11-15 | Linde Gas Ag | Gasgenerator und Verfahren zur Erzeugung eines CO- und H2-haltigen Behandlungsgases für die Wärmebehandlung von metallischem Gut sowie Wärmebehandlungsanlage mit einem Gasgenerator |
| JP3646625B2 (ja) * | 2000-06-01 | 2005-05-11 | 日産自動車株式会社 | 燃料改質装置 |
| PT1298089E (pt) * | 2000-06-22 | 2005-04-29 | Consejo Superior Investigacion | Metodo para obtencao de hidrogenio por oxidacao parcial de metanol |
| DE10046692C2 (de) | 2000-09-21 | 2003-09-18 | Ballard Power Systems | Vorrichtung zur Verdampfung einer Flüssigkeit |
| DE10064441A1 (de) * | 2000-12-22 | 2002-06-27 | Volkswagen Ag | Verfahren zur Betriebstemperatureinstellung in einem Reformer |
| US20020108307A1 (en) * | 2001-02-12 | 2002-08-15 | Gene Lightner | Hydrogen devoid of carbon monoxide from a reformer |
| JP2006502938A (ja) | 2002-06-13 | 2006-01-26 | ヌヴェラ フューエル セルズ インコーポレイテッド | 優先的酸化反応装置の温度調整 |
| US20040171900A1 (en) * | 2003-02-28 | 2004-09-02 | Conocophillips Company | Method and device for reactions start-up |
| JP4709507B2 (ja) * | 2003-07-14 | 2011-06-22 | 株式会社ケー・イー・エム | 改質器 |
| US8529864B2 (en) | 2008-09-26 | 2013-09-10 | National Tsing Hua University | Process for hydrogen production |
| TWI381992B (zh) * | 2008-09-26 | 2013-01-11 | Nat Univ Tsing Hua | 反應器室溫啟動的低溫氫氣製程 |
| EP2228340B1 (en) * | 2009-02-25 | 2012-05-30 | K.M.W.E. Management B.V. | Process for producing hydrogen from methanol |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3179500A (en) * | 1961-04-24 | 1965-04-20 | Thompson Ramo Wooldridge Inc | Hydrogen generation and purification system |
| GB1010574A (en) * | 1963-04-23 | 1965-11-17 | British Petroleum Co | Production of hydrogen-containing gases |
| FR1549201A (es) * | 1967-03-21 | 1968-12-13 | ||
| US3469944A (en) * | 1968-05-13 | 1969-09-30 | Joseph P Bocard | Process and apparatus for the manufacture of hydrogen for fuel cells |
| US3874116A (en) * | 1970-05-20 | 1975-04-01 | Chevron Res | Synthesis gas manufacture |
| DE2224223C3 (de) * | 1972-05-18 | 1975-10-23 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von rußfreien oder rußarmen Verbrennungsgasen |
| JPS5227085A (en) * | 1975-08-27 | 1977-03-01 | Nippon Soken Inc | Catalyst for reforming of hydrocarbon fuel |
| JPS5231995A (en) * | 1975-09-08 | 1977-03-10 | Nissan Motor Co Ltd | Gas generator |
| US4091086A (en) * | 1976-12-20 | 1978-05-23 | Engelhard Minerals & Chemicals Corporation | Process for production of hydrogen |
| GB1577069A (en) * | 1977-07-27 | 1980-10-15 | British Petroleum Co | Process for the production of synthesis gas by the catalysed decomposition of methanol |
| DE2950251A1 (de) * | 1979-12-13 | 1981-06-19 | Kraftwerk Union AG, 4330 Mülheim | Verfahren zur umwandlung von waermeenergie in chemisch gebundene energie |
| NZ196836A (en) * | 1980-04-23 | 1983-06-17 | British Petroleum Co | Production of synthesis gas from methanol |
| BE884720A (fr) * | 1980-08-11 | 1981-02-11 | Catalysts & Chem Europ | Procede de reformage de methanol et dispositif mis en oeuvre |
| JPS58181702A (ja) * | 1982-04-12 | 1983-10-24 | Matsushita Electric Ind Co Ltd | 炭化水素燃料改質装置 |
| US4444158A (en) * | 1982-09-03 | 1984-04-24 | Conoco Inc. | Alcohol dissociation process for automobiles |
| NO171409C (no) * | 1982-09-30 | 1993-03-10 | Engelhard Corp | Fremgangsmaate ved fremstilling av en hydrogenrik gass vedautotermisk reformering av et hydrokarbonholdig utgangsmateriale |
| JPS5987045A (ja) * | 1982-11-08 | 1984-05-19 | Nissan Motor Co Ltd | メタノ−ル改質用触媒 |
| JPS59199042A (ja) * | 1983-04-28 | 1984-11-12 | Nissan Motor Co Ltd | メタノ−ル改質用触媒 |
| SU1144977A1 (ru) * | 1983-06-07 | 1985-03-15 | Ворошиловградский машиностроительный институт | Способ получени водородсодержащего газа |
| US4595024A (en) * | 1984-08-31 | 1986-06-17 | R. J. Reynolds Tobacco Company | Segmented cigarette |
| US4676972A (en) * | 1985-07-29 | 1987-06-30 | The Standard Oil Company | Process for the conversion of alcohols to gaseous products |
-
1985
- 1985-09-04 GB GB858521953A patent/GB8521953D0/en active Pending
-
1986
- 1986-08-21 EP EP19860306500 patent/EP0217532B1/en not_active Expired
- 1986-08-21 DE DE8686306500T patent/DE3666689D1/de not_active Expired
- 1986-08-21 AT AT86306500T patent/ATE47705T1/de not_active IP Right Cessation
- 1986-09-02 AU AU62156/86A patent/AU580443B2/en not_active Ceased
- 1986-09-03 ES ES8601598A patent/ES2001647A6/es not_active Expired
- 1986-09-03 JP JP61208811A patent/JPH0798641B2/ja not_active Expired - Fee Related
- 1986-09-04 CA CA000517479A patent/CA1290548C/en not_active Expired - Lifetime
- 1986-09-04 US US06/903,644 patent/US4789540A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ATE47705T1 (de) | 1989-11-15 |
| GB8521953D0 (en) | 1985-10-09 |
| US4789540A (en) | 1988-12-06 |
| DE3666689D1 (en) | 1989-12-07 |
| CA1290548C (en) | 1991-10-15 |
| EP0217532B1 (en) | 1989-11-02 |
| AU580443B2 (en) | 1989-01-12 |
| AU6215686A (en) | 1987-03-05 |
| JPS6259501A (ja) | 1987-03-16 |
| JPH0798641B2 (ja) | 1995-10-25 |
| EP0217532A1 (en) | 1987-04-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| SA6 | Expiration date (snapshot 920101) |
Free format text: 2006-09-03 |
|
| FD1A | Patent lapsed |
Effective date: 20030904 |