ES2002048A6 - Un procedimiento y un sistema catalizador para la polimerizacion en masa de diciclopentadieno. - Google Patents

Un procedimiento y un sistema catalizador para la polimerizacion en masa de diciclopentadieno.

Info

Publication number
ES2002048A6
ES2002048A6 ES8602765A ES8602765A ES2002048A6 ES 2002048 A6 ES2002048 A6 ES 2002048A6 ES 8602765 A ES8602765 A ES 8602765A ES 8602765 A ES8602765 A ES 8602765A ES 2002048 A6 ES2002048 A6 ES 2002048A6
Authority
ES
Spain
Prior art keywords
diciclopentadiene
procedure
catalyst system
mass polymerization
alkyl group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES8602765A
Other languages
English (en)
Inventor
Willem Sjardijn
Arris Herman Kramer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Publication of ES2002048A6 publication Critical patent/ES2002048A6/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Polymerization Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

UN PROCEDIMIENTO Y UN SISTEMA CATALIZADOR PARA LA POLIMERIZACION EN MASA DE DICICLOPENTADIENO, EN DONDE SE PONE EN CONTACTO DICICLOPENTADIENO CON UN CATALIZADOR QUE COMPRENDE A) UN COMPUESTO DE WOLFRAMIO DE FORMULA EN QUE R REPRESENTA UN GRUPO ALQUILO VOLUMINOSO QUE TIENE AL MENOS 3 ATOMOS DE CARBONO, O UN ATOMO DE HIDROGENO, CON LA CONDICION DE QUE AL MENOS UN R REPRESENTA UN GRUPO ALQUILO VOLUMINOSO, R1 ES UN ATOMO DE HIDROGENO O UN GRUPO ALQUILO DE 1 A 10 ATOMOS DE CARBONO, (MBN) SON 6 Y N ES 1 O 2, Y B) UN COMPUESTO DE ESTAÑO DE FORMULA EN QUE R2 ES UN GRUPO ALQUILO DE 1 A 10 ATOMOS DE CARBONO O UN GRUPO FENILO.
ES8602765A 1985-10-28 1986-10-27 Un procedimiento y un sistema catalizador para la polimerizacion en masa de diciclopentadieno. Expired ES2002048A6 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB858526539A GB8526539D0 (en) 1985-10-28 1985-10-28 Bulk polymerization of dicyclopentadiene

Publications (1)

Publication Number Publication Date
ES2002048A6 true ES2002048A6 (es) 1988-07-01

Family

ID=10587358

Family Applications (1)

Application Number Title Priority Date Filing Date
ES8602765A Expired ES2002048A6 (es) 1985-10-28 1986-10-27 Un procedimiento y un sistema catalizador para la polimerizacion en masa de diciclopentadieno.

Country Status (9)

Country Link
US (2) US4729976A (es)
EP (1) EP0222432B1 (es)
JP (1) JPH0692459B2 (es)
BR (1) BR8605207A (es)
CA (1) CA1276136C (es)
DE (1) DE3676052D1 (es)
ES (1) ES2002048A6 (es)
GB (1) GB8526539D0 (es)
MX (1) MX163269B (es)

Families Citing this family (36)

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USRE35717E (en) * 1986-04-11 1998-01-20 Metton America, Inc. Cycloolefin copolymerization method, feed composition and product
FR2603041B1 (fr) * 1986-08-22 1988-12-02 Elf Aquitaine Polymerisation d'hydrocarbures insatures avec une periode d'induction
CA1335374C (en) * 1988-03-30 1995-04-25 Willem Sjardijn Polymerization of norbornene derivatives and catalytic system suitable for use therein
GB8822911D0 (en) * 1988-09-29 1988-11-02 Shell Int Research Polymerization of norbornene derivatives & catalytic system suitable for use therein
AU613168B2 (en) * 1988-03-30 1991-07-25 Shell Internationale Research Maatschappij B.V. Polymerization of norbornene derivatives and catalytic system suitable for use therein
US5248745A (en) * 1988-11-22 1993-09-28 Shell Oil Company Copolymerization of dicyclopentadiene with norbornene derivatives
GB8827320D0 (en) * 1988-11-23 1988-12-29 Shell Int Research Process for polymerization of structurally different monomers
US5369195A (en) * 1988-11-30 1994-11-29 Shell Oil Company Polymerization of cyclic olefins
KR900007878A (ko) * 1988-11-30 1990-06-02 오노 알버어스 촉매 조성물, 그를 사용한 시클릭 올레핀의 금형내의 중합방법 및 그로부터 제조된 중합체
US5254629A (en) * 1988-11-30 1993-10-19 Shell Oil Company Polymerization of cyclic olefins
US4981931A (en) * 1989-02-24 1991-01-01 Hercules Incoporated Discrete tungsten complexes as oxygen and water resistant DCPD polymerization catalysts
US5019544A (en) * 1989-02-24 1991-05-28 Hercules Incorporated Discrete tungsten complexes as oxygen and water resistant DCPD polymerization catalysts
GB8904575D0 (en) * 1989-02-28 1989-04-12 Shell Int Research Polymerization of bulky norbornene derivatives and polymers obtainable therewith
US5071812A (en) * 1989-03-31 1991-12-10 Shell Oil Company Polymerization of cyclic olefins
US5147950A (en) * 1989-03-31 1992-09-15 Shell Oil Company In-mold polmerization of cyclic olefins with borohydride cocatalyst
US5142006A (en) * 1990-01-29 1992-08-25 Shell Oil Company Polymerization of cyclic olefins
US5075272A (en) * 1990-10-12 1991-12-24 Hercules Incorporated Mixed activators for stabilized metathesis catalysts
US5082909A (en) * 1990-10-12 1992-01-21 Hercules Incorporated Pure tungsten oxyphenolate complexes as DCPD polymerization catalysts
US5120806A (en) * 1990-10-12 1992-06-09 Hercules Incorporated Mixed activators for stabilized metathesis catalysts
US5143992A (en) * 1991-07-12 1992-09-01 Shell Oil Company Methathesis polymerizable adducts of a divinylcyclohydrocarbon and cyclopentadiene
GB9117744D0 (en) * 1991-08-16 1991-10-02 Shell Int Research Polymerization of cycloolefins and catalytic system suitable for use therein
US5218065A (en) * 1991-08-30 1993-06-08 Shell Oil Company Polymerization process
US5198511A (en) * 1991-12-20 1993-03-30 Minnesota Mining And Manufacturing Company Polymerizable compositions containing olefin metathesis catalysts and cocatalysts, and methods of use therefor
US5276119A (en) * 1992-12-29 1994-01-04 Shell Oil Company Transition metal hydrides as co-catalysts for olefin polymerization
US5312794A (en) * 1992-12-29 1994-05-17 Shell Oil Company Catalyst system for olefin polymerization
US5276118A (en) * 1992-12-31 1994-01-04 Shell Oil Company Diaryl carbinol metathesis catalysts for ring-opening polymerization of cyclic olefins
US5278305A (en) * 1992-12-31 1994-01-11 Shell Oil Company Catalysts for ring-opening, metathesis polymerization of cyclic olefins
US5316994A (en) * 1992-12-31 1994-05-31 Shell Oil Company Copper hydrides as co-catalysts for olefin polymerization
US5405924A (en) * 1993-07-22 1995-04-11 Shell Oil Company Imido transition metal complex metathesis catalysts
US6235856B1 (en) * 1994-12-23 2001-05-22 Ciba Specialty Chemicals Corporation Polymerization of dicyclopentadiene
TW350851B (en) * 1995-01-31 1999-01-21 Ciba Sc Holding Ag Polymerizable composition and process for the preparation of network polymer
US7468417B2 (en) * 2005-08-26 2008-12-23 Korea Kumho Petrochemical Co., Ltd. Method of preparing cyclic olefin copolymer having controlled gel contents
US8981012B2 (en) * 2008-07-09 2015-03-17 University Of Iowa Research Foundation Modified polydicyclopentadienes
CN101659678B (zh) * 2009-09-27 2013-04-10 河南科技大学 一种有机膦基钨络合物及其制备方法及其应用
US8778186B2 (en) 2011-07-11 2014-07-15 University Of Iowa Research Foundation High-density polydicyclopentadiene
CN113024614B (zh) * 2021-03-08 2021-11-02 大成普瑞新材料有限责任公司 一种用于聚双环戊二烯复合材料注射成型的有机钨催化剂的制备方法

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US3026269A (en) * 1958-09-11 1962-03-20 Du Pont Polymerization catalyst
DE1195497B (de) * 1963-02-01 1965-06-24 Basf Ag Verfahren zur Herstellung von Homo- oder Copolymeren von olefinisch ungesaettigten cyclischen Kohlenwasserstoffen
FR1382569A (fr) * 1963-02-14 1964-12-18 Kurashiki Rayon Co Polymérisation de l'éthylène
BE747316A (fr) * 1969-03-14 1970-08-17 Sumitomo Chemical Co Procede de production de composes epoxydes
US3627739A (en) * 1970-08-13 1971-12-14 Shell Oil Co Polycyclodelfin polymerization process and products
NL7014132A (en) * 1970-09-24 1972-03-28 Cycloalkene polymn catalyst - contg aluminium and tungsten compounds
DE2106302C3 (de) * 1971-02-10 1979-06-07 Bayer Ag, 5090 Leverkusen Verfahren zur Polymerisation von acyclischen Verbindungen
NL7205003A (es) * 1972-04-14 1973-10-16
NL7317783A (es) * 1972-12-29 1974-07-02
JPS5594928A (en) * 1979-01-12 1980-07-18 Sumitomo Chem Co Ltd Preparation of dicyclopentadiene opened ring polymer and copolymer
EP0084888B2 (en) * 1982-01-25 1995-10-25 Hercules Incorporated A dicyclopentadiene thermoset polymer and a catalyst and a method for making it
US4507453A (en) * 1982-01-25 1985-03-26 Hercules Incorporated Dicyclopentadiene thermoset polymer
EP0129474B1 (fr) * 1983-06-15 1986-04-23 Societe Nationale Elf Aquitaine Catalyseur perfectionné pour la métathèse d'oléfines
US4604447A (en) * 1983-11-22 1986-08-05 Hercules Incorporated Halogen-free, high flash point reactant solution

Also Published As

Publication number Publication date
JPS62106907A (ja) 1987-05-18
CA1276136C (en) 1990-11-13
GB8526539D0 (en) 1985-12-04
BR8605207A (pt) 1987-07-28
JPH0692459B2 (ja) 1994-11-16
MX163269B (es) 1992-03-31
EP0222432A1 (en) 1987-05-20
DE3676052D1 (de) 1991-01-17
US4810762A (en) 1989-03-07
EP0222432B1 (en) 1990-12-05
US4729976A (en) 1988-03-08

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Legal Events

Date Code Title Description
SA6 Expiration date (snapshot 920101)

Free format text: 2006-10-27

FD1A Patent lapsed

Effective date: 20010201