ES2080247T3 - Catalizadores solidos de polimerizacion de olefinas y procedimientos para la polimerizacion de olefinas. - Google Patents
Catalizadores solidos de polimerizacion de olefinas y procedimientos para la polimerizacion de olefinas.Info
- Publication number
- ES2080247T3 ES2080247T3 ES91301168T ES91301168T ES2080247T3 ES 2080247 T3 ES2080247 T3 ES 2080247T3 ES 91301168 T ES91301168 T ES 91301168T ES 91301168 T ES91301168 T ES 91301168T ES 2080247 T3 ES2080247 T3 ES 2080247T3
- Authority
- ES
- Spain
- Prior art keywords
- polymerization
- procedures
- solid
- olephine
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
LA PRESENTE INVENCION SUMINISTRA UN CATALIZADOR SOLIDO PARA LA POLIMERIZACION DE LA OLEFINA PREPARADO POR LA PRE-POLIMERIZACION DE LA OLEFINA EN UNA SUSPENSION QUE CONTENGA A) UN COMPONENTE OBTENIBLE MEDIANTE LA PUESTA EN CONTACTO ENTRE SI DE UN PORTADOR EN PARTICULAS, UN COMPUESTO [A-A] DE ORGANOALUMINIO Y AGUA, B) UN COMPUESTO DE METAL DE TRANSICION QUE CONTENGA UN LIGANTE QUE TENGA UN ESQUELETO DE CICLOALQUIDIENIL Y, SI FUERA NECESARIO, C) UN COMPUESTO DE ORGANOALUMINIO.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3209190 | 1990-02-13 | ||
| JP2032091A JP2826362B2 (ja) | 1990-02-13 | 1990-02-13 | オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2080247T3 true ES2080247T3 (es) | 1996-02-01 |
| ES2080247T5 ES2080247T5 (es) | 2004-07-01 |
Family
ID=12349211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES91301168T Expired - Lifetime ES2080247T5 (es) | 1990-02-13 | 1991-02-13 | Catalizadores solidos de polimerizacion de olefinas y procedimientos para la polimerizacion de olefinas. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5234878A (es) |
| EP (1) | EP0442725B2 (es) |
| JP (1) | JP2826362B2 (es) |
| KR (1) | KR930012267B1 (es) |
| CN (1) | CN1048255C (es) |
| AT (1) | ATE128721T1 (es) |
| CA (1) | CA2036141C (es) |
| DE (1) | DE69113489T3 (es) |
| ES (1) | ES2080247T5 (es) |
| MY (1) | MY106524A (es) |
Families Citing this family (75)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE59107926D1 (de) | 1990-11-12 | 1996-07-18 | Hoechst Ag | Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
| USRE39561E1 (en) | 1990-11-12 | 2007-04-10 | Basell Polyoefine Gmbh | Metallocenes containing ligands of 2-substituted indenyl derivatives, process for their preparation, and their use as catalysts |
| TW218884B (es) | 1991-05-01 | 1994-01-11 | Mitsubishi Kakoki Kk | |
| TW300901B (es) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| DE69224600T2 (de) * | 1991-11-12 | 1998-08-27 | Nippon Oil Co Ltd | Katalysatorbestandteile für Olefinpolymerisation |
| EP0549900B1 (de) * | 1991-11-30 | 1996-08-21 | Hoechst Aktiengesellschaft | Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
| US5932669A (en) * | 1991-11-30 | 1999-08-03 | Targor Gmbh | Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts |
| TW309523B (es) * | 1991-11-30 | 1997-07-01 | Hoechst Ag | |
| US5830821A (en) * | 1991-11-30 | 1998-11-03 | Targor Gmbh | Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands |
| FI112233B (fi) * | 1992-04-01 | 2003-11-14 | Basell Polyolefine Gmbh | Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö |
| JP3193110B2 (ja) * | 1992-04-15 | 2001-07-30 | 三菱化学株式会社 | プロピレン重合体の製造法 |
| KR100281607B1 (ko) * | 1992-04-28 | 2001-02-15 | 벡귀, 바인 | 올레핀 중합반응 촉매, 이의 제조방법 및 이의 용도 |
| EP0578838A1 (en) * | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
| EP0567952B1 (en) * | 1992-04-29 | 1997-12-03 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
| TW294669B (es) * | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
| DE59308494D1 (de) * | 1992-08-03 | 1998-06-10 | Targor Gmbh | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden |
| JPH06100614A (ja) * | 1992-08-06 | 1994-04-12 | Mitsui Petrochem Ind Ltd | オレフィン重合用触媒およびこれを用いるオレフィンの重合方法 |
| USRE39156E1 (en) | 1992-08-15 | 2006-07-04 | Basell Polyolefine Gmbh | Process for the preparation of polyolefins |
| US5332706A (en) * | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| US5608019A (en) * | 1992-12-28 | 1997-03-04 | Mobil Oil Corporation | Temperature control of MW in olefin polymerization using supported metallocene catalyst |
| US5602067A (en) * | 1992-12-28 | 1997-02-11 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| GB9300934D0 (en) * | 1993-01-19 | 1993-03-10 | Bp Chem Int Ltd | Metallocene complexes |
| CN1087326C (zh) * | 1993-05-13 | 2002-07-10 | 埃克森美孚化学专利公司 | 乙烯共聚物制备的薄膜及其制备方法 |
| IT1264680B1 (it) | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
| US5459117A (en) * | 1993-08-27 | 1995-10-17 | Ewen; John A. | Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers |
| US5631202A (en) | 1993-09-24 | 1997-05-20 | Montell Technology Company B.V. | Stereospecific metallocene catalysts with stereolocking α-CP substituents |
| US5455741A (en) * | 1993-10-26 | 1995-10-03 | Pulse Engineering, Inc. | Wire-lead through hole interconnect device |
| DE4336659A1 (de) * | 1993-10-27 | 1995-05-04 | Witco Gmbh | Verfahren zur Herstellung von Alkylaluminoxanen auf inerten Trägermaterialien |
| US5614456A (en) * | 1993-11-15 | 1997-03-25 | Mobil Oil Corporation | Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers |
| DE4344672C1 (de) * | 1993-12-27 | 1995-06-14 | Basf Ag | Verfahren zur Herstellung von Polymerisaten des Ethylens durch Suspensionspolymerisation |
| US6391817B1 (en) | 1993-12-28 | 2002-05-21 | Exxonmobil Chemical Patents Inc. | Method for producing a prepolymerized catalyst |
| DE4409249A1 (de) * | 1994-03-18 | 1995-09-21 | Witco Gmbh | Verfahren zur Herstellung von Alkylaluminoxan auf inerten Trägermaterialien |
| TR28720A (tr) * | 1994-07-11 | 1997-02-18 | Montell Technology Company Bv | Olefinlerin polimerizasyonu icin desteklenmis katalizörler. |
| TW454020B (en) † | 1994-08-09 | 2001-09-11 | Mitsui Chemicals Inc | Olefin polymerization catalyst |
| US5525678A (en) * | 1994-09-22 | 1996-06-11 | Mobil Oil Corporation | Process for controlling the MWD of a broad/bimodal resin produced in a single reactor |
| US6124230A (en) * | 1995-07-13 | 2000-09-26 | Exxon Chemical Patents, Inc. | Polymerization catalyst systems, their production and use |
| US6140432A (en) * | 1995-07-13 | 2000-10-31 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| US5882750A (en) * | 1995-07-03 | 1999-03-16 | Mobil Oil Corporation | Single reactor bimodal HMW-HDPE film resin with improved bubble stability |
| US6403772B1 (en) * | 1995-09-11 | 2002-06-11 | Montell Technology Company, Bv | Open-pentadienyl metallocenes, precursors thereof and polymerization catalysts therefrom |
| DE59500197D1 (de) * | 1995-09-13 | 1997-05-28 | Witco Gmbh | Verfahren zur Herstellung von Metallocen-Katalysatorsystemen auf inerten Trägermaterialien |
| ATE153675T1 (de) * | 1995-09-13 | 1997-06-15 | Witco Gmbh | Verfahren zur herstellung von metallocen- katalysatorsystemen auf inerten trägermaterialien unter verwendung von gasphasenreaktoren |
| US6486089B1 (en) | 1995-11-09 | 2002-11-26 | Exxonmobil Oil Corporation | Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution |
| US6787618B1 (en) | 1995-12-01 | 2004-09-07 | Basell Polypropylen Gmbh | Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms |
| US5914289A (en) * | 1996-02-19 | 1999-06-22 | Fina Research, S.A. | Supported metallocene-alumoxane catalysts for the preparation of polyethylene having a broad monomodal molecular weight distribution |
| US6417130B1 (en) | 1996-03-25 | 2002-07-09 | Exxonmobil Oil Corporation | One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization |
| WO1998002247A1 (en) | 1996-07-15 | 1998-01-22 | Mobil Oil Corporation | Comonomer pretreated bimetallic catalyst for blow molding and film applications |
| US6005463A (en) * | 1997-01-30 | 1999-12-21 | Pulse Engineering | Through-hole interconnect device with isolated wire-leads and component barriers |
| US6160072A (en) * | 1997-05-02 | 2000-12-12 | Ewen; John A. | Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes |
| US6153551A (en) | 1997-07-14 | 2000-11-28 | Mobil Oil Corporation | Preparation of supported catalyst using trialkylaluminum-metallocene contact products |
| US6051525A (en) * | 1997-07-14 | 2000-04-18 | Mobil Corporation | Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution |
| EP0949273B1 (en) | 1997-08-21 | 2003-04-02 | Sumitomo Chemical Company, Limited | Modified particles, carrier prepared therefrom, olefin polymerization catalyst component prepared therefrom, olefin polymerization catalyst prepared therefrom, and process for preparing olefin polymer |
| US5990035A (en) * | 1997-10-21 | 1999-11-23 | Koeppl; Alexander | Polymerization catalyst systems, their preparation, and use |
| JP4440355B2 (ja) | 1998-03-25 | 2010-03-24 | 住友化学株式会社 | 改質された粒子、それよりなる担体、それよりなるオレフィン重合用触媒成分、それを用いてなるオレフィン重合用触媒、およびオレフィン重合体の製造方法 |
| KR100380018B1 (ko) | 1998-04-09 | 2003-10-04 | 주식회사 엘지화학 | 메탈로센담지촉매및이를이용한올레핀중합방법 |
| KR100358225B1 (ko) | 1998-04-09 | 2003-01-24 | 주식회사 엘지화학 | 조촉매의 재순환이 가능한 메탈로센 촉매 중합 방법 |
| US6214946B1 (en) * | 1999-05-19 | 2001-04-10 | Union Carbide Chemicals & Plastics Technology Corporation | Inert particulate material passivation for single-site catalyst in EPDM production |
| GB0017547D0 (en) * | 2000-07-17 | 2000-09-06 | Bp Chem Int Ltd | Supported polymerisation catalysts |
| US6777510B1 (en) | 2000-09-12 | 2004-08-17 | California Institute Of Technology | Internal Lewis acid single site catalyst family for polymerization of polar monomers |
| BR0214577A (pt) * | 2001-11-30 | 2004-11-03 | Exxonmobil Chem Patents Inc | Copolìmero de etileno/alfa-olefina feito com uma combinação de um catalisador de sìtio-único/sìtio-não-único, sua preparação e uso |
| CA2412488C (en) | 2001-12-11 | 2009-09-08 | Crompton Gmbh | Process for preparing partial hydrolysates of organometallic compounds or transition metal catalysts immobilized on inert support materials |
| DE60137638D1 (de) * | 2001-12-19 | 2009-03-26 | Borealis Tech Oy | Herstellung von geträgerten Katalysatoren für die Olefinpolymerisation |
| DE10163457A1 (de) * | 2001-12-21 | 2003-07-03 | Merck Patent Gmbh | Heterogenisierung von katalytischen Komponenten |
| EP1572761A1 (en) | 2002-12-16 | 2005-09-14 | Basell Polyolefine GmbH | Preparation of supported catalyst systems containing reduced amounts of aluminoxanes |
| EP1847555A1 (en) | 2006-04-18 | 2007-10-24 | Borealis Technology Oy | Multi-branched Polypropylene |
| CL2008002053A1 (es) * | 2007-07-17 | 2009-05-22 | Hoffmann La Roche | Metodo para la purificacion de una eritropoyetina monopeguilada (epompeg) que consiste en proporcionar una solucion que contiene eritropoyetina mono, poli y no peguilada y hacerla pasar por dos pasos de cromatografia de intercambio cationico y metodo para producir epo mpeg que incluye metodo de purificacion. |
| CL2008002054A1 (es) * | 2007-07-17 | 2009-05-29 | Hoffmann La Roche | Metodo para la regeneracion de una columna de cromatografia de intercambio cationico despues de la elusion de eritropoyetina monopeguilada y metodo para obtener una eritropoyetina monopeguilada, incorporando el metodo de regeneracion de la columna de intercambio cationico. |
| BRPI0703586B1 (pt) | 2007-10-19 | 2018-02-06 | Braskem S.A | Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular |
| KR101084677B1 (ko) * | 2008-05-14 | 2011-11-22 | 주식회사 엘지화학 | 올레핀 중합체의 제조방법 |
| US11041029B2 (en) | 2015-08-31 | 2021-06-22 | Exxonmobil Chemical Patents Inc. | Aluminum alkyls with pendant olefins for polyolefin reactions |
| US10618988B2 (en) | 2015-08-31 | 2020-04-14 | Exxonmobil Chemical Patents Inc. | Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof |
| US10676547B2 (en) | 2015-08-31 | 2020-06-09 | Exxonmobil Chemical Patents Inc. | Aluminum alkyls with pendant olefins on clays |
| US10059788B2 (en) | 2016-04-29 | 2018-08-28 | Exxonmobil Chemical Patents Inc. | Organoaluminum activators on clays |
| US10562987B2 (en) | 2016-06-30 | 2020-02-18 | Exxonmobil Chemical Patents Inc. | Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents |
| US10626200B2 (en) | 2017-02-28 | 2020-04-21 | Exxonmobil Chemical Patents Inc. | Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof |
| WO2018160278A1 (en) | 2017-03-01 | 2018-09-07 | Exxonmobil Chemical Patents Inc. | Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3424697C2 (de) * | 1984-07-05 | 1999-07-08 | Targor Gmbh | Verfahren zur Polymerisation von Ethylen oder von Mischungen von Ethylen mit anderen 1-Olefinen |
| JPH0639496B2 (ja) * | 1985-06-03 | 1994-05-25 | 旭化成工業株式会社 | オレフインの重合方法 |
| JP2538588B2 (ja) * | 1987-04-03 | 1996-09-25 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒の製法 |
| US4912075A (en) * | 1987-12-17 | 1990-03-27 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
| US5008228A (en) * | 1988-03-29 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for preparing a silica gel supported metallocene-alumoxane catalyst |
| US4871705A (en) * | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| DE68919156T3 (de) * | 1988-08-05 | 2002-08-14 | Fina Technology, Inc. | Verfahren zur Herstellung grosser symmetrischer Polymerteilchen. |
| JP2764106B2 (ja) * | 1988-08-18 | 1998-06-11 | 三井化学株式会社 | 重合方法 |
| US4935397A (en) * | 1988-09-28 | 1990-06-19 | Exxon Chemical Patents Inc. | Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same |
-
1990
- 1990-02-13 JP JP2032091A patent/JP2826362B2/ja not_active Expired - Fee Related
-
1991
- 1991-01-22 MY MYPI91000097A patent/MY106524A/en unknown
- 1991-02-05 KR KR1019910001958A patent/KR930012267B1/ko not_active Expired - Fee Related
- 1991-02-12 US US07/653,943 patent/US5234878A/en not_active Expired - Fee Related
- 1991-02-12 CN CN91101036A patent/CN1048255C/zh not_active Expired - Fee Related
- 1991-02-12 CA CA002036141A patent/CA2036141C/en not_active Expired - Fee Related
- 1991-02-13 EP EP91301168A patent/EP0442725B2/en not_active Expired - Lifetime
- 1991-02-13 ES ES91301168T patent/ES2080247T5/es not_active Expired - Lifetime
- 1991-02-13 DE DE69113489T patent/DE69113489T3/de not_active Expired - Fee Related
- 1991-02-13 AT AT91301168T patent/ATE128721T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ATE128721T1 (de) | 1995-10-15 |
| MY106524A (en) | 1995-06-30 |
| US5234878A (en) | 1993-08-10 |
| DE69113489T3 (de) | 2004-05-13 |
| DE69113489D1 (de) | 1995-11-09 |
| ES2080247T5 (es) | 2004-07-01 |
| CA2036141C (en) | 1996-08-06 |
| CN1054423A (zh) | 1991-09-11 |
| EP0442725B2 (en) | 2003-10-22 |
| JP2826362B2 (ja) | 1998-11-18 |
| CA2036141A1 (en) | 1991-08-14 |
| EP0442725A2 (en) | 1991-08-21 |
| EP0442725B1 (en) | 1995-10-04 |
| CN1048255C (zh) | 2000-01-12 |
| DE69113489T2 (de) | 1996-05-02 |
| KR930012267B1 (ko) | 1993-12-28 |
| JPH03234710A (ja) | 1991-10-18 |
| EP0442725A3 (en) | 1992-10-28 |
| KR910015595A (ko) | 1991-09-30 |
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