ES2092130T3 - Materiales que presentan propiedades anti-reflexion, hidrofobas y de resistencia a la abrasion, y procedimiento de deposito de una capa anti-reflexion hidrofoba y de resistencia a la abrasion sobre un substrato. - Google Patents
Materiales que presentan propiedades anti-reflexion, hidrofobas y de resistencia a la abrasion, y procedimiento de deposito de una capa anti-reflexion hidrofoba y de resistencia a la abrasion sobre un substrato.Info
- Publication number
- ES2092130T3 ES2092130T3 ES92919051T ES92919051T ES2092130T3 ES 2092130 T3 ES2092130 T3 ES 2092130T3 ES 92919051 T ES92919051 T ES 92919051T ES 92919051 T ES92919051 T ES 92919051T ES 2092130 T3 ES2092130 T3 ES 2092130T3
- Authority
- ES
- Spain
- Prior art keywords
- hydrophobic
- abrasion resistance
- substrate
- layer
- reflection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title abstract 6
- 238000005299 abrasion Methods 0.000 title abstract 3
- 230000002209 hydrophobic effect Effects 0.000 title abstract 3
- 239000000758 substrate Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- ROGDGDPDLIVQFZ-OGFXRTJISA-N (2r)-2-(4-chloro-2-methylphenoxy)propanoic acid;n-methylmethanamine Chemical compound CNC.OC(=O)[C@@H](C)OC1=CC=C(Cl)C=C1C ROGDGDPDLIVQFZ-OGFXRTJISA-N 0.000 abstract 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002318 adhesion promoter Substances 0.000 abstract 1
- 239000000084 colloidal system Substances 0.000 abstract 1
- 239000007822 coupling agent Substances 0.000 abstract 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/113—Anti-reflection coatings using inorganic layer materials only
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/0005—Other surface treatment of glass not in the form of fibres or filaments by irradiation
- C03C23/006—Other surface treatment of glass not in the form of fibres or filaments by irradiation by plasma or corona discharge
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/009—Poling glass
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
- F24S80/00—Details, accessories or component parts of solar heat collectors not provided for in groups F24S10/00-F24S70/00
- F24S80/50—Elements for transmitting incoming solar rays and preventing outgoing heat radiation; Transparent coverings
- F24S80/52—Elements for transmitting incoming solar rays and preventing outgoing heat radiation; Transparent coverings characterised by the material
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/73—Anti-reflective coatings with specific characteristics
- C03C2217/734—Anti-reflective coatings with specific characteristics comprising an alternation of high and low refractive indexes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/76—Hydrophobic and oleophobic coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/31—Pre-treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/40—Solar thermal energy, e.g. solar towers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
- Y10T428/31544—Addition polymer is perhalogenated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31609—Particulate metal or metal compound-containing
- Y10T428/31612—As silicone, silane or siloxane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31667—Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Engineering & Computer Science (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- Combustion & Propulsion (AREA)
- Plasma & Fusion (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Inorganic Chemistry (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
LA INVENCION CONCIERNE A UN MATERIAL QUE PRESENTA PROPIEDADES ANTIREFLEJO, ASI COMO A UN PROCESO DE DEPOSITO DE UNA CAPA ANTIREFLEJO SOBRE UN SUBSTRATO. EL OBJETIVO DE LA INVENCION ES OBTENER UNA CAPA QUE PRESENTA SIMULTANEAMENTE PROPIEDADES ANTIREFLEJO, HIDROFOBAS Y QUE SEA RESISTENTE A LA ABRASION. ESTE OBJETIVO ES ALCANZADO CON LA AYUDA DE UN MATERIAL QUE COMPRENDE: UN SUBSTRATO (2) DE NATURALEZA ORGANICA O INORGANICA, UNA CAPA DE PROMOTOR DE ADHERENCIA (4) REALIZADA POR UN MATERIAL ESCOGIDO ENTRE LOS SILANOS, UNA CAPA ANTIREFLEJO (6) FORMADA POR COLOIDES DE SILICE EN UN LIGANTE SILOXANO, UNA CAPA DE AGENTE DE ACOPLAMIENTO (8) REALIZADA POR UN MATERIAL ESCOGIDO ENTRE LOS SILAZANOS, Y UNA CAPA ANTIABRASIVA (10) DE UN POLIMERO FLUORADO. ESTOS MATERIALES TIENEN APLICACIONES PARTICULARES EN OPTICA.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9110519A FR2680583B1 (fr) | 1991-08-22 | 1991-08-22 | Materiau presentant des proprietes antireflet, hydrophobes et de resistance a l'abrasion et procede de depot d'une couche antireflet, hydrophobe et resistante a l'abrasion sur un substrat. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2092130T3 true ES2092130T3 (es) | 1996-11-16 |
Family
ID=9416342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92919051T Expired - Lifetime ES2092130T3 (es) | 1991-08-22 | 1992-08-21 | Materiales que presentan propiedades anti-reflexion, hidrofobas y de resistencia a la abrasion, y procedimiento de deposito de una capa anti-reflexion hidrofoba y de resistencia a la abrasion sobre un substrato. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5476717A (es) |
| EP (1) | EP0600022B1 (es) |
| JP (1) | JP3186768B2 (es) |
| AU (1) | AU657000B2 (es) |
| DE (1) | DE69212606T2 (es) |
| ES (1) | ES2092130T3 (es) |
| FR (1) | FR2680583B1 (es) |
| WO (1) | WO1993004386A1 (es) |
Families Citing this family (106)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5873931A (en) * | 1992-10-06 | 1999-02-23 | Minnesota Mining And Manufacturing Company | Coating composition having anti-reflective and anti-fogging properties |
| FR2703791B1 (fr) * | 1993-04-05 | 1995-05-19 | Commissariat Energie Atomique | Procédé de fabrication de couches minces présentant des propriétés optiques et des propriétés de résistance à l'abrasion . |
| US5698266A (en) * | 1993-04-05 | 1997-12-16 | Commissariat A L'energie Atomique | Process for the production of thin coatings having optical and abrasion resistance properties |
| EP0619504A1 (de) * | 1993-04-08 | 1994-10-12 | Optische Werke G. Rodenstock | Antireflex-Belag |
| FR2707763B1 (fr) * | 1993-07-16 | 1995-08-11 | Commissariat Energie Atomique | Matériau composite à indice de réfraction élevé, procédé de fabrication de ce matériau composite et matériau optiquement actif comprenant ce matériau composite. |
| US5585186A (en) * | 1994-12-12 | 1996-12-17 | Minnesota Mining And Manufacturing Company | Coating composition having anti-reflective, and anti-fogging properties |
| CA2162451A1 (en) * | 1994-12-22 | 1996-06-23 | John P. Murphy | Anti-reflective clarifier film for eyeglasses |
| US5981059A (en) * | 1995-04-03 | 1999-11-09 | Southwall Technologies, Inc. | Multi-layer topcoat for an optical member |
| JPH09110476A (ja) * | 1995-10-13 | 1997-04-28 | Sony Corp | 表示装置 |
| JP3694703B2 (ja) * | 1996-04-25 | 2005-09-14 | Azエレクトロニックマテリアルズ株式会社 | 反射防止コーティング用組成物 |
| US6040053A (en) * | 1996-07-19 | 2000-03-21 | Minnesota Mining And Manufacturing Company | Coating composition having anti-reflective and anti-fogging properties |
| KR100495338B1 (ko) * | 1997-01-27 | 2005-06-14 | 피터 디. 하랜드 | 광학 기판으로부터의 반사를 감소시키기 위한 코팅막, 반사 감소 방법 및 장치 |
| US6172812B1 (en) | 1997-01-27 | 2001-01-09 | Peter D. Haaland | Anti-reflection coatings and coated articles |
| FR2759464B1 (fr) | 1997-02-10 | 1999-03-05 | Commissariat Energie Atomique | Procede de preparation d'un materiau optique multicouches avec reticulation-densification par insolation aux rayons ultraviolets et materiau optique ainsi prepare |
| FR2759360B1 (fr) | 1997-02-10 | 1999-03-05 | Commissariat Energie Atomique | Materiau polymerique inorganique a base d'oxyde de tantale notamment a indice de refraction eleve, mecaniquement resistant a l'abrasion, son procede de fabrication et materiau optique comprenant ce materiau |
| DE19710685B4 (de) * | 1997-03-14 | 2005-12-01 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Nanokristalline Partikel enthaltendes Material, Verfahren zur Herstellung und dessen Verwendung |
| AU6040198A (en) * | 1997-04-03 | 1998-10-22 | W.L. Gore & Associates, Inc. | Low dielectric constant material with improved dielectric strength |
| US5989462A (en) | 1997-07-31 | 1999-11-23 | Q2100, Inc. | Method and composition for producing ultraviolent blocking lenses |
| FR2768522B1 (fr) * | 1997-09-18 | 1999-10-15 | Commissariat Energie Atomique | Detecteur a scintillation, revetement refracteur pour scintillateur et procede de fabrication d'un tel revetement |
| FR2772142B1 (fr) | 1997-12-09 | 2001-11-09 | Commissariat Energie Atomique | Procede de traitement antireflet et materiau presentant des proprietes antireflet |
| US6436541B1 (en) | 1998-04-07 | 2002-08-20 | Ppg Industries Ohio, Inc. | Conductive antireflective coatings and methods of producing same |
| US6245428B1 (en) | 1998-06-10 | 2001-06-12 | Cpfilms Inc. | Low reflective films |
| US6451226B1 (en) | 1998-09-25 | 2002-09-17 | Q2100, Inc. | Plastic lens compositions |
| US6273143B1 (en) * | 1998-11-17 | 2001-08-14 | Ameron International Corporation | Bonding of steel strips in steel strip laminate pipe |
| US6403223B1 (en) | 1999-01-05 | 2002-06-11 | Telspan Services Inc. | Circular polarizer comprising anti-reflection material |
| US6419873B1 (en) | 1999-03-19 | 2002-07-16 | Q2100, Inc. | Plastic lens systems, compositions, and methods |
| US6582823B1 (en) | 1999-04-30 | 2003-06-24 | North Carolina State University | Wear-resistant polymeric articles and methods of making the same |
| JP3700479B2 (ja) * | 1999-06-25 | 2005-09-28 | 松下電器産業株式会社 | 投写形受像機 |
| US6372354B1 (en) * | 1999-09-13 | 2002-04-16 | Chemat Technology, Inc. | Composition and method for a coating providing anti-reflective and anti-static properties |
| US6542302B2 (en) * | 1999-12-01 | 2003-04-01 | Bushnell Corporation | Lens coating to reduce external fogging of scope lenses |
| US6960312B2 (en) | 2000-03-30 | 2005-11-01 | Q2100, Inc. | Methods for the production of plastic lenses |
| US6528955B1 (en) | 2000-03-30 | 2003-03-04 | Q2100, Inc. | Ballast system for a fluorescent lamp |
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| US6723260B1 (en) | 2000-03-30 | 2004-04-20 | Q2100, Inc. | Method for marking a plastic eyeglass lens using a mold assembly holder |
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| US6743516B2 (en) | 2000-09-29 | 2004-06-01 | Guardian Industries Corporation | Highly durable hydrophobic coatings and methods |
| US7351471B2 (en) * | 2000-12-06 | 2008-04-01 | 3M Innovative Properties Company | Fluoropolymer coating compositions with multifunctional fluoroalkyl crosslinkers for anti-reflective polymer films |
| JP3722418B2 (ja) | 2000-12-08 | 2005-11-30 | 信越化学工業株式会社 | 反射防止膜及びこれを利用した光学部材 |
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| US6840752B2 (en) | 2001-02-20 | 2005-01-11 | Q2100, Inc. | Apparatus for preparing multiple eyeglass lenses |
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| US7124995B2 (en) | 2001-02-20 | 2006-10-24 | Q2100, Inc. | Holder for mold assemblies and molds |
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| US6758663B2 (en) | 2001-02-20 | 2004-07-06 | Q2100, Inc. | System for preparing eyeglass lenses with a high volume curing unit |
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Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1275208C (en) * | 1985-01-25 | 1990-10-16 | Roger W. Lange | Silica coating |
| US4929278A (en) * | 1988-01-26 | 1990-05-29 | United States Department Of Energy | Sol-gel antireflective coating on plastics |
-
1991
- 1991-08-22 FR FR9110519A patent/FR2680583B1/fr not_active Expired - Lifetime
-
1992
- 1992-08-21 DE DE69212606T patent/DE69212606T2/de not_active Expired - Lifetime
- 1992-08-21 US US08/193,122 patent/US5476717A/en not_active Expired - Lifetime
- 1992-08-21 WO PCT/FR1992/000814 patent/WO1993004386A1/fr not_active Ceased
- 1992-08-21 ES ES92919051T patent/ES2092130T3/es not_active Expired - Lifetime
- 1992-08-21 EP EP92919051A patent/EP0600022B1/fr not_active Expired - Lifetime
- 1992-08-21 JP JP50415593A patent/JP3186768B2/ja not_active Expired - Lifetime
- 1992-08-21 AU AU25038/92A patent/AU657000B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| AU657000B2 (en) | 1995-02-23 |
| DE69212606T2 (de) | 1997-02-20 |
| EP0600022A1 (fr) | 1994-06-08 |
| FR2680583B1 (fr) | 1993-10-08 |
| FR2680583A1 (fr) | 1993-02-26 |
| WO1993004386A1 (fr) | 1993-03-04 |
| EP0600022B1 (fr) | 1996-07-31 |
| JPH06510608A (ja) | 1994-11-24 |
| DE69212606D1 (de) | 1996-09-05 |
| AU2503892A (en) | 1993-03-16 |
| JP3186768B2 (ja) | 2001-07-11 |
| US5476717A (en) | 1995-12-19 |
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