ES2104288T3 - Procedimiento para la produccion de esteres del acido metacrilico. - Google Patents
Procedimiento para la produccion de esteres del acido metacrilico.Info
- Publication number
- ES2104288T3 ES2104288T3 ES94308342T ES94308342T ES2104288T3 ES 2104288 T3 ES2104288 T3 ES 2104288T3 ES 94308342 T ES94308342 T ES 94308342T ES 94308342 T ES94308342 T ES 94308342T ES 2104288 T3 ES2104288 T3 ES 2104288T3
- Authority
- ES
- Spain
- Prior art keywords
- esters
- procedure
- production
- metacrilic
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title 1
- ROWKJAVDOGWPAT-UHFFFAOYSA-N Acetoin Chemical compound CC(O)C(C)=O ROWKJAVDOGWPAT-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- GFAZHVHNLUBROE-UHFFFAOYSA-N hydroxymethyl propionaldehyde Natural products CCC(=O)CO GFAZHVHNLUBROE-UHFFFAOYSA-N 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 238000007086 side reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/18—Preparation of carboxylic acid esters by conversion of a group containing nitrogen into an ester group
- C07C67/20—Preparation of carboxylic acid esters by conversion of a group containing nitrogen into an ester group from amides or lactams
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
- C07C67/327—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
ESTA INVENCION SE REFIERE A UN METODO PARA PRODUCIR ESTERES CARBOXILICOS INSATURADOS ALFA, BETA IANOHIDRINA DE ACETOINA Y ACIDO SULFURICO A TRAVES DE LA REDUCCION DE PRODUCTOS LATERALES DE REACCION Y EL RECICLADO DE INTERMEDIOS DE PROCESO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/160,697 US5393918A (en) | 1993-12-02 | 1993-12-02 | High yield process for the production of methacrylic acid esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2104288T3 true ES2104288T3 (es) | 1997-10-01 |
Family
ID=22578043
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94308342T Expired - Lifetime ES2104288T3 (es) | 1993-12-02 | 1994-11-11 | Procedimiento para la produccion de esteres del acido metacrilico. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5393918A (es) |
| EP (1) | EP0656343B1 (es) |
| JP (1) | JP3860234B2 (es) |
| KR (1) | KR100411499B1 (es) |
| CN (1) | CN1041410C (es) |
| BR (1) | BR9404473A (es) |
| CA (1) | CA2135438A1 (es) |
| CZ (1) | CZ303494A3 (es) |
| DE (1) | DE69403883T2 (es) |
| ES (1) | ES2104288T3 (es) |
| RU (1) | RU2131867C1 (es) |
| SG (1) | SG81884A1 (es) |
| TW (1) | TW319774B (es) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9802662D0 (en) * | 1998-02-10 | 1998-04-01 | Ici Plc | Unsaturated compounds |
| ATE220657T1 (de) | 1998-11-04 | 2002-08-15 | Rohm & Haas | Verfahren zum herstellen mit grosser ausbeute von methylmethacrylat oder methacrylsäure |
| EP1186592A1 (en) * | 2000-09-11 | 2002-03-13 | Mitsubishi Gas Chemical Company, Ltd. | Production of methacrylates |
| ZA200303241B (en) * | 2002-05-01 | 2003-11-04 | Rohm & Haas | Improved process for methacrylic acid and methcrylic acid ester production. |
| TWI254648B (en) * | 2002-05-01 | 2006-05-11 | Rohm & Haas | Process for manufacturing high purity methacrylic acid |
| RU2372130C9 (ru) * | 2003-07-11 | 2010-10-10 | Басф Акциенгезельшафт | Термический способ разделения для отделения, по меньшей мере, одного массового потока, обогащенного акриловой кислотой |
| CN100584822C (zh) * | 2004-04-02 | 2010-01-27 | 西巴特殊化学水处理有限公司 | 由α或β-羟基羧酸制备丙烯酸衍生物 |
| DE102006058251A1 (de) * | 2006-12-08 | 2008-06-12 | Evonik Röhm Gmbh | Verfahren und Vorrichtung zur Herstellung von Methacrylsäurealkylestern |
| DE102006060161A1 (de) * | 2006-12-18 | 2008-06-26 | Evonik Röhm Gmbh | Verfahren zur adsorptiven Aufreinigung von Methacrylsäurealkylestern |
| JP5432852B2 (ja) * | 2009-09-30 | 2014-03-05 | ローム アンド ハース カンパニー | メタクリル酸メチルの精製によって生じる流れから価値のある化合物を回収する方法 |
| SG189244A1 (en) | 2010-10-07 | 2013-05-31 | Rohm & Haas | Process for production of methacrylic acid ester |
| DE102011076642A1 (de) * | 2011-05-27 | 2012-11-29 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Methacrylsäure |
| EP2760598B1 (en) | 2011-09-27 | 2016-04-27 | Rohm and Haas Company | Method for cleaning a (meth) acrylate ester process tank |
| WO2013184345A1 (en) | 2012-06-04 | 2013-12-12 | Rohm And Haas Company | Process for production of methacrylic acid esters |
| JP6088058B2 (ja) * | 2012-09-28 | 2017-03-01 | ローム アンド ハース カンパニーRohm And Haas Company | アセトンシアノヒドリンおよび硫酸からmmaおよび/またはmaaを生成するプロセス |
| CN103130671B (zh) * | 2013-03-28 | 2015-06-17 | 重庆紫光化工股份有限公司 | 一种清洁的甲基丙烯酰胺的制备和提纯方法 |
| CN105324172B (zh) * | 2013-06-26 | 2019-05-31 | 罗门哈斯公司 | 用于制造甲基丙烯酸酯的工艺 |
| CA2964762A1 (en) | 2014-10-14 | 2016-04-21 | Gevo, Inc. | Methods for conversion of ethanol to functionalized lower hydrocarbons and downstream hydrocarbons |
| CN111936452B (zh) | 2018-01-04 | 2024-05-03 | 吉沃公司 | 经非均相催化剂将杂醇油混合物改质为更高价值的可再生化学品 |
| US20240010604A1 (en) | 2020-10-23 | 2024-01-11 | Röhm Gmbh | Optimized process for synthesizing methacrylic acid (maa) and/or alkyl methacrylate by reducing unwanted byproducts |
| US20230399286A1 (en) | 2020-10-23 | 2023-12-14 | Röhm Gmbh | Improved process for preparing methyl methacrylate and/or methacrylic acid by reduced back mixing during conversion |
| ES2935290T3 (es) | 2020-10-23 | 2023-03-03 | Roehm Gmbh | Procedimiento optimizado para la preparación de metacrilato de alquilo mediante reducción de productos secundarios perturbadores |
| EP4452919A1 (de) | 2021-12-23 | 2024-10-30 | Röhm GmbH | Verfahren zur herstellung von alkylmethacrylaten mit verbesserter ausbeute und verminderten emissionen flüchtiger organischer verbindungen |
| WO2023169810A1 (de) | 2022-03-11 | 2023-09-14 | Röhm Gmbh | Verfahren zur herstellung von alpha-hydroxyisobuttersäuremethylester und dessen anwendung in der elektronik-industrie |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2416756A (en) * | 1941-10-23 | 1947-03-04 | Du Pont | Continuous production of esters of methacrylic acid |
| US2786739A (en) * | 1954-05-10 | 1957-03-26 | Allied Chem & Dye Corp | Continuous process for the production of methacrylic acid esters and ammonium sulphate |
| US3027328A (en) * | 1958-12-09 | 1962-03-27 | Degussa | Process for the preparation of acetonecyanohydrin/sulfuric acid mixtures |
| JPS5767534A (en) * | 1980-10-16 | 1982-04-24 | Mitsui Toatsu Chem Inc | Preparation of alpha,beta-unsaturated carboxylic ester and alpha,beta-unsaturated carboxylic acid |
| US4529816A (en) * | 1984-02-13 | 1985-07-16 | E. I. Du Pont De Nemours And Company | Process for producing alkyl methacrylates |
| ES2012539A6 (es) * | 1987-08-20 | 1990-04-01 | Du Pont | Procedimiento para la produccion de acido metacrilico y sus esteres dealquilo. |
| JP2727618B2 (ja) * | 1989-01-26 | 1998-03-11 | 三菱瓦斯化学株式会社 | 不飽和カルボン酸エステルの製造方法 |
| JP2778131B2 (ja) * | 1989-07-14 | 1998-07-23 | 三菱瓦斯化学株式会社 | メタクリル酸メチルの製造方法 |
| JP2884639B2 (ja) * | 1989-11-28 | 1999-04-19 | 三菱瓦斯化学株式会社 | 不飽和カルボン酸エステルの製造法 |
| JP2884638B2 (ja) * | 1989-11-28 | 1999-04-19 | 三菱瓦斯化学株式会社 | 不飽和カルボン酸エステルの製造法 |
| JPH03264551A (ja) * | 1990-03-15 | 1991-11-25 | Kuraray Co Ltd | メタクリル酸メチルの回収方法 |
-
1993
- 1993-12-02 US US08/160,697 patent/US5393918A/en not_active Expired - Lifetime
-
1994
- 1994-11-09 CA CA002135438A patent/CA2135438A1/en not_active Abandoned
- 1994-11-11 SG SG9605540A patent/SG81884A1/en unknown
- 1994-11-11 DE DE69403883T patent/DE69403883T2/de not_active Expired - Fee Related
- 1994-11-11 ES ES94308342T patent/ES2104288T3/es not_active Expired - Lifetime
- 1994-11-11 EP EP94308342A patent/EP0656343B1/en not_active Expired - Lifetime
- 1994-11-16 BR BR9404473A patent/BR9404473A/pt not_active IP Right Cessation
- 1994-11-22 TW TW083110831A patent/TW319774B/zh active
- 1994-11-28 JP JP31600494A patent/JP3860234B2/ja not_active Expired - Fee Related
- 1994-11-30 RU RU94042228A patent/RU2131867C1/ru active
- 1994-11-30 KR KR1019940032179A patent/KR100411499B1/ko not_active Expired - Fee Related
- 1994-12-01 CN CN94112755A patent/CN1041410C/zh not_active Expired - Fee Related
- 1994-12-02 CZ CZ943034A patent/CZ303494A3/cs unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN1109865A (zh) | 1995-10-11 |
| RU94042228A (ru) | 1996-10-10 |
| KR100411499B1 (ko) | 2004-03-20 |
| RU2131867C1 (ru) | 1999-06-20 |
| CN1041410C (zh) | 1998-12-30 |
| SG81884A1 (en) | 2001-07-24 |
| BR9404473A (pt) | 1995-07-25 |
| JPH07196576A (ja) | 1995-08-01 |
| US5393918A (en) | 1995-02-28 |
| EP0656343B1 (en) | 1997-06-18 |
| CZ303494A3 (en) | 1995-11-15 |
| TW319774B (es) | 1997-11-11 |
| CA2135438A1 (en) | 1995-06-03 |
| JP3860234B2 (ja) | 2006-12-20 |
| DE69403883T2 (de) | 1998-02-12 |
| KR950017904A (ko) | 1995-07-20 |
| EP0656343A1 (en) | 1995-06-07 |
| DE69403883D1 (de) | 1997-07-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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