ES2111080T3 - Composiciones conductoras de llama retardada basadas en eter de polifenileno. - Google Patents
Composiciones conductoras de llama retardada basadas en eter de polifenileno.Info
- Publication number
- ES2111080T3 ES2111080T3 ES92917912T ES92917912T ES2111080T3 ES 2111080 T3 ES2111080 T3 ES 2111080T3 ES 92917912 T ES92917912 T ES 92917912T ES 92917912 T ES92917912 T ES 92917912T ES 2111080 T3 ES2111080 T3 ES 2111080T3
- Authority
- ES
- Spain
- Prior art keywords
- compositions
- polyphenylene ether
- ether based
- conductive compositions
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 229920001955 polyphenylene ether Polymers 0.000 title abstract 2
- 230000003111 delayed effect Effects 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229920000049 Carbon (fiber) Polymers 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000004917 carbon fiber Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 239000001177 diphosphate Substances 0.000 abstract 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 abstract 1
- 235000011180 diphosphates Nutrition 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 abstract 1
- 239000003365 glass fiber Substances 0.000 abstract 1
- 239000010439 graphite Substances 0.000 abstract 1
- 229910002804 graphite Inorganic materials 0.000 abstract 1
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000010445 mica Substances 0.000 abstract 1
- 229910052618 mica group Inorganic materials 0.000 abstract 1
- 239000001205 polyphosphate Substances 0.000 abstract 1
- 235000011176 polyphosphates Nutrition 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/29—Protection against damage caused by extremes of temperature or by flame
- H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Reinforced Plastic Materials (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
SE DESCRIBEN COMPOSICIONES BASADAS EN UN ETER DE POLIFENILENO MEJORADAS QUE TAMBIEN CONTIENEN POLIESTIRENO.; CANTIDADES SELECCIONADAS DE FIBRAS DE VIDRIO Y DE AGENTES NO FIBROSOS INORGANICOS TALES COMO ARCILLA O MICA; FIBRAS DE CARBON O FIBRAS DE GRAFITO REVESTIDAS DE METAL; Y CIERTAS COMPOSICIONES IGNIFUGAS BASADAS EN DIFOSFATOS O POLIFOSFATOS. LAS COMPOSICIONES, QUE SE PUEDEN MOLDEAR POR INYECCION, PRESENTAN UNAS CARACTERISTICAS DE DISIPACION ELECTRICA EXCELENTES, ASI COMO UNAS PROPIEDADES IGNIFUGAS EXCELENTES (SIN CRACKING O "FORMACION DE JUGOS"); CARACTERISTICAS DE TEMPERATURA DE DISTORSION TERMICA; DISTORSION A LA TRACCION, Y MODULO FLEXIONAL. UNA SERIE DE METODOS ESPECIFICOS PARA LA PREPARACION DE TALES COMPOSICIONES CONTRIBUYE TAMBIEN A SU RENDIMIENTO MEJORADO. ADEMAS, SE PUEDE FORMAR UNA ESPUMA CON LAS COMPOSICIONES.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US74384991A | 1991-08-12 | 1991-08-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2111080T3 true ES2111080T3 (es) | 1998-03-01 |
Family
ID=24990442
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES92917912T Expired - Lifetime ES2111080T3 (es) | 1991-08-12 | 1992-08-07 | Composiciones conductoras de llama retardada basadas en eter de polifenileno. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5294654A (es) |
| EP (1) | EP0552355B1 (es) |
| JP (1) | JPH0822945B2 (es) |
| DE (1) | DE69223758T2 (es) |
| ES (1) | ES2111080T3 (es) |
| WO (1) | WO1993004119A1 (es) |
Families Citing this family (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3137400B2 (ja) * | 1992-01-16 | 2001-02-19 | 旭化成工業株式会社 | ポリフェニレンエーテル系難燃樹脂組成物 |
| JPH07278318A (ja) * | 1994-04-08 | 1995-10-24 | Asahi Chem Ind Co Ltd | 難燃性cd−rom帰属部品 |
| TW360681B (en) * | 1995-06-07 | 1999-06-11 | Gen Electric | Phosphate flame retardant polymers |
| US6388120B1 (en) | 1998-02-13 | 2002-05-14 | Pabu Services, Inc. | Continuous process for the manufacture of phosphoric acid esters |
| US6031035A (en) * | 1998-02-13 | 2000-02-29 | Great Lakes Chemical Corporation | Process for making and using bisaryl diphosphates |
| JP2002504611A (ja) * | 1998-02-27 | 2002-02-12 | ゼネラル・エレクトリック・カンパニイ | 難燃性ポリマーブレンド |
| GB9807180D0 (en) | 1998-04-04 | 1998-06-03 | Ecc Int Ltd | Pigment products |
| US6359043B1 (en) * | 1998-09-24 | 2002-03-19 | General Electric Company | Mica as flame retardant in glass filled noryl |
| US6379795B1 (en) * | 1999-01-19 | 2002-04-30 | E. I. Du Pont De Nemours And Company | Injection moldable conductive aromatic thermoplastic liquid crystalline polymeric compositions |
| US6689613B1 (en) | 1999-03-31 | 2004-02-10 | General Electric Company | Method for preparing and screening catalysts |
| US6518218B1 (en) | 1999-03-31 | 2003-02-11 | General Electric Company | Catalyst system for producing carbon fibrils |
| AU764156B2 (en) | 1999-04-01 | 2003-08-14 | Imerys Pigments, Inc. | Kaolin clay pigments, their preparation and use |
| CA2368747C (en) | 1999-04-01 | 2008-02-12 | Imerys Pigments, Inc. | Kaolin pigments, their preparation and use |
| US6258879B1 (en) * | 1999-04-02 | 2001-07-10 | General Electric Company | Polyphenylene ether resin concentrates containing organic phosphates |
| US6096821A (en) * | 1999-04-02 | 2000-08-01 | General Electric Company | Polyphenylene ether resin concentrates |
| US6554892B1 (en) | 1999-07-02 | 2003-04-29 | Imerys Kaolin, Inc. | Compositions and methods for making a coarse platey, high brightness kaolin product |
| US6476116B1 (en) * | 1999-09-22 | 2002-11-05 | Ntn Corporation | Resin compositions and precision sliding parts made of the same |
| US6268408B1 (en) * | 1999-10-22 | 2001-07-31 | Lucent Technologies Inc. | Conductive fire-retardant thermoplastic elastomer mixture |
| US6579926B2 (en) | 1999-11-15 | 2003-06-17 | General Electric Company | Fire retardant polyphenylene ether-organoclay composition and method of making same |
| EP1278799A1 (en) * | 2000-03-30 | 2003-01-29 | General Electric Company | Transparent, flame retardant poly(arylene ether) blends |
| US6576700B2 (en) * | 2000-04-12 | 2003-06-10 | General Electric Company | High flow polyphenylene ether formulations |
| GB0020179D0 (en) | 2000-08-17 | 2000-10-04 | Imerys Minerals Ltd | Kaolin products and their use |
| GB0020180D0 (en) | 2000-08-17 | 2000-10-04 | Imerys Minerals Ltd | Kaolin products and their production |
| AU2001273053A1 (en) * | 2000-08-31 | 2002-03-13 | General Electric Company | Flame-retarded polyphenylene ether composition and method of making same |
| JP3905477B2 (ja) | 2000-10-26 | 2007-04-18 | 日本エイアンドエル株式会社 | 難燃電磁波シールド性熱可塑性樹脂組成物 |
| US20030085012A1 (en) | 2001-09-07 | 2003-05-08 | Jones J Philip E | Hyperplaty clays and their use in paper coating and filling, methods for making same, and paper products having improved brightness |
| US6808559B2 (en) | 2002-02-26 | 2004-10-26 | Imerys Pigments, Inc. | Kaolin clay pigments suited to rotogravure printing applications and method for preparing the same |
| EP1490428A1 (en) * | 2002-03-28 | 2004-12-29 | Imerys Minerals Limited | Flame retardant polymer compositions comprising a particulate clay mineral |
| JP4190941B2 (ja) * | 2002-08-22 | 2008-12-03 | 旭化成ケミカルズ株式会社 | 製造方法及びその樹脂組成物 |
| US7354887B2 (en) * | 2002-12-18 | 2008-04-08 | E. I. Du Pont De Nemours And Company | High temperature LCP for wear resistance |
| US20040158005A1 (en) * | 2002-12-18 | 2004-08-12 | Bloom Joy Sawyer | Low coefficient of friction thermoplastic containing filler |
| US7183350B2 (en) * | 2003-02-28 | 2007-02-27 | General Electric Company | Poly(arylene ether) blends having low melt viscosity in the absence of plasticizer |
| JP2006008802A (ja) * | 2004-06-24 | 2006-01-12 | Masahiro Matsumura | 抗菌性発泡体 |
| US7285595B2 (en) * | 2004-06-30 | 2007-10-23 | Kimberly-Clark Worldwide, Inc. | Synergistic fluorochemical treatment blend |
| US20060003154A1 (en) * | 2004-06-30 | 2006-01-05 | Snowden Hue S | Extruded thermoplastic articles with enhanced surface segregation of internal melt additive |
| US7230046B2 (en) * | 2004-08-19 | 2007-06-12 | General Electric Company | Flame-retardant polyphenylene ether compositions, and related articles |
| CN101351491B (zh) | 2005-10-28 | 2012-06-27 | 沙伯基础创新塑料知识产权有限公司 | 制备聚(亚芳基醚)的方法,以及相关的组合物 |
| US20070106050A1 (en) * | 2005-11-08 | 2007-05-10 | Sokolowski Alex D | Crosslinked poly(arylene ether) composition, method, and article |
| US7550534B2 (en) * | 2005-11-16 | 2009-06-23 | Sabic Innovative Plastics Ip B.V. | Thermoplastic method, composition, and article |
| US8022123B2 (en) * | 2005-12-22 | 2011-09-20 | Glen Burnie Technologies, Llc | Method for manufacturing and dispersing nanoparticles in thermoplastics |
| EP2412699A1 (en) * | 2005-12-28 | 2012-02-01 | E.I. Du Pont De Nemours And Company | Compositions comprising novel compounds and electronic devices made with such compositions |
| US20100152348A1 (en) * | 2006-04-06 | 2010-06-17 | David Abecassis | Nanocompatibilized novel polymer blends |
| US20080023679A1 (en) * | 2006-05-11 | 2008-01-31 | David Abecassis | Novel flame retardant nanoclay |
| US20080227899A1 (en) * | 2006-05-11 | 2008-09-18 | David Abecassis | Novel method for polymer RDP-clay nanocomposites and mechanisms for polymer/polymer blending |
| US20080071013A1 (en) * | 2006-07-12 | 2008-03-20 | David Abecassis | Novel thermoplastic pelletizing technology |
| US20080317987A1 (en) * | 2006-07-21 | 2008-12-25 | David Abecassis | Nanocomposite materials for ethanol, methanol and hydrocarbon transportation use and storage |
| US20080064798A1 (en) * | 2006-07-21 | 2008-03-13 | David Abecassis | Novel method for nanoclay particle dispersion |
| US20080064802A1 (en) * | 2006-07-26 | 2008-03-13 | David Abecassis | Method for polymer-polymer compatiblization and non polymer filler dispersion and compositions made therefrom |
| US7751382B2 (en) * | 2007-01-09 | 2010-07-06 | Nokia Corporation | Power for uplink acknowledgment transmission |
| WO2008115414A2 (en) * | 2007-03-15 | 2008-09-25 | Glen Burnie Technologies, L.L.C. | A novel method for producing an organoclay additive for use in polypropylene |
| US8679371B2 (en) | 2007-04-11 | 2014-03-25 | Sabic Innovative Plastics Ip B.V. | Electrically conducting polymeric compositions, methods of manufacture thereof and articles comprising the same |
| US20090042044A1 (en) * | 2007-08-08 | 2009-02-12 | David Abecassis | Novel nanocomposite coating for the reduction of pigment particles loss and UV fade and chemical degradation for decorative & structural products made from concrete and concrete composites |
| US20100029986A1 (en) * | 2007-10-19 | 2010-02-04 | David Abecassis | Novel amine functionalized carbon nanotube |
| TWI379860B (en) | 2008-06-24 | 2012-12-21 | Univ Chung Yuan Christian | Modified clay and clay-polymer composite |
| US8779081B2 (en) * | 2011-03-15 | 2014-07-15 | Sabic Global Technologies B.V. | Process for formation of poly(arylene ethers) with lower fine particle content |
| US8975329B2 (en) * | 2011-12-02 | 2015-03-10 | Sabic Global Technologies B.V. | Poly(phenylene ether) articles and compositions |
| US8674012B1 (en) | 2012-09-07 | 2014-03-18 | Sabic Innovative Plastics Ip B.V. | Poly(phenylene ether) composition, article, and method |
| US8791181B2 (en) | 2012-11-08 | 2014-07-29 | Sabic Innovative Plastics Ip B.V. | Reinforced poly(phenylene ether)-polysiloxane block copolymer composition, and article comprising same |
| US20140357757A1 (en) * | 2013-05-30 | 2014-12-04 | Sabic Global Technologies B.V. | Poly(phenylene ether) composition and article |
| US9193868B1 (en) | 2014-05-06 | 2015-11-24 | Sabic Global Technologies B.V. | Article comprising poly(phenylene ether)-polysiloxane copolymer composition |
| WO2016174534A1 (en) | 2015-04-27 | 2016-11-03 | Sabic Global Technologies B.V. | Poly(phenylene ether) composition and article |
| US10294369B2 (en) * | 2015-05-13 | 2019-05-21 | Sabic Global Technologies B.V. | Reinforced poly(phenylene ether) compositions, and articles prepared therefrom |
| CN105623180B (zh) * | 2016-01-12 | 2018-10-09 | 安徽中鼎橡塑制品有限公司 | 用于电线电缆的无卤阻燃热塑性弹性体材料及其制备方法 |
| CN107236279B (zh) * | 2016-03-28 | 2020-05-05 | 旭化成株式会社 | 聚苯醚系树脂组合物 |
| CN105907019B (zh) * | 2016-04-27 | 2019-03-08 | 安徽中鼎橡塑制品有限公司 | 用于电线电缆的无卤阻燃热塑性弹性体材料及其制备方法 |
| CN112812446B (zh) * | 2020-12-28 | 2022-10-21 | 金发科技股份有限公司 | 一种ppe复合材料及其制备方法和应用 |
| CN114989552B (zh) * | 2022-05-20 | 2023-06-27 | 江西江铜碳纳米材料有限公司 | 基于包覆改性碳素法制备的合金及其制备方法 |
| JP7784524B2 (ja) * | 2022-09-01 | 2025-12-11 | エルジー・ケム・リミテッド | ポリ(アリーレンエーテル)樹脂組成物、その製造方法及びそれを含む成形品 |
| CN117624868B (zh) * | 2023-11-15 | 2025-03-25 | 金发科技股份有限公司 | 一种抗缩痕聚苯醚组合物及其制备方法和应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4283326A (en) * | 1977-07-11 | 1981-08-11 | Gaf Corporation | PBT Molding compositions containing mica and a composite polymer |
| JPS5543169A (en) * | 1978-09-25 | 1980-03-26 | Mitsubishi Gas Chem Co Inc | Fiber-reinforced resin composition containing polyphenylene ether resin |
| US4467057A (en) * | 1978-12-06 | 1984-08-21 | General Electric Company | Modified polyester composition |
| US4404125A (en) * | 1981-10-14 | 1983-09-13 | General Electric Company | Polyphenylene ether resin compositions for EMI electromagnetic interference shielding |
| US4423189A (en) * | 1981-10-28 | 1983-12-27 | General Electric Company | Compositions of a polyphenylene ether resin, low molecular weight polystyrene and a block copolymer |
| US4560715A (en) * | 1983-03-31 | 1985-12-24 | Kuraray Co., Ltd. | Mica flake mass and resin composition with the same incorporated therein |
| NL8301284A (nl) * | 1983-04-12 | 1984-11-01 | Gen Electric | Polymeermengsel dat een polyfenyleenether en eventueel een polystyreen en/of een met rubber gemodificeerd polystyreen bevat en daaruit gevormde voorwerpen. |
| JPS59189170A (ja) * | 1983-04-13 | 1984-10-26 | Polyplastics Co | 成形用熱可塑性樹脂組成物 |
| US4892904A (en) * | 1984-10-09 | 1990-01-09 | General Electric Company | Glass-reinforced blends of polyphenylene ether resin and polyolefin having improved heat distortion temperature |
| DE3445570A1 (de) * | 1984-12-14 | 1986-06-19 | Basf Ag, 6700 Ludwigshafen | Selbstverloeschende thermoplastische polyesterformmassen |
| US4849469A (en) * | 1985-02-28 | 1989-07-18 | Ici Americas Inc. | Void control in thermoplastics containing silicone interpenetrating polymer networks |
| JPH0639568B2 (ja) * | 1985-04-24 | 1994-05-25 | 東レ・ダウコーニング・シリコーン株式会社 | シリコ−ン水性エマルジヨン組成物の製造方法 |
| US4874810A (en) * | 1986-03-07 | 1989-10-17 | General Electric Company | Impact modified polyphenylene ether-polyamide compositions |
| US4816510A (en) * | 1987-08-12 | 1989-03-28 | General Electric Company | Compatible polyphenylene ether-linear polyester blends containing mica reinforcement |
| US4831071A (en) * | 1987-09-21 | 1989-05-16 | Ici Americas Inc. | Enhanced melt extrusion of thermoplastics containing silicone interpenetrating polymer networks |
| JPH02187452A (ja) * | 1988-12-13 | 1990-07-23 | Nippon G Ii Plast Kk | ポリフェニレンエーテル系樹脂およびポリエステルを含む組成物 |
| US5019616A (en) | 1989-05-16 | 1991-05-28 | General Electric Company | Composition comprising a polyphenylene-ether-containing polymeric component and reinforcing fibers |
| JPH03229756A (ja) * | 1989-12-15 | 1991-10-11 | General Electric Co <Ge> | 改善されたメルトフロー値をもつ強化ポリフェニレンエーテル樹脂組成物 |
| JPH0756005B2 (ja) * | 1990-02-28 | 1995-06-14 | 日本ジーイープラスチックス株式会社 | 導電性樹脂組成物 |
-
1992
- 1992-08-07 ES ES92917912T patent/ES2111080T3/es not_active Expired - Lifetime
- 1992-08-07 JP JP5504352A patent/JPH0822945B2/ja not_active Expired - Fee Related
- 1992-08-07 WO PCT/US1992/006597 patent/WO1993004119A1/en not_active Ceased
- 1992-08-07 DE DE69223758T patent/DE69223758T2/de not_active Expired - Lifetime
- 1992-08-07 EP EP92917912A patent/EP0552355B1/en not_active Expired - Lifetime
-
1993
- 1993-01-11 US US08/002,524 patent/US5294654A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69223758T2 (de) | 1998-07-30 |
| JPH06502684A (ja) | 1994-03-24 |
| DE69223758D1 (de) | 1998-02-05 |
| WO1993004119A1 (en) | 1993-03-04 |
| JPH0822945B2 (ja) | 1996-03-06 |
| EP0552355B1 (en) | 1997-12-29 |
| EP0552355A1 (en) | 1993-07-28 |
| US5294654A (en) | 1994-03-15 |
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