ES2115149T3 - Un procedimiento para producir continuamente dioxido de cloro. - Google Patents
Un procedimiento para producir continuamente dioxido de cloro.Info
- Publication number
- ES2115149T3 ES2115149T3 ES94200268T ES94200268T ES2115149T3 ES 2115149 T3 ES2115149 T3 ES 2115149T3 ES 94200268 T ES94200268 T ES 94200268T ES 94200268 T ES94200268 T ES 94200268T ES 2115149 T3 ES2115149 T3 ES 2115149T3
- Authority
- ES
- Spain
- Prior art keywords
- approximately
- chlorine dioxide
- reaction
- chlorate
- procedure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title abstract 8
- 239000004155 Chlorine dioxide Substances 0.000 title abstract 4
- 235000019398 chlorine dioxide Nutrition 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 abstract 6
- 239000002184 metal Substances 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000012431 aqueous reaction media Substances 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C01B11/02—Oxides of chlorine
- C01B11/022—Chlorine dioxide (ClO2)
- C01B11/023—Preparation from chlorites or chlorates
- C01B11/026—Preparation from chlorites or chlorates from chlorate ions in the presence of a peroxidic compound, e.g. hydrogen peroxide, ozone, peroxysulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Treating Waste Gases (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Compounds Of Unknown Constitution (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
LA INVENCION SE REFIERE A UN PROCESO PARA LA PRODUCCION CONTINUA DE DIOXIDO DE CLORO QUE CONSISTE EN HACER REACCIONAR UN CLORATO DE METALES ALCALINOS, ACIDO SULFURICO Y CUALQUIER OTRO ACIDO MINERAL SIN CLORO Y PEROXIDO DE HIDROGENO COMO AGENTE REDUCTOR PARA PRODUCIR DIOXIDO DE CLORO EN UN MEDIO DE REACCION ACUOSO. EL DIOXIDO DE CLORO SE GENERA EN AL MENOS UN PASO DE REACCION QUE COMPRENDE UN RECIPIENTE DE REACCION POR LO MENOS, A BASE DE ALIMENTAR CLORATO DE METALES ALCALINOS, ACIDO, PEROXIDO DE HIDROGENO Y GAS INERTE EN DICHO RECIPIENTE DE REACCION, EN AUSENCIA SUSTANCIALMENTE DE IONES DE CLORURO AÑADIDOS, MANTENER EL MEDIO DE REACCION ACUOSO EN DICHO RECIPIENTE DE REACCION A UNA PRESION ENTRE 400 MM HG APROXIMADAMENTE Y 900 MM HG APROXIMADAMENTE Y A UNA TEMPERATURA ENTRE 35 (GRADOS) C APROXIMADAMENTE Y 100 (GRADOS) C APROXIMADAMENTE Y A UNA ACIDEZ ENTRE 4 APROXIMADAMENTE Y 14 N APROXIMADAMENTE Y LA CONCENTRACION DE CLORATO ENTRE 0,05 MOLES/L APROXIMADAMENTE HASTA LA SATURACION, RETIRAR ELDIOXIDO DE CLORO, EL OXIGENO Y EL GAS INERTE Y EL MEDIO DE REACCION ACUOSO AGOTADO DE DICHA ZONA DE REACCION SIN QUE SE PRODUZCA UNA CRISTALIZACION SUSTANCIAL DEL SULFATO DE METALES ALCALINOS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08023561 US5380517B1 (en) | 1993-02-26 | 1993-02-26 | Process for continuously producing chlorine dioxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2115149T3 true ES2115149T3 (es) | 1998-06-16 |
Family
ID=21815867
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94200268T Expired - Lifetime ES2115149T3 (es) | 1993-02-26 | 1994-02-02 | Un procedimiento para producir continuamente dioxido de cloro. |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5380517B1 (es) |
| EP (1) | EP0612686B1 (es) |
| JP (1) | JP2584718B2 (es) |
| AT (1) | ATE165312T1 (es) |
| AU (1) | AU657648B2 (es) |
| BR (1) | BR9400640A (es) |
| CA (1) | CA2097525C (es) |
| CZ (1) | CZ290914B6 (es) |
| DE (1) | DE69409694T2 (es) |
| ES (1) | ES2115149T3 (es) |
| FI (1) | FI112353B (es) |
| NO (1) | NO314798B1 (es) |
| NZ (1) | NZ250958A (es) |
| RU (1) | RU2089487C1 (es) |
| SE (1) | SE9302279L (es) |
| SK (1) | SK283131B6 (es) |
| ZA (2) | ZA941323B (es) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5855861A (en) * | 1996-02-23 | 1999-01-05 | Water Technologies Limited | Method and apparatus for making aqueous chlorine dioxide |
| CA2267295A1 (en) * | 1996-09-27 | 1998-04-02 | Arthur J. Nonni | Method for producing chlorine dioxide using methanol and hydrogen peroxide as reducing agents |
| CA2268173A1 (en) * | 1996-09-27 | 1998-04-02 | Timothy R. Hammond | Method for producing chlorine dioxide using methanol, chloride, and hydrogen peroxide as reducing agents |
| FI980351L (fi) | 1997-02-19 | 1998-08-20 | Nokia Telecommunications Oy | Solukkoradioaccessverkko sekä sijainninpäivitys langattomassa tietoliikennejärjestelmässä |
| US5895638A (en) * | 1997-03-20 | 1999-04-20 | Akzo Nobel N.V. | Method of producing chlorine dioxide |
| RU2163882C2 (ru) * | 1998-06-09 | 2001-03-10 | Акцо Нобель Н.В. | Способ получения двуокиси хлора |
| US6322768B1 (en) | 1998-09-29 | 2001-11-27 | International Paper Company | Recovery of chlorine dioxide from gas streams |
| US6287533B1 (en) | 1999-09-20 | 2001-09-11 | Mohammed N. I. Khan | Production of chlorine dioxide by chemical reduction of ammonium chlorate in aqueous acidic solution |
| CA2333247C (en) | 2000-02-01 | 2010-07-20 | Sterling Canada, Inc. | A method of improving yield of chlorine dioxide generation processes |
| US6569285B2 (en) | 2000-02-09 | 2003-05-27 | Akzo Nobel N.V. | Process for gas phase pretreating of lignocellulosic containing material |
| AU2001243167A1 (en) | 2000-02-18 | 2001-08-27 | Selective Micro Technologies, Llc | Apparatus and method for controlled delivery of a gas |
| US6607696B1 (en) * | 2000-02-18 | 2003-08-19 | Selective Micro Technologies, Llc | Apparatus and method for controlled delivery of a gas |
| US7922984B2 (en) * | 2000-02-18 | 2011-04-12 | Selective Micro Technologies, Llc | Apparatus and method for controlled delivery of a gas |
| CA2400362C (en) * | 2000-03-17 | 2010-11-09 | Sterling Pulp Chemicals, Ltd. | Advanced control strategies for chlorine dioxide generating processes |
| FI108536B (fi) * | 2000-04-12 | 2002-02-15 | Kemira Chemicals Oy | Menetelmä klooridioksidin valmistamiseksi eri pelkistimien yhteiskäytöllä |
| US6790427B2 (en) | 2001-06-25 | 2004-09-14 | Eka Chemicals, Inc. | Process for producing chlorine dioxide |
| US20030095917A1 (en) * | 2001-07-27 | 2003-05-22 | Debra Wilcox | Chemical composition and process |
| US20030138371A1 (en) * | 2002-01-18 | 2003-07-24 | Cdg Technology, Inc. | Method and apparatus for generating gaseous chlorine dioxide-chlorine mixtures |
| US20040175322A1 (en) * | 2003-03-03 | 2004-09-09 | Woodruff Thomas E. | Process for producing chlorine dioxide |
| US20060034750A1 (en) * | 2004-08-11 | 2006-02-16 | Water Technologies Limited | Chlorine dioxide generator and associated methods |
| BRPI0516016B1 (pt) * | 2004-09-24 | 2018-11-21 | Akzo Nobel Chemicals Int Bv | um processo para a produção de dióxido de cloro |
| US20060067873A1 (en) * | 2004-09-24 | 2006-03-30 | Akzo Nobel N.V. | Process for the production of chlorine dioxide |
| BRPI0518358B1 (pt) * | 2004-12-06 | 2016-09-13 | Akzo Nobel Nv | processo e aparelho para a produção de dióxido de cloro |
| DE602005019778D1 (de) | 2004-12-06 | 2010-04-15 | Akzo Nobel Nv | Chemisches verfahren und produktionseinheit |
| MX2009007470A (es) | 2007-01-12 | 2009-07-22 | Akzo Nobel Nv | Procedimiento para la produccion de dioxido de cloro. |
| TWI447065B (zh) | 2007-07-13 | 2014-08-01 | Akzo Nobel Nv | 二氧化氯之製造方法 |
| US8563046B2 (en) * | 2007-08-23 | 2013-10-22 | Dharma IP, LLC | Compositions, systems, and/or methods involving chlorine dioxide (“ClO2”) |
| CA2726233A1 (en) * | 2008-05-30 | 2009-12-10 | Ken Harrison | Systems, methods, and compositions involving chlorine dioxide and zeolite |
| AU2010261878B2 (en) | 2009-06-16 | 2013-08-01 | Akzo Nobel Chemicals International B.V. | Process for the production of chlorine dioxide |
| EP2526047B1 (en) | 2010-01-18 | 2017-08-23 | Akzo Nobel Chemicals International B.V. | Process for the production of chlorine dioxide |
| MX2012013408A (es) * | 2010-05-19 | 2013-05-20 | Dharma Ip Llc | Composiciones, sistemas y/o metodos que incluyen dioxido de cloro ("cio2"). |
| RU2562997C2 (ru) * | 2010-07-08 | 2015-09-10 | Акцо Нобель Кемикалз Интернэшнл Б.В. | Способ получения диоксида хлора |
| US9567216B2 (en) | 2014-02-12 | 2017-02-14 | Chemtreat, Inc. | Reducing agents for producing chlorine dioxide |
| TWI750330B (zh) | 2017-02-27 | 2021-12-21 | 美商藝康美國公司 | 用於現場產生二氧化氯之方法 |
| WO2018175732A1 (en) | 2017-03-24 | 2018-09-27 | Ecolab USA, Inc. | Low risk chlorine dioxide onsite generation system |
| AR111541A1 (es) | 2017-08-17 | 2019-07-24 | Ecolab Usa Inc | Sistema de generación in situ de dióxido de cloro de bajo riesgo |
| CN108439341A (zh) * | 2018-05-18 | 2018-08-24 | 广西大学 | 一种生产高纯度二氧化氯气体的方法及装置 |
| US11970393B2 (en) | 2018-07-05 | 2024-04-30 | Ecolab Usa Inc. | Decomposition mediation in chlorine dioxide generation systems through sound detection and control |
| WO2022093970A1 (en) | 2020-10-27 | 2022-05-05 | Selective Micro Technologies, Llc | Gas generation apparatus and method utilizing hydrophobic membrane pouch reactor |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2332181A (en) * | 1941-07-15 | 1943-10-19 | Mathieson Alkali Works Inc | Manufacture of chlorine dioxide |
| US2484402A (en) * | 1946-01-04 | 1949-10-11 | Brown Co | Process for producing chlorine dioxide |
| US2833624A (en) * | 1956-10-02 | 1958-05-06 | Du Pont | Production of chlorine dioxide |
| GB1054456A (es) * | 1963-10-10 | |||
| US3341288A (en) * | 1963-12-27 | 1967-09-12 | Hooker Chemical Corp | Production of chlorine dioxide |
| US3563702A (en) * | 1968-03-05 | 1971-02-16 | Hooker Chemical Corp | Production of chlorine dioxide |
| CA1080434A (en) * | 1976-03-19 | 1980-07-01 | Erco Industries Limited | High efficiency chlorine dioxide production using hc1 as acid |
| US4129484A (en) * | 1976-05-11 | 1978-12-12 | Kemanord Ab | Process for regeneration of spent reaction solutions |
| JPS5953205B2 (ja) * | 1981-05-19 | 1984-12-24 | 日本カ−リツト株式会社 | 高純度の二酸化塩素を製造する方法 |
| JPS638203A (ja) * | 1986-06-26 | 1988-01-14 | Japan Carlit Co Ltd:The | 高純度の二酸化塩素を製造する方法 |
| JPH0621005B2 (ja) * | 1989-09-29 | 1994-03-23 | ダイソー株式会社 | 二酸化塩素の製造法 |
| SE500043C2 (sv) * | 1990-08-31 | 1994-03-28 | Eka Nobel Ab | Förfarande för kontinuerlig framställning av klordioxid |
| SE500042C2 (sv) * | 1990-08-31 | 1994-03-28 | Eka Nobel Ab | Förfarande för kontinuerlig framställning av klordioxid |
-
1993
- 1993-02-26 US US08023561 patent/US5380517B1/en not_active Expired - Lifetime
- 1993-06-02 CA CA002097525A patent/CA2097525C/en not_active Expired - Lifetime
- 1993-07-02 SE SE9302279A patent/SE9302279L/ not_active Application Discontinuation
-
1994
- 1994-02-02 EP EP94200268A patent/EP0612686B1/en not_active Revoked
- 1994-02-02 DE DE69409694T patent/DE69409694T2/de not_active Expired - Fee Related
- 1994-02-02 AT AT94200268T patent/ATE165312T1/de not_active IP Right Cessation
- 1994-02-02 ES ES94200268T patent/ES2115149T3/es not_active Expired - Lifetime
- 1994-02-21 AU AU55259/94A patent/AU657648B2/en not_active Expired
- 1994-02-21 SK SK202-94A patent/SK283131B6/sk not_active IP Right Cessation
- 1994-02-21 CZ CZ1994377A patent/CZ290914B6/cs not_active IP Right Cessation
- 1994-02-22 BR BR9400640A patent/BR9400640A/pt not_active IP Right Cessation
- 1994-02-23 FI FI940853A patent/FI112353B/fi not_active IP Right Cessation
- 1994-02-23 NZ NZ250958A patent/NZ250958A/en not_active IP Right Cessation
- 1994-02-24 JP JP6049961A patent/JP2584718B2/ja not_active Expired - Lifetime
- 1994-02-24 NO NO19940639A patent/NO314798B1/no not_active IP Right Cessation
- 1994-02-25 ZA ZA941323A patent/ZA941323B/xx unknown
- 1994-02-25 RU RU9494006021A patent/RU2089487C1/ru active
- 1994-02-25 ZA ZA941322A patent/ZA941322B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO940639D0 (no) | 1994-02-24 |
| SE9302279L (sv) | 1994-08-27 |
| SK283131B6 (sk) | 2003-03-04 |
| FI112353B (fi) | 2003-11-28 |
| EP0612686B1 (en) | 1998-04-22 |
| US5380517A (en) | 1995-01-10 |
| JP2584718B2 (ja) | 1997-02-26 |
| EP0612686A3 (en) | 1994-10-05 |
| BR9400640A (pt) | 1994-09-27 |
| ZA941323B (en) | 1994-09-23 |
| EP0612686A2 (en) | 1994-08-31 |
| AU5525994A (en) | 1994-09-01 |
| DE69409694T2 (de) | 1998-08-27 |
| NO314798B1 (no) | 2003-05-26 |
| US5380517B1 (en) | 1999-01-19 |
| CA2097525C (en) | 2000-05-02 |
| AU657648B2 (en) | 1995-03-16 |
| FI940853A7 (fi) | 1994-08-27 |
| CZ37794A3 (en) | 1994-09-14 |
| CA2097525A1 (en) | 1994-08-27 |
| SK20294A3 (en) | 1994-10-05 |
| ZA941322B (en) | 1994-09-23 |
| FI940853A0 (fi) | 1994-02-23 |
| DE69409694D1 (de) | 1998-05-28 |
| NZ250958A (en) | 1994-12-22 |
| CZ290914B6 (cs) | 2002-11-13 |
| SE9302279D0 (sv) | 1993-07-02 |
| ATE165312T1 (de) | 1998-05-15 |
| JPH06263407A (ja) | 1994-09-20 |
| RU2089487C1 (ru) | 1997-09-10 |
| NO940639L (no) | 1994-08-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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