ES2096176T3 - Iniciadores de la polimerizacion anionica y productos de los mismos de histeresis reducida. - Google Patents

Iniciadores de la polimerizacion anionica y productos de los mismos de histeresis reducida.

Info

Publication number
ES2096176T3
ES2096176T3 ES93116622T ES93116622T ES2096176T3 ES 2096176 T3 ES2096176 T3 ES 2096176T3 ES 93116622 T ES93116622 T ES 93116622T ES 93116622 T ES93116622 T ES 93116622T ES 2096176 T3 ES2096176 T3 ES 2096176T3
Authority
ES
Spain
Prior art keywords
products
polymer
anionic polymerization
sol
lithium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93116622T
Other languages
English (en)
Inventor
Takashi Kitamura
David F Lawson
Koichi Morita
Yoichi Ozawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Application granted granted Critical
Publication of ES2096176T3 publication Critical patent/ES2096176T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Tires In General (AREA)

Abstract

LA PRESENTE INVENCION SE DIRIGE A POLIMERIZACION ANIONICA QUE EMPLEA AMINAS DE LITIO MEZCLADAS CON UN COMPUESTO METALICO ALCALINO ORGANICO Y OPCIONALMENTE, UN QUELATO REACTIVO. LAS AMINAS DE LITIO TIENEN LA FORMULA GENERAL (A)LI(SOL)Y, DONDE SOL ES UN COMPONENTE SOLUBILIZADO, A ES UN ALQUILO, DIALQUILO, RADICAL AMINA CICLOALQUILO O DICICLOALQUILO O UNA AMINA CICLICA, E Y ES 0 O ES DESDE ALREDEDOR DE 0,5 A ALREDEDOR DE 3. LA INVENCION TAMBIEN SE DIRIGE HACIA POLIMEROS Y OTROS PRODUCTOS HECHOS USANDO EL INICIADOR, Y METODOS PARA ELLO. ADEMAS, LA INVENCION CONTEMPLA UN POLIMERO, UNA COMPOSICION POLIMERA Y PRODUCTOS DE ELLOS, LOS CUALES INCLUYEN UN GRUPO FUNCIONAL DEL PRODUCTO DE REACCION DE UNA AMINA Y UN COMPUESTO ORGANO-LITIO. LOS POLIMEROS RESULTANTES PUEDEN SER TERMINADOS CON UN AGENTE DE TERMINACION, ACOPLAMIENTO O ENLACE, EL CUAL PUEDE PROPORCIONAR EL POLIMERO CON MULTIFUNCIONALIDAD.
ES93116622T 1992-10-16 1993-10-14 Iniciadores de la polimerizacion anionica y productos de los mismos de histeresis reducida. Expired - Lifetime ES2096176T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/962,373 US5393721A (en) 1992-10-16 1992-10-16 Anionic polymerization initiators and reduced hysteresis products therefom

Publications (1)

Publication Number Publication Date
ES2096176T3 true ES2096176T3 (es) 1997-03-01

Family

ID=25505762

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93116622T Expired - Lifetime ES2096176T3 (es) 1992-10-16 1993-10-14 Iniciadores de la polimerizacion anionica y productos de los mismos de histeresis reducida.

Country Status (6)

Country Link
US (1) US5393721A (es)
EP (1) EP0593049B1 (es)
JP (4) JPH06199923A (es)
CA (1) CA2108514C (es)
DE (1) DE69307086T2 (es)
ES (1) ES2096176T3 (es)

Families Citing this family (94)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5519086A (en) * 1991-12-30 1996-05-21 Bridgestone Corporation Low-hysteresis elastomer compositions using amino-substituted aryllithium polymerization initiators
US5523371A (en) * 1991-12-30 1996-06-04 Bridgestone Corporation Functionalized polymer of improved hysteresis properties prepared using amino-substituted aryllithium polymerization initiators
US5552473A (en) * 1992-10-02 1996-09-03 Bridgestone Corporation Functionalized polymer and rubber compositions produced from solubilized anionic polymerization initiators
US6025450A (en) * 1992-10-02 2000-02-15 Bridgestone Corporation Amine containing polymers and products therefrom
US5674798A (en) * 1992-10-16 1997-10-07 Bridgestone Corporation Hydrocarbon soluble anionic polymerization initiators
US5393721A (en) * 1992-10-16 1995-02-28 Bridgestone Corporation Anionic polymerization initiators and reduced hysteresis products therefom
ES2110557T3 (es) * 1992-10-30 1998-02-16 Bridgestone Corp Iniciadores de polimerizacion anionica solubles y productos de aquellos.
US5643848A (en) * 1992-10-30 1997-07-01 Bridgestone Corporation Soluble anionic polymerization initiators and products therefrom
DE69423375T2 (de) * 1993-01-29 2000-10-12 Bridgestone Corp., Tokio/Tokyo Herstellung eines Polymers oder Copolymers eines Diolefins und dieses Polymer oder Copolymer enthaltende Zusammensetzung
US5491230A (en) * 1993-12-29 1996-02-13 Bridgestone Corporation Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom
US6160054A (en) * 1995-05-08 2000-12-12 Fmc Corporation Hetero-telechelic polymers and processes for making same
US5821307A (en) * 1994-05-13 1998-10-13 Fmc Corporation Functionalized chain extended initiators for anionic polymerization
US6197891B1 (en) 1994-05-13 2001-03-06 Fmc Corporation Functionalized chain extended initiators for anionic polymerization
US5521309A (en) * 1994-12-23 1996-05-28 Bridgestone Corporation Tertiary-amino allyl-or xylyl-lithium initiators and method of preparing same
US6080835A (en) 1995-02-01 2000-06-27 Bridgestone Corporation Aminoalkyllithium compounds containing cyclic amines and polymers therefrom
US5496940A (en) * 1995-02-01 1996-03-05 Bridgestone Corporation Alkyllithium compounds containing cyclic amines and their use in polymerization
US5610227A (en) * 1995-06-07 1997-03-11 Bridgestone/Firestone, Inc. Lithium amino magnesiate polymerization initiators and elastomers having reduced hysteresis
US5922810A (en) * 1995-07-31 1999-07-13 Fmc Corporation Deprotection of protected functional polymers
US5919870A (en) * 1995-07-31 1999-07-06 Fmc Corporation Functional telechelic star polymers
US5798418A (en) * 1995-07-31 1998-08-25 Fmc Corporation Star polymers from mixed initiators
AU6643196A (en) * 1995-08-04 1997-03-05 Fmc Corporation Telechelic polystyrene/polyethylene copolymers and processes for making same
US5677402A (en) * 1995-09-22 1997-10-14 The Goodyear Tire & Rubber Company Process for preparing 3,4-polyisoprene rubber
US5534592A (en) * 1995-09-22 1996-07-09 The Goodyear Tire & Rubber Company High performance blend for tire treads
US5780551A (en) * 1995-11-02 1998-07-14 Fmc Corporation Telechelic polymers from mixed initiator
US5679751A (en) * 1996-02-12 1997-10-21 The Goodyear Tire & Rubber Company Solution polymerization process for synthesis of styrene-butadiene or styrene-isoprene rubber
DE69712962T2 (de) 1996-03-29 2002-11-14 Bridgestone Corp., Tokio/Tokyo Styrol-Butadien-Copolymer und dieses Copolymer enthaltende Gummimischung
US5965681A (en) * 1996-06-18 1999-10-12 Fmc Corporation Protected functionalized telechelic polymers and processes for making the same
AU3641897A (en) 1996-07-17 1998-02-09 Conrad W Kamienski Protected functionalized heterotelechelic polymers and processes for preparing the same
US5866650A (en) * 1997-07-11 1999-02-02 Bridgestone Corporation Composition of cyclic amine-initiated elastomers and amorphous silica and process for the production thereof
US6252007B1 (en) * 1997-07-11 2001-06-26 Bridgestone Corporation Elastomers having a reduced hysteresis via interaction of polymer with silica surfaces
US5916961A (en) * 1997-07-11 1999-06-29 Bridgestone Corporation Amine-initiated elastomers having hysteresis reducing interaction with silica
US6153706A (en) * 1997-07-30 2000-11-28 Fmc Corporation Protected multi-functionalized star polymers and processes for making the same
DE69822278T2 (de) * 1997-12-16 2004-08-12 Jsr Corp. Kautschuk aus einem konjugierten Diolefin -Copolymer und dessen Zusammensetzungen
US6362272B1 (en) 1998-10-07 2002-03-26 Jsr Corporation Oil extended rubber and rubber composition
US7723440B2 (en) * 2002-08-30 2010-05-25 Bridgestone Corporation Functionalized polymers and improved vulcanizates therefrom
JP5066338B2 (ja) * 2003-03-28 2012-11-07 株式会社ブリヂストン 変性共役ジエン系重合体を用いたゴム組成物及びタイヤ
TWI385182B (zh) 2004-03-15 2013-02-11 Jsr Corp Conjugated diene (co) poly rubber and method for producing the same
JP4628009B2 (ja) * 2004-04-09 2011-02-09 株式会社ブリヂストン ゴム組成物及びそれを用いたタイヤ
US7671139B1 (en) 2004-06-18 2010-03-02 Bridgestone Corporation Functionalized polymers and tires made therefrom
JP2008509254A (ja) * 2004-08-05 2008-03-27 ファイヤーストーン ポリマーズ エルエルシー 機能性マルチブロックポリマーの単一工程合成
CN101040007A (zh) * 2004-10-02 2007-09-19 费尔斯通聚合物有限责任公司 聚合物及其在沥青组合物和沥青混凝土中的用途
US7868081B2 (en) 2005-03-04 2011-01-11 Bridgestone Corporation Rubber composition and tire using same
JP5350577B2 (ja) 2005-09-15 2013-11-27 株式会社ブリヂストン ゴム組成物およびそれを用いたタイヤ
US7875671B2 (en) 2006-08-03 2011-01-25 Bridgestone Corporation Process for preparing filler-dispersed polymeric compositions
WO2008045372A2 (en) * 2006-10-06 2008-04-17 Bridgestone Corporation Branched polymers and methods for their synthesis and use
ZA200711159B (en) 2006-12-28 2009-03-25 Bridgestone Corp Amine-containing alkoxysilyl-functionalized polymers
US8022129B2 (en) * 2007-03-15 2011-09-20 Jsr Corporation Conjugated diolefin copolymer rubber, method for producing the same, rubber composition and tire
WO2008130695A1 (en) 2007-04-20 2008-10-30 Heritage Research Group Polymer-modified asphalt compositions
US7829624B2 (en) 2007-06-29 2010-11-09 Bridgestone Corporation One-pot synthesis of nanoparticles and liquid polymer for rubber applications
US8314189B2 (en) 2007-10-12 2012-11-20 Bridgestone Corporation Polymers functionalized with heterocyclic nitrile compounds
US20090326176A1 (en) * 2007-12-28 2009-12-31 Yuan-Yong Yan Novel multifunctional initiators for anionic polymerization and polymers therefrom
FR2930554B1 (fr) 2008-04-29 2012-08-17 Michelin Soc Tech Melange elastomerique comprenant majoritairement un elastomere dienique couple par un groupe amino-alcoxysilane, composition de caoutchouc le comprenant et leurs procedes d'obtention.
HUE029872T2 (en) 2008-06-06 2017-04-28 Trinseo Europe Gmbh Modified elastomeric polymers
US9732178B1 (en) 2008-07-24 2017-08-15 Bridgestone Corporation Block copolymers including high vinyl segments
US20110196063A1 (en) * 2008-10-08 2011-08-11 Bridgestone Corporation Rubber composition for tread and tire using the rubber composition
FR2940294B1 (fr) 2008-12-23 2011-02-18 Michelin Soc Tech Nouveau systeme d'amorcage pour polymerisation anionique de dienes conjugues, procede de preparation d'elastomeres dieniques.
EP2476710B1 (en) * 2009-10-14 2015-03-18 Nippon Soda Co., Ltd. Method for producing polybutadiene
PL2516478T3 (pl) 2009-12-21 2014-11-28 Trinseo Europe Gmbh Modyfikowane kompozycje polimerowe
WO2011079922A1 (en) 2009-12-21 2011-07-07 Styron Europe Gmbh Modified polymer compositions
US8338544B2 (en) 2009-12-21 2012-12-25 Bridgestone Corporation Polymers functionalized with polyoxime compounds and methods for their manufacture
EP2516410B1 (en) 2009-12-22 2014-04-23 Bridgestone Corporation Improved vinyl modifier composition and processes for utilizing such composition
WO2011091346A2 (en) 2010-01-22 2011-07-28 Bridgestone Corporation Polymers functionalized with nitrile compounds containing a protected amino group
FR2962729B1 (fr) 2010-07-13 2012-09-21 Arkema France Molecules porteuses de groupes associatifs
FR2962733B1 (fr) 2010-07-13 2012-08-17 Michelin Soc Tech Polymere greffe par des molecules associatives azotees.
US8748531B2 (en) 2010-12-10 2014-06-10 Bridgestone Corporation Polymers functionalized with oxime compounds containing an acyl group
US8962745B2 (en) 2010-12-27 2015-02-24 Bridgestone Corporation Functionalized polymers and vulcanizates with reduced hysteretic loss
WO2012135451A2 (en) 2011-03-29 2012-10-04 Bridgestone Corporation Polymers functionalized with a carboxylic or thiocarboxylic ester containing a silylated amino group
JP5866155B2 (ja) * 2011-07-25 2016-02-17 旭化成ケミカルズ株式会社 共役ジエン系重合体、その製造方法、及び共役ジエン系重合体組成物
US9000070B2 (en) 2011-10-19 2015-04-07 Bridgestone Corporation Mixing of telechelic rubber formulations
US9458270B2 (en) 2011-11-18 2016-10-04 Bridgestone Corporation Method for producing polydienes and polydiene copolymers with reduced cold flow
US9512263B2 (en) 2011-12-09 2016-12-06 Bridgestone Corporation Method for producing polydienes and polydiene copolymers with reduced cold flow
US8685513B1 (en) 2012-02-29 2014-04-01 Carolyn M. Dry Inflatable articles comprising a self-repairing laminate
US9694629B1 (en) 2012-02-29 2017-07-04 Carolyn Dry Self-repairing inflatable articles incorporating an integrated self-repair system
SG11201407010RA (en) 2012-05-01 2014-11-27 Bridgestone Corp Polydienes and diene copolymers having organophosphine functionality
US9469706B2 (en) 2012-06-08 2016-10-18 Bridgestone Corporation Polymers functionalized with unsaturated heterocycles containing a protected amino group
WO2014074872A1 (en) 2012-11-09 2014-05-15 Bridgestone Corporation Uses of biobased styryene
US9127092B2 (en) 2012-12-31 2015-09-08 Bridgestone Corporation Method for producing polydienes and polydiene copolymers with reduced cold flow
US9663637B2 (en) 2012-12-31 2017-05-30 Bridgestone Corporation Polymers functionalized with unsaturated heterocycles containing an azolinyl group
US9315599B2 (en) 2013-01-02 2016-04-19 Bridgestone Corporation Functionalized polymers
SG11201507489VA (en) 2013-03-15 2015-10-29 Bridgestone Corp Polymers functionalized with heterocyclic imines
KR102456909B1 (ko) 2013-10-02 2022-10-21 가부시키가이샤 브리지스톤 시아노 기를 함유하는 이민 화합물로 작용화된 중합체
EP3080167B1 (en) 2013-12-12 2024-12-04 Firestone Polymers, LLC Method for producing polymeric compositions including functionalized polymers
US10030083B2 (en) 2014-05-15 2018-07-24 Bridgestone Corporation Polymers functionalized with protected oxime compounds containing a cyano group
CN107567464B (zh) 2014-10-07 2020-04-14 株式会社普利司通 用于生产冷流性降低的聚二烯和聚二烯共聚物的方法
US10077323B2 (en) 2015-07-24 2018-09-18 Bridgestone Corporation Polymers functionalized with imine compounds containing a protected thiol group
EP3328919B1 (en) 2015-07-29 2021-03-10 Bridgestone Corporation Processes for preparing functionalized polymers, related functionalizing compound and preparation thereof
US10519266B2 (en) 2015-09-23 2019-12-31 Bridgestone Corporation Polydienes and diene copolymers using 1,1-bis(hydrocarbylthio)hydrocarbyl-1-ene compounds
WO2018016985A1 (en) 2016-07-22 2018-01-25 Public Joint Stock Company "Sibur Holding" A method for producing branched modified rubber and a rubber composition comprising branched modified rubber prepared by the method, and use thereof
CN109563196B (zh) 2016-07-22 2021-07-27 公共型股份公司希布尔控股 通过阴离子溶液聚合来生产改性橡胶的方法、包含所述橡胶的橡胶组合物及其用途
EP3724246B1 (en) 2017-12-14 2023-05-31 Bridgestone Corporation Coupled polymer products, methods of making and compositions containing
CN111630075B (zh) 2017-12-15 2023-04-28 株式会社普利司通 官能化聚合物、用于制备该官能化聚合物的方法和含有该官能化聚合物的橡胶组合物
US12054573B2 (en) 2020-02-05 2024-08-06 Bridgestone Corporation Functionalized polymers having thermoresponsive behavior
EP4148075A4 (en) * 2020-05-21 2023-11-08 China Petroleum & Chemical Corporation LIQUID BUTYLBENZENE POLYMER, PRODUCTION PROCESS THEREOF AND APPLICATION THEREOF, AS WELL AS COMPOSITION, POLYMER COATING, ADHESIVE AND CROSSLINKING AGENT
EP4263621A1 (en) 2020-12-18 2023-10-25 Bridgestone Corporation Tire rubber compositions combining bagasse-containing guayule rubber with silane and related methods

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2849432A (en) * 1956-02-06 1958-08-26 Firestone Tire & Rubber Co Polymerization of diolefines
US3317918A (en) * 1956-08-21 1967-05-02 Firestone Tire & Rubber Co Butadiene polymers prepared with a lithium based catalyst characterized by having at least 29 percent of the butadiene as cis-1, 4
US3290277A (en) * 1963-05-20 1966-12-06 Shell Oil Co Amino-containing block polymers of ethylene and alpha-alkyl styrene
US3331821A (en) * 1963-11-14 1967-07-18 Phillips Petroleum Co Catalyst composition and process of preparing conjugated diene polymers utilizing same
DE1300240B (de) * 1964-01-22 1969-07-31 Bayer Ag Verfahren zur Herstellung von Polymerisaten konjugierter Diolefine
DE2355941A1 (de) * 1973-11-09 1975-05-15 Bayer Ag Polymerisation und copolymerisation von dienen
US4015061A (en) * 1975-02-14 1977-03-29 The Firestone Tire & Rubber Company Protected amino-functional initiators and amino-terminated polymers and their production
US4316001A (en) * 1976-05-26 1982-02-16 Societe Nationale Des Poudres Et Explosifs Anionic polymerization of heterocyclic monomers with alkali metal amide hydroxylated compound initiator
JPS5465788A (en) * 1977-11-07 1979-05-26 Denki Kagaku Kogyo Kk Preparation of copolymer
JPS57180615A (en) * 1981-04-30 1982-11-06 Sumitomo Chem Co Ltd Production of diene polymer having polymodal molecular weight distribution
JPS5884809A (ja) * 1981-11-16 1983-05-21 Japan Synthetic Rubber Co Ltd スチレン−ブタジエン共重合体の製造方法
JPS58154703A (ja) * 1982-03-09 1983-09-14 Daicel Chem Ind Ltd 光学活性な高分子の合成方法
JPS59164308A (ja) * 1983-03-09 1984-09-17 Asahi Chem Ind Co Ltd ポリエチレンの製造方法
FR2567135B1 (fr) * 1984-07-03 1989-01-13 Asahi Chemical Ind Polymere ou copolymere de butadiene et procede de preparation
US4616069A (en) * 1984-10-26 1986-10-07 Nippon Zeon Co., Ltd. Process for making diene polymer rubbers
DE3650721T2 (de) * 1985-10-11 2000-02-17 Asahi Kasei Kogyo K.K., Osaka Endmodifizierte Blockcopolymere enthaltende Zusammensetzungen
JPH0798880B2 (ja) * 1987-09-11 1995-10-25 株式会社ブリヂストン 空気入りタイヤ
US4935471A (en) * 1987-10-15 1990-06-19 The Goodyear Tire & Rubber Company Capped polydienes
CA1322750C (en) * 1987-12-17 1993-10-05 Mitsui Toatsu Chemicals, Inc. Preparation process of unsaturated carboxylic acid amide
US5149457A (en) * 1989-06-30 1992-09-22 Cyprus Foote Mineral Company Stable mixed lithium amide reagent compositions
US5153159A (en) * 1990-04-09 1992-10-06 Bridgestone/Firestone, Inc. Elastomers and products having reduced hysteresis
US5112929A (en) * 1991-04-05 1992-05-12 Bridgestone Corporation Oxolanyl cyclic acetals as anionic polymerization modifiers
US5332810A (en) * 1992-10-02 1994-07-26 Bridgestone Corporation Solubilized anionic polymerization initiator and preparation thereof
US5393721A (en) * 1992-10-16 1995-02-28 Bridgestone Corporation Anionic polymerization initiators and reduced hysteresis products therefom

Also Published As

Publication number Publication date
DE69307086T2 (de) 1997-05-07
CA2108514C (en) 2008-01-29
JPH06199923A (ja) 1994-07-19
JP2007070642A (ja) 2007-03-22
JP2007262420A (ja) 2007-10-11
DE69307086D1 (de) 1997-02-13
US5393721A (en) 1995-02-28
JP2004124105A (ja) 2004-04-22
EP0593049B1 (en) 1997-01-02
CA2108514A1 (en) 1994-04-17
EP0593049A1 (en) 1994-04-20

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