ES2175954T3 - Solucion y procedimiento para el tratamiento preliminar de superficies de cobre. - Google Patents

Solucion y procedimiento para el tratamiento preliminar de superficies de cobre.

Info

Publication number
ES2175954T3
ES2175954T3 ES99908756T ES99908756T ES2175954T3 ES 2175954 T3 ES2175954 T3 ES 2175954T3 ES 99908756 T ES99908756 T ES 99908756T ES 99908756 T ES99908756 T ES 99908756T ES 2175954 T3 ES2175954 T3 ES 2175954T3
Authority
ES
Spain
Prior art keywords
acids
copper surfaces
acid
selenium
heterocycle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES99908756T
Other languages
English (en)
Inventor
Udo Grieser
Heinrich Meyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Atotech Deutschland GmbH and Co KG
Original Assignee
Atotech Deutschland GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19830038A external-priority patent/DE19830038C2/de
Application filed by Atotech Deutschland GmbH and Co KG filed Critical Atotech Deutschland GmbH and Co KG
Application granted granted Critical
Publication of ES2175954T3 publication Critical patent/ES2175954T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00—Etching metallic material by chemical means
    • C23F1/10—Etching compositions
    • C23F1/14—Aqueous compositions
    • C23F1/16—Acidic compositions
    • C23F1/18—Acidic compositions for etching copper or alloys thereof
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • C23C22/52—Treatment of copper or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/82—After-treatment
    • C23C22/83—Chemical after-treatment
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00—Apparatus or processes for manufacturing printed circuits
    • H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
    • H05K3/382—Improvement of the adhesion between the insulating substrate and the metal by special treatment of the metal
    • H05K3/383—Improvement of the adhesion between the insulating substrate and the metal by special treatment of the metal by microetching
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00—Apparatus or processes for manufacturing printed circuits
    • H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
    • H05K3/389—Improvement of the adhesion between the insulating substrate and the metal by the use of a coupling agent, e.g. silane
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/07—Treatments involving liquids, e.g. plating, rinsing
    • H05K2203/0779—Treatments involving liquids, e.g. plating, rinsing characterised by the specific liquids involved
    • H05K2203/0786—Using an aqueous solution, e.g. for cleaning or during drilling of holes
    • H05K2203/0796—Oxidant in aqueous solution, e.g. permanganate
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
    • H05K2203/12—Using specific substances
    • H05K2203/122—Organic non-polymeric compounds, e.g. oil, wax or thiol
    • H05K2203/124—Heterocyclic organic compounds, e.g. azole, furan
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00—Apparatus or processes for manufacturing printed circuits
    • H05K3/46—Manufacturing multilayer circuits
    • H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing Of Printed Wiring (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Chemical Treatment Of Metals (AREA)
  • ing And Chemical Polishing (AREA)
  • Production Of Multi-Layered Print Wiring Board (AREA)

Abstract

Solución para el tratamiento preliminar de superficies de cobre para la formación posterior de una unión adhesiva rme entre las superficies de cobre y los sustratos de material plástico, que contiene a. Peróxido de hidrógeno, b. al menos un ácido y c. al menos un compuesto heterocíclico de cinco miembros que contiene nitrógeno, que no contiene ningún átomo de azufre, selenio o telurio en el heterociclo, que se caracteriza por que d. adicionalmente al menos se incluye un compuesto adherente del grupo de ácidos sulfínico, selénico, telúrico, compuestos heterocíclicos que contienen al menos un átomo de sulfuro, selenio y/o telurio en el heterociclo, así como sales de sulfonio, selenio y telurio, donde las sales de telurio, selenio y sulfonio serán compuestos con la fórmula general I **fórmula** en la cual A = S, Se ó Te, R1, R2 y R3 =alquilo, alquilo sustituido, alquenilo, fenilo, fenilo sustituido, benzilo, cicloalquilo, cicloalquilo sustituido, siendo R1, R2 y R3 iguales o diferentes y X = anión de un ácido orgánico o inorgánico o bien hidróxido, teniendo en cuenta que el ácido seleccionado para el componente b no es idéntico a los ácidos sulfínico, selénico o telúrico seleccionados para el componente d.
ES99908756T 1998-02-03 1999-01-25 Solucion y procedimiento para el tratamiento preliminar de superficies de cobre. Expired - Lifetime ES2175954T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19806190 1998-02-03
DE19830038A DE19830038C2 (de) 1998-02-03 1998-06-26 Lösung und Verfahren zum Vorbehandeln von Kupferoberflächen

Publications (1)

Publication Number Publication Date
ES2175954T3 true ES2175954T3 (es) 2002-11-16

Family

ID=26043882

Family Applications (1)

Application Number Title Priority Date Filing Date
ES99908756T Expired - Lifetime ES2175954T3 (es) 1998-02-03 1999-01-25 Solucion y procedimiento para el tratamiento preliminar de superficies de cobre.

Country Status (8)

Country Link
US (1) US6562149B1 (es)
EP (1) EP1051888B1 (es)
JP (1) JP4644365B2 (es)
AT (1) ATE215299T1 (es)
CA (1) CA2318784A1 (es)
ES (1) ES2175954T3 (es)
TW (1) TW460622B (es)
WO (1) WO1999040764A1 (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6117250A (en) * 1999-02-25 2000-09-12 Morton International Inc. Thiazole and thiocarbamide based chemicals for use with oxidative etchant solutions
US7351353B1 (en) 2000-01-07 2008-04-01 Electrochemicals, Inc. Method for roughening copper surfaces for bonding to substrates
DE10034022C2 (de) * 2000-07-07 2003-05-08 Atotech Deutschland Gmbh Saure Behandlungsflüssigkeit und deren Verwendung sowie Verfahren zum Behandeln von Kupferoberflächen
DE10066028C2 (de) * 2000-07-07 2003-04-24 Atotech Deutschland Gmbh Kupfersubstrat mit aufgerauhten Oberflächen
US6506314B1 (en) * 2000-07-27 2003-01-14 Atotech Deutschland Gmbh Adhesion of polymeric materials to metal surfaces
US6716281B2 (en) 2002-05-10 2004-04-06 Electrochemicals, Inc. Composition and method for preparing chemically-resistant roughened copper surfaces for bonding to substrates
US6969638B2 (en) * 2003-06-27 2005-11-29 Texas Instruments Incorporated Low cost substrate for an integrated circuit device with bondpads free of plated gold
US7232478B2 (en) * 2003-07-14 2007-06-19 Enthone Inc. Adhesion promotion in printed circuit boards
US20050067378A1 (en) * 2003-09-30 2005-03-31 Harry Fuerhaupter Method for micro-roughening treatment of copper and mixed-metal circuitry
US7078809B2 (en) * 2003-12-31 2006-07-18 Dynacraft Industries Sdn. Bhd. Chemical leadframe roughening process and resulting leadframe and integrated circuit package
WO2006110279A1 (en) * 2005-04-08 2006-10-19 Sachem, Inc. Selective wet etching of metal nitrides
ATE445031T1 (de) 2006-02-17 2009-10-15 Atotech Deutschland Gmbh Zusammensetzung und verfahren zur behandlung der oberflächen von kupferlegierungen, um die haftfähigkeit zwischen der metalloberfläche und dem gebundenen polymerischen material zu verbessern
JP5620365B2 (ja) † 2008-03-21 2014-11-05 エンソン インコーポレイテッド 多官能分子システムを用いた積層体への金属の接着促進
EP2240005A1 (en) 2009-04-09 2010-10-13 ATOTECH Deutschland GmbH A method of manufacturing a circuit carrier layer and a use of said method for manufacturing a circuit carrier
US8512504B2 (en) * 2009-05-06 2013-08-20 Steven A. Castaldi Process for improving adhesion of polymeric materials to metal surfaces
CN102822390B (zh) * 2010-05-26 2014-11-26 安美特德国有限公司 用于铜和铜合金微蚀刻的组合物和方法
EP2453041B1 (en) 2010-11-10 2014-02-12 Atotech Deutschland GmbH Solution and process for the pre-treatment of copper surfaces using an N-alkoxylated adhesion-promoting compound
US9338896B2 (en) * 2012-07-25 2016-05-10 Enthone, Inc. Adhesion promotion in printed circuit boards
CN109851539A (zh) * 2017-11-30 2019-06-07 罗门哈斯电子材料有限责任公司 盐和包含其的光致抗蚀剂
EP4279634A1 (en) * 2022-05-17 2023-11-22 Atotech Deutschland GmbH & Co. KG Method for nano etching of copper and copper alloy surfaces

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3645772A (en) 1970-06-30 1972-02-29 Du Pont Process for improving bonding of a photoresist to copper
JPS5221460B1 (es) 1971-04-26 1977-06-10
BE791457A (fr) 1971-11-18 1973-05-16 Du Pont Solutions acides stabilisees d'eau oxygenee
SE400575B (sv) 1974-12-13 1978-04-03 Nordnero Ab Bad for betning av koppar och dess legeringar
US4140646A (en) 1977-11-08 1979-02-20 Dart Industries Inc. Dissolution of metals with a selenium catalyzed H2 O2 -H2 SO4 etchant containing t-butyl hydroperoxide
US4158593A (en) 1977-11-08 1979-06-19 Dart Industries Inc. Dissolution of metals utilizing a H2 O2 -sulfuric acid solution catalyzed with selenium compounds
US4373744A (en) 1980-01-23 1983-02-15 Lucas Industries Limited Suspension control system for a road vehicle
US4784785A (en) * 1987-12-29 1988-11-15 Macdermid, Incorporated Copper etchant compositions
EP0342669B1 (en) 1988-05-20 1995-08-23 Mitsubishi Gas Chemical Company, Inc. Method for preparing thin copper foil-clad substrate for circuit boards
US4915781A (en) * 1988-07-27 1990-04-10 E. I. Du Pont De Nemours And Company Stabilized hydrogen peroxide compositions
JP3332047B2 (ja) * 1993-07-22 2002-10-07 三菱瓦斯化学株式会社 内層銅箔の処理方法
JP3880636B2 (ja) 1994-01-10 2007-02-14 味の素株式会社 発酵法によるｌ−グルタミン酸の製造法
JP2781954B2 (ja) * 1994-03-04 1998-07-30 メック株式会社 銅および銅合金の表面処理剤
JPH0897559A (ja) * 1994-09-26 1996-04-12 Okuno Chem Ind Co Ltd 多層プリント配線板の内層用回路板の銅箔処理方法、及び該内層用回路板の銅箔処理液
JPH0897599A (ja) 1994-09-28 1996-04-12 Fuji Xerox Co Ltd 混成集積回路基板端子の保持治具
GB9425090D0 (en) * 1994-12-12 1995-02-08 Alpha Metals Ltd Copper coating
JPH11140669A (ja) * 1997-11-04 1999-05-25 Ebara Densan Ltd エッチング液

Also Published As

Publication number Publication date
CA2318784A1 (en) 1999-08-12
JP4644365B2 (ja) 2011-03-02
TW460622B (en) 2001-10-21
WO1999040764A1 (de) 1999-08-12
JP2002503040A (ja) 2002-01-29
EP1051888B1 (de) 2002-03-27
ATE215299T1 (de) 2002-04-15
HK1030717A1 (en) 2001-05-11
US6562149B1 (en) 2003-05-13
EP1051888A1 (de) 2000-11-15

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