ES2189388T3 - Sistema de catalizador, procedimiento para su obtencion y utilizacion del mismo para la polimerizacion de olefinas. - Google Patents
Sistema de catalizador, procedimiento para su obtencion y utilizacion del mismo para la polimerizacion de olefinas.Info
- Publication number
- ES2189388T3 ES2189388T3 ES99904880T ES99904880T ES2189388T3 ES 2189388 T3 ES2189388 T3 ES 2189388T3 ES 99904880 T ES99904880 T ES 99904880T ES 99904880 T ES99904880 T ES 99904880T ES 2189388 T3 ES2189388 T3 ES 2189388T3
- Authority
- ES
- Spain
- Prior art keywords
- group
- same
- different
- catalyst system
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 4
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000004429 atom Chemical group 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 abstract 1
- 101100058670 Aeromonas hydrophila subsp. hydrophila (strain ATCC 7966 / DSM 30187 / BCRC 13018 / CCUG 14551 / JCM 1027 / KCTC 2358 / NCIMB 9240 / NCTC 8049) bsr gene Proteins 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- 125000004104 aryloxy group Chemical group 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000003426 co-catalyst Substances 0.000 abstract 1
- 229910052732 germanium Inorganic materials 0.000 abstract 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 125000002950 monocyclic group Chemical group 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- -1 o- phenylene Chemical group 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000011135 tin Substances 0.000 abstract 1
- 229910052718 tin Inorganic materials 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Sistema de catalizador que contiene a) por lo menos un soporte, b) por lo menos un co-catalizador, c) una mezcla de isómeros rac y meso de por lo menos un metaloceno de la fórmula (I) en la que R1 y R2 son iguales o distintos y significan un átomo de hidrógeno o un grupo hidrocarburo C1-C20, con la limitación de que R1 no sea metilo cuando R2 es hidrógeno, M1 es un metal de transición del grupo 4, 5 ó 6 del Sistema Periódico de Elementos, A es un eslabón de la fórmula o =BR3, AlR3, -S-, -SO-, -SO2-, =NR3, =PR3, =P(O)R3, o- fenileno, 2, 2''-bifenileno, en las que M2 es carbono, silicio, germanio, estaño, nitrógeno o fósforo, "o" es el número 1, 2, 3 ó 4, R3 y R4, con independencia entre sí, son iguales o distintos y significan un átomo de hidrógeno, halógeno, un grupo hidrocarbonado C1-C20, y R3 junto con R4 puede formar un sistema de anillos mono- o policíclico, y X, según su aparición, puede ser igual o distinto y significa un átomo de hidrógeno, un átomo de halógeno, un grupo hidroxilo, un grupo alquilo C1-C10, un grupo arilo C6-C15, un grupo alcoxi C1-C10, un grupo ariloxi C6-C15, un grupo bencilo, un grupo NR52, en el que R5 según su aparición puede ser igual o distinto y significa un grupo alquilo C1-C10, un grupo arilo C6-C15, un grupo (CH3)3Si, teniendo en cuenta que la proporción entre el isómero rac y el isómero meso del metaloceno de la fórmula (I) en el sistema de catalizador de la invención se sitúa entre 1:10 y 2:1.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19806918A DE19806918A1 (de) | 1998-02-19 | 1998-02-19 | Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2189388T3 true ES2189388T3 (es) | 2003-07-01 |
Family
ID=7858263
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99904880T Expired - Lifetime ES2189388T3 (es) | 1998-02-19 | 1999-02-13 | Sistema de catalizador, procedimiento para su obtencion y utilizacion del mismo para la polimerizacion de olefinas. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6350830B1 (es) |
| EP (1) | EP1054911B1 (es) |
| JP (1) | JP2002504569A (es) |
| BR (1) | BR9907935A (es) |
| DE (2) | DE19806918A1 (es) |
| ES (1) | ES2189388T3 (es) |
| WO (1) | WO1999042497A1 (es) |
Families Citing this family (94)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0016723B1 (pt) * | 1999-12-23 | 2018-02-27 | Basell Polyolefine Gmbh. | Metaloceno, sistema catalisador, e, processo para a copolimerização de propileno com etileno |
| JP4785315B2 (ja) | 2000-01-21 | 2011-10-05 | ユー．エス．ボラックス インコーポレイテッド | ノナボレート組成物およびその製法 |
| US6380330B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6870016B1 (en) | 2000-06-30 | 2005-03-22 | Exxonmobil Chemical Patents Inc. | Polymerization process and polymer composition |
| US6376408B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6380124B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6376627B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6380121B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6380334B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US7122498B2 (en) | 2000-06-30 | 2006-10-17 | Exxonmobil Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| US6376411B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6414095B1 (en) | 2000-06-30 | 2002-07-02 | Exxon Mobil Chemical Patents Inc. | Metallocene compositions |
| US6380123B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6380122B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6399723B1 (en) | 2000-06-30 | 2002-06-04 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6376410B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6380331B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6380120B1 (en) | 2000-06-30 | 2002-04-30 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6376409B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6376412B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6376413B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| US6376407B1 (en) | 2000-06-30 | 2002-04-23 | Exxonmobil Chemical Patents Inc. | Metallocene compositions |
| JP2005522406A (ja) | 2001-06-29 | 2005-07-28 | エクソンモービル・ケミカル・パテンツ・インク | メタロセン及び該メタロセン由来の触媒組成物 |
| WO2003029256A1 (en) * | 2001-10-01 | 2003-04-10 | Dow Global Technologies Inc. | Bulky amido group substituted group 4 metal compounds and polymerization process |
| US7157591B2 (en) | 2001-12-10 | 2007-01-02 | Exxonmobie Chemical Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| JP2006502260A (ja) * | 2002-10-10 | 2006-01-19 | バセル ポリオレフィン ジーエムビーエイチ | エチレンの共重合方法 |
| WO2004046214A2 (en) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7223822B2 (en) * | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7541402B2 (en) * | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7432336B2 (en) * | 2003-04-15 | 2008-10-07 | Exxonmobil Chemical Patents Inc. | Catalysts for propylene copolymers |
| DE602004006223T2 (de) * | 2004-03-12 | 2008-01-17 | Saudi Basic Industries Corp. | Katalysatorzusammensetzung für die Polymerisation von Olefinen und Polymerisationsverfahren unter dessen Verwendung |
| US7285608B2 (en) * | 2004-04-21 | 2007-10-23 | Novolen Technology Holdings C.V. | Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| EP1737893A1 (en) * | 2004-04-23 | 2007-01-03 | ExxonMobil Chemical Patents Inc. | Phosphorus bridged metallocene compounds for olefin polymerization |
| JP2008506825A (ja) * | 2004-07-22 | 2008-03-06 | バーゼル・ポリオレフィン・ゲーエムベーハー | フラクション化可能な１−ブテンポリマー類の製造法 |
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| JP6176015B2 (ja) | 2012-11-01 | 2017-08-09 | 日本ポリプロ株式会社 | メタロセン錯体およびオレフィンの重合方法 |
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| JP2016050189A (ja) * | 2014-08-31 | 2016-04-11 | 日本ポリエチレン株式会社 | メタロセン化合物、それを用いるオレフィン重合触媒及びオレフィン重合体の製造方法 |
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| KR101723488B1 (ko) * | 2014-12-24 | 2017-04-06 | 주식회사 엘지화학 | 폴리프로필렌의 제조방법 및 이로부터 수득되는 폴리프로필렌 |
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| EP3178853B1 (en) | 2015-12-07 | 2018-07-25 | Borealis AG | Process for polymerising alpha-olefin monomers |
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| WO2020023193A1 (en) * | 2018-07-23 | 2020-01-30 | Exxonmobil Chemical Patents Inc. | Preparation of bimodal rubber, thermoplastic vulcanizates, and articles made therefrom |
| US20210277290A1 (en) | 2018-08-06 | 2021-09-09 | Borealis Ag | Propylene random copolymer based hot melt adhesive composition |
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| EP0812854B2 (en) | 1993-06-07 | 2011-04-20 | Mitsui Chemicals, Inc. | Novel transition metal compound, olefin polymerization catalyst comprising said compound, process for olefin polymerization using said catalyst and propylene homo- and copolymer |
| DE4333569A1 (de) | 1993-10-01 | 1995-04-06 | Hoechst Ag | Verfahren zur Olefinpolymerisation |
| JP3423378B2 (ja) | 1993-11-12 | 2003-07-07 | 三井化学株式会社 | 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法 |
| ATE245665T1 (de) * | 1995-09-28 | 2003-08-15 | Basell Polyolefine Gmbh | Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen |
| DE19630845A1 (de) | 1996-07-31 | 1998-02-05 | Sel Alcatel Ag | Verfahren zum Betreiben einer Schnittstelleneinrichtung, sowie Schnittstelleneinrichtung und Vermittlungsstelle mit einer solchen Schnittstelleneinrichtung |
| KR100624632B1 (ko) | 1997-03-07 | 2006-09-15 | 타고르 게엠베하 | 메탈로센 및 그의 제조 방법 |
-
1998
- 1998-02-19 DE DE19806918A patent/DE19806918A1/de not_active Withdrawn
-
1999
- 1999-02-13 BR BR9907935-6A patent/BR9907935A/pt not_active Application Discontinuation
- 1999-02-13 WO PCT/EP1999/000958 patent/WO1999042497A1/de not_active Ceased
- 1999-02-13 EP EP99904880A patent/EP1054911B1/de not_active Expired - Lifetime
- 1999-02-13 JP JP2000532449A patent/JP2002504569A/ja active Pending
- 1999-02-13 ES ES99904880T patent/ES2189388T3/es not_active Expired - Lifetime
- 1999-02-13 US US09/622,310 patent/US6350830B1/en not_active Expired - Fee Related
- 1999-02-13 DE DE59904090T patent/DE59904090D1/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US6350830B1 (en) | 2002-02-26 |
| DE19806918A1 (de) | 1999-08-26 |
| WO1999042497A1 (de) | 1999-08-26 |
| JP2002504569A (ja) | 2002-02-12 |
| BR9907935A (pt) | 2000-10-24 |
| DE59904090D1 (de) | 2003-02-27 |
| EP1054911B1 (de) | 2003-01-22 |
| EP1054911A1 (de) | 2000-11-29 |
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