ES2214437T3 - Compuestos de bisfosfito, sus complejos metalicos y uso de los compuestos y complejos en la hidroformilacion de olefinas. - Google Patents

Compuestos de bisfosfito, sus complejos metalicos y uso de los compuestos y complejos en la hidroformilacion de olefinas.

Info

Publication number
ES2214437T3
ES2214437T3 ES01956490T ES01956490T ES2214437T3 ES 2214437 T3 ES2214437 T3 ES 2214437T3 ES 01956490 T ES01956490 T ES 01956490T ES 01956490 T ES01956490 T ES 01956490T ES 2214437 T3 ES2214437 T3 ES 2214437T3
Authority
ES
Spain
Prior art keywords
aliphatic
alicyclic
heterocyclic
compounds
aromatic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES01956490T
Other languages
English (en)
Inventor
Dirk Rottger
Renat Kadyrov
Armin Borner
Detlef Selent
Dieter Hess
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
Oxeno Olefinchemie GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oxeno Olefinchemie GmbH filed Critical Oxeno Olefinchemie GmbH
Application granted granted Critical
Publication of ES2214437T3 publication Critical patent/ES2214437T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0086—Platinum compounds
    • C07F15/0093—Platinum compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Materials For Medical Uses (AREA)

Abstract

Bisfosfito de fórmula I con R1, R2, R3, R4, R5, R6 = H, un resto hidrocarbonado alifático, alicíclico, alicicloalifático, heterocíclico, heterocicloalifático, aromático, alifático-aromático con 1 a 50 átomos de carbono, F, Cl, Br, I, -OR7, -COR7, -CO2R7, -CO2M, -SR7, -SO2R7, - SOR7, -SO3R7, -SO3M, -SO2NR7R8, NR7R8, N=CR7R8, NH2, donde R1 a R6 poseen un significado igual o diferente y pueden estar enlazados entre sí covalentemente, R7, R8 = H, un resto hidrocarbonado alifático o aromático, sustituido o no sustituido, con 1 a 25 átomos de carbono, de significado igual o diferente, M = un ion de metal alcalino, metal alcalinotérreo, amonio, fosfonio, Q = un resto hidrocarbonado según la fórmula IV con R17, R18, R19, R20, R21, R22, R23, R24 = H, un resto hidrocarbonado alifático, alicíclico, alicicloalifático, heterocíclico, heterocicloalifático, aromático, alifático-aromático con 1 a 50 átomos de carbono, F, Cl, Br, I, -OR25, -COR25, -CO2R25, -CO2M, - SR25, -SO2R25, -SOR25, -SO3R25,-SO3M, -SO2NR25R26, NR25R26, N=CR25R26, NH2, donde R1 a R6 poseen un significado igual o diferente y pueden estar enlazados entre sí covalentemente, R25, R26 = H, un resto hidrocarbonado alifático o aromático, sustituido o no sustituido, con 1 a 25 átomos de carbono, M = un ion de metal alcalino, metal alcalinotérreo, amonio, fosfonio, sirviendo las posiciones a y b de puntos de unión, W, X = restos hidrocarbonados alifáticos, alicíclicos, alicicloalifáticos, heterocíclicos, heterocicloalifáticos, aromáticos, alifático-aromáticos con 1 a 50 átomos de carbono que pueden ser iguales o diferentes o estar enlazados entre sí de forma covalente.
ES01956490T 2000-06-28 2001-06-20 Compuestos de bisfosfito, sus complejos metalicos y uso de los compuestos y complejos en la hidroformilacion de olefinas. Expired - Lifetime ES2214437T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10031493A DE10031493A1 (de) 2000-06-28 2000-06-28 Neue Bisphosphitverbindungen und deren Metallkomplexe

Publications (1)

Publication Number Publication Date
ES2214437T3 true ES2214437T3 (es) 2004-09-16

Family

ID=7647092

Family Applications (1)

Application Number Title Priority Date Filing Date
ES01956490T Expired - Lifetime ES2214437T3 (es) 2000-06-28 2001-06-20 Compuestos de bisfosfito, sus complejos metalicos y uso de los compuestos y complejos en la hidroformilacion de olefinas.

Country Status (11)

Country Link
US (1) US20030195368A1 (es)
EP (1) EP1294731B1 (es)
JP (1) JP2004501927A (es)
CN (1) CN1449402A (es)
AT (1) ATE259820T1 (es)
AU (1) AU2001278460A1 (es)
BR (1) BR0112069A (es)
CA (1) CA2414123A1 (es)
DE (2) DE10031493A1 (es)
ES (1) ES2214437T3 (es)
WO (1) WO2002000670A1 (es)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10058383A1 (de) 2000-11-24 2002-05-29 Oxeno Olefinchemie Gmbh Neue Phosphininverbindungen und deren Metallkomplexe
DE60304034T2 (de) 2002-03-11 2006-10-12 Union Carbide Chemicals & Plastics Technology Corp., Danbury Bisphosphit-ligande für carbonylierungsverfahren
DE10210918B4 (de) 2002-03-13 2004-06-03 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Bisphosphiten
DE10223593A1 (de) * 2002-05-27 2003-12-11 Degussa Hydroxydiphosphine und deren Verwendung in der Katalyse
BR0313866A (pt) 2002-08-31 2005-07-05 Oxeno Olefinchemie Gmbh Processo para a hidroformilação de compostos olefinicamente insaturados, especialmente olefinas na presença de ésteres de ácido carbÈnico cìclicos
RU2336261C2 (ru) 2002-08-31 2008-10-20 Оксено Олефинхеми Гмбх Способ каталитического гидроформилирования высших олефинов в присутствии циклических эфиров угольной кислоты
WO2004035595A1 (en) 2002-10-15 2004-04-29 Union Carbide Chemicals & Plastics Technology Corporation Bis-chelating ligand and use thereof in carbonylation processes
US7118276B2 (en) * 2003-04-03 2006-10-10 Kool Wraps, L.L.C. Gift bag with napped filamentary surface
US6890102B2 (en) * 2003-04-03 2005-05-10 Kool Wraps, L. L. C. Gift bag with napped filamentary surface
DE10360771A1 (de) * 2003-12-23 2005-07-28 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von dreiwertigen Organophosphor-Verbindungen
DE10360772A1 (de) * 2003-12-23 2005-07-28 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Organoacylphosphiten
DE102004013514A1 (de) * 2004-03-19 2005-10-06 Oxeno Olefinchemie Gmbh Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen
WO2005090369A1 (ja) * 2004-03-23 2005-09-29 Kuraray. Co., Ltd. ビスホスファイトおよび該ビスホスファイトを用いたアルデヒド化合物の製造方法
JP4964760B2 (ja) * 2005-02-25 2012-07-04 株式会社クラレ ビスホスファイト、並びに該ビスホスファイトおよび第８〜１０族金属化合物を用いたアルデヒド化合物の製造方法
DE102005014055A1 (de) * 2005-03-23 2006-09-28 Degussa Ag Unsymmetrisch substituierte Phospholankatalysatoren
DE102005042464A1 (de) * 2005-09-07 2007-03-08 Oxeno Olefinchemie Gmbh Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen
WO2007109549A2 (en) 2006-03-17 2007-09-27 University Of Kansas Tuning product selectivity in catalytic hyroformylation reactions with carbon dioxide expanded liquids
WO2007114445A1 (ja) 2006-04-04 2007-10-11 Kuraray Co., Ltd. ビスホスファイトおよび第８～１０族金属化合物を用いたアルデヒドの製造方法、並びに該ビスホスファイト
DE102006034442A1 (de) * 2006-07-26 2008-01-31 Oxeno Olefinchemie Gmbh Katalysatorvorstufe für einen Rh-Komplexkatalysator
DE102006058682A1 (de) * 2006-12-13 2008-06-19 Evonik Oxeno Gmbh Bisphosphitliganden für die übergangsmetallkatalysierte Hydroformylierung
DE102007023514A1 (de) * 2007-05-18 2008-11-20 Evonik Oxeno Gmbh Stabile Katalysatorvorstufe von Rh-Komplexkatalysatoren
DE102008002188A1 (de) * 2008-06-03 2009-12-10 Evonik Oxeno Gmbh Verfahren zur Abtrennung von 1-Buten aus C4-haltigen Kohlenwasserstoffströmen durch Hydroformylierung
MX2011005103A (es) 2008-11-14 2011-08-04 Univ Kansas Complejos de catalizador de metal de transicion soportados en polimeros y metodos de uso.
DE102011085883A1 (de) 2011-11-08 2013-05-08 Evonik Oxeno Gmbh Neue Organophosphorverbindungen auf Basis von Anthracentriol
SG11201502824VA (en) * 2012-10-12 2015-05-28 Evonik Degussa Gmbh Mixture of different asymmetrical bisophosphites and use thereof as a catalyst mixture for hydroformylation
DE102013219512A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemisch aus verschiedenen unsymmetrischen Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
DE102013219506A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Unsymmetrisches Bisphosphit
DE102013219510A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemisch von Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
DE102013219508A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemische konstitutionsisomerer Bisphosphite
DE102013214378A1 (de) 2013-07-23 2015-01-29 Evonik Industries Ag Phosphoramiditderivate in der Hydroformylierung von olefinhaltigen Gemischen
DE102013217166A1 (de) * 2013-08-28 2015-03-05 Evonik Industries Ag Verfahren zur Hydroformylierung von ungesättigten Verbindungen durch SILP-Katalyse
EP3029056B1 (de) 2014-12-04 2018-11-07 Evonik Degussa GmbH Bisphosphite die einen unsymmetrischen biaryl-zentral-baustein aufweisen
DE102015207860A1 (de) * 2015-04-29 2016-11-03 Evonik Degussa Gmbh Neue Monophosphitverbindungen mit einer Methylgruppe
DE102015207864A1 (de) * 2015-04-29 2016-11-03 Evonik Degussa Gmbh Neue Monophosphitverbindungen mit einer Ethergruppe
EP3293191B1 (de) * 2016-09-07 2018-11-14 Evonik Degussa GmbH Phosphite mit einem dihydroxyterphenyl
CN115814833B (zh) * 2022-11-16 2024-10-29 北京化工大学 低负载量的双金属纳米催化剂、合成方法及其应用
EP4663649A1 (de) 2024-06-14 2025-12-17 Evonik Oxeno GmbH & Co. KG Bisphosphite mit einem 3,4-dialkylphenol-flügelbaustein
EP4663647A1 (de) 2024-06-14 2025-12-17 Evonik Oxeno GmbH & Co. KG Bisphosphite mit einem 2-phenylphenol flügelbaustein
EP4663648A1 (de) 2024-06-14 2025-12-17 Evonik Oxeno GmbH & Co. KG Bisphosphite mit einem naphthol-flügelbaustein
EP4663650A1 (de) 2024-06-14 2025-12-17 Evonik Oxeno GmbH & Co. KG Bisphosphite mit einem monoalkylphenol-flügelbaustein
EP4663651A1 (de) 2024-06-14 2025-12-17 Evonik Oxeno GmbH & Co. KG Bisphosphite mit tert-butylresten am zentralbaustein und substituiertem flügelbaustein
EP4700006A1 (de) * 2024-08-20 2026-02-25 Evonik Oxeno GmbH & Co. KG Bisphosphite mit einem ether-rest am flügelbaustein
EP4700007A1 (de) * 2024-08-20 2026-02-25 Evonik Oxeno GmbH & Co. KG Bisphosphite mit einem substituierten tert-butylrest am flügelbaustein
EP4737468A1 (de) 2024-11-05 2026-05-06 Evonik Oxeno GmbH & Co. KG Bisphosphite mit einem naphthalindiol-rückgrat
EP4737466A1 (de) 2024-11-05 2026-05-06 Evonik Oxeno GmbH & Co. KG Bisphosphite mit einem naphthyl-flügelbaustein und einem phenyl-phenyl-flügelbaustein
EP4737467A1 (de) 2024-11-05 2026-05-06 Evonik Oxeno GmbH & Co. KG Bisphosphite mit einem naphthalindiol-zentralbaustein

Family Cites Families (1)

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Publication number Priority date Publication date Assignee Title
US5312996A (en) * 1992-06-29 1994-05-17 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process for producing 1,6-hexanedials

Also Published As

Publication number Publication date
US20030195368A1 (en) 2003-10-16
DE50101518D1 (de) 2004-03-25
DE10031493A1 (de) 2002-01-10
EP1294731A1 (de) 2003-03-26
JP2004501927A (ja) 2004-01-22
BR0112069A (pt) 2003-04-01
EP1294731B1 (de) 2004-02-18
CA2414123A1 (en) 2002-12-23
CN1449402A (zh) 2003-10-15
AU2001278460A1 (en) 2002-01-08
ATE259820T1 (de) 2004-03-15
WO2002000670A1 (de) 2002-01-03

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