ES2322465T3 - Aleacion ternaria de plata. - Google Patents

Aleacion ternaria de plata. Download PDF

Info

Publication number: ES2322465T3
Authority: ES; Spain
Prior art keywords: alloy; weight; silver; copper; tarnish
Prior art date: 2003-06-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES04735594T

Other languages

English (en)

Spanish (es)

Inventor

Peter Gammon Johns

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Argentium International Ltd

Original Assignee

Argentium International Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2003-06-03

Filing date

2004-06-01

Publication date

2009-06-22

2004-06-01 Application filed by Argentium International Ltd filed Critical Argentium International Ltd

2009-06-22 Application granted granted Critical

2009-06-22 Publication of ES2322465T3 publication Critical patent/ES2322465T3/es

2024-06-01 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title description 53
239000004332 silver Substances 0.000 title description 51
229910052709 silver Inorganic materials 0.000 title description 48
229910002058 ternary alloy Inorganic materials 0.000 title description 10
229910045601 alloy Inorganic materials 0.000 claims abstract description 89
239000000956 alloy Substances 0.000 claims abstract description 89
239000010949 copper Substances 0.000 claims abstract description 42
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 34
229910052802 copper Inorganic materials 0.000 claims abstract description 33
238000000137 annealing Methods 0.000 claims abstract description 17
238000011161 development Methods 0.000 claims abstract description 9
229910052793 cadmium Inorganic materials 0.000 claims abstract description 8
239000012535 impurity Substances 0.000 claims abstract description 7
238000001816 cooling Methods 0.000 claims abstract description 5
238000005336 cracking Methods 0.000 claims abstract description 5
230000007547 defect Effects 0.000 claims abstract description 4
229910052718 tin Inorganic materials 0.000 claims abstract 2
229910052725 zinc Inorganic materials 0.000 claims abstract 2
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 15
229910052796 boron Inorganic materials 0.000 claims description 14
239000000243 solution Substances 0.000 description 23
QJAOYSPHSNGHNC-UHFFFAOYSA-N octadecane-1-thiol Chemical group CCCCCCCCCCCCCCCCCCS QJAOYSPHSNGHNC-UHFFFAOYSA-N 0.000 description 22
229910052732 germanium Inorganic materials 0.000 description 21
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 21
230000015572 biosynthetic process Effects 0.000 description 18
239000002904 solvent Substances 0.000 description 18
239000000203 mixture Substances 0.000 description 17
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
238000007254 oxidation reaction Methods 0.000 description 15
238000011282 treatment Methods 0.000 description 15
229910001316 Ag alloy Inorganic materials 0.000 description 14
238000004519 manufacturing process Methods 0.000 description 14
230000003647 oxidation Effects 0.000 description 14
239000007788 liquid Substances 0.000 description 13
229910001118 argentium sterling silver Inorganic materials 0.000 description 11
239000003599 detergent Substances 0.000 description 11
239000010410 layer Substances 0.000 description 11
238000004140 cleaning Methods 0.000 description 10
230000005496 eutectics Effects 0.000 description 10
238000010438 heat treatment Methods 0.000 description 9
238000000034 method Methods 0.000 description 9
238000012360 testing method Methods 0.000 description 9
238000003466 welding Methods 0.000 description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 8
238000005266 casting Methods 0.000 description 8
238000000465 moulding Methods 0.000 description 8
229920001021 polysulfide Polymers 0.000 description 8
239000005077 polysulfide Substances 0.000 description 8
150000008117 polysulfides Polymers 0.000 description 8
238000002604 ultrasonography Methods 0.000 description 8
239000003795 chemical substances by application Substances 0.000 description 7
238000002844 melting Methods 0.000 description 7
230000001681 protective effect Effects 0.000 description 7
239000010944 silver (metal) Substances 0.000 description 7
239000011877 solvent mixture Substances 0.000 description 7
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 6
239000003570 air Substances 0.000 description 6
239000012298 atmosphere Substances 0.000 description 6
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 6
150000001875 compounds Chemical class 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
229910000898 sterling silver Inorganic materials 0.000 description 6
239000010934 sterling silver Substances 0.000 description 6
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
229910000927 Ge alloy Inorganic materials 0.000 description 5
230000004927 fusion Effects 0.000 description 5
239000007789 gas Substances 0.000 description 5
YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 5
239000000463 material Substances 0.000 description 5
230000008018 melting Effects 0.000 description 5
238000005498 polishing Methods 0.000 description 5
230000009467 reduction Effects 0.000 description 5
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
229920000742 Cotton Polymers 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
239000004744 fabric Substances 0.000 description 4
229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
238000012545 processing Methods 0.000 description 4
239000000344 soap Substances 0.000 description 4
229910052717 sulfur Inorganic materials 0.000 description 4
239000011593 sulfur Substances 0.000 description 4
-1 thiol compounds Chemical class 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
229910017821 Cu—Ge Inorganic materials 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
ONJMCYREMREKSA-UHFFFAOYSA-N [Cu].[Ge] Chemical compound [Cu].[Ge] ONJMCYREMREKSA-UHFFFAOYSA-N 0.000 description 3
238000009835 boiling Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000001704 evaporation Methods 0.000 description 3
230000008020 evaporation Effects 0.000 description 3
238000003475 lamination Methods 0.000 description 3
239000002932 luster Substances 0.000 description 3
239000003960 organic solvent Substances 0.000 description 3
239000003223 protective agent Substances 0.000 description 3
230000002829 reductive effect Effects 0.000 description 3
238000007670 refining Methods 0.000 description 3
238000005096 rolling process Methods 0.000 description 3
239000006104 solid solution Substances 0.000 description 3
239000002344 surface layer Substances 0.000 description 3
239000008399 tap water Substances 0.000 description 3
235000020679 tap water Nutrition 0.000 description 3
238000005491 wire drawing Methods 0.000 description 3
UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 2
CYNYIHKIEHGYOZ-UHFFFAOYSA-N 1-bromopropane Chemical compound CCCBr CYNYIHKIEHGYOZ-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
239000005751 Copper oxide Substances 0.000 description 2
229910000881 Cu alloy Inorganic materials 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
NEIHULKJZQTQKJ-UHFFFAOYSA-N [Cu].[Ag] Chemical compound [Cu].[Ag] NEIHULKJZQTQKJ-UHFFFAOYSA-N 0.000 description 2
ZHWDKWFGZPWVMU-UHFFFAOYSA-N [Ge].[Cu].[Ag] Chemical compound [Ge].[Cu].[Ag] ZHWDKWFGZPWVMU-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
239000012080 ambient air Substances 0.000 description 2
239000003125 aqueous solvent Substances 0.000 description 2
238000003556 assay Methods 0.000 description 2
239000010953 base metal Substances 0.000 description 2
DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000000470 constituent Substances 0.000 description 2
229910000431 copper oxide Inorganic materials 0.000 description 2
238000005238 degreasing Methods 0.000 description 2
238000002845 discoloration Methods 0.000 description 2
238000009826 distribution Methods 0.000 description 2
150000002019 disulfides Chemical class 0.000 description 2
238000001035 drying Methods 0.000 description 2
235000019441 ethanol Nutrition 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
239000006260 foam Substances 0.000 description 2
239000003517 fume Substances 0.000 description 2
ORTRWBYBJVGVQC-UHFFFAOYSA-N hexadecane-1-thiol Chemical compound CCCCCCCCCCCCCCCCS ORTRWBYBJVGVQC-UHFFFAOYSA-N 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
230000007774 longterm Effects 0.000 description 2
210000000056 organ Anatomy 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
238000005554 pickling Methods 0.000 description 2
230000009993 protective function Effects 0.000 description 2
230000001105 regulatory effect Effects 0.000 description 2
229910000679 solder Inorganic materials 0.000 description 2
238000001179 sorption measurement Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
150000004763 sulfides Chemical class 0.000 description 2
238000004381 surface treatment Methods 0.000 description 2
239000004094 surface-active agent Substances 0.000 description 2
238000005494 tarnishing Methods 0.000 description 2
150000003505 terpenes Chemical class 0.000 description 2
235000007586 terpenes Nutrition 0.000 description 2
229940071127 thioglycolate Drugs 0.000 description 2
150000003573 thiols Chemical class 0.000 description 2
238000004383 yellowing Methods 0.000 description 2
FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
RBACIKXCRWGCBB-UHFFFAOYSA-N 1,2-Epoxybutane Chemical compound CCC1CO1 RBACIKXCRWGCBB-UHFFFAOYSA-N 0.000 description 1
WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
229910002699 Ag–S Inorganic materials 0.000 description 1
229910017944 Ag—Cu Inorganic materials 0.000 description 1
241000206761 Bacillariophyta Species 0.000 description 1
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
229910000906 Bronze Inorganic materials 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 1
BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
206010028980 Neoplasm Diseases 0.000 description 1
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
206010041662 Splinter Diseases 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
229910052946 acanthite Inorganic materials 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000007824 aliphatic compounds Chemical class 0.000 description 1
150000008051 alkyl sulfates Chemical class 0.000 description 1
238000005275 alloying Methods 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
FZQBLSFKFKIKJI-UHFFFAOYSA-N boron copper Chemical compound [B].[Cu] FZQBLSFKFKIKJI-UHFFFAOYSA-N 0.000 description 1
238000005219 brazing Methods 0.000 description 1
239000010974 bronze Substances 0.000 description 1
201000011510 cancer Diseases 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
239000012459 cleaning agent Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000009749 continuous casting Methods 0.000 description 1
230000008602 contraction Effects 0.000 description 1
KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
238000002788 crimping Methods 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
229940112669 cuprous oxide Drugs 0.000 description 1
KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000004049 embossing Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000011888 foil Substances 0.000 description 1
238000005242 forging Methods 0.000 description 1
238000009472 formulation Methods 0.000 description 1
238000007499 fusion processing Methods 0.000 description 1
239000011521 glass Substances 0.000 description 1
239000004519 grease Substances 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
WDRMFQRBFDVBPJ-UHFFFAOYSA-N hexadecyl 2-sulfanylacetate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CS WDRMFQRBFDVBPJ-UHFFFAOYSA-N 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
238000005304 joining Methods 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
230000005923 long-lasting effect Effects 0.000 description 1
231100000053 low toxicity Toxicity 0.000 description 1
238000005259 measurement Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Natural products OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
239000010956 nickel silver Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
229910000510 noble metal Inorganic materials 0.000 description 1
230000009972 noncorrosive effect Effects 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000035515 penetration Effects 0.000 description 1
239000002957 persistent organic pollutant Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000002985 plastic film Substances 0.000 description 1
229920006255 plastic film Polymers 0.000 description 1
239000003495 polar organic solvent Substances 0.000 description 1
238000003825 pressing Methods 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
239000011253 protective coating Substances 0.000 description 1
230000001012 protector Effects 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000004065 semiconductor Substances 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
229940056910 silver sulfide Drugs 0.000 description 1
XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 description 1
229910000108 silver(I,III) oxide Inorganic materials 0.000 description 1
239000002356 single layer Substances 0.000 description 1
239000002689 soil Substances 0.000 description 1
238000005476 soldering Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000007858 starting material Substances 0.000 description 1
230000003068 static effect Effects 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
238000006557 surface reaction Methods 0.000 description 1
238000010301 surface-oxidation reaction Methods 0.000 description 1
229950011008 tetrachloroethylene Drugs 0.000 description 1
CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
238000009834 vaporization Methods 0.000 description 1
230000008016 vaporization Effects 0.000 description 1
238000012795 verification Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1
230000003313 weakening effect Effects 0.000 description 1
238000009736 wetting Methods 0.000 description 1
210000002268 wool Anatomy 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C5/00—Alloys based on noble metals
- C22C5/06—Alloys based on silver
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/16—Sulfur-containing compounds
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/16—Sulfur-containing compounds
- C23F11/161—Mercaptans

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Mechanical Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Preventing Corrosion Or Incrustation Of Metals (AREA)
Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Manufacture And Refinement Of Metals (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Chemical Treatment Of Metals (AREA)
Conductive Materials (AREA)

ES04735594T 2003-06-03 2004-06-01 Aleacion ternaria de plata. Expired - Lifetime ES2322465T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB0312693		2003-06-03
GB0312693A GB2402399B (en)	2003-06-03	2003-06-03	Silver ternary alloy

Publications (1)

Publication Number	Publication Date
ES2322465T3 true ES2322465T3 (es)	2009-06-22

Family

ID=9959219

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES04735594T Expired - Lifetime ES2322465T3 (es)	2003-06-03	2004-06-01	Aleacion ternaria de plata.

Country Status (13)

Country	Link
US (1)	US20070009375A1 (de)
EP (1)	EP1631692B1 (de)
JP (1)	JP2007535616A (de)
CN (2)	CN1846007A (de)
AT (1)	ATE420980T1 (de)
AU (1)	AU2004243654A1 (de)
CA (1)	CA2527430A1 (de)
DE (1)	DE602004019080D1 (de)
EA (1)	EA011015B1 (de)
ES (1)	ES2322465T3 (de)
GB (1)	GB2402399B (de)
PT (1)	PT1631692E (de)
WO (1)	WO2004106567A1 (de)

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GB2485374B (en)	2010-11-11	2013-07-24	Argentium Internat Ltd	Alloy for investment casting
GB2426250A (en) *	2005-05-20	2006-11-22	Middlesex Silver Co Ltd	Silver alloys
WO2006123190A1 (en) *	2005-05-20	2006-11-23	Middlesex Silver Co. Limited	Silver-copper-germanium alloy manufacturing
US9222150B2 (en)	2004-06-02	2015-12-29	Peter Gamon Johns	Process for making finished or semi-finished articles of silver alloy
GB2428045A (en) *	2005-07-07	2007-01-17	Middlesex Silver Co Ltd	Silver-copper-germanium alloy
GB0517166D0 (en) *	2005-08-23	2005-09-28	Middlesex Silver Co Ltd	Silver wire
IT1398698B1 (it) *	2010-02-24	2013-03-08	Mesa S A S Di Malimpensa Simona E Davide E C	Metodo per la protezione di superfici di argento e sue leghe dall'imbrunimento.
GB2561376A (en) *	2017-04-12	2018-10-17	Argentium International Ltd	Silver alloys, investment casting using the alloys and casting grain
CN111910524A (zh) *	2020-08-19	2020-11-10	山东鼎鲁建筑有限公司	一种桥梁工程施工用支撑设备
US12214416B2 (en)	2021-07-13	2025-02-04	James Avery Craftsman, Inc.	Laser weldable sterling alloy
DE102022106410A1 (de)	2022-03-18	2023-09-21	Leonhard Kurz Stiftung & Co. Kg	Mehrschichtkörper, Verfahren zur Herstellung eines Mehrschichtkörpers, Verwendung eines Mehrschichtkörpers sowie Verwendung einer Wärmebeaufschlagungsvorrichtung

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2003
- 2003-06-03 GB GB0312693A patent/GB2402399B/en not_active Expired - Fee Related
2004
- 2004-06-01 AT AT04735594T patent/ATE420980T1/de not_active IP Right Cessation
- 2004-06-01 US US10/559,092 patent/US20070009375A1/en not_active Abandoned
- 2004-06-01 CN CNA2004800154108A patent/CN1846007A/zh active Pending
- 2004-06-01 EP EP04735594A patent/EP1631692B1/de not_active Expired - Lifetime
- 2004-06-01 JP JP2006508380A patent/JP2007535616A/ja not_active Withdrawn
- 2004-06-01 AU AU2004243654A patent/AU2004243654A1/en not_active Abandoned
- 2004-06-01 EA EA200501875A patent/EA011015B1/ru not_active IP Right Cessation
- 2004-06-01 CN CN201210188563.9A patent/CN102690969B/zh not_active Expired - Fee Related
- 2004-06-01 CA CA002527430A patent/CA2527430A1/en not_active Abandoned
- 2004-06-01 DE DE602004019080T patent/DE602004019080D1/de not_active Expired - Lifetime
- 2004-06-01 WO PCT/GB2004/002317 patent/WO2004106567A1/en not_active Ceased
- 2004-06-01 ES ES04735594T patent/ES2322465T3/es not_active Expired - Lifetime
- 2004-06-01 PT PT04735594T patent/PT1631692E/pt unknown

Also Published As

Publication number	Publication date
PT1631692E (pt)	2009-04-16
GB2402399A (en)	2004-12-08
EP1631692A1 (de)	2006-03-08
ATE420980T1 (de)	2009-01-15
GB2402399B (en)	2005-10-12
CN102690969B (zh)	2016-05-04
CA2527430A1 (en)	2004-12-09
WO2004106567A1 (en)	2004-12-09
AU2004243654A1 (en)	2004-12-09
JP2007535616A (ja)	2007-12-06
EP1631692B1 (de)	2009-01-14
CN1846007A (zh)	2006-10-11
DE602004019080D1 (de)	2009-03-05
US20070009375A1 (en)	2007-01-11
GB0312693D0 (en)	2003-07-09
EA011015B1 (ru)	2008-12-30
CN102690969A (zh)	2012-09-26
EA200501875A1 (ru)	2006-06-30

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ES2322465T3 (es)	2009-06-22	Aleacion ternaria de plata.
EA008833B1 (ru)	2007-08-31	Повышение устойчивости серебра к потускнению
BR0108916A (pt)	2003-01-28	Processo de proteção contra corrosão para superfìcies metálicas
US20100239454A1 (en)	2010-09-23	Silver ternary alloy
ES2425172T3 (es)	2013-10-11	Fundente y procedimiento de galvanizado por inmersión en caliente
ES2559387T3 (es)	2016-02-11	Procedimiento para el tratamiento de superficie de acero inoxidable
US4775511A (en)	1988-10-04	Method of sulfide tarnish inhibiting of silver-copper, silver-gold and silver-copper-gold alloys
ES2318490T3 (es)	2009-05-01	Procedimiento para la produccion de articulos acabados o semi-acabados a base de aleacion de plata que comprende cobre y germanio.
US20080069722A1 (en)	2008-03-20	Metal alloy manufacturing
Grimwade	1999	The surface enrichment of carat gold alloys-depletion gilding
US20070277906A1 (en)	2007-12-06	Water-Based Metal Treatment Composition
Sparavigna	2016	Depletion gilding: An ancient method for surface enrichment of gold alloys
EP1888797A1 (de)	2008-02-20	Herstellung von silber-kupfer-germanium-legierungen
MXPA05012991A (en)	2006-10-17	Silver ternary alloy
ES2318436T3 (es)	2009-05-01	Procedimiento de tratamiento por carboxilacion de superficies metalicas, uso de este procedimiento para la proteccion temporal contra la corrosion y procedimiento de fabricacion de una chapa conformada asi carboxilada.
JPH0617167A (ja)	1994-01-25	高硬度，高耐蝕性銀合金
MXPA06010964A (es)	2007-04-20	Composicion de tratamiento de metales basada en agua
Ottenwelter	2013	Cleaning of silver Great Moravian Jewellery by potentiostatic reduction
ES2285035T3 (es)	2007-11-16	Procedimiento para proporcionar un efecto cromatico de caparazon de tortuga a substratos metalicos.
IT201800003349U1 (it)	2019-12-20	Protezione dall'ossidazione di oggetti d'argento(ag)leghe di argento, oro(au) ed altri metalli in lega ottenuti anche come deposito galvanico
ITFI20070106A1 (it)	2008-11-01	"perfezionamento ad una lega di argento resistente ad ossidazione e corro- sione"
CZ7832U1 (cs)	1998-09-14	Přípravek pro černění železných předmětů
JPH07207383A (ja)	1995-08-08	装飾品用Ｐｔ−Ｐｄ系材料及びその製造方法
JPS616221A (ja)	1986-01-11	装飾品用銀材料
ITAR980033A1 (it)	2000-04-22	Lega di argento inattaccabile dagli agenti esogeni per la produzionedi articoli ornamentali ed orologi