ES2331788T3 - Pastillas de detergente. - Google Patents

Pastillas de detergente. Download PDF

Info

Publication number: ES2331788T3
Authority: ES; Spain
Prior art keywords: zone; tablet; weight; soft; solid
Prior art date: 2002-06-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES03076744T

Other languages

English (en)

Spanish (es)

Inventor

Peter William Appel

Peter Iwan Stuut

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever NV

Original Assignee

Unilever NV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2002-06-11

Filing date

2003-06-04

Publication date

2010-01-15

2003-06-04 Application filed by Unilever NV filed Critical Unilever NV

2010-01-15 Application granted granted Critical

2010-01-15 Publication of ES2331788T3 publication Critical patent/ES2331788T3/es

2023-06-04 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title description 16
239000000203 mixture Substances 0.000 claims abstract description 66
239000007787 solid Substances 0.000 claims abstract description 56
238000004140 cleaning Methods 0.000 claims abstract description 8
239000003826 tablet Substances 0.000 claims description 81
239000006187 pill Substances 0.000 claims description 40
239000002245 particle Substances 0.000 claims description 29
238000000034 method Methods 0.000 claims description 28
239000004094 surface-active agent Substances 0.000 claims description 22
239000000463 material Substances 0.000 claims description 19
238000007906 compression Methods 0.000 claims description 15
239000007891 compressed tablet Substances 0.000 claims description 6
239000007779 soft material Substances 0.000 claims description 2
239000011236 particulate material Substances 0.000 abstract description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
238000005406 washing Methods 0.000 description 15
239000012071 phase Substances 0.000 description 13
238000004061 bleaching Methods 0.000 description 11
239000000843 powder Substances 0.000 description 10
239000004615 ingredient Substances 0.000 description 9
239000003945 anionic surfactant Substances 0.000 description 8
238000006073 displacement reaction Methods 0.000 description 8
-1 for example Substances 0.000 description 8
239000011734 sodium Substances 0.000 description 8
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
230000006835 compression Effects 0.000 description 7
229910052708 sodium Inorganic materials 0.000 description 7
210000001519 tissue Anatomy 0.000 description 7
150000001875 compounds Chemical class 0.000 description 6
239000000344 soap Substances 0.000 description 6
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 5
239000012190 activator Substances 0.000 description 5
229910052783 alkali metal Inorganic materials 0.000 description 5
239000002518 antifoaming agent Substances 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
239000006185 dispersion Substances 0.000 description 5
239000008187 granular material Substances 0.000 description 5
210000004872 soft tissue Anatomy 0.000 description 5
238000012360 testing method Methods 0.000 description 5
102000004190 Enzymes Human genes 0.000 description 4
108090000790 Enzymes Proteins 0.000 description 4
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
229910019142 PO4 Inorganic materials 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
239000007844 bleaching agent Substances 0.000 description 4
235000014113 dietary fatty acids Nutrition 0.000 description 4
229940088598 enzyme Drugs 0.000 description 4
239000000194 fatty acid Substances 0.000 description 4
229930195729 fatty acid Natural products 0.000 description 4
150000004665 fatty acids Chemical class 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
239000002736 nonionic surfactant Substances 0.000 description 4
235000021317 phosphate Nutrition 0.000 description 4
239000002243 precursor Substances 0.000 description 4
229910000503 Na-aluminosilicate Inorganic materials 0.000 description 3
239000002202 Polyethylene glycol Substances 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
150000001340 alkali metals Chemical class 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
238000005056 compaction Methods 0.000 description 3
239000004744 fabric Substances 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000011159 matrix material Substances 0.000 description 3
150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
229920005646 polycarboxylate Polymers 0.000 description 3
229920001223 polyethylene glycol Polymers 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000000047 product Substances 0.000 description 3
150000004760 silicates Chemical class 0.000 description 3
235000012217 sodium aluminium silicate Nutrition 0.000 description 3
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
108091005804 Peptidases Proteins 0.000 description 2
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
239000004365 Protease Substances 0.000 description 2
239000004115 Sodium Silicate Substances 0.000 description 2
108010056079 Subtilisins Proteins 0.000 description 2
102000005158 Subtilisins Human genes 0.000 description 2
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
239000000853 adhesive Substances 0.000 description 2
230000001070 adhesive effect Effects 0.000 description 2
229910052910 alkali metal silicate Inorganic materials 0.000 description 2
150000008051 alkyl sulfates Chemical class 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
150000004649 carbonic acid derivatives Chemical class 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
238000010586 diagram Methods 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
PMPJQLCPEQFEJW-GNTLFSRWSA-L disodium;2-[(z)-2-[4-[4-[(z)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C/C1=CC=C(C=2C=CC(\C=C/C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-GNTLFSRWSA-L 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
229910001385 heavy metal Inorganic materials 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
238000009434 installation Methods 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
238000005259 measurement Methods 0.000 description 2
239000011574 phosphorus Substances 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
229920000058 polyacrylate Polymers 0.000 description 2
150000003138 primary alcohols Chemical class 0.000 description 2
239000003352 sequestering agent Substances 0.000 description 2
229910052911 sodium silicate Inorganic materials 0.000 description 2
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
235000019832 sodium triphosphate Nutrition 0.000 description 2
239000007790 solid phase Substances 0.000 description 2
230000003381 solubilizing effect Effects 0.000 description 2
239000010457 zeolite Substances 0.000 description 2
CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 1
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
102000013142 Amylases Human genes 0.000 description 1
108010065511 Amylases Proteins 0.000 description 1
WJSLZXMQHNTOBA-UHFFFAOYSA-N C(CCC(=O)O)(=O)O.C(CCC(=O)O)(=O)O.C(CCC(=O)O)(=O)O.OCC(O)CO Chemical class C(CCC(=O)O)(=O)O.C(CCC(=O)O)(=O)O.C(CCC(=O)O)(=O)O.OCC(O)CO WJSLZXMQHNTOBA-UHFFFAOYSA-N 0.000 description 1
FJUIPMBNXJIKLZ-UHFFFAOYSA-N C1COCCN1C2=NC(=NC(=N2)NC3=CC=C(C=C3)C=CC4=C(C(=C(C=C4)NC5=NC(=NC(=N5)NC6=CC=CC=C6)N7CCOCC7)S(=O)(=O)O)S(=O)(=O)O)NC8=CC=CC=C8 Chemical compound C1COCCN1C2=NC(=NC(=N2)NC3=CC=C(C=C3)C=CC4=C(C(=C(C=C4)NC5=NC(=NC(=N5)NC6=CC=CC=C6)N7CCOCC7)S(=O)(=O)O)S(=O)(=O)O)NC8=CC=CC=C8 FJUIPMBNXJIKLZ-UHFFFAOYSA-N 0.000 description 1
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
102000005575 Cellulases Human genes 0.000 description 1
108010084185 Cellulases Proteins 0.000 description 1
OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
229920000896 Ethulose Polymers 0.000 description 1
239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
102000004882 Lipase Human genes 0.000 description 1
239000004367 Lipase Substances 0.000 description 1
108090001060 Lipase Proteins 0.000 description 1
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
WFRXSOIFNFJAFL-UHFFFAOYSA-N P1(OCCCCO1)=O.C(CN)N Chemical compound P1(OCCCCO1)=O.C(CN)N WFRXSOIFNFJAFL-UHFFFAOYSA-N 0.000 description 1
102000035195 Peptidases Human genes 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
229920000388 Polyphosphate Polymers 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
235000019484 Rapeseed oil Nutrition 0.000 description 1
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
GBFLZEXEOZUWRN-VKHMYHEASA-N S-carboxymethyl-L-cysteine Chemical compound OC(=O)[C@@H](N)CSCC(O)=O GBFLZEXEOZUWRN-VKHMYHEASA-N 0.000 description 1
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
235000019486 Sunflower oil Nutrition 0.000 description 1
208000031737 Tissue Adhesions Diseases 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000011149 active material Substances 0.000 description 1
239000013543 active substance Substances 0.000 description 1
230000006978 adaptation Effects 0.000 description 1
239000002671 adjuvant Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000005037 alkyl phenyl group Chemical group 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
235000019418 amylase Nutrition 0.000 description 1
229940025131 amylases Drugs 0.000 description 1
235000015278 beef Nutrition 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
229920003086 cellulose ether Polymers 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
239000003240 coconut oil Substances 0.000 description 1
235000019864 coconut oil Nutrition 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
239000002872 contrast media Substances 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 1
238000004851 dishwashing Methods 0.000 description 1
VUJGKADZTYCLIL-YHPRVSEPSA-L disodium;5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 VUJGKADZTYCLIL-YHPRVSEPSA-L 0.000 description 1
238000009826 distribution Methods 0.000 description 1
239000000428 dust Substances 0.000 description 1
239000000975 dye Substances 0.000 description 1
239000003623 enhancer Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
239000002979 fabric softener Substances 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
238000009499 grossing Methods 0.000 description 1
229910052739 hydrogen Chemical group 0.000 description 1
239000001257 hydrogen Chemical group 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
125000001165 hydrophobic group Chemical group 0.000 description 1
229910052816 inorganic phosphate Inorganic materials 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
239000002198 insoluble material Substances 0.000 description 1
239000002563 ionic surfactant Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
235000019421 lipase Nutrition 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000005341 metaphosphate group Chemical group 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
235000010981 methylcellulose Nutrition 0.000 description 1
108010020132 microbial serine proteinases Proteins 0.000 description 1
239000000178 monomer Substances 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
ATFJZOOCCNCYRL-UHFFFAOYSA-N octasodium disilicate Chemical compound [Si]([O-])([O-])([O-])[O-].[Si]([O-])([O-])([O-])[O-].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+] ATFJZOOCCNCYRL-UHFFFAOYSA-N 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
239000002304 perfume Substances 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
235000019271 petrolatum Nutrition 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
239000011253 protective coating Substances 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
150000003333 secondary alcohols Chemical class 0.000 description 1
239000012056 semi-solid material Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
235000017281 sodium acetate Nutrition 0.000 description 1
229910001388 sodium aluminate Inorganic materials 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000008247 solid mixture Substances 0.000 description 1
239000002195 soluble material Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
239000002600 sunflower oil Substances 0.000 description 1
230000001629 suppression Effects 0.000 description 1
239000003760 tallow Substances 0.000 description 1
238000004154 testing of material Methods 0.000 description 1
238000012549 training Methods 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0078—Multilayered tablets

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Cosmetics (AREA)
Medicinal Preparation (AREA)

ES03076744T 2002-06-11 2003-06-04 Pastillas de detergente. Expired - Lifetime ES2331788T3 (es)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP02077267		2002-06-11
EP02077267		2002-06-11

Publications (1)

Publication Number	Publication Date
ES2331788T3 true ES2331788T3 (es)	2010-01-15

Family

ID=40935172

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES03076744T Expired - Lifetime ES2331788T3 (es)	2002-06-11	2003-06-04	Pastillas de detergente.

Country Status (4)

Country	Link
EP (1)	EP1382668B1 (de)
AT (1)	ATE439422T1 (de)
DE (1)	DE60328746D1 (de)
ES (1)	ES2331788T3 (de)

Families Citing this family (86)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP1466964A1 (de) *	2003-02-11	2004-10-13	Unilever N.V.	Renigungsmittel
EP1466965A1 (de) *	2003-02-11	2004-10-13	Unilever N.V.	Reinigungsmittel
EP1705240A1 (de)	2005-03-23	2006-09-27	Unilever N.V.	Wasch- oder Reinigungsmitteltabletten
EP1845153A1 (de) *	2006-04-12	2007-10-17	Unilever N.V.	Waschmitteltabletten
USD650523S1 (en)	2007-02-12	2011-12-13	Jeyes Group Limited	Lavatory cleansing block
USD632843S1 (en)	2007-02-12	2011-02-15	Jeyes Group Limited	Lavatory cleansing block
MX2012012096A (es)	2010-04-26	2012-12-17	Novozymes As	Granulos de enzima.
DE102010051226A1 (de)	2010-11-12	2012-05-31	Dental Care Innovation Gmbh	Ausspültablete mit abrasiven Bestandteilen
CN107475235B (zh)	2011-06-20	2022-09-13	诺维信公司	颗粒组合物
EP2723858B1 (de)	2011-06-24	2017-04-12	Novozymes A/S	Polypeptide mit protease-aktivität und diese kodierende polynukleotide
CN103703124B (zh)	2011-06-30	2021-01-15	诺维信公司	用于筛选α-淀粉酶的方法
EP2732018B1 (de)	2011-07-12	2017-01-04	Novozymes A/S	Lagerstabile enzymgranulate
US9000138B2 (en)	2011-08-15	2015-04-07	Novozymes A/S	Expression constructs comprising a Terebella lapidaria nucleic acid encoding a cellulase, host cells, and methods of making the cellulase
ES2628190T3 (es)	2011-09-22	2017-08-02	Novozymes A/S	Polipéptidos con actividad de proteasa y polinucleótidos que codifican los mismos
EP2782988A1 (de)	2011-11-25	2014-10-01	Novozymes A/S	Subtilasevarianten und dafür codierende polynucleotide
CN104011204A (zh)	2011-12-20	2014-08-27	诺维信公司	枯草杆菌酶变体和编码它们的多核苷酸
MX2014008764A (es)	2012-01-26	2014-08-27	Novozymes As	Uso de polipeptidos que tienen actividad proteasa en alimentos para animales y detergentes.
EP2814956B1 (de)	2012-02-17	2017-05-10	Novozymes A/S	Subtilisinvarianten und polynukleotide zu deren codierung
EP2823026A1 (de)	2012-03-07	2015-01-14	Novozymes A/S	Waschmittelzusammensetzung und substitution von optischen aufhellern in waschmittelzusammensetzungen
US9458441B2 (en)	2012-05-07	2016-10-04	Novozymes A/S	Polypeptides having xanthan degrading activity and polynucleotides encoding same
BR112014031882A2 (pt)	2012-06-20	2017-08-01	Novozymes As	uso de um polipeptídeo isolado, polipeptídeo, composição, polinucleotídeo isolado, construto de ácido nucleico ou vetor de expressão, célula hospedeira de expressão recombinante, métodos para produção de um polipeptídeo, para melhoria do valor nutricional de uma ração animal, e para o tratamento de proteínas, uso de pelo menos um polipeptídeo, aditivo de ração animal, ração animal, e, composição detergente
US9551042B2 (en)	2012-12-21	2017-01-24	Novozymes A/S	Polypeptides having protease activity and polynucleotides encoding same
US9902946B2 (en)	2013-01-03	2018-02-27	Novozymes A/S	Alpha-amylase variants and polynucleotides encoding same
WO2014183921A1 (en)	2013-05-17	2014-11-20	Novozymes A/S	Polypeptides having alpha amylase activity
US10538751B2 (en)	2013-06-06	2020-01-21	Novozymes A/S	Alpha-amylase variants and polynucleotides encoding same
US10378001B2 (en)	2013-06-27	2019-08-13	Novozymes A/S	Subtilase variants and compositions comprising same
EP3013955A1 (de)	2013-06-27	2016-05-04	Novozymes A/S	Subtilasevarianten und polynukleotide zur codierung davon
RU2015156280A (ru)	2013-07-04	2017-08-09	Новозимс А/С	Полипептиды, обладающие эффектом против переосаждения, и полинуклеотиды, кодирующие их
US9926550B2 (en)	2013-07-29	2018-03-27	Novozymes A/S	Protease variants and polynucleotides encoding same
EP2832853A1 (de)	2013-07-29	2015-02-04	Henkel AG&Co. KGAA	Waschmittelzusammensetzung mit Proteasevarianten
CN117904081A (zh)	2013-07-29	2024-04-19	诺维信公司	蛋白酶变体以及对其进行编码的多核苷酸
WO2015049370A1 (en)	2013-10-03	2015-04-09	Novozymes A/S	Detergent composition and use of detergent composition
CN105814200A (zh)	2013-12-20	2016-07-27	诺维信公司	具有蛋白酶活性的多肽以及编码它们的多核苷酸
EP3114272A1 (de)	2014-03-05	2017-01-11	Novozymes A/S	Zusammensetzungen und verfahren zur verbesserung der eigenschaften von cellulosischen textilmaterialien mit xyloglucan-endotransglycosylase
US20160348035A1 (en)	2014-03-05	2016-12-01	Novozymes A/S	Compositions and Methods for Improving Properties of Non-Cellulosic Textile Materials with Xyloglucan Endotransglycosylase
EP3126479A1 (de)	2014-04-01	2017-02-08	Novozymes A/S	Polypeptide mit alpha-amylase-aktivität
CN106414729A (zh)	2014-06-12	2017-02-15	诺维信公司	α‑淀粉酶变体以及对其进行编码的多核苷酸
EP3140399B1 (de)	2014-07-04	2018-03-28	Novozymes A/S	Subtilasevarianten und polynukleotide zur codierung davon
EP3739029A1 (de)	2014-07-04	2020-11-18	Novozymes A/S	Subtilasevarianten und polynukleotide zur codierung davon
WO2016079305A1 (en)	2014-11-20	2016-05-26	Novozymes A/S	Alicyclobacillus variants and polynucleotides encoding same
RU2710720C2 (ru)	2014-12-04	2020-01-10	Новозимс А/С	Варианты субтилазы и кодирующие их полинуклеотиды
PL3608403T3 (pl)	2014-12-15	2025-06-23	Henkel Ag & Co. Kgaa	Kompozycja detergentowa zawierająca warianty subtylazy
EP3310912B1 (de)	2015-06-18	2021-01-27	Novozymes A/S	Subtilasevarianten und polynukleotide zur codierung davon
EP3106508B1 (de)	2015-06-18	2019-11-20	Henkel AG & Co. KGaA	Reinigungsmittelzusammensetzung mit subtilasevarianten
EP3362556B1 (de)	2015-10-14	2024-07-10	Novozymes A/S	Polypeptidvarianten
CN108291215A (zh)	2015-10-14	2018-07-17	诺维信公司	具有蛋白酶活性的多肽以及编码它们的多核苷酸
EP3464582A1 (de)	2016-06-03	2019-04-10	Novozymes A/S	Subtilasevarianten und polynukleotide zur codierung davon
WO2018011277A1 (en)	2016-07-13	2018-01-18	Novozymes A/S	Bacillus cibi dnase variants
JP7565157B2 (ja)	2017-02-02	2024-10-10	ウォーターピックインコーポレイテッド	歯牙清掃用研磨剤を含む錠剤
CN111542604A (zh)	2017-10-27	2020-08-14	诺维信公司	Dna酶变体
PL3476936T3 (pl)	2017-10-27	2022-04-11	The Procter & Gamble Company	Kompozycje detergentu zawierające odmiany polipeptydowe
WO2019180111A1 (en)	2018-03-23	2019-09-26	Novozymes A/S	Subtilase variants and compositions comprising same
EP3781660A1 (de)	2018-04-17	2021-02-24	Novozymes A/S	Polypeptide mit kohlenhydratbindungsaktivität in waschmittelzusammensetzungen und ihre verwendung zur verminderung von falten in textilien oder geweben
WO2020002255A1 (en)	2018-06-29	2020-01-02	Novozymes A/S	Subtilase variants and compositions comprising same
WO2020114965A1 (en)	2018-12-03	2020-06-11	Novozymes A/S	LOW pH POWDER DETERGENT COMPOSITION
WO2020114968A1 (en)	2018-12-03	2020-06-11	Novozymes A/S	Powder detergent compositions
EP3702452A1 (de)	2019-03-01	2020-09-02	Novozymes A/S	Waschmittelzusammensetzungen mit zwei proteasen
CA3122942A1 (en)	2019-03-21	2020-09-24	Novozymes A/S	Alpha-amylase variants and polynucleotides encoding same
EP3953462A1 (de)	2019-04-10	2022-02-16	Novozymes A/S	Polypeptidvarianten
WO2021037895A1 (en)	2019-08-27	2021-03-04	Novozymes A/S	Detergent composition
US20220315866A1 (en)	2019-09-19	2022-10-06	Novozymes A/S	Detergent Composition
WO2021064068A1 (en)	2019-10-03	2021-04-08	Novozymes A/S	Polypeptides comprising at least two carbohydrate binding domains
EP3892708A1 (de)	2020-04-06	2021-10-13	Henkel AG & Co. KGaA	Reinigungszusammensetzungen mit dispersinvarianten
US20230212548A1 (en)	2020-05-26	2023-07-06	Novozymes A/S	Subtilase variants and compositions comprising same
WO2022043563A1 (en)	2020-08-28	2022-03-03	Novozymes A/S	Polyester degrading protease variants
US20250346879A1 (en)	2020-10-07	2025-11-13	Novozymes A/S	Alpha-amylase variants
EP4291646A2 (de)	2021-02-12	2023-12-20	Novozymes A/S	Alpha-amylase-varianten
EP4305146A1 (de)	2021-03-12	2024-01-17	Novozymes A/S	Polypeptidvarianten
US20240060061A1 (en)	2021-03-15	2024-02-22	Novozymes A/S	Dnase variants
EP4060036A1 (de)	2021-03-15	2022-09-21	Novozymes A/S	Polypeptidvarianten
EP4359518A1 (de)	2021-06-23	2024-05-01	Novozymes A/S	Alpha-amylase-polypeptide
US20250171719A1 (en)	2022-02-24	2025-05-29	Evonik Operations Gmbh	Bio based composition
EP4234664A1 (de)	2022-02-24	2023-08-30	Evonik Operations GmbH	Zusammensetzung mit glucolipiden und enzymen
WO2023165950A1 (en)	2022-03-04	2023-09-07	Novozymes A/S	Dnase variants and compositions
JP2025511813A (ja)	2022-04-08	2025-04-16	ノボザイムスアクティーゼルスカブ	ヘキソサミニダーゼバリアント及び組成物
KR20250033238A (ko)	2022-06-28	2025-03-07	에보닉 오퍼레이션스 게엠베하	생물계면활성제 및 페르시코마이신을 포함하는 조성물
JP2026508744A (ja)	2022-12-05	2026-03-12	ノボザイムスアクティーゼルスカブ	プロテアーゼバリアント、及びそれをコードするポリヌクレオチド
CN120303382A (zh)	2022-12-15	2025-07-11	赢创运营有限公司	包含槐糖脂和鼠李糖脂和/或葡萄糖脂的组合物
JP2026501223A (ja)	2022-12-23	2026-01-14	ノボザイムスアクティーゼルスカブ	カタラーゼ及びアミラーゼを含む洗剤組成物
WO2024213513A1 (en)	2023-04-12	2024-10-17	Novozymes A/S	Compositions comprising polypeptides having alkaline phosphatase activity
WO2025036642A1 (en)	2023-08-15	2025-02-20	Evonik Operations Gmbh	Improved method for cleaning
WO2025257254A1 (en)	2024-06-12	2025-12-18	Novozymes A/S	Lipases and lipase variants and the use thereof
WO2026032783A1 (en)	2024-08-06	2026-02-12	Evonik Operations Gmbh	Bacillus velezensis strains in cleaning and animal feeding
EP4692292A1 (de)	2024-08-06	2026-02-11	Evonik Operations GmbH	Verbessertes verfahren zur keimung von bakteriensporen
WO2026046881A1 (en)	2024-08-26	2026-03-05	Novozymes A/S	Compositions comprising a hexosaminidase and a protease
WO2026068782A1 (en)	2024-09-30	2026-04-02	Novozymes A/S	Protease variants and polynucleotides encoding same

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB9721363D0 (en) *	1997-10-09	1997-12-10	Mcbride Robert Ltd	Dishwasher tablets
ES2198769T3 (es) *	1997-11-10	2004-02-01	THE PROCTER & GAMBLE COMPANY	Pastilla de detergente de multiples capas que tiene tanto porciones comprimidas como no comprimidas.
GB9815525D0 (en) *	1998-07-17	1998-09-16	Procter & Gamble	Detergent tablet
EP1043390A1 (de) *	1999-04-09	2000-10-11	The Procter & Gamble Company	Wasch- und Reinigungsmittel in Tablettenform

2003
- 2003-06-04 EP EP03076744A patent/EP1382668B1/de not_active Expired - Lifetime
- 2003-06-04 DE DE60328746T patent/DE60328746D1/de not_active Expired - Lifetime
- 2003-06-04 AT AT03076744T patent/ATE439422T1/de not_active IP Right Cessation
- 2003-06-04 ES ES03076744T patent/ES2331788T3/es not_active Expired - Lifetime

Also Published As

Publication number	Publication date
EP1382668A1 (de)	2004-01-21
DE60328746D1 (de)	2009-09-24
EP1382668B1 (de)	2009-08-12
ATE439422T1 (de)	2009-08-15

Publication	Publication Date	Title
ES2313539T3 (es)	2009-03-01	Composiciones de detergente en forma de pastillas.
ES2210789T3 (es)	2004-07-01	Composiciones detergentes.
EP1382668B1 (de)	2009-08-12	Waschmitteltabletten
US6306814B1 (en)	2001-10-23	Detergent compositions
US6313080B1 (en)	2001-11-06	Detergent compositions
ES2269597T5 (es)	2011-02-14	Composiciones detergentes en forma de pastilla.
ES2249731T3 (es)	2006-04-01	Pastillas detergentes.
ES2301755T3 (es)	2008-07-01	Pastillas detergentes.
ES2257511T3 (es)	2006-08-01	Composiciones detergentes.
ES2254602T3 (es)	2006-06-16	Procedimiento de produccion de una pastilla de limpieza.
ES2287408T3 (es)	2007-12-16	Composiciones detergentes.
ES2304489T3 (es)	2008-10-16	Pastillas de detergente.
ES2254862T3 (es)	2006-06-16	Composiciones detergentes.
US6310028B1 (en)	2001-10-30	Water-softening and detergent compositions containing partially hydrated Na acetate
ES2375369T3 (es)	2012-02-29	Pastillas multi-fases de tratamiento de lavandería.
ES2310225T3 (es)	2009-01-01	Composiciones detergentes.
ES2292051T3 (es)	2008-03-01	Pastilla de detergente.
ES2326983T3 (es)	2009-10-22	Pastillas detergentes.
ES2289424T3 (es)	2008-02-01	Metodo para la preparacion de comprimidos limpiadores multi-fase que comprenden una fase suave.
EP1522575B1 (de)	2006-06-07	Waschmittelzusammensetzungen
EP1746151A1 (de)	2007-01-24	Wasch- und Reinigungsmitteltabletten
ES2294628T3 (es)	2008-04-01	Composiciones de detergente en forma de pastillas.
EP1496106A1 (de)	2005-01-12	Reinigungsmittelzusammensetzung
EP1710297A1 (de)	2006-10-11	Waschmittelzusammensetzungen in Tablettenform
PT1574563E (pt)	2007-08-03	Utilização de pastilhas de detergente