ES2501391T3 - Procedimiento para producir una composición anticongelante que contiene alcoholes inferiores y glicerol a través de alcohólisis de un glicérido - Google Patents

Procedimiento para producir una composición anticongelante que contiene alcoholes inferiores y glicerol a través de alcohólisis de un glicérido Download PDF

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Publication number
ES2501391T3
ES2501391T3 ES10184192.2T ES10184192T ES2501391T3 ES 2501391 T3 ES2501391 T3 ES 2501391T3 ES 10184192 T ES10184192 T ES 10184192T ES 2501391 T3 ES2501391 T3 ES 2501391T3
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Prior art keywords
alcohololysis
glyceride
producing
glycerol
procedure
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Expired - Lifetime
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ES10184192.2T
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English (en)
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Galen J. Suppes
William Rusty Sutterlin
Mohanprasad A. Dasari
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C09K3/185—Thawing materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/20—Antifreeze additives therefor, e.g. for radiator liquids
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
    • C12C11/00—Fermentation processes for beer
    • C12C11/02—Pitching yeast
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Wood Science & Technology (AREA)
  • Food Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Mycology (AREA)
  • Zoology (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)

Abstract

Un proceso para producir anticongelante a partir de un subproducto de glicerina bruta de la alcohólisis de un glicérido por un alcohol alquílico C1 a C4, que comprende los pasos de: 5 neutralizar la glicerina bruta para conseguir un pH entre 5 y 12, separar el alcohol C1 a C4 y el agua de la glicerina bruta de forma tal que las concentraciones conjuntas de agua y alcohol C1 a C4 sean inferiores al % (en peso); y poner en contacto la glicerina bruta separada con un catalizador de hidrogenación e hidrógeno a una presión de entre 1 y 20 bares y a una temperatura entre 10 100 °C y 290 °C durante un período de tiempo suficiente para conseguir una conversión de la glicerina de entre 60 y 90 %.

Description

1
DESCRIPCIÓN
ES10184192.2T 2004-03-25 2005-03-24 Procedimiento para producir una composición anticongelante que contiene alcoholes inferiores y glicerol a través de alcohólisis de un glicérido Expired - Lifetime ES2501391T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US55633404P 2004-03-25 2004-03-25
US556334P 2004-03-25

Publications (1)

Publication Number Publication Date
ES2501391T3 true ES2501391T3 (es) 2014-10-01

Family

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Family Applications (1)

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ES10184192.2T Expired - Lifetime ES2501391T3 (es) 2004-03-25 2005-03-24 Procedimiento para producir una composición anticongelante que contiene alcoholes inferiores y glicerol a través de alcohólisis de un glicérido

Country Status (4)

Country Link
EP (4) EP2298720B1 (es)
BR (1) BRPI0507874B1 (es)
ES (1) ES2501391T3 (es)
WO (1) WO2005095536A2 (es)

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US7663004B2 (en) 2002-04-22 2010-02-16 The Curators Of The University Of Missouri Method of producing lower alcohols from glycerol
US8252961B2 (en) 2002-04-22 2012-08-28 The Curators Of The University Of Missouri Method of producing lower alcohols from glycerol
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EP2024320A1 (en) * 2006-06-07 2009-02-18 The Procter and Gamble Company Process for the alternating conversion of glycerol to propylene glycol or amino alcohols
US7619118B2 (en) 2006-06-07 2009-11-17 The Procter & Gamble Company Process for the conversion of glycerol to propylene glycol and amino alcohols
US7619119B2 (en) 2006-06-07 2009-11-17 The Procter & Gamble Company Processes for converting glycerol to amino alcohols
GB0614823D0 (en) * 2006-07-26 2006-09-06 Davy Process Techn Ltd Process
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EP1889825A1 (de) * 2006-08-17 2008-02-20 Cognis Oleochemicals GmbH Verfahren zur Herstellung von 1,2-Propandiol
US20080103340A1 (en) * 2006-10-27 2008-05-01 Archer-Daniels-Midland Company Applications of biobased glycol compositions
GB0625614D0 (en) * 2006-12-27 2007-01-31 Leuven K U Res & Dev Catalytic process for the production of oxygenated hydrocarbons
US20100094066A1 (en) * 2007-01-17 2010-04-15 The Curators Of The University Of Missouri Gas phase reaction process for polyhydric compounds
BRPI0808970B1 (pt) 2007-03-23 2017-02-14 Metabolic Explorer Sa microrganismos e métodos de produção de 1,2-propanodiol e acetol
EP2010644A1 (en) * 2007-03-23 2009-01-07 Metabolic Explorer New micro-organisms for the production of acetol obtained by a combination of evolution and rational design.
EP2138478B1 (en) 2007-04-17 2019-07-24 Kao Corporation Process for producing hydrogenolysis products of polyhydric alcohols
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DE102007027372A1 (de) * 2007-06-11 2008-12-18 Cognis Oleochemicals Gmbh Verfahren zur Hydrierung von Glycerin
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BRPI0815783A2 (pt) 2007-08-31 2015-02-24 Basf Se Processo para a preparação de 1,2-propanodiol.
BRPI0815971B1 (pt) 2007-08-31 2017-10-24 Basf Se Method for preparing 1,2-propanodiol
CN101176848B (zh) * 2007-11-12 2011-03-02 青岛科技大学 一种3-羟基丙酸酯加氢制备1,3-丙二醇的催化剂及其制备方法
WO2009079667A1 (en) 2007-12-19 2009-06-25 The Curators Of The University Of Missouri Method of producing lower alcohols from glycerol
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JP5612806B2 (ja) * 2008-01-30 2014-10-22 花王株式会社 多価アルコールの水素化分解物の製造方法
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WO2009145691A1 (en) * 2008-05-30 2009-12-03 Perstorp Specialty Chemicals Ab Production of 1,2-propanediol
BRPI0909963A2 (pt) 2008-06-05 2019-03-06 Huntsman Petrochemical Llc processo para a produção e purificação de propileno glicol
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WO2011009936A2 (en) 2009-07-24 2011-01-27 Basf Se Process for the preparation of 1,2-propanediol from glycerol
US8969053B2 (en) 2009-07-30 2015-03-03 Metabolic Explorer Mutant YqhD enzyme for the production of a biochemical by fermentation
BR112012002153A2 (pt) 2009-07-30 2015-09-15 Metabolic Explorer Sa metilglioxal sintase mutante (mgs) para a produção de material bioquímico por fermentação
BRPI1000430A2 (pt) 2010-02-24 2011-10-25 Petroleo Brasileiro Sa produção de propilenoglicol a partir de glicerina
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EP2565175B1 (en) 2011-08-31 2021-04-21 Aristotle University of Thessaloniki Catalytic process for the production of 1,2-propanediol from crude glycerol stream
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Also Published As

Publication number Publication date
EP2298722A2 (en) 2011-03-23
EP2298721A3 (en) 2011-07-27
WO2005095536A2 (en) 2005-10-13
EP2298722A3 (en) 2011-07-27
WO2005095536A3 (en) 2006-03-16
BRPI0507874A (pt) 2007-07-24
EP2298720B1 (en) 2020-01-01
EP2298721B1 (en) 2014-06-04
EP2298721A2 (en) 2011-03-23
EP2298720A3 (en) 2011-07-27
BRPI0507874B1 (pt) 2019-03-12
EP2298720A2 (en) 2011-03-23
EP1727875A2 (en) 2006-12-06
EP1727875B1 (en) 2015-11-04

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