ES2523029T3 - Pastilla de detergente revestida de polímero - Google Patents
Pastilla de detergente revestida de polímero Download PDFInfo
- Publication number
- ES2523029T3 ES2523029T3 ES08021163.4T ES08021163T ES2523029T3 ES 2523029 T3 ES2523029 T3 ES 2523029T3 ES 08021163 T ES08021163 T ES 08021163T ES 2523029 T3 ES2523029 T3 ES 2523029T3
- Authority
- ES
- Spain
- Prior art keywords
- coating
- detergent
- acid
- detergent composition
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000003599 detergent Substances 0.000 title claims abstract description 77
- 229920000642 polymer Polymers 0.000 title description 19
- 239000000203 mixture Substances 0.000 claims abstract description 76
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 50
- 238000000576 coating method Methods 0.000 claims abstract description 46
- 239000011248 coating agent Substances 0.000 claims abstract description 42
- 235000000346 sugar Nutrition 0.000 claims abstract description 27
- 150000001413 amino acids Chemical class 0.000 claims abstract description 23
- 150000008163 sugars Chemical class 0.000 claims abstract description 17
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 15
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 12
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 9
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims description 33
- 238000004851 dishwashing Methods 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 2
- 150000003384 small molecules Chemical class 0.000 abstract description 9
- -1 vinyl polyol Chemical class 0.000 description 33
- 239000003826 tablet Substances 0.000 description 30
- 229920001577 copolymer Polymers 0.000 description 28
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 15
- 239000000654 additive Substances 0.000 description 14
- 239000000975 dye Substances 0.000 description 14
- 239000004615 ingredient Substances 0.000 description 14
- 230000000996 additive effect Effects 0.000 description 13
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- 125000004432 carbon atom Chemical group C* 0.000 description 8
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- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
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- 125000000217 alkyl group Chemical group 0.000 description 6
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- 230000002209 hydrophobic effect Effects 0.000 description 6
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- 239000010410 layer Substances 0.000 description 5
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical class CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 239000008199 coating composition Substances 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- 239000011976 maleic acid Substances 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
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- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
- SERLAGPUMNYUCK-YJOKQAJESA-N 6-O-alpha-D-glucopyranosyl-D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O SERLAGPUMNYUCK-YJOKQAJESA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- 229920000289 Polyquaternium Polymers 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000002671 adjuvant Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 238000007046 ethoxylation reaction Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 150000002314 glycerols Chemical class 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 150000004702 methyl esters Chemical class 0.000 description 3
- 125000006353 oxyethylene group Chemical group 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000006187 pill Substances 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 239000000047 product Substances 0.000 description 3
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- 108090000623 proteins and genes Proteins 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
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- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- QHZLMUACJMDIAE-UHFFFAOYSA-N 1-monopalmitoylglycerol Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(O)CO QHZLMUACJMDIAE-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- NKVJCKOMRJVZLO-UHFFFAOYSA-N 3,6,7-trioxabicyclo[7.2.2]trideca-1(11),9,12-triene-2,8-dione Chemical compound O=C1OCCOOC(=O)C2=CC=C1C=C2 NKVJCKOMRJVZLO-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- QEWLHSNMEXFSCI-UHFFFAOYSA-N Alloclamide hydrochloride Chemical compound Cl.CCN(CC)CCNC(=O)C1=CC=C(Cl)C=C1OCC=C QEWLHSNMEXFSCI-UHFFFAOYSA-N 0.000 description 2
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 description 2
- 235000021357 Behenic acid Nutrition 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
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- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
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- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- RUAIJHHRCIHFEV-UHFFFAOYSA-N methyl 4-amino-5-chlorothiophene-2-carboxylate Chemical compound COC(=O)C1=CC(N)=C(Cl)S1 RUAIJHHRCIHFEV-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
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- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
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- 238000003801 milling Methods 0.000 description 1
- XFHJDMUEHUHAJW-UHFFFAOYSA-N n-tert-butylprop-2-enamide Chemical compound CC(C)(C)NC(=O)C=C XFHJDMUEHUHAJW-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
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- 239000003921 oil Substances 0.000 description 1
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- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 239000004006 olive oil Substances 0.000 description 1
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- 239000003960 organic solvent Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
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- 239000002861 polymer material Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
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- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000004172 quinoline yellow Substances 0.000 description 1
- 229940051201 quinoline yellow Drugs 0.000 description 1
- 235000012752 quinoline yellow Nutrition 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
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- 235000005713 safflower oil Nutrition 0.000 description 1
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- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
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- 235000013874 shellac Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
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- 229910052709 silver Inorganic materials 0.000 description 1
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- 238000002791 soaking Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
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- 229950003429 sorbitan palmitate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 229940035023 sucrose monostearate Drugs 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 230000009747 swallowing Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229920006029 tetra-polymer Polymers 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- ODBLHEXUDAPZAU-UHFFFAOYSA-N threo-D-isocitric acid Natural products OC(=O)C(O)C(C(O)=O)CC(O)=O ODBLHEXUDAPZAU-UHFFFAOYSA-N 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 239000010981 turquoise Substances 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0082—Coated tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08021163.4A EP2196531B1 (en) | 2008-12-05 | 2008-12-05 | Polymer coated detergent tablet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2523029T3 true ES2523029T3 (es) | 2014-11-20 |
Family
ID=40568633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES08021163.4T Active ES2523029T3 (es) | 2008-12-05 | 2008-12-05 | Pastilla de detergente revestida de polímero |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP2196531B1 (pl) |
| ES (1) | ES2523029T3 (pl) |
| PL (1) | PL2196531T3 (pl) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103068959B (zh) * | 2010-08-06 | 2015-03-04 | 雷利维股份公司 | 覆有薄膜的清洁剂 |
| US9683199B2 (en) | 2010-11-10 | 2017-06-20 | Colgate-Palmolive Company | Fabric conditioners containing soil releasing polymer |
| ITRE20110036A1 (it) * | 2011-05-24 | 2012-11-25 | Re Le Vi Spa | Sistema per l'applicazione di un agente sanitario adesivo ad una parete di un apparato sanitario |
| DE102012214607A1 (de) * | 2012-08-16 | 2014-02-20 | Henkel Ag & Co. Kgaa | Wasserlösliche Verpackung mit Bittermittel I |
| DE102012214608A1 (de) | 2012-08-16 | 2014-02-20 | Henkel Ag & Co. Kgaa | Wasserlösliche Verpackung mit Bittermittel II |
| WO2015085204A1 (en) | 2013-12-06 | 2015-06-11 | Monosol Llc | Fluorescent tracer for water-soluble films, related methods, and related articles |
| WO2015120886A1 (en) | 2014-02-11 | 2015-08-20 | Eurvest Sa | Sanitary self-adhesive products |
| EP3334817B2 (en) * | 2015-08-11 | 2023-08-23 | Unilever IP Holdings B.V. | Water-soluble package |
| HUE052500T2 (hu) | 2015-08-11 | 2021-04-28 | Unilever Nv | Vízben oldódó csomagolás |
| EP3334816B1 (en) | 2015-08-11 | 2019-01-23 | Unilever Plc. | Water-soluble package |
| EP3138901A1 (en) * | 2015-09-04 | 2017-03-08 | The Procter & Gamble Company | Water soluble unit dose detergent article comprising an aversive or bittering agent |
| FR3044678B1 (fr) | 2015-12-04 | 2017-12-08 | Eurotab | Tablette detergente enrobee |
| WO2017137225A1 (en) | 2016-02-09 | 2017-08-17 | Unilever Plc | Water-soluble package |
| EP3694964B1 (en) | 2017-10-13 | 2025-08-06 | Unilever IP Holdings B.V. | Aqueous spray composition |
| BR112020007337B1 (pt) | 2017-10-13 | 2023-09-26 | Unilever Ip Holdings B.V | Composição spray aquosa para tecido, método de rejuvenescimento de tecido, método de inserção de uma dobra em uma peça de vestuário e uso da composição |
| EP3694965B1 (en) | 2017-10-13 | 2025-02-12 | Unilever IP Holdings B.V. | Aqueous spray composition |
| WO2019072648A1 (en) | 2017-10-13 | 2019-04-18 | Unilever Plc | SPRAY COMPOSITIONS ON FABRICS |
| CN114302944A (zh) | 2019-09-23 | 2022-04-08 | 埃科莱布美国股份有限公司 | 颜色变化洗涤剂组合物和使用方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0726935B1 (en) | 1993-11-03 | 2000-08-30 | The Procter & Gamble Company | Control of calcium carbonate precipitation in automatic dishwashing |
| DE69427696T2 (de) | 1994-09-12 | 2002-05-08 | Procter & Gamble | Portionsverpacktes Waschmittel |
| CA2236605A1 (en) | 1997-05-09 | 1998-11-09 | Yves Duccini | Scale inhibitors |
| CA2329618A1 (en) | 1998-04-27 | 1999-11-04 | The Procter & Gamble Company | Coated non-particulate detergent product having contoured surface |
| DE19920118B4 (de) | 1999-05-03 | 2016-08-11 | Henkel Ag & Co. Kgaa | Wasch- und Reinigungsmittelformkörper mit Beschichtung und Verfahren zu seiner Herstellung |
| CA2404579C (en) | 2000-03-29 | 2009-08-11 | National Starch And Chemical Investment Holding Corporation | Polymers that inhibit calcium phosphate and calcium carbonate scale in autodish applications |
| DE10050622A1 (de) | 2000-07-07 | 2002-05-02 | Henkel Kgaa | Klarspülmittel II a |
| DE10050958A1 (de) * | 2000-10-13 | 2002-04-18 | Basf Ag | Verwendung von wasserlöslichen oder wasserdispergierbaren Polyetherblöcken enthaltenden Pfropfpolymerisaten als Beschichtungs- und Verpackungsmittel für Wasch-, Reinigungs- und Wäschebehandlungsmitte |
| ATE305886T1 (de) * | 2000-10-18 | 2005-10-15 | Reckitt Benckiser Nv | Waschmittel verpackt mit ethoxyliertem polyvinylalkohol |
| DE10109799A1 (de) | 2001-03-01 | 2002-09-05 | Henkel Kgaa | 3in1-Geschirrspülmittel und Verfahren zur Herstellung derselben |
| DE10207427A1 (de) * | 2002-02-21 | 2003-09-04 | Basf Ag | Schnelllöslicher Filmüberzug basierend auf Polyvinylalkohol-Polyether-Pfropfcopolymeren in Kombination mit Hydroxy-, Amid-, oder Esterfunktionen enthaltenden Komponenten |
| JP4189213B2 (ja) | 2002-08-30 | 2008-12-03 | 花王株式会社 | 洗剤粒子 |
| EP1520908A1 (de) | 2003-10-01 | 2005-04-06 | Dalli-Werke GmbH & Co. KG | Maschinengeschirrreiniger mit verbesserten Spüleigenschaften |
| EP1571198A1 (en) | 2004-03-02 | 2005-09-07 | Dalli-Werke GmbH & Co. KG. | Polymer bound manganese compounds in cleaning compositions |
| EP1903099A1 (en) * | 2006-09-22 | 2008-03-26 | Dalli-Werke GmbH & Co. KG | Coated detergent compositions and manufacture process |
| JP2010514723A (ja) * | 2006-12-29 | 2010-05-06 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリビニルアルコール−ポリエーテルグラフトコポリマーをベースとする迅速に分散可能な粒状フィルムコーティング剤 |
-
2008
- 2008-12-05 PL PL08021163T patent/PL2196531T3/pl unknown
- 2008-12-05 ES ES08021163.4T patent/ES2523029T3/es active Active
- 2008-12-05 EP EP08021163.4A patent/EP2196531B1/en not_active Not-in-force
Also Published As
| Publication number | Publication date |
|---|---|
| EP2196531A1 (en) | 2010-06-16 |
| PL2196531T3 (pl) | 2015-02-27 |
| EP2196531B1 (en) | 2014-09-03 |
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