ES2524585T3 - Sistema catalizador para la polimerización de olefinas, su producción y su uso - Google Patents

Sistema catalizador para la polimerización de olefinas, su producción y su uso Download PDF

Info

Publication number
ES2524585T3
ES2524585T3 ES05741820.4T ES05741820T ES2524585T3 ES 2524585 T3 ES2524585 T3 ES 2524585T3 ES 05741820 T ES05741820 T ES 05741820T ES 2524585 T3 ES2524585 T3 ES 2524585T3
Authority
ES
Spain
Prior art keywords
catalyst system
mixture
olefins
polymerization
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES05741820.4T
Other languages
English (en)
Inventor
Shahram Mihan
Harald Schmitz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Application granted granted Critical
Publication of ES2524585T3 publication Critical patent/ES2524585T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Un procedimiento para producir un sistema catalizador, el cual comprende las siguientes etapas: A) la provisión de una mezcla de por lo menos dos compuestos diferentes de metales de transición, de los grupos 3 a 12 de Tabla Periódica de los Elementos, o los lantánidos, los cuales contengan grupos orgánicos, por lo menos un compuesto de organoaluminio hidrolizado, seleccionado de entre el grupo consistente en los aluminoxanos y los hidroxialuminoxanos, y un disolvente y B) la impregnación de un componente de soporte poroso, seco, con la mezcla procedente de la etapa A), siendo, el volumen total de la mezcla, de 0,6 a 1,5 veces el volumen de poros total del componente de soporte, según se determina mediante porosimetría, en concordancia con la norma DIN 66133

Description

imagen1
imagen2
imagen3
imagen4
imagen5
imagen6
imagen7
imagen8
imagen9
imagen10
imagen11
imagen12
imagen13
imagen14
imagen15
imagen16
imagen17
imagen18
imagen19
imagen20
imagen21
imagen22
imagen23
imagen24
imagen25

Claims (1)

  1. imagen1
ES05741820.4T 2004-04-26 2005-04-21 Sistema catalizador para la polimerización de olefinas, su producción y su uso Expired - Lifetime ES2524585T3 (es)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE102004020525 2004-04-26
DE102004020525A DE102004020525A1 (de) 2004-04-26 2004-04-26 Katalysatorsystem zur Olefinpolymerisation, dessen Herstellung und Verwendung
US57908104P 2004-06-10 2004-06-10
US579081P 2004-06-10
PCT/EP2005/004255 WO2005103099A1 (en) 2004-04-26 2005-04-21 Catalyst system for olefin polymerization, its production and use

Publications (1)

Publication Number Publication Date
ES2524585T3 true ES2524585T3 (es) 2014-12-10

Family

ID=35456104

Family Applications (1)

Application Number Title Priority Date Filing Date
ES05741820.4T Expired - Lifetime ES2524585T3 (es) 2004-04-26 2005-04-21 Sistema catalizador para la polimerización de olefinas, su producción y su uso

Country Status (10)

Country Link
US (1) US7671148B2 (es)
EP (1) EP1740626B1 (es)
JP (1) JP4820361B2 (es)
KR (1) KR101222237B1 (es)
CN (1) CN101065410B (es)
BR (1) BRPI0509734B1 (es)
DE (1) DE102004020525A1 (es)
ES (1) ES2524585T3 (es)
SG (1) SG155162A1 (es)
WO (1) WO2005103099A1 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004020524A1 (de) * 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
DE102004029465A1 (de) 2004-06-18 2006-01-05 Basell Polyolefine Gmbh Verfahren zur Bestimmung und Regelung der Zusammensetzung von Polymermischungen bei der Polymerisation
GB0520085D0 (en) 2005-10-03 2005-11-09 Sasol Tech Pty Ltd Oligomerisation of olefinic compounds in the presence of an oligomerisation catalyst, and a catalyst activator including a halogenated -AR group
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
JP4431605B2 (ja) * 2007-08-09 2010-03-17 シャープ株式会社 トナーの製造方法、トナー、二成分現像剤、現像装置および画像形成装置
KR101018484B1 (ko) * 2007-12-27 2011-03-03 한국과학기술원 프로필렌 중합용 담지 촉매, 및 이를 이용한 프로필렌중합체의 제조방법
US8999875B2 (en) 2010-05-28 2015-04-07 Basell Polyolefine Gmbh Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use
EP2676972A1 (en) * 2012-06-19 2013-12-25 Basell Polyolefine GmbH Process for the obtainment of a polyolefin composition
GB201408615D0 (en) * 2014-05-15 2014-06-25 Scg Chemicals Co Ltd Oligomerisation of ethylene
CN110964141B (zh) * 2019-12-06 2022-04-01 中玺新材料（安徽）有限公司 一种负载铬锆钼三金属催化剂及其制备方法和应用
KR102947655B1 (ko) 2020-12-01 2026-04-01 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용한 올레핀 중합체의 제조방법

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242150A (en) 1960-03-31 1966-03-22 Phillips Petroleum Co Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US5763547A (en) * 1992-10-02 1998-06-09 The Dow Chemical Company Supported catalyst complexes for olefin in polymerization
FI96866C (fi) 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
AU686836B2 (en) * 1994-06-24 1998-02-12 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
JP2004043823A (ja) * 1995-01-25 2004-02-12 Mitsui Chemicals Inc オレフィンの気相重合方法
US5527752A (en) 1995-03-29 1996-06-18 Union Carbide Chemicals & Plastics Technology Corporation Catalysts for the production of polyolefins
IT1275573B (it) 1995-07-20 1997-08-07 Spherilene Spa Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use
IL129929A0 (en) 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
ES2229683T3 (es) 1998-03-12 2005-04-16 Bp Chemicals Limited Catalizadores de polimerizacion.
US7906451B2 (en) * 1998-03-30 2011-03-15 E.I. Du Pont De Nemours And Company Mixed polymerization catalyst component for polymerizing olefins
DE19903306A1 (de) * 1999-01-28 2000-08-03 Targor Gmbh Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung
US6160145A (en) 1998-10-23 2000-12-12 Albemarle Corporation Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components
BR9906934B1 (pt) 1998-11-25 2010-08-24 composto, catalisador, processo para preparar uma poliolefina, e, uso de um catalisador.
GB9906296D0 (en) 1999-03-18 1999-05-12 Bp Chem Int Ltd Polymerisation catalysts
DE19935592A1 (de) 1999-08-02 2001-02-08 Elenac Gmbh Imidochromverbindungen in Katalysatorsystemen für die Olefinpolymerisation
JP2003510427A (ja) * 1999-09-29 2003-03-18 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー ポリエチレンの製造
WO2002038628A2 (en) 2000-11-07 2002-05-16 Symyx Technologies, Inc. Substituted pyridyl amine ligands, complexes and catalysts therefrom; processes for producing polyolefins therewith
ATE337343T1 (de) * 2001-04-30 2006-09-15 Grace W R & Co Geträgerte dualübergangsmetallkatalysatorsysteme
WO2003040201A1 (en) 2001-11-06 2003-05-15 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
CN1259347C (zh) * 2002-11-07 2006-06-14 中国科学院化学研究所 一种载体化烯烃聚合催化剂及其制备方法

Also Published As

Publication number Publication date
EP1740626B1 (en) 2014-10-22
JP2007534809A (ja) 2007-11-29
CN101065410A (zh) 2007-10-31
KR20070015407A (ko) 2007-02-02
EP1740626A1 (en) 2007-01-10
BRPI0509734A (pt) 2007-09-25
KR101222237B1 (ko) 2013-01-16
US7671148B2 (en) 2010-03-02
WO2005103099A1 (en) 2005-11-03
SG155162A1 (en) 2009-09-30
US20070207916A1 (en) 2007-09-06
JP4820361B2 (ja) 2011-11-24
BRPI0509734B1 (pt) 2016-08-16
CN101065410B (zh) 2010-10-13
DE102004020525A1 (de) 2005-11-10

Similar Documents

Publication Publication Date Title
AR084818A2 (es) Catalizador metaloceno, su sintesis y sus usos en la polimerizacion de olefinas
NI200700057A (es) Compuestos de aminoheteroarilo enantioméricamente puros como inhibidores de proteina quinasa
CR10937A (es) Inhibidores de cinasa mapk/erk
AR067316A1 (es) Moleculas secuestradoras de oxigeno, articulos que las contienen y metodos para su uso
ES2176180T3 (es) Uso de compuestos organometalicos de fluorenilo.
ES479102A1 (es) Procedimiento para preparar una composicion catalitica a ba-se de titanio y magnesio.
CR8938A (es) Compuestos de aminoheteroarilo o sustituidos con pirazol como inhibidores de proteina quinasa
ECSP088932A (es) Nuevos compuestos químicos
CR9544A (es) Metodos para sintetizar 3-cianoquinolinas sustituidas e intermedios de estas
ES2083728T3 (es) Procedimiento para la preparacion de hidroximetil-5 furfural mediante catalisis heterogenea.
ATE462731T1 (de) Katalysatorzusammensetzung zur olefinpolymerisierung
CR9985A (es) Metodos para preparar rapamicina cristalina y para medir la cristalinidad de los compuestos de rapamicina utilizando calorimetria diferencial del barrido
UY30475A1 (es) Procedimientos para fabricar bromuro de 3(r)-(2-hidroxi-2,2-dietien-2-ilaxetoxi)-1-(3-fenoxipropil)-1-azoniabiciclo[2.2.2]octano.
CR10780A (es) Inhibidores de cinasa
AR109669A1 (es) Proceso para preparar 2-exo-(2-metilbenciloxi)-1-metil-4-isopropil-7-oxabiciclo[2.2.1]heptano
ECSP045219A (es) Derivados de quinazolinona y su uso como agonistas cb
PY0223362A (es) Compuestos de benzimidazol sustituido y su uso para el tratamiento del cancer
ES2542080T3 (es) Sistema catalizador para la polimerización de olefinas
DE602007002294D1 (de) Verfahren zur Herstellung organischer poröser Festkörper und mit diesem Verfahren herstellbare Festkörper
BRPI0509734A (pt) processo para produzir um sistema de catalisador, sistema de catalisador, uso do mesmo, e, processo para preparar poliolefinas
AR073640A1 (es) Metodo para obtener un drivado aminoindan mesilato
PA8636101A1 (es) Metodo para la preparacion de acidos hidroxamicos
AR048501A1 (es) Compuesto de benzoazabicicloheptano dimerico, composicion farmaceutica que lo comprende y su uso para prepararla
EP1650200A4 (en) SULPHONATE COMPOUND AND FLUORESCENCE ENCODER USING THIS
ES2531393T3 (es) Proceso de semisíntesis para la preparación de 10 desacetil-N-desbenzoil-paclitaxel