ES2528402T3 - Adhesivo para laminados de barrera para gas y películas laminadas - Google Patents

Adhesivo para laminados de barrera para gas y películas laminadas Download PDF

Info

Publication number
ES2528402T3
ES2528402T3 ES02762976.5T ES02762976T ES2528402T3 ES 2528402 T3 ES2528402 T3 ES 2528402T3 ES 02762976 T ES02762976 T ES 02762976T ES 2528402 T3 ES2528402 T3 ES 2528402T3
Authority
ES
Spain
Prior art keywords
epoxy resin
curing agent
xylylenediamine
adhesive
ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES02762976.5T
Other languages
English (en)
Inventor
Takaaki Kutsuna
Shuta Kihara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Gas Chemical Co Inc
Original Assignee
Mitsubishi Gas Chemical Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Gas Chemical Co Inc filed Critical Mitsubishi Gas Chemical Co Inc
Application granted granted Critical
Publication of ES2528402T3 publication Critical patent/ES2528402T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/02—Polyamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10018—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5033—Amines aromatic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J179/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09J161/00 - C09J177/00
    • C09J179/02—Polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
    • C08L2666/20—Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Laminated Bodies (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Epoxy Resins (AREA)

Abstract

Adhesivo para laminados que contiene, como componente principal, una composición de resina epoxi que comprende una resina epoxi que contiene restos de glicidilamina derivados de m-xililendiamina y un agente de curado de resina epoxi, estando la composición de resina epoxi formada en un producto curado de resina epoxi que contiene una estructura de esqueleto representada por la fórmula (1):**Fórmula** en una cantidad de al menos el 40 % en peso, en el que el agente de curado de resina epoxi es un producto de reacción de m-xililendiamina con al menos uno seleccionado del grupo que consiste en ácido acrílico, ácido metacrílico o un derivado de los mismos, donde una relación molar de al menos uno seleccionado del grupo que consiste en ácido acrílico, ácido metacrílico o un derivado de los mismos con respecto a m-xililendiamina se encuentra dentro del intervalo de 0,8 a 0,97, donde la relación de mezcla entre la resina epoxi y el agente de curado de resina epoxi en la composición de resina epoxi es tal que una relación equivalente de hidrógeno activo contenido en el agente de curado de resina epoxi con respecto a los grupos epoxi contenidos en la resina epoxi se encuentra dentro del intervalo de 0,8 a 1,4, y donde una película laminada preparada usando el adhesivo tiene una fuerza de adhesión inicial de 30 g/15 mm o superior como se mide entre materiales de película de los mismos sometiendo la película laminada a la prueba de pelado en T a una velocidad de pelado de 300 mm/min inmediatamente después de la laminación.

Description

imagen1
imagen2
imagen3
imagen4
imagen5
imagen6
imagen7
imagen8
imagen9
imagen10
imagen11
imagen12
imagen13
imagen14
imagen15
imagen16

Claims (1)

  1. imagen1
ES02762976.5T 2001-09-05 2002-09-03 Adhesivo para laminados de barrera para gas y películas laminadas Expired - Lifetime ES2528402T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2001269073 2001-09-05
JP2001269073 2001-09-05
PCT/JP2002/008920 WO2003022952A1 (en) 2001-09-05 2002-09-03 Adhesive for gas barrier laminates and laminated films

Publications (1)

Publication Number Publication Date
ES2528402T3 true ES2528402T3 (es) 2015-02-09

Family

ID=19094953

Family Applications (1)

Application Number Title Priority Date Filing Date
ES02762976.5T Expired - Lifetime ES2528402T3 (es) 2001-09-05 2002-09-03 Adhesivo para laminados de barrera para gas y películas laminadas

Country Status (9)

Country Link
US (1) US7425598B2 (es)
EP (1) EP1437393B1 (es)
KR (1) KR100923609B1 (es)
CN (1) CN1280375C (es)
AU (1) AU2002328410B2 (es)
CA (1) CA2459379C (es)
ES (1) ES2528402T3 (es)
TW (1) TWI302932B (es)
WO (1) WO2003022952A1 (es)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2365922C (en) * 2000-12-26 2010-03-09 Mitsubishi Gas Chemical Company, Inc. Composition for coating having a gas barrier property, coating and coated film having a gas barrier property using the same
JP2005054145A (ja) * 2003-08-07 2005-03-03 Mitsubishi Gas Chem Co Inc ガスバリア性（メタ）アクリレート樹脂硬化物および塗料、接着剤、フィルム
DE102004037045A1 (de) * 2004-07-29 2006-04-27 Degussa Ag Wässrige Silan-Nanokomposite
DE602005024653D1 (de) * 2004-08-27 2010-12-23 Mitsubishi Gas Chemical Co Verfahren zum Herstellen von Hohlkörpern
BRPI0710129A2 (pt) * 2006-04-13 2011-08-02 Toray Industries filme de barreira de gás
EP2065178B1 (en) * 2006-09-22 2014-06-25 Toray Industries, Inc. Gas barrier film
WO2008101887A1 (de) * 2007-02-20 2008-08-28 Basf Se SIEGELBARES LAMINAT FÜR WIEDERVERSCHLIEßBARE VERPACKUNGEN
US8128782B2 (en) * 2007-05-21 2012-03-06 Mitsubishi Gas Chemical Company, Inc. Amine epoxy resin curing agent, gas barrier epoxy resin composition comprising the curing agent, coating agent, and adhesive agent for laminate
JP5213522B2 (ja) * 2008-05-16 2013-06-19 三菱樹脂株式会社 有機デバイス用ガスバリア性積層フィルム
DE102009027329A1 (de) 2009-06-30 2011-01-05 Henkel Ag & Co. Kgaa 2-Komponenten Kaschierklebstoff
US8580984B2 (en) 2009-07-10 2013-11-12 Dow Global Technologies Llc Esters of secondary hydroxy fatty acid oligomers and preparation thereof
WO2011106186A1 (en) * 2010-02-26 2011-09-01 Dow Global Technologies Llc Estolide derivatives useful as biolubricants
CN102812067B (zh) * 2010-03-16 2014-09-10 三菱瓦斯化学株式会社 环氧树脂固化剂、环氧树脂组合物以及层压用粘接剂
EP2562194A4 (en) * 2010-04-21 2016-08-03 Mitsubishi Gas Chemical Co EPOXY RESIN CURING AGENT, EPOXY RESIN COMPOSITION, AND ADHESIVE AGENT FOR LAMINATE
CN102906155A (zh) 2010-04-29 2013-01-30 陶氏环球技术有限责任公司 低聚酯烷氧基化物组合物
EP2546230A1 (de) 2011-07-15 2013-01-16 Sika Technology AG Emissionsarmer Härter für Epoxidharze
JP5800659B2 (ja) * 2011-10-05 2015-10-28 オリンパス株式会社 医療器具用接着剤組成物、および内視鏡装置
JP6241674B2 (ja) * 2012-04-27 2017-12-06 三菱瓦斯化学株式会社 エポキシ樹脂硬化剤、エポキシ樹脂組成物、及びガスバリア性接着剤、並びにガスバリア性積層体
KR20150048166A (ko) * 2012-08-23 2015-05-06 헨켈 아게 운트 코. 카게아아 2성분 (2k) 적층 접착제
WO2014157151A1 (ja) * 2013-03-26 2014-10-02 三菱瓦斯化学株式会社 活性エネルギー線硬化性樹脂及び該樹脂の硬化物を含むガスバリア性積層体
CN103360993B (zh) * 2013-07-05 2016-03-16 全椒海丰印刷包装有限公司 一种白乳胶复合纸箱胶粘剂及其制备方法
CN103360987B (zh) * 2013-07-05 2016-03-30 全椒海丰印刷包装有限公司 一种包装纸材料用的胶粘剂及其制备方法
WO2016006125A1 (ja) * 2014-07-11 2016-01-14 Dic株式会社 シーラントフィルムを有する積層体
WO2017151898A1 (en) * 2016-03-02 2017-09-08 3M Innovative Properties Company Composition including epoxy adhesive and aluminum flakes and method for making the same
JP7638889B2 (ja) 2019-03-15 2025-03-04 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン ガスバリア性接着剤を含有するスルホン樹脂
US12281195B2 (en) 2019-08-14 2025-04-22 Mitsubishi Gas Chemical Company, Inc. Epoxy resin composition, gas barrier film, and laminate
RS65548B1 (sr) * 2020-08-31 2024-06-28 Ivetic Aleksandra Stabilizatori silaže

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3683044A (en) * 1969-12-29 1972-08-08 Japan Gas Chemical Co Heat-curable composition comprising polyglycidyl xylylene-diamine and process for preparation of polyglycidyl xylylenediamine
JPS5780470A (en) * 1980-11-10 1982-05-20 Mitsubishi Chem Ind Ltd Adhesive for laminating polyolefin to metal
CH650767A5 (de) * 1981-12-17 1985-08-15 Ciba Geigy Ag Amingruppenhaltige carbonsaeureamide und ihre verwendung als haerter fuer epoxidharze.
JPS63301264A (ja) * 1987-05-30 1988-12-08 Nitto Electric Ind Co Ltd 塗料組成物
NZ281449A (en) 1994-03-31 1997-07-27 Ppg Industries Inc Barrier coatings based on polyepoxide-polyamine resin
JPH08104738A (ja) * 1994-08-10 1996-04-23 Mitsubishi Gas Chem Co Inc エポキシ樹脂硬化剤
AU3679995A (en) * 1994-12-16 1996-07-03 Ppg Industries, Inc. Epoxy-amine barrier coatings with aryloxy or aryloate groups
US5728439A (en) * 1996-12-04 1998-03-17 Ppg Industries, Inc. Multilayer packaging material for oxygen sensitive food and beverage
US20020006484A1 (en) * 1998-05-20 2002-01-17 Balasubramaniam Ramalingam Adhesive and coating formulations for flexible packaging
CA2365922C (en) * 2000-12-26 2010-03-09 Mitsubishi Gas Chemical Company, Inc. Composition for coating having a gas barrier property, coating and coated film having a gas barrier property using the same
EP1270206B1 (en) * 2001-06-27 2005-11-02 Mitsubishi Gas Chemical Company, Inc. Oxygen-absorbing multi-layer film
EP1352933B1 (en) * 2002-04-08 2011-06-08 Mitsubishi Gas Chemical Company, Inc. Flexible gas barrier film
CN100343046C (zh) * 2002-06-25 2007-10-17 三菱瓦斯化学株式会社 气体屏蔽性容器

Also Published As

Publication number Publication date
AU2002328410B2 (en) 2008-06-26
KR100923609B1 (ko) 2009-10-23
CA2459379C (en) 2010-08-17
EP1437393A1 (en) 2004-07-14
WO2003022952A1 (en) 2003-03-20
CN1551910A (zh) 2004-12-01
US20050014908A1 (en) 2005-01-20
EP1437393A4 (en) 2005-01-12
KR20040044857A (ko) 2004-05-31
CA2459379A1 (en) 2003-03-20
CN1280375C (zh) 2006-10-18
US7425598B2 (en) 2008-09-16
TWI302932B (es) 2008-11-11
EP1437393B1 (en) 2014-12-03

Similar Documents

Publication Publication Date Title
JP5201347B2 (ja) 有機ｅｌ素子封止用光硬化性樹脂組成物
WO2003022952A1 (en) Adhesive for gas barrier laminates and laminated films
KR101788911B1 (ko) 3d 프린팅용 수지 조성물
ES2685912T3 (es) Cinta adhesiva
CN110894361A (zh) 光固化封装组合物、封装结构及半导体器件
BRPI0516699A (pt) composição de resina epóxi adesiva curável, processo para preparar uma composição de resina epóxi adesiva curável e dois ou mais substratos
MY156295A (en) High performance adhesive compositions
BR112015007956A2 (pt) composição, processo para preparar uma composição, pré-impregnado, revestimento, compósito, laminado elétrico e adesivo eletrônico
BR112016029780A2 (pt) composições adesivas de epóxi de cura rápida
ES2525240T3 (es) Cuerpo laminado de alta barrera
NI201000129A (es) Materiales elastomericos.
BRPI0512077A (pt) pelìculas de múltiplas camadas
BR112012011534A2 (pt) materiais de liberação de blenda de fluorossilicone
WO2009069562A1 (ja) 樹脂組成物
ES2971016T3 (es) Compuesto para el moldeo de láminas y material compuesto reforzado con fibra
CN107207836A (zh) 电子器件密封用固化性吸湿性树脂组合物、树脂固化物和电子器件
CN110982346A (zh) 墨水组合物、封装结构及半导体器件
JP2015098567A (ja) 活性エネルギー線重合性接着剤、及び積層体
PE20090860A1 (es) Aductos amina-funcionales y composiciones curables que los contienen
BR112013023688A2 (pt) solução aceleradora adequada para formar um sistema redox com peróxidos e composição de resina pré-aceleradora
BRPI0520574A2 (pt) método de tratamento superficial de estruturas de material composto com feixes de plasma atmosférico
BR112021011945B8 (pt) Composição adesiva sem solvente de dois componentes, laminado e método de formação de uma composição adesiva sem solvente de dois componentes
JP2015040278A (ja) 活性エネルギー線重合性樹脂組成物及び積層体
KR102456269B1 (ko) 활성 에너지선 중합성 수지 조성물 및 적층체
JP2015104917A (ja) 剥離フィルム、それを用いた粘着フィルム構造体