ES2656823T3 - Compuestos fotocrómicos - Google Patents

Compuestos fotocrómicos Download PDF

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ES2656823T3
ES2656823T3 ES11001431.3T ES11001431T ES2656823T3 ES 2656823 T3 ES2656823 T3 ES 2656823T3 ES 11001431 T ES11001431 T ES 11001431T ES 2656823 T3 ES2656823 T3 ES 2656823T3
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phenyl
naphtho
pyran
piperidin
indene
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Meng He
Terry A. II Kellar
Anil Kumar
Forrest R. Blakburn
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Transitions Optical Inc
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Transitions Optical Inc
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    • C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
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    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
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    • C07D311/94—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems condensed with rings other than six-membered or with ring systems containing such rings
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    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/10—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing aromatic rings
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    • C07—ORGANIC CHEMISTRY
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    • C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
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    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
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    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/22—Absorbing filters
    • G02B5/23—Photochromic filters
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3016—Polarising elements involving passive liquid crystal elements
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/72—Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705
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  • Optical Filters (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Polarising Elements (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Pyrane Compounds (AREA)
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  • Liquid Crystal (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Steroid Compounds (AREA)
  • Paints Or Removers (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

Un compuesto fotocrómico: (I) que comprende: (A) al menos un grupo fotocrómico seleccionado entre un pirano, una oxazina y un fúlgido; y (B) al menos un agente de alargamiento unido a al menos un grupo fotocrómico, en donde el al menos un agente de alargamiento se selecciona entre: (1) 4-(4-fluoro-fenoxicarboniloxi)-piperidin-1-ilo; (2) 4-(bifenil-4-carboniloxi)-piperidin-1-ilo; (3) 4-(naftalen-2-carboniloxi)-piperidin-1-ilo; (4) 4-(4-pentadecafluoroheptiloxi-fenilcarbamoil)-benciloxi; (5) 4-(3-piperidin-4-il-propil)-piperidin-1-ilo; (6) éster de bis-[1-nombre del PC]-piperidin-4-ilo] del ácido bifenil-4,4'-dicarboxílico o (II) seleccionado entre: (a) 3-fenil-3-(4-(4-piperidinopiperidino)fenil)-13,13-dimetil-indeno[2',3':3,4]nafto[1,2-b]pirano; (b) 3-fenil-3-(4-(4-fenilpiperazina)fenil)-13,13-dimetil-indeno[2',3':3,4]nafto[1,2-b]pirano; (c) 3-fenil-3-(4-pirrolidin-1-il-fenil)-13,13-dimetil-6-metoxi-7-(4-fenil-piperazin-1-il)indeno[2',3':3,4]nafto[1,2- b]pirano; (d) 3-fenil-3-(4-pirrolidin-1-il-fenil)-13,13-dimetil-6-metoxi-7-([1,4']bipiperidinil-1``-il)indeno[2',3':3,4]nafto[1,2- b]pirano; (e) 3-fenil-3-(4-([1,4']bipiperidinil-1'-il)fenil)-13,13-dimetil-6-metoxi-7-([1,4']bipiperidinil-1'- il)indeno[2',3':3,4]nafto[1,2-b]pirano; (f) 3-fenil-3-(4-([1,4']bipiperidinil-1'-il)fenil)-13,13-dimetil-6-metoxi-7-(4-bencilpiperidin-1-il)indeno[2',3':3,4] nafto[1,2-b]pirano; (g) 3-fenil-3-(4-([1,4']bipiperidinil-1'-il)fenil)-13,13-dimetil-6-metoxi-7-(piperadin-1-il)indeno[2',3':3,4]nafto[1,2- b]pirano; (h) 3-fenil-3-(4-(4-fenil-piperazin-1-il)fenil)-13,13-dimetil-6-metoxi-7-(4-fenil-piperazin-1- il)indeno[2',3':3,4]nafto[1,2-b]pirano; (i) 1,3,3-trimetil-6'-(4-etoxicarbonil)-piperidin-1-il)-espiro[indolina-2,3'-3H-nafto[2,1-b][1,4]oxazina].

Description

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(xiv) grupos R1 inmediatamente adyacentes junto a un grupo representado por una de las Fórmulas vii, viii y ix:
imagen8
5 en donde
(A) W y W’ se seleccionan independientemente en cada ocasión entre -O-, -N(X7)-, -C(X14)-, -C(X17)-, (en donde X7, X14 y X17 son como se han expuesto anteriormente),
(B) X14, X15 y X17 son como se ha expuesto anteriormente y 10 (C) q es un número entero seleccionado entre 0, 1, 2, 3 y 4.
Otra realización no limitante proporciona un compuesto fotocrómico que comprende:
(a) al menos un grupo fotocrómico seleccionado entre un pirano, una oxazina y un fúlgido; y
15 (b) al menos un agente de alargamiento (L) unido al al menos un grupo fotocrómico, en donde el al menos un agente de alargamiento se selecciona entre uno de los siguientes compuestos enumerados (y representados gráficamente) a continuación en la Tabla I.
Tabla I:
(1) 4-(4-fluoro-fenoxicarboniloxi)-piperidin-1-ilo
(2) 4-(bifenil-4-carboniloxi)-piperidin-1-ilo
imagen9
(3) 4-(naftalen-2-carboniloxi)-piperidin-1-ilo
(4) 4-(4-pentadecafluoroheptiloxi-fenilcarbamoil)-benciloxi
(5) 4-(3-piperidin-4-il-propil)-piperidin-1-ilo
(6) éster bis-[1-nombre del PC]-piperidin-4-ílico] del ácido bifenil4,4’-dicarboxílico
Otra realización no limitante desvelada en el presente documento proporciona un compuesto fotocrómico representado por la Fórmula II:
imagen10
En referencia a la Fórmula II, A es un anillo aromático o un anillo aromático condensado seleccionado entre: nafto, benzo, fenantro, fluoranteno, anteno, quinolino, tieno, furo, indolo, indolino, indeno, benzofuro, benzotieno, tiofeno, nafto indenocondensado, nafto heterociclocondensado y benzo heterociclocondensado. Además, de acuerdo con diversas realizaciones no limitantes, B y B’ pueden seleccionarse cada uno independientemente entre:
9
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(xiii) un anillo que contiene nitrógeno representado por la Fórmula i, que se ha expuesto anteriormente;
(xiv) un grupo representado por una de las Fórmulas ii o iii, que se han expuesto anteriormente; y
(xv) los grupos R3 inmediatamente adyacentes juntos forman un grupo representado por una de las Fórmulas vii, viii o ix, que se han expuesto anteriormente.
5 Además, de acuerdo con diversas realizaciones no limitantes desveladas en el presente documento, el compuesto fotocrómico representado por la Fórmula XII comprende al menos un agente de alargamiento (L) como se ha definido anteriormente.
10 Como se ha analizado anteriormente con respecto a los compuestos fotocrómicos generalmente representados por la Fórmula II desvelados en el presente documento, los compuestos fotocrómicos generalmente representados por la Fórmula XII pueden extenderse en cualquier posición disponible mediante sustitución con L o un grupo R3 sustituido con L, y/o en cualquier dirección deseada mediante distintas combinaciones de sustituciones de posiciones disponibles con L o grupos R3 sustituidos con L. Por lo tanto, por ejemplo, aunque de manera no limitante
15 en el presente documento, los compuestos fotocrómicos generalmente representados por la Fórmula XII pueden extenderse sustituyendo el grupo SP con L o un grupo R3 sustituido con L y/o sustituyendo el grupo A con L o un grupo R3 sustituido con L para proporcionar una relación de absorción promedio deseada para el compuesto fotocrómico.
20 Como se ha analizado anteriormente en referencia a la Fórmula XII, de acuerdo con diversas realizaciones no limitantes desveladas en el presente documento, el grupo SP puede ser indolino. Más específicamente, de acuerdo con diversas realizaciones no limitantes desveladas en el presente documento, el compuestos fotocrómico puede representarse por la Fórmula XIII:
imagen24
25
en donde cada R’’ se selecciona independientemente en cada ocasión entre hidrógeno, un alquilo sustituido o sin sustituir, cicloalquilo, arilalquilo o juntos forman cicloalquilo que está sustituido o sin sustituir; R’’’ se selecciona entre un grupo alquilo, arilo o arilalquilo que está sin sustituir o sustituido con al menos uno de: (i) -CH(CN)2 o 30 CH(COOX1)2; (ii) -CH(X2)(X3); y (iii) -C(O)X24 (en donde X1, X2, X3 y X24 son como se ha definido anteriormente); y
(iv) halógeno, hidroxi, éster o amina; y en donde al menos uno de i y r es al menos 1 y al menos un R3 comprende L.
Por ejemplo, aunque de manera no limitante en el presente documento, de acuerdo con diversas realizaciones no limitantes desveladas en el presente documento en donde el grupo SP es indolino, el compuesto fotocrómico puede 35 representarse por al menos una de Fórmula XIV y Fórmula XV:
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23
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Secuencia de reacción I
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5 Las secuencias de reacción más específicas para sintetizar los compuestos fotocrómicos de acuerdo con diversas realizaciones no limitantes desveladas en el presente documento y generalmente representadas por la Fórmula XII anterior y más específicamente representadas por la Fórmula XIII anterior, en donde Y es N y SP es indolino se representan a continuación en las Secuencias de reacción J y K.
10 En la Secuencia de reacción J (a continuación), un nitrosofenol representado por la Fórmula φ1 se hace reaccionar en metanol con un agente de alargamiento L, que es piperazino fenol (representado por la Fórmula φ2), para formar el nitrosonaftol sustituido con L representado por la Fórmula φ3. Como se representa en la Secuencia de reacción J, el nitrosonaftol sustituido con L puede además sustituirse con uno o más grupos R, cada uno de los cuales puede comprender un agente de alargamiento L que es igual o diferente a los restantes sustituyentes L. El nitrosonaftol
15 sustituido con L representado por la Fórmula φ3 después se acopla por calentamiento con la base de Fischer representada por la Fórmula φ4 para producir la naftoxazina sustituida con L representada por la Fórmula φ5.
28
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Claims (1)

  1. imagen1
ES11001431.3T 2003-07-01 2004-05-26 Compuestos fotocrómicos Expired - Lifetime ES2656823T3 (es)

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EP (4) EP2357217B9 (es)
JP (12) JP5197956B2 (es)
KR (4) KR100875002B1 (es)
CN (4) CN101276015B (es)
AU (1) AU2004256030B2 (es)
BR (4) BR122015025453B1 (es)
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WO2004041961A1 (en) * 2002-11-04 2004-05-21 Polymers Australia Pty Limited Photochromic compositions and light transmissible articles
US7256921B2 (en) * 2003-07-01 2007-08-14 Transitions Optical, Inc. Polarizing, photochromic devices and methods of making the same
US8545984B2 (en) * 2003-07-01 2013-10-01 Transitions Optical, Inc. Photochromic compounds and compositions
US20110140056A1 (en) * 2003-07-01 2011-06-16 Transitions Optical, Inc. Indeno-fused ring compounds
US7632540B2 (en) 2003-07-01 2009-12-15 Transitions Optical, Inc. Alignment facilities for optical dyes
US8211338B2 (en) 2003-07-01 2012-07-03 Transitions Optical, Inc Photochromic compounds
US8518546B2 (en) * 2003-07-01 2013-08-27 Transitions Optical, Inc. Photochromic compounds and compositions
US8545015B2 (en) 2003-07-01 2013-10-01 Transitions Optical, Inc. Polarizing photochromic articles
US7342112B2 (en) * 2003-07-01 2008-03-11 Ppg Industries Ohio, Inc. Photochromic compounds
US8089678B2 (en) * 2003-07-01 2012-01-03 Transitions Optical, Inc Clear to circular polarizing photochromic devices and methods of making the same
US7978391B2 (en) * 2004-05-17 2011-07-12 Transitions Optical, Inc. Polarizing, photochromic devices and methods of making the same
US9096014B2 (en) 2003-07-01 2015-08-04 Transitions Optical, Inc. Oriented polymeric sheets exhibiting dichroism and articles containing the same
US8582192B2 (en) 2003-07-01 2013-11-12 Transitions Optical, Inc. Polarizing photochromic articles
US8698117B2 (en) * 2003-07-01 2014-04-15 Transitions Optical, Inc. Indeno-fused ring compounds
US7097303B2 (en) * 2004-01-14 2006-08-29 Ppg Industries Ohio, Inc. Polarizing devices and methods of making the same
EP1740628B1 (en) * 2004-04-30 2010-03-10 Advanced Polymerik Pty Ltd Photochromic compositions and articles comprising polyether oligomer
US8563212B2 (en) * 2004-07-16 2013-10-22 Transitions Optical, Inc. Methods for producing photosensitive microparticles, non-aqueous dispersions thereof and articles prepared therewith
US8563213B2 (en) * 2004-07-16 2013-10-22 Transitions Optical, Inc. Methods for producing photosensitive microparticles
US7556750B2 (en) * 2005-04-08 2009-07-07 Transitions Optical, Inc. Photochromic materials with reactive substituents
US9028728B2 (en) 2005-04-08 2015-05-12 Transitions Optical, Inc. Photochromic materials that include indeno-fused naphthopyrans
US8647538B2 (en) * 2005-04-08 2014-02-11 Transitions Optical, Inc. Photochromic compounds having at least two photochromic moieties
US9139552B2 (en) 2005-04-08 2015-09-22 Transitions Optical, Inc. Indeno-fused naphthopyrans having ethylenically unsaturated groups
US9052438B2 (en) 2005-04-08 2015-06-09 Johnson & Johnson Vision Care, Inc. Ophthalmic devices comprising photochromic materials with reactive substituents
US7229740B2 (en) * 2005-09-08 2007-06-12 Xerox Corporation Reimageable paper
US7381506B2 (en) * 2005-09-08 2008-06-03 Xerox Corporation Reimageable paper
US7556751B2 (en) * 2005-12-21 2009-07-07 Transitions Optical, Inc. Photochromic materials having electron-withdrawing substituents
EP2066650B1 (en) * 2006-09-06 2011-12-21 ESSILOR INTERNATIONAL (Compagnie Générale d'Optique) 3h-naphtho[2,1-b]pyrans as photochromic dichroic dyes and optical article containing them
US9102652B2 (en) 2006-10-20 2015-08-11 Alphamicron Incorporated Dichroic-photochromic 2H-naphtho[1,2-b]pyran compounds and devices
US8697890B2 (en) * 2006-10-20 2014-04-15 Alphamicron Incorporated Dichroic-photochromic 2H-naphtho[1,2-b]pyran compounds and devices
US20080187749A1 (en) * 2007-01-11 2008-08-07 Ppg Industries Ohio, Inc. Optical element having light influencing property
US7906214B2 (en) 2007-01-26 2011-03-15 Transitions Optical, Inc. Optical elements comprising compatiblizing coatings and methods of making the same
CN102112528B (zh) * 2008-06-05 2013-08-28 先进聚合有限公司 光致变色聚合物以及包含光致变色聚合物的组合物
US8110127B2 (en) 2008-06-19 2012-02-07 Essilor International (Compagnie Generale D'optique) Photochromic coating exhibiting improved performance
US20090326186A1 (en) * 2008-06-27 2009-12-31 Transitions Optical, Inc. Mesogen containing compounds
US20100014010A1 (en) * 2008-06-27 2010-01-21 Transitions Optical, Inc. Formulations comprising mesogen containing compounds
US8628685B2 (en) 2008-06-27 2014-01-14 Transitions Optical, Inc Mesogen-containing compounds
US7910019B2 (en) 2008-06-27 2011-03-22 Transitions Optical, Inc. Mesogen containing compounds
US8613868B2 (en) 2008-06-27 2013-12-24 Transitions Optical, Inc Mesogenic stabilizers
US7910020B2 (en) 2008-06-27 2011-03-22 Transitions Optical, Inc. Liquid crystal compositions comprising mesogen containing compounds
US8349210B2 (en) 2008-06-27 2013-01-08 Transitions Optical, Inc. Mesogenic stabilizers
US8431039B2 (en) 2008-06-27 2013-04-30 Transitions Optical, Inc. Mesogenic stabilizers
US8623238B2 (en) 2008-06-27 2014-01-07 Transitions Optical, Inc. Mesogenic stabilizers
JP5377014B2 (ja) * 2009-03-18 2013-12-25 株式会社トクヤマ クロメン化合物の製造方法
US9475901B2 (en) * 2009-12-08 2016-10-25 Transitions Optical, Inc. Photoalignment materials having improved adhesion
US8501220B2 (en) * 2009-12-31 2013-08-06 R&D Lifesciences Stabilized liquid egg material for extended shelf life
US9063358B2 (en) * 2010-05-03 2015-06-23 Kent State University Smart photochromic chiral nematic liquid crystal window
US20130242368A1 (en) * 2010-12-09 2013-09-19 Kilolambda Technologies Ltd. Fast response photochromic composition and device
US9034219B2 (en) * 2010-12-16 2015-05-19 Transitions Optical, Inc. Photochromic compounds and compositions
US8859097B2 (en) * 2010-12-16 2014-10-14 Transitions Optical, Inc. Photochromic compounds, compositions and articles
KR101837950B1 (ko) * 2011-03-30 2018-04-26 금호석유화학 주식회사 신규 아크릴계 모노머를 포함하는 레지스트용 공중합체 및 이를 포함하는 레지스트용 수지 조성물
ES2973880T3 (es) 2011-06-06 2024-06-24 Transitions Optical Inc Artículos fotocromáticos polarizantes
CN103013532A (zh) * 2012-11-30 2013-04-03 浙江工业大学 偶氮苯光致变色液晶化合物及其合成方法
US9304330B2 (en) * 2013-02-20 2016-04-05 Transitions Optical, Inc. Experiential optical device
US20140264979A1 (en) 2013-03-13 2014-09-18 Transitions Opticals, Inc. Method of preparing photochromic-dichroic films having reduced optical distortion
US9334439B2 (en) * 2013-03-15 2016-05-10 Transitions Optical, Inc. Photochromic articles that include photochromic-dichroic materials
TWI593668B (zh) * 2013-03-29 2017-08-01 Tokyo Ohka Kogyo Co Ltd Compositions containing vinyl-containing compounds
EP3018115B1 (en) 2013-07-01 2018-08-22 Tokuyama Corporation Novel phenyl napthol derivative
CN103333608B (zh) * 2013-07-04 2015-10-07 江苏科技大学 一种不可逆光致变色涂料、制备方法及其应用
US9335562B2 (en) * 2013-09-17 2016-05-10 Johnson & Johnson Vision Care, Inc. Method and apparatus for ophthalmic devices comprising dielectrics and liquid crystal polymer networks
CN105612047B (zh) 2013-10-11 2018-02-23 光学转变公司 用于将多个涂层施加到光学基底的旋转涂布机
CN104558600B (zh) * 2013-10-21 2016-08-17 乐凯华光印刷科技有限公司 一种含氮多官能度丙烯酸酯树脂、制备方法及其应用
US9051332B1 (en) * 2013-11-20 2015-06-09 Transitions Optical, Inc. Photochromic indeno-fused ring pyran compounds
CN104072532A (zh) * 2014-04-14 2014-10-01 上海大学 氧二硅基萘并吡喃或蒽并吡喃衍生物及其合成方法
CA2962919C (en) 2014-09-30 2024-01-02 Transitions Optical, Inc. Ultraviolet light absorbers
KR102297205B1 (ko) 2015-01-09 2021-09-01 삼성전자주식회사 광학 필름용 조성물, 필름 및 표시 장치
CN104817528A (zh) * 2015-02-17 2015-08-05 江苏视客光电新材料有限公司 一种螺吡喃类光致变色化合物及其制备方法
EP3268375B1 (en) * 2015-03-10 2022-06-15 Transitions Optical, Inc. Photochromic thienochromene compounds
US10723883B2 (en) * 2015-06-10 2020-07-28 Council Of Scientific And Industrial Research Spiropyran based composition and application thereof as security tag
JP2018533073A (ja) 2015-10-30 2018-11-08 トランジションズ オプティカル， インコーポレイテッド 光学的物品およびそれを調製する方法
JP6823653B2 (ja) 2015-10-30 2021-02-03 トランジションズ オプティカル， インコーポレイテッド 勾配のある光影響特性を有する光学的物品の製造方法
US11036065B2 (en) 2015-10-30 2021-06-15 Transitions Optical, Ltd. Method of making an optical article with an inkjet printing device
JP6823061B2 (ja) 2015-10-30 2021-01-27 トランジションズ オプティカル， インコーポレイテッド 勾配のある光影響特性を有する光学的物品およびその製造方法
EP3808800B1 (en) * 2016-09-14 2022-01-05 Riken Technos Corporation Hard coat laminated film
CA3046809A1 (en) * 2016-12-12 2018-06-21 The University Of Sydney Non-peptide oxytocin receptor agonists
WO2018113999A1 (en) 2016-12-23 2018-06-28 Transitions Optical, Ltd. Method of manufacture of a lens with gradient properties using imbibition technology
EP3562655B1 (en) 2016-12-28 2024-11-20 Transitions Optical, Ltd. Method for imparting an optical element with a light influencing property in a gradient pattern
CN110114703B (zh) 2016-12-30 2022-01-11 光学转变有限公司 偏振化制品和形成偏振化制品的方法
EP3621958B9 (en) 2017-05-10 2024-09-25 Transitions Optical, Ltd. Photochromic indeno fused phenanthrenopyran compounds
US11746283B2 (en) 2017-06-30 2023-09-05 Transitions Optical, Ltd. Silole and germole fused ring photochromic compounds
CN107546335B (zh) * 2017-08-14 2019-07-02 深圳市华星光电技术有限公司 Oled面板及其制作方法
US10866455B2 (en) 2017-10-19 2020-12-15 Ppg Industries Ohio, Inc. Display devices including photochromic-dichroic compounds and dichroic compounds
KR101986192B1 (ko) * 2017-11-29 2019-06-05 주식회사 스포컴 광 투과율을 조절할 수 있는 아이웨어
EP3732533B1 (en) * 2017-12-27 2025-12-10 Transitions Optical, Ltd. System and method for customization of a photochromic article
CN108148464A (zh) * 2018-02-07 2018-06-12 温州深奥科技有限公司 光变色墙贴专用环保油墨制备工艺
US12208138B2 (en) * 2018-02-19 2025-01-28 Boise State University Radiation-triggered liposomes
CN109445196B (zh) * 2018-12-21 2021-12-31 张家港康得新光电材料有限公司 一种2d-3d显示切换光学模组及其制备方法、显示装置
CN110407481A (zh) * 2019-08-06 2019-11-05 太仓碧奇新材料研发有限公司 一种多功能光致变色薄膜的制备方法
KR20220083674A (ko) 2019-10-17 2022-06-20 가부시끼가이샤 도꾸야마 포토크로믹 화합물 및 해당 포토크로믹 화합물을 포함하는 경화성 조성물
CN110930883B (zh) * 2019-12-12 2021-09-10 昆山国显光电有限公司 显示面板和显示装置
CN115697249A (zh) 2020-06-01 2023-02-03 应用奈米医材科技股份有限公司 双面非球面衍射多焦点透镜及其制造和用途
CN112341343B (zh) * 2020-11-04 2023-04-25 陕西莱特光电材料股份有限公司 一种有机化合物及包含其的电子元件和电子装置
MX2023005404A (es) 2020-11-10 2023-05-22 Transitions Optical Ltd Articulos fotocromaticos-dicroicos.
CN115710278B (zh) * 2022-12-27 2023-09-29 烟台九目化学股份有限公司 一种荧蒽并氧杂卓类有机化合物及其制备方法与应用
WO2024183883A1 (en) 2023-03-07 2024-09-12 Transitions Optical, Ltd. Heatable photochromic laminate and method of making the same
WO2024183882A1 (en) 2023-03-07 2024-09-12 Transitions Optical, Ltd. Heatable photochromic optical article and method of making the same
CN117304450B (zh) * 2023-11-24 2024-02-13 西南石油大学 一种共混型光响应苯并噁嗪材料及其制备方法

Family Cites Families (208)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2475921A (en) 1940-06-26 1949-07-12 Polaroid Corp Glare reduction filter comprising light polarizing area merging gradually with transparent nonpolarizing area
GB583842A (en) 1941-01-21 1947-01-01 Polaroid Corp Improvements in or relating to combined light-filtering and light-polarizing means
US2319826A (en) 1941-10-10 1943-05-25 Gen Electric Adhesive composition
US2334446A (en) 1941-12-26 1943-11-16 Polaroid Corp Polarizing goggles
US2544659A (en) 1946-05-14 1951-03-13 John F Dreyer Dichroic light-polarizing sheet materials and the like and the formation and use thereof
US2481830A (en) 1946-05-14 1949-09-13 Gen Polarizing Company Optically polarizing dichroic film and method of preparing the same
US3276316A (en) 1961-08-02 1966-10-04 Polaroid Corp Process for polarizing ultraviolet light utilizing oriented polymer sheet with incorporated dichroic fluorescent dye
US3361706A (en) 1964-03-06 1968-01-02 American Cyanamid Co Control of the photochromic return rate of (arylazo) thioformic arylhydrazidates
FR1451332A (fr) * 1965-06-23 1966-01-07 Saint Gobain Nouvelles substances photochromiques di-spiropyranniques et procédé de préparation de ces substances
US3653863A (en) 1968-07-03 1972-04-04 Corning Glass Works Method of forming photochromic polarizing glasses
GB1278415A (en) * 1968-10-03 1972-06-21 Agfa Gevaert Photochromic indolino-spiropyrans
US4043637A (en) 1973-06-15 1977-08-23 American Optical Corporation Photochromic light valve
US4049338A (en) * 1974-11-19 1977-09-20 Texas Instruments Incorporated Light polarizing material method and apparatus
US4166043A (en) 1974-12-23 1979-08-28 American Optical Corporation Stabilized photochromic materials
US4367170A (en) 1975-01-24 1983-01-04 American Optical Corporation Stabilized photochromic materials
US4039254A (en) 1976-05-27 1977-08-02 Mack Gordon Electro-optic welding lens assembly using multiple liquid crystal light shutters and polarizers
US4190330A (en) 1977-12-27 1980-02-26 Bell Telephone Laboratories, Incorporated Variable focus liquid crystal lens system
US4279474A (en) 1980-03-25 1981-07-21 Belgorod Barry M Spectacle lens having continuously variable controlled density and fast response time
US4459662A (en) * 1980-09-29 1984-07-10 Texas Instruments Incorporated Microcomputer having ROM mass memory for downloading main RAM memory with microcomputer instructions
FR2531235B1 (fr) 1982-07-27 1985-11-15 Corning Glass Works Verres stratifies transparents polarisants et leur procede d'obtention
US4556605A (en) 1982-09-09 1985-12-03 Kabushiki Kaisha Suwa Seikosha Photochromic coating composition and photochromic synthetic resin ophthalmic lens
US4637896A (en) 1982-12-15 1987-01-20 Armstrong World Industries, Inc. Polymeric liquid crystals
JPS59135428A (ja) 1983-01-24 1984-08-03 Toshiba Corp 絶縁膜形成方法
US4685783A (en) 1983-09-07 1987-08-11 The Plessey Company P.L.C. Polychromic tetracyclo-spiro-adamatylidene derivatives, and polychromic lens incorporating said compounds
SE464264B (sv) 1984-02-24 1991-03-25 Esab Ab Optiskt filter foer svetsskyddsglas
US4549894A (en) 1984-06-06 1985-10-29 Corning Glass Works Ultraviolet absorbing photochromic glass of low silver content
FR2568568A1 (fr) 1984-08-01 1986-02-07 Corning Glass Works Perfectionnement a la fabrication de verres stratifies transparents polarisants et verres ainsi obtenus
GB2169417A (en) 1984-12-28 1986-07-09 Olympus Optical Co Liquid crystal lens having a variable focal length
US4756605A (en) 1985-02-01 1988-07-12 Olympus Optical Co., Ltd. Liquid crystal spectacles
AU564689B2 (en) 1985-07-09 1987-08-20 Kureha Kagaku Kogyo K.K. Photochromic lens
FR2590889B1 (fr) * 1985-08-13 1988-01-22 Corning Glass Works Perfectionnements a la fabrication de verres stratifies transparents polarisants et verres ainsi obtenus
DE3531923A1 (de) 1985-09-07 1987-03-12 Bayer Ag Verfahren zur herstellung von 1-aminonaphthalin-2,4,7-trisulfonsaeure und 1-aminonaphthalin-7-sulfonsaeure
US4810433A (en) 1985-09-25 1989-03-07 Fuji Photo Film Co., Ltd. Process for producing oriented film
IT1190508B (it) 1986-03-24 1988-02-16 Daniele Senatore Occhiali a trasparenza regolabile
JPS62227794A (ja) * 1986-03-31 1987-10-06 東洋インキ製造株式会社 改さん防止物
GB2189417B (en) 1986-04-18 1990-03-21 Nii Tekh Avtomobil Promy Automated line for production of castings
DE3774437D1 (de) 1986-07-08 1991-12-12 Nissan Motor Spirooxazin-verbindungen, photoempfindliche materialien, die diese enthalten und verfahren zur herstellung derselben.
CA1340939C (en) 1987-02-02 2000-03-28 Ryojiro Akashi Photochromic compound
US4838673A (en) 1987-04-27 1989-06-13 J. R. Richards, Inc. Polarized lens and method of making the same
JP2578442B2 (ja) 1987-07-13 1997-02-05 三菱化学株式会社 分子配向性薄膜
JPS6490286A (en) 1987-10-01 1989-04-06 Tokuyama Soda Kk Photochromic composition
JPH0794657B2 (ja) 1987-10-16 1995-10-11 日産自動車株式会社 フォトクロミック感光性材料
US4873029A (en) 1987-10-30 1989-10-10 Blum Ronald D Method for manufacturing lenses
US4931220A (en) 1987-11-24 1990-06-05 Ppg Industries, Inc. Organic photochromic pigment particulates
JPH01170904A (ja) * 1987-12-25 1989-07-06 Toray Ind Inc フォトクロミック性を有する偏光シート
NL8802832A (nl) 1988-02-29 1989-09-18 Philips Nv Methode voor het vervaardigen van een gelaagd element en het aldus verkregen element.
EP0330733B1 (de) 1988-03-04 1994-01-26 GAO Gesellschaft für Automation und Organisation mbH Sicherheitselement in Form eines Fadens oder Bandes zur Einbettung in Sicherheitsdokumente sowie Verfahren zur Herstellung desselben
US4986934A (en) * 1988-03-25 1991-01-22 Ppg Industries, Inc. Photochromic compound and articles containing the same
GB2219098A (en) 1988-05-25 1989-11-29 Plessey Co Plc Optically anisotropic materials and applications
US5130058A (en) 1988-07-01 1992-07-14 Tokuyama Soda Kabushiki Kaisha Photochromic compound, process for production thereof, use thereof and composition containing said photochromic compound
DE3825066A1 (de) 1988-07-23 1990-01-25 Roehm Gmbh Verfahren zur herstellung von duennen, anisotropen schichten auf oberflaechenstrukturierten traegern
JP2780180B2 (ja) * 1989-01-20 1998-07-30 三井化学株式会社 光変調素子
US4974941A (en) 1989-03-08 1990-12-04 Hercules Incorporated Process of aligning and realigning liquid crystal media
NL8901167A (nl) 1989-05-10 1990-12-03 Philips Nv Methode voor de vervaardiging van een polarisatiefilter, een aldus verkregen polarisatiefilter en een display dat voorzien is van het polarisatiefilter.
US5180470A (en) 1989-06-05 1993-01-19 The Regents Of The University Of California Deposition of highly-oriented PTFE films and uses therefor
FR2647789B1 (fr) 1989-06-05 1994-07-22 Essilor Int Composes photochromiques de type indolino-spiro-oxazine, leur procede de preparation, compositions et articles photochromiques contenant de tels composes
ATE130850T1 (de) 1989-07-28 1995-12-15 Wako Pure Chem Ind Ltd Fulgimidderivate.
JP2692290B2 (ja) 1989-08-31 1997-12-17 ソニー株式会社 ディスク記録及び／又は再生装置
JP2795352B2 (ja) * 1989-09-11 1998-09-10 呉羽化学工業株式会社 調光作用を有する偏光性樹脂製光学部材
JPH03200118A (ja) 1989-12-28 1991-09-02 Toyota Central Res & Dev Lab Inc 液晶セル
JPH03200218A (ja) 1989-12-28 1991-09-02 Toyota Central Res & Dev Lab Inc 面内配向重合薄膜を有する機能部材、およびその製造方法
US5130353A (en) 1990-03-07 1992-07-14 Ppg Industries, Inc. Method for preparing photochromic plastic article
US5185390A (en) 1990-03-07 1993-02-09 Ppg Industries, Inc. Water strippable photochromic resin composition
US5073294A (en) 1990-03-07 1991-12-17 Hercules Incorporated Process of preparing compositions having multiple oriented mesogens
DE4007636A1 (de) 1990-03-10 1991-09-12 Basf Ag Photochrome monomere und hieraus hergestellte photochrome polymerisate
JPH063528B2 (ja) * 1990-03-16 1994-01-12 富士ゼロックス株式会社 光変調表示素子及び表示方法
JP2938124B2 (ja) * 1990-04-05 1999-08-23 オプトレックス株式会社 配向膜の形成方法及び液晶表示素子の製造方法
US5200116A (en) 1990-07-23 1993-04-06 Ppg Industries, Inc. Photochromic chromene compounds
JPH04199024A (ja) 1990-11-29 1992-07-20 Hitachi Ltd 液晶表示素子およびそれを用いた表示装置
US5202053A (en) 1991-02-22 1993-04-13 Hercules Incorporated Polymerizable nematic monomer compositions
DE59209499D1 (de) 1991-07-26 1998-10-22 Rolic Ag Orientierte Photopolymere und Verfahren zu ihrer Herstellung
US5189448A (en) 1991-08-08 1993-02-23 Katsumi Yaguchi Unit for searching for a lost contact lens
JPH05105730A (ja) * 1991-10-16 1993-04-27 Fuji Xerox Co Ltd フオトクロミツク性液晶共重合体
US5608567A (en) 1991-11-05 1997-03-04 Asulab S.A. Variable transparency electro-optical device
US5359443A (en) 1991-11-22 1994-10-25 Nippon Oil Company, Limited Process for producing heat-resistant optical element by heating liquid crystal polymer at polymerization temperature during or after orientation treatment
DE4138386A1 (de) * 1991-11-22 1993-05-27 Basf Ag Flammfeste thermoplastische formmassen
US5644416A (en) 1991-11-26 1997-07-01 Fuji Xerox Co., Ltd. Light modulation device and method of light modulation using the same
US5289547A (en) 1991-12-06 1994-02-22 Ppg Industries, Inc. Authenticating method
US5238981A (en) 1992-02-24 1993-08-24 Transitions Optical, Inc. Photochromic naphthopyrans
JP3016533B2 (ja) 1992-03-03 2000-03-06 株式会社トクヤマ フォトクロミック組成物
CA2100400C (en) * 1992-07-14 1999-06-15 Shinichi Nishiyama Antiferroelectric liquid crystal composite material, process for preparing the same, and liquid crystal element using the same
US6160597A (en) 1993-02-17 2000-12-12 Rolic Ag Optical component and method of manufacture
SG50569A1 (en) 1993-02-17 2001-02-20 Rolic Ag Optical component
EP0622789B1 (de) 1993-03-30 2002-08-07 Bayer Ag Flächenhafte Gebilde aus Seitengruppenpolymeren
US5578252A (en) * 1993-06-21 1996-11-26 Transitions Optical, Inc. Photochromic substituted naphthopyran compounds
JPH0762337A (ja) 1993-08-23 1995-03-07 Toray Ind Inc 液晶性高分子フォトクロミック材料
KR970000356B1 (ko) 1993-09-18 1997-01-08 엘지전자 주식회사 액정표시소자(lcd)용 광 폴리머 배향막 형성방법
US5529864A (en) * 1993-12-16 1996-06-25 Canon Kabushiki Kaisha Optical recording medium having mask layer
US5481830A (en) * 1994-03-04 1996-01-09 General Motors Corporation Door check for vehicle sliding door
US5395567A (en) * 1994-04-18 1995-03-07 Ppg Industries, Inc. Photochromic spironaphthopyran compounds
DE4420378C1 (de) 1994-06-10 1995-11-30 Rodenstock Optik G Photochrome Farbstoffe
WO1996001884A1 (de) 1994-07-11 1996-01-25 Optische Werke G. Rodenstock Diaryl-2h-naphthopyrane
US5514817A (en) * 1994-08-04 1996-05-07 Ppg Industries, Inc. Substituted phenanthropyrans
DE4434966A1 (de) 1994-09-30 1996-04-04 Bayer Ag Neue Seitengruppenpolymere und ihre Verwendung für optische Bauelemente
US5645767A (en) 1994-11-03 1997-07-08 Transitions Optical, Inc. Photochromic indeno-fused naphthopyrans
US6049428A (en) 1994-11-18 2000-04-11 Optiva, Inc. Dichroic light polarizers
FR2727971A1 (fr) * 1994-12-12 1996-06-14 Corning Inc Nouveaux materiaux organiques photochromiques a indice de refraction eleve, leur preparation et articles formes de ces materiaux
US5962617A (en) 1995-02-02 1999-10-05 Simula Inc. Impact resistant polyurethane and method of manufacture thereof
US5846452A (en) 1995-04-06 1998-12-08 Alliant Techsystems Inc. Liquid crystal optical storage medium with gray scale
US5658501A (en) 1995-06-14 1997-08-19 Transitions Optical, Inc. Substituted naphthopyrans
AUPN443695A0 (en) 1995-07-28 1995-08-17 Sola International Holdings Ltd Photochromic polymer
KR100474131B1 (ko) * 1995-10-19 2005-06-08 롤리크 아게 광학부재및이의제조방법
US5903330A (en) 1995-10-31 1999-05-11 Rolic Ag Optical component with plural orientation layers on the same substrate wherein the surfaces of the orientation layers have different patterns and direction
US5746949A (en) 1995-11-21 1998-05-05 Hoechst Celanese Corp. Polarizer films comprising aromatic liquid crystalline polymers comprising dichroic dyes in their main chains
AUPN718195A0 (en) 1995-12-18 1996-01-18 Sola International Holdings Ltd Laminate wafers
US5698141A (en) 1996-06-17 1997-12-16 Ppg Industries, Inc. Photochromic heterocyclic fused indenonaphthopyrans
US5723072A (en) 1996-06-17 1998-03-03 Ppg Industries, Inc. Photochromic heterocyclic fused indenonaphthopyrans
FR2751971B1 (fr) 1996-07-31 1998-11-20 Essilor Int Nouvelles spirooxazines homoazaadamantane et leur utilisation dans le domaine de l'optique ophtalmique
TW472081B (en) * 1996-09-17 2002-01-11 Merck Patent Gmbh Optical retardation film
DE19644726A1 (de) 1996-10-28 1998-04-30 Zeiss Carl Fa Durchsichtkörper
IL131483A0 (en) 1997-02-21 2001-01-28 Ppg Industries Inc Photochromic polyurethane coating and articles having such a coating
JPH10251631A (ja) * 1997-03-12 1998-09-22 Dainippon Printing Co Ltd 液晶性フォトクロミック材料及び該材料からなる記録媒体
US5943104A (en) 1997-03-25 1999-08-24 University Technology Corporation Liquid crystal eyewear with two identical guest host subcells and tilted homeotropic alignment
AUPO625797A0 (en) 1997-04-17 1997-05-15 Sola International Holdings Ltd Spectacles bearing sunglass lenses
US6025026A (en) 1997-06-30 2000-02-15 Transitions Optical, Inc. Process for producing an adherent polymeric layer on polymeric substrates and articles produced thereby
JPH11101964A (ja) * 1997-08-01 1999-04-13 Sony Corp 偏光素子及び表示装置
GB9722127D0 (en) 1997-10-20 1997-12-17 James Robinson Ltd Photochromic compounds
US6268055B1 (en) 1997-12-08 2001-07-31 Ppg Industries Ohio, Inc. Photochromic epoxy resin coating composition and articles having such a coating
US5879592A (en) 1997-12-10 1999-03-09 Ppg Industries, Inc. Water soluble photochromic compounds, compositions and optical elements comprising the compounds
US6630597B1 (en) 1997-12-15 2003-10-07 Transitions Optical, Inc. Photochromic 6-aryl substituted 3H-naphtho(2,1-b)pyrans
JPH11256147A (ja) * 1998-03-13 1999-09-21 Dainippon Printing Co Ltd コレステリック液晶性フォトクロミック高分子材料及びそれを用いた光機能性媒体
JP2000008031A (ja) 1998-06-18 2000-01-11 Tokuyama Corp フォトクロミック組成物
US6239778B1 (en) 1998-06-24 2001-05-29 Alphamicron, Inc. Variable light attentuating dichroic dye guest-host device
DE69903042T2 (de) 1998-07-10 2003-08-07 Transitions Optical, Inc. Photochrome sechsgliedrige heterocyclisch kondensierte naphthopyrane
US6022497A (en) 1998-07-10 2000-02-08 Ppg Industries Ohio, Inc. Photochromic six-membered heterocyclic-fused naphthopyrans
US6177032B1 (en) 1998-09-08 2001-01-23 Alcat, Incorporated Polarized ophthalmic lenses and methods for making same
US5961892A (en) * 1998-09-11 1999-10-05 Ppg Industries Ohio, Inc. Polyalkoxylated naphthopyrans
JP4531984B2 (ja) 1998-09-11 2010-08-25 トランジションズ・オプティカル・インコーポレイテッド 重合性ポリアルコキシル化ナフトピラン
US6555028B2 (en) * 1998-09-11 2003-04-29 Transitions Optical, Inc. Polymeric matrix compatibilized naphthopyrans
US6276632B1 (en) 1998-09-16 2001-08-21 Bobby W. Sanders Axi-symmetric mixed compression inlet with variable geometry centerbody
GB9821121D0 (en) * 1998-09-29 1998-11-25 James Robinson Ltd Grey colouring photochromic fused pyrans
US6208393B1 (en) 1998-09-30 2001-03-27 Intel Corporation Liquid crystal color filter with integrated infrared blocking
US6245399B1 (en) 1998-10-14 2001-06-12 3M Innovative Properties Company Guest-host polarizers
US6284418B1 (en) 1998-11-16 2001-09-04 Cambridge Scientific, Inc. Biopolymer-based optical element
US6436525B1 (en) 1998-12-11 2002-08-20 Ppg Industries Ohio, Inc. Polyanhydride photochromic coating composition and photochromic articles
US6060001A (en) 1998-12-14 2000-05-09 Ppg Industries Ohio, Inc. Alkoxyacrylamide photochromic coatings compositions and photochromic articles
DE69919585T2 (de) 1998-12-15 2005-08-11 Rolic Ag Orientierungsschicht für flüssigkristallmaterial
US6506488B1 (en) 1998-12-18 2003-01-14 Ppg Industries Ohio, Inc. Aminoplast resin photochromic coating composition and photochromic articles
US6432544B1 (en) 1998-12-18 2002-08-13 Ppg Industries Ohio, Inc. Aminoplast resin photochromic coating composition and photochromic articles
KR100285610B1 (ko) * 1999-03-04 2001-03-15 김충섭 광변색 액정 스피로벤조피란 화합물, 이를 포함하는 조성물, 이들을 이용하여 제조된 광변색성 박막 및 상기 화합물의 제조방법
US6338808B1 (en) 1999-03-31 2002-01-15 Fuji Photo Film Co., Ltd. Liquid crystal composition comprising liquid crystal molecules and alignment promoter
JP3522189B2 (ja) * 1999-05-20 2004-04-26 株式会社トクヤマ クロメン化合物
JP4157227B2 (ja) * 1999-06-01 2008-10-01 株式会社トクヤマ クロメン化合物
JP2000351280A (ja) * 1999-06-11 2000-12-19 Toppan Printing Co Ltd 画像形成装置および感熱転写記録媒体
EP1194809A1 (en) 1999-06-11 2002-04-10 PPG Industries Ohio, Inc. Electro-optical device and variable transparent article with such device
JP4567932B2 (ja) 1999-07-02 2010-10-27 ピーピージー・インダストリーズ・オハイオ・インコーポレイテッド フォトクロミックポリ（メタ）アクリルコーティングを含む物品
US6150430A (en) 1999-07-06 2000-11-21 Transitions Optical, Inc. Process for adhering a photochromic coating to a polymeric substrate
US6579422B1 (en) 1999-07-07 2003-06-17 Sony Corporation Method and apparatus for manufacturing flexible organic EL display
FR2796077B1 (fr) 1999-07-08 2001-10-05 Essilor Int Composes photochromiques naphto (2,1-b) pyranes a substitutions bi ou terthienyle, leur procede de fabrication, materiaux et articles photochromiques obtenus
JP3756019B2 (ja) * 1999-08-20 2006-03-15 太陽誘電株式会社 偏光ユニット及びその製造方法並びに遠隔指示位置検出方法及び遠隔位置指示装置及び遠隔指示位置検出装置及びポインティング装置
US20030099910A1 (en) * 1999-08-24 2003-05-29 Eun-Kyoung Kim Photochromic spirobenzopyran compounds and their derivatives, spiropyran group-containing polymers, process for producing the same, compositions comprising said spiropyrans or spiropyran group-containing polymers and photochromic switch thin films prepared
US6296785B1 (en) * 1999-09-17 2001-10-02 Ppg Industries Ohio, Inc. Indeno-fused photochromic naphthopyrans
US6348604B1 (en) 1999-09-17 2002-02-19 Ppg Industries Ohio, Inc. Photochromic naphthopyrans
JP2001113900A (ja) * 1999-10-21 2001-04-24 Toppan Printing Co Ltd 偽造防止シート及び偽造防止シール
AU1763701A (en) * 1999-11-12 2001-06-06 3M Innovative Properties Company Liquid crystal alignment structures and optical devices containing same
US6353102B1 (en) 1999-12-17 2002-03-05 Ppg Industries Ohio, Inc. Photochromic naphthopyrans
US6759090B2 (en) 1999-12-29 2004-07-06 Younger Mfg. Co. Method for improved adhesion of an optical coating to a polarizing film
EP1120737A1 (en) 2000-01-27 2001-08-01 Rolic AG Optical security device
US6531076B2 (en) 2000-02-04 2003-03-11 Ppg Industries Ohio, Inc. Photochromic organic resin composition
JP4157245B2 (ja) 2000-02-21 2008-10-01 株式会社トクヤマ クロメン化合物
US6281366B1 (en) 2000-02-29 2001-08-28 Essilor International Compagnie Generale D'optique Photochromic [3H]naphtho[2,1-b]pyran compounds containing an acetylenic substituent, process for their manufacture, and photochromic materials and articles obtained
DE60106311T2 (de) 2000-03-02 2006-02-09 Merck Patent Gmbh Mehrschichtiger reflektierender Film oder Pigment mit von Blickwinkel abhängigen Reflektionseigenschaften
ES2243460T3 (es) 2000-03-22 2005-12-01 Transitions Optical, Inc. Naftopiranos hidroxilados/carboxilados.
JP2001337225A (ja) * 2000-05-29 2001-12-07 Nitto Denko Corp 積層光学素子及び液晶表示装置
EP1291388B1 (en) 2000-05-31 2005-07-13 Tokuyama Corporation Curable composition and photochromic cured article
JP4586953B2 (ja) * 2000-06-09 2010-11-24 三菱瓦斯化学株式会社 偏光性とフォトクロミック性を併せ持つ合成樹脂積層体
TW534869B (en) 2000-06-09 2003-06-01 Mitsubishi Gas Chemical Co Synthetic resin laminate having both polarization characteristic and photochromism characteristic, and molded article obtained therefrom
US6555029B1 (en) 2000-06-27 2003-04-29 Bausch & Lomb Incorporated Arbor for lathing a lens
US6875483B2 (en) 2000-07-06 2005-04-05 Fuji Photo Film Co., Ltd. Liquid crystal composition comprising liquid crystal molecules and alignment promoter
JP4455743B2 (ja) 2000-09-12 2010-04-21 山本光学株式会社 偏光レンズの製造方法
US6690495B1 (en) 2000-10-03 2004-02-10 Alphamicron, Inc. Device exhibiting photo-induced dichroism for adaptive anti-glare vision protection
EP1203967A1 (en) 2000-11-03 2002-05-08 Rolic AG Polarizing film
US6433043B1 (en) 2000-11-28 2002-08-13 Transitions Optical, Inc. Removable imbibition composition of photochromic compound and kinetic enhancing additive
US6736998B2 (en) * 2000-12-29 2004-05-18 Transitions Optical, Inc. Indeno-fused photochromic naphthopyrans
GB2374081B (en) 2001-04-06 2004-06-09 Central Research Lab Ltd A method of forming a liquid crystal polymer layer
DE10122188B4 (de) 2001-05-08 2007-04-12 Ems-Chemie Ag Polyamidformmassen zur Herstellung optischer Linsen
US6672697B2 (en) 2001-05-30 2004-01-06 Eastman Kodak Company Compensation method for overlapping print heads of an ink jet printer
WO2002099513A1 (en) * 2001-06-01 2002-12-12 Mitsubishi Gas Chemical Company, Inc. Plastic molded product having photochromic characteristics and/or polarizing characteristics
DE60216469T2 (de) * 2001-07-27 2007-10-04 Insight Equity A.P.X, LP, Southlake Lichtpolarisierender film mit melanin
JP2003057440A (ja) * 2001-08-09 2003-02-26 Konica Corp 偏光板、運動物体の計測方法、運動物体の計測装置及びインクジェット射出検査装置
KR100399250B1 (ko) 2001-08-30 2003-09-26 김수진 광 가역성 변색 도수 편광 선글라스 렌즈 및 제조방법
JP2003073669A (ja) * 2001-08-31 2003-03-12 Fuji Photo Film Co Ltd 液晶性組成物、表示デバイスおよび光学フィルム
EP1433020A1 (en) 2001-10-05 2004-06-30 E-Vision, LLC Hybrid electro-active lens
ATE470166T1 (de) 2002-02-13 2010-06-15 Merck Patent Gmbh Verfahren zur herstellung von einem anisotropen polymerfilm auf einem substrat mit einer strukturierten oberfläche
GB0214989D0 (en) 2002-06-28 2002-08-07 Qinetiq Ltd Photochromic liquid crystals
US20040046927A1 (en) * 2002-08-27 2004-03-11 Montgomery Mark E. Polarized and non-polarized bifocal spectacles
US7036932B2 (en) * 2002-10-04 2006-05-02 Vision-Ease Lens Laminated functional wafer for plastic optical elements
WO2004041961A1 (en) 2002-11-04 2004-05-21 Polymers Australia Pty Limited Photochromic compositions and light transmissible articles
AU2003297496A1 (en) 2002-12-20 2004-07-22 Vision-Ease Lens, Inc. Polarizing plate and eyewear plastic article containing the same
US6874888B1 (en) * 2003-04-21 2005-04-05 Wendy Dudai Polarized contact lenses with a clear peripheral portion
US7632540B2 (en) * 2003-07-01 2009-12-15 Transitions Optical, Inc. Alignment facilities for optical dyes
US8089678B2 (en) * 2003-07-01 2012-01-03 Transitions Optical, Inc Clear to circular polarizing photochromic devices and methods of making the same
US9096014B2 (en) * 2003-07-01 2015-08-04 Transitions Optical, Inc. Oriented polymeric sheets exhibiting dichroism and articles containing the same
EP1644762A2 (en) * 2003-07-01 2006-04-12 Transitions Optical, Inc. Alignment facilities for optical dyes
US7256921B2 (en) 2003-07-01 2007-08-14 Transitions Optical, Inc. Polarizing, photochromic devices and methods of making the same
US8211338B2 (en) * 2003-07-01 2012-07-03 Transitions Optical, Inc Photochromic compounds
US7342112B2 (en) * 2003-07-01 2008-03-11 Ppg Industries Ohio, Inc. Photochromic compounds
US6844686B1 (en) 2003-07-28 2005-01-18 Michael M. Schneck Jewelry gift box with illuminated display
WO2005043678A1 (en) 2003-10-30 2005-05-12 Koninklijke Philips Electronics N.V. Receiving loop antenna
US7128414B2 (en) 2003-12-24 2006-10-31 Essilor International Compagnie Cenerale D'optique Methods for coating lenses
US7097303B2 (en) 2004-01-14 2006-08-29 Ppg Industries Ohio, Inc. Polarizing devices and methods of making the same
EP1722899B1 (en) 2004-03-02 2009-05-27 ESSILOR INTERNATIONAL Compagnie Générale d'Optique Method for coating curved surfaces with a polarizing liquid and apparatus
WO2005085912A1 (en) 2004-03-02 2005-09-15 Essilor International(Compagnie Generale D'optique) Ophthalmic lens with an optically transparent composite film exhibiting both impact-resistance property and polarizing property, and a process for its manufacture
US7465415B2 (en) 2004-07-30 2008-12-16 Ppg Industries Ohio, Inc. Photochromic materials derived from ring-opening monomers and photochromic initiators
US7910019B2 (en) * 2008-06-27 2011-03-22 Transitions Optical, Inc. Mesogen containing compounds
JP2010134424A (ja) * 2008-11-04 2010-06-17 Hoya Corp 偏光レンズの製造方法
JP5377014B2 (ja) * 2009-03-18 2013-12-25 株式会社トクヤマ クロメン化合物の製造方法
CN103282800B (zh) * 2010-12-27 2018-01-23 Dic株式会社 立体图像显示装置用双折射透镜材料和立体图像显示装置用双折射透镜的制造方法

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