ES8105162A1 - Procedimiento para mejorar la eficacia de catalizadores con soporte de plata - Google Patents
Procedimiento para mejorar la eficacia de catalizadores con soporte de plataInfo
- Publication number
- ES8105162A1 ES8105162A1 ES495065A ES495065A ES8105162A1 ES 8105162 A1 ES8105162 A1 ES 8105162A1 ES 495065 A ES495065 A ES 495065A ES 495065 A ES495065 A ES 495065A ES 8105162 A1 ES8105162 A1 ES 8105162A1
- Authority
- ES
- Spain
- Prior art keywords
- activity
- improving
- catalyst
- supported silver
- silver catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 7
- 230000000694 effects Effects 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 3
- 229910052709 silver Inorganic materials 0.000 abstract 3
- 239000004332 silver Substances 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 229910052792 caesium Inorganic materials 0.000 abstract 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- -1 aliphatic amines Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229910052701 rubidium Inorganic materials 0.000 abstract 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 abstract 1
- 150000003298 rubidium compounds Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/485—Impregnating or reimpregnating with, or deposition of metal compounds or catalytically active elements
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
Abstract
PROCEDIMIENTO PARA MEJORAR LA EFICACIA DE CATALIZADORES CON SOPORTE DE PLATA PARA LA OXIDACION DIRECTA DE ETILENO AL FORMAR OXIDO DE ETILENO CON OXIGENO MOLECULAR O AIRE. CONSISTE EN LAVAR EL CATALIZADOR USADO PARA LA OXIDACION DIRECTA CON UN LIQUIDO INERTE Y DESPUES DE ELLO APLICAR SOBRE EL CATALIZADOR HASTA 1.000 PARTES, POR CADA MILLON DE PARTES DE CATALIZADOR, DE CESIO, RUBIDIO O UNA MEZCLA DE ELLOS. PARA EL LAVADO SE EMPLEA UN LIQUIDO INERTE FORMADO POR UNA MEZCLA DE AMONIACO Y/O AMINAS ALIFATICAS DISUELTAS. LA SOLUCION EMPLEADA CONTIENE 0,1 HASTA 25 POR 100 EN PESO DE AMONIACO Y/O AMINAS ALIFATICAS, Y COMO DISOLVENTE SE EMPLEA AGUA, ALCOHOLES ALIFATICOS CON 1 HASTA 6 ATOMOS DE CARBONO, CETONAS ALIFATICAS CON 3 HASTA 10 ATOMOS DE CARBONO O UNA MEZCLA DE ESTOS DISOLVENTES.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19792938245 DE2938245A1 (de) | 1979-09-21 | 1979-09-21 | Verfahren zur verbesserung der wirksamkeit von silber-traegerkatalysatoren |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES8105162A1 true ES8105162A1 (es) | 1981-06-16 |
| ES495065A0 ES495065A0 (es) | 1981-06-16 |
Family
ID=6081480
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES495065A Granted ES495065A0 (es) | 1979-09-21 | 1980-09-15 | Procedimiento para mejorar la eficacia de catalizadores con soporte de plata |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4335014A (es) |
| EP (1) | EP0025963B1 (es) |
| JP (1) | JPS6022972B2 (es) |
| AU (1) | AU6254980A (es) |
| BR (1) | BR8005991A (es) |
| CA (1) | CA1152973A (es) |
| DE (2) | DE2938245A1 (es) |
| ES (1) | ES495065A0 (es) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4391735A (en) * | 1981-07-17 | 1983-07-05 | Internorth, Inc. | Cleaning and regenerating ethylene oxide catalysts |
| SE8203955L (sv) * | 1981-07-17 | 1983-01-18 | Northern Petro Chem Co | Forfarande for avlegsnande av kalium fran anvenda etenoxidkatalysatorer? |
| US4419276A (en) * | 1981-09-30 | 1983-12-06 | Union Carbide Corporation | Silver catalyst for the manufacture of ethylene oxide and a process for preparing the catalyst |
| EP0085237B1 (en) * | 1981-12-30 | 1986-07-30 | Imperial Chemical Industries Plc | Catalysts for the production of alkylene oxides |
| BG37835A3 (en) * | 1982-06-30 | 1985-08-15 | Hoechst Aktiengesellschaft | Method for preparing silver catalyst |
| DE3310685A1 (de) * | 1982-07-24 | 1984-02-09 | Hoechst Ag, 6230 Frankfurt | Silberkatalysatoren, verfahren zu ihrer herstellung und ihre verwendung zur herstellung von ethylenoxid |
| DE3229541A1 (de) * | 1982-08-07 | 1984-02-09 | Hoechst Ag, 6230 Frankfurt | Verfahren zur verbesserung der wirksamkeit von gebrauchten silber-traegerkatalysatoren |
| JPS6110570A (ja) * | 1984-06-25 | 1986-01-18 | Mitsui Toatsu Chem Inc | エチレンオキシドの製造方法 |
| DE3905578A1 (de) * | 1989-02-23 | 1990-08-30 | Basf Ag | Verfahren zur herstellung eines silberkatalysators |
| WO2010040688A1 (de) | 2008-10-08 | 2010-04-15 | Basf Se | Verfahren zur herstellung eines alkylenoxids |
| CN102558099B (zh) * | 2010-12-29 | 2014-11-12 | 中国石油化工股份有限公司 | 由乙烯生产环氧乙烷的方法 |
| CN111468110B (zh) * | 2020-04-21 | 2023-04-25 | 郴州高鑫材料有限公司 | 一种双贵金属催化剂的制备方法 |
| CN112225285B (zh) * | 2020-09-25 | 2022-10-11 | 四川轻化工大学 | 一种利用改性活性炭去除油田采出水中污染物的方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1065400B (de) * | 1954-01-05 | 1959-09-17 | National Research Council, Ottawa, Ontario (Kanada) | Verfahren zur Regeneration von vergifteten Silberkatalysatoren für die Oxydation von Äthylen zu Äthylenoxyd |
| GB1325715A (en) * | 1969-12-23 | 1973-08-08 | Exxon Research Engineering Co | Bimetallic catalyst manufacture and use in ethylene oxidation |
| CA1026763A (en) * | 1974-05-20 | 1978-02-21 | Robert P. Nielsen | Silver catalysts used in ethylene oxide production |
| DE2636680C3 (de) * | 1976-08-14 | 1979-04-05 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Verbesserung der Wirksamkeit von Silber-Trägerkatalysatoren |
| GB1575810A (en) * | 1976-10-21 | 1980-10-01 | Shell Int Research | Process for the performance of silver catalysts |
| DE2740480B2 (de) * | 1977-09-08 | 1979-07-05 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Verbesserung der Wirksamkeit von Silber-Trägerkatalysatoren |
| DE2861030D1 (en) * | 1977-11-19 | 1981-11-26 | Basf Ag | Process for preparing an ethylene oxide catalyst |
| DE2751767A1 (de) * | 1977-11-19 | 1979-05-23 | Basf Ag | Verfahren zur herstellung eines aethylenoxidkatalysators |
-
1979
- 1979-09-21 DE DE19792938245 patent/DE2938245A1/de not_active Withdrawn
-
1980
- 1980-09-13 DE DE8080105513T patent/DE3063906D1/de not_active Expired
- 1980-09-13 EP EP80105513A patent/EP0025963B1/de not_active Expired
- 1980-09-15 ES ES495065A patent/ES495065A0/es active Granted
- 1980-09-17 US US06/188,237 patent/US4335014A/en not_active Expired - Lifetime
- 1980-09-19 BR BR8005991A patent/BR8005991A/pt unknown
- 1980-09-19 JP JP55129392A patent/JPS6022972B2/ja not_active Expired
- 1980-09-19 AU AU62549/80A patent/AU6254980A/en not_active Abandoned
- 1980-09-19 CA CA000360614A patent/CA1152973A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP0025963B1 (de) | 1983-06-22 |
| BR8005991A (pt) | 1981-03-31 |
| JPS6022972B2 (ja) | 1985-06-05 |
| EP0025963A1 (de) | 1981-04-01 |
| DE3063906D1 (en) | 1983-07-28 |
| ES495065A0 (es) | 1981-06-16 |
| US4335014A (en) | 1982-06-15 |
| CA1152973A (en) | 1983-08-30 |
| DE2938245A1 (de) | 1981-04-09 |
| AU6254980A (en) | 1981-04-09 |
| JPS5653747A (en) | 1981-05-13 |
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