FI112204B - Menetelmä cesiumsuolojen valmistamiseksi aluminiumcesiumsulfaatista - Google Patents

Menetelmä cesiumsuolojen valmistamiseksi aluminiumcesiumsulfaatista Download PDF

Info

Publication number: FI112204B
Authority: FI; Finland
Prior art keywords: cesium; aluminum; preparation; amount; calcium
Prior art date: 1993-04-24

Application number

FI955049A

Other languages

English (en)

Finnish (fi)

Swedish (sv)

Other versions

FI955049L (fi

FI955049A0 (fi

Inventor

Horst Prinz

Hartmut Hofmann

Klaus Koebele

Alexander Schiedt

Bernd Phillipp

Gerd Harms

Ulrike Hecktor

Original Assignee

Metallgesellschaft Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-04-24

Filing date

1995-10-23

Publication date

2003-11-14

1995-10-23 Application filed by Metallgesellschaft Ag filed Critical Metallgesellschaft Ag

1995-10-23 Publication of FI955049L publication Critical patent/FI955049L/fi

1995-10-23 Publication of FI955049A0 publication Critical patent/FI955049A0/fi

2003-11-14 Application granted granted Critical

2003-11-14 Publication of FI112204B publication Critical patent/FI112204B/fi

Links

YRAMACNQEYDINL-UHFFFAOYSA-J aluminum;cesium;disulfate Chemical compound [Al+3].[Cs+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O YRAMACNQEYDINL-UHFFFAOYSA-J 0.000 title claims abstract description 15
238000000034 method Methods 0.000 title claims abstract description 11
238000002360 preparation method Methods 0.000 title claims abstract description 11
159000000006 cesium salts Chemical class 0.000 title claims abstract description 7
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims abstract description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
229910052792 caesium Inorganic materials 0.000 claims abstract description 9
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 7
239000000920 calcium hydroxide Substances 0.000 claims abstract description 7
229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 7
159000000007 calcium salts Chemical class 0.000 claims abstract description 5
229910052782 aluminium Inorganic materials 0.000 claims abstract description 3
238000005119 centrifugation Methods 0.000 claims abstract description 3
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract 2
238000006243 chemical reaction Methods 0.000 claims description 9
CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 3
229940044172 calcium formate Drugs 0.000 claims description 3
239000004281 calcium formate Substances 0.000 claims description 3
235000019255 calcium formate Nutrition 0.000 claims description 3
239000000725 suspension Substances 0.000 claims description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 2
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract 1
238000001914 filtration Methods 0.000 abstract 1
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
-1 cesium halide Chemical class 0.000 description 5
HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 4
RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 3
229910001863 barium hydroxide Inorganic materials 0.000 description 3
ATZQZZAXOPPAAQ-UHFFFAOYSA-M caesium formate Chemical compound [Cs+].[O-]C=O ATZQZZAXOPPAAQ-UHFFFAOYSA-M 0.000 description 3
239000001569 carbon dioxide Substances 0.000 description 3
229910002092 carbon dioxide Inorganic materials 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
238000010992 reflux Methods 0.000 description 3
239000007787 solid Substances 0.000 description 3
MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 2
229910052788 barium Inorganic materials 0.000 description 2
ZOAIGCHJWKDIPJ-UHFFFAOYSA-M caesium acetate Chemical compound [Cs+].CC([O-])=O ZOAIGCHJWKDIPJ-UHFFFAOYSA-M 0.000 description 2
239000011575 calcium Substances 0.000 description 2
239000001639 calcium acetate Substances 0.000 description 2
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
239000000292 calcium oxide Substances 0.000 description 2
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
230000008030 elimination Effects 0.000 description 2
238000003379 elimination reaction Methods 0.000 description 2
239000000706 filtrate Substances 0.000 description 2
239000012266 salt solution Substances 0.000 description 2
239000000243 solution Substances 0.000 description 2
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
150000001553 barium compounds Chemical class 0.000 description 1
238000009835 boiling Methods 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
229960005147 calcium acetate Drugs 0.000 description 1
235000011092 calcium acetate Nutrition 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
239000001354 calcium citrate Substances 0.000 description 1
229940043430 calcium compound Drugs 0.000 description 1
150000001674 calcium compounds Chemical class 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
238000011109 contamination Methods 0.000 description 1
229910052602 gypsum Inorganic materials 0.000 description 1
239000010440 gypsum Substances 0.000 description 1
238000005580 one pot reaction Methods 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D17/00—Rubidium, caesium or francium compounds

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Oil, Petroleum & Natural Gas (AREA)
Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Processing Of Solid Wastes (AREA)
Inorganic Insulating Materials (AREA)
Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)

FI955049A 1993-04-24 1995-10-23 Menetelmä cesiumsuolojen valmistamiseksi aluminiumcesiumsulfaatista FI112204B (fi)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
DE4313480		1993-04-24
DE4313480A DE4313480C1 (de)	1993-04-24	1993-04-24	Verfahren zur Herstellung von Cäsiumsalzen aus Cäsium-Aluminium-Alaun
EP9401202		1994-04-19
PCT/EP1994/001202 WO1994025422A1 (de)	1993-04-24	1994-04-19	Verfahren zur herstellung von cäsiumsalzen aus cäsium-aluminium-alaun

Publications (3)

Publication Number	Publication Date
FI955049L FI955049L (fi)	1995-10-23
FI955049A0 FI955049A0 (fi)	1995-10-23
FI112204B true FI112204B (fi)	2003-11-14

Family

ID=6486296

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
FI955049A FI112204B (fi)	1993-04-24	1995-10-23	Menetelmä cesiumsuolojen valmistamiseksi aluminiumcesiumsulfaatista

Country Status (22)

Country	Link
US (1)	US5605669A (cs)
EP (1)	EP0695286B1 (cs)
JP (1)	JP4079991B2 (cs)
KR (1)	KR100303251B1 (cs)
CN (1)	CN1055677C (cs)
AT (1)	ATE161818T1 (cs)
AU (1)	AU679528B2 (cs)
BR (1)	BR9406214A (cs)
CA (1)	CA2161245C (cs)
CZ (1)	CZ287380B6 (cs)
DE (2)	DE4313480C1 (cs)
DK (1)	DK0695286T3 (cs)
FI (1)	FI112204B (cs)
HU (1)	HU214206B (cs)
LV (1)	LV11540B (cs)
NO (1)	NO303984B1 (cs)
PL (1)	PL177619B1 (cs)
RO (1)	RO113983B1 (cs)
SK (1)	SK280404B6 (cs)
WO (1)	WO1994025422A1 (cs)
ZA (1)	ZA942813B (cs)
ZW (1)	ZW4994A1 (cs)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6015535A (en) *	1995-04-06	2000-01-18	Cabot Corporation	Process for producing purified cesium compound from cesium alum
CA2217343C (en) *	1995-04-06	2007-11-13	Cabot Corporation	Process for the production of cesium compounds
US6652820B2 (en)	2001-04-02	2003-11-25	Cabot Corporation	Methods of making cesium salts and other alkali metal salts
UA92905C2 (ru) *	2005-01-27	2010-12-27	Хеметалль Гмбх	Способ получения растворов гидроксида цезия
US7759273B2 (en) *	2005-04-20	2010-07-20	Cabot Corporation	Methods of forming an alkali metal salt
CN110256232B (zh) *	2019-06-28	2022-05-03	百杰瑞(荆门)新材料有限公司	一种甲酸铯生产方法
CN110172575B (zh) *	2019-07-05	2021-03-05	新疆有色金属研究所	一种铯矾原料的处理方法
CN116283548A (zh) *	2022-12-29	2023-06-23	江西赣锋锂业集团股份有限公司	利用工业级碳酸铯制备高纯乙酸铯的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2481455A (en) *	1948-06-01	1949-09-06	Dow Chemical Co	Cesium bromide separation
GB949483A (en) *	1961-05-25	1964-02-12	Atomic Energy Authority Uk	Improvements in or relating to the recovery of caesium
US3207571A (en) *	1962-04-09	1965-09-21	San Antonio Chemicals Inc	Process for preparing cesium compounds from cesium alum
US3130010A (en) *	1962-12-04	1964-04-21	Dow Chemical Co	Process for production of high purity cesium metal and cesium compounds
DE1253252B (de) *	1963-03-01	1967-11-02	Atomic Energy Commission	Verfahren zum Abtrennen von radioaktivem Caesium aus waessrigen Loesungen
US3489509A (en) *	1967-05-18	1970-01-13	Kewanee Oil Co	Process for recovery of cesium compounds of high purity

1993
- 1993-04-24 DE DE4313480A patent/DE4313480C1/de not_active Expired - Lifetime
1994
- 1994-04-19 AU AU66792/94A patent/AU679528B2/en not_active Expired
- 1994-04-19 BR BR9406214A patent/BR9406214A/pt not_active IP Right Cessation
- 1994-04-19 KR KR1019950704634A patent/KR100303251B1/ko not_active Expired - Lifetime
- 1994-04-19 CZ CZ19952737A patent/CZ287380B6/cs not_active IP Right Cessation
- 1994-04-19 RO RO95-01847A patent/RO113983B1/ro unknown
- 1994-04-19 AT AT94914402T patent/ATE161818T1/de not_active IP Right Cessation
- 1994-04-19 SK SK1311-95A patent/SK280404B6/sk unknown
- 1994-04-19 DK DK94914402.6T patent/DK0695286T3/da active
- 1994-04-19 ZW ZW4994A patent/ZW4994A1/xx unknown
- 1994-04-19 HU HU9503041A patent/HU214206B/hu not_active IP Right Cessation
- 1994-04-19 CN CN94191890A patent/CN1055677C/zh not_active Expired - Lifetime
- 1994-04-19 EP EP94914402A patent/EP0695286B1/de not_active Expired - Lifetime
- 1994-04-19 CA CA002161245A patent/CA2161245C/en not_active Expired - Lifetime
- 1994-04-19 US US08/537,927 patent/US5605669A/en not_active Expired - Lifetime
- 1994-04-19 DE DE59404963T patent/DE59404963D1/de not_active Expired - Lifetime
- 1994-04-19 WO PCT/EP1994/001202 patent/WO1994025422A1/de not_active Ceased
- 1994-04-19 PL PL94311231A patent/PL177619B1/pl unknown
- 1994-04-19 JP JP52382394A patent/JP4079991B2/ja not_active Expired - Lifetime
- 1994-04-22 ZA ZA942813A patent/ZA942813B/xx unknown
1995
- 1995-10-17 NO NO954134A patent/NO303984B1/no not_active IP Right Cessation
- 1995-10-23 FI FI955049A patent/FI112204B/fi not_active IP Right Cessation
- 1995-10-24 LV LVP-95-321A patent/LV11540B/lv unknown

Also Published As

Publication number	Publication date
JPH08509235A (ja)	1996-10-01
PL311231A1 (en)	1996-02-05
SK131195A3 (en)	1996-04-03
FI955049L (fi)	1995-10-23
EP0695286A1 (de)	1996-02-07
US5605669A (en)	1997-02-25
ZA942813B (en)	1995-10-23
DE4313480C1 (de)	1994-04-14
LV11540A (lv)	1996-10-20
KR100303251B1 (ko)	2001-11-22
NO954134L (no)	1995-10-17
CA2161245A1 (en)	1994-11-10
CN1055677C (zh)	2000-08-23
JP4079991B2 (ja)	2008-04-23
RO113983B1 (ro)	1998-12-30
CN1121705A (zh)	1996-05-01
NO303984B1 (no)	1998-10-05
ATE161818T1 (de)	1998-01-15
AU679528B2 (en)	1997-07-03
DE59404963D1 (de)	1998-02-12
FI955049A0 (fi)	1995-10-23
HU9503041D0 (en)	1995-12-28
CZ273795A3 (en)	1996-12-11
PL177619B1 (pl)	1999-12-31
LV11540B (en)	1996-12-20
HU214206B (hu)	1998-01-28
NO954134D0 (no)	1995-10-17
CA2161245C (en)	2001-04-10
ZW4994A1 (en)	1994-11-23
DK0695286T3 (da)	1998-02-09
WO1994025422A1 (de)	1994-11-10
AU6679294A (en)	1994-11-21
CZ287380B6 (en)	2000-11-15
HUT72014A (en)	1996-03-28
EP0695286B1 (de)	1998-01-07
SK280404B6 (sk)	2000-01-18
BR9406214A (pt)	1996-01-09

Legal Events

Date	Code	Title	Description
2004-10-31	MA	Patent expired

Publication	Publication Date	Title
US5182094A (en)	1993-01-26	Process for the preparation of polyaluminum compounds
KR950014212B1 (ko)	1995-11-23	신규 폴리알루미늄클로로술페이트, 그의 제조방법 및 용도
GB2128977A (en)	1984-05-10	Process for the manufacture of basic aluminium chlorosulphates
NO140897B (no)	1979-08-27	Fremgangsmaate for kontinuerlig farvning av aromatiske polyester/cellulosetekstilblandinger
CA2161245C (en)	2001-04-10	Process of preparing cesium salts from cesium-aluminum-alum
US5099049A (en)	1992-03-24	Chelate compositions and their production
CA1160425A (en)	1984-01-17	Preparation of dihydroxyaluminium sodium carbonate
US4670594A (en)	1987-06-02	Continuous process for the preparation of dimethyldiallylammonium chloride
CA2720885A1 (en)	2009-12-03	Method for producing the trisodium salt of 2,4,6-trimercapto-s-triazine
JP3532500B2 (ja)	2004-05-31	船底塗料用防汚剤およびそれに用いる高純度銅ピリチオンの製造方法
US3347863A (en)	1967-10-17	Process for basic aluminum salt of pyridinethione
ES2399913T3 (es)	2013-04-04	Método para la producción de 2,4,6-trimercapto-1,3,5-triazina
JPS5921510A (ja)	1984-02-03	リン酸一水素カルシウム二水化物の製法
CS276111B6 (en)	1992-04-15	Process for separating barium from strontium salts being dissolved in water
JPH0725539B2 (ja)	1995-03-22	ジシアナミド金属塩の製造方法
EP0141267A1 (en)	1985-05-15	Acid salts of valproic acid
JP3444876B2 (ja)	2003-09-08	塩基性次亜塩素酸マグネシウムの製造方法
KR910008733B1 (ko)	1991-10-19	L-아스코르빈산-2-인산에스테르 마그네슘염의 제조방법
RU2224763C2 (ru)	2004-02-27	Способ получения бис (1-гидроксиэтан-1,1-дифосфоната(1-)) меди (II)
JP2985362B2 (ja)	1999-11-29	臭化マンガン水溶液の製造方法
US4950819A (en)	1990-08-21	Process for the preparation of alkali metal salts of phosphonic acid monoalkyl esters
JPH04261189A (ja)	1992-09-17	トリフルオロメタンスルホン酸スズの製造法
US1881430A (en)	1932-10-11	Process for the manufacture of solutions containing alpha compound of fluorine and aluminium
US5097030A (en)	1992-03-17	Process for the preparation of 2-(methylthio)barbituric acid
US4166909A (en)	1979-09-04	Process for preparation of a substituted triazine