SK280404B6 - Spôsob výroby solí cézia z kamenca hlinitocézneho - Google Patents

Spôsob výroby solí cézia z kamenca hlinitocézneho Download PDF

Info

Publication number: SK280404B6
Authority: SK; Slovakia
Prior art keywords: calcium; water; cesium; caesium; hydroxide
Prior art date: 1993-04-24

Application number

SK1311-95A

Other languages

English (en)

Slovak (sk)

Other versions

SK131195A3 (en

Inventor

Hartmut Hofmann

Klaus K�Bele

Horst Prinz

Bernd Phillipp

Gerd Harms

Alexander Schiedt

Urlike Hecktor

Original Assignee

Metallgesellschaft Aktiengesellschaft

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-04-24

Filing date

1994-04-19

Publication date

2000-01-18

1994-04-19 Application filed by Metallgesellschaft Aktiengesellschaft filed Critical Metallgesellschaft Aktiengesellschaft

1996-04-03 Publication of SK131195A3 publication Critical patent/SK131195A3/sk

2000-01-18 Publication of SK280404B6 publication Critical patent/SK280404B6/sk

Links

TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 title claims abstract description 12
229940037003 alum Drugs 0.000 title claims abstract description 11
229910052792 caesium Inorganic materials 0.000 title claims abstract description 10
229910052782 aluminium Inorganic materials 0.000 title claims abstract description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 5
238000000034 method Methods 0.000 title claims description 9
239000004411 aluminium Substances 0.000 title abstract 3
150000001663 caesium Chemical class 0.000 title 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 8
239000000920 calcium hydroxide Substances 0.000 claims abstract description 8
229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 8
159000000007 calcium salts Chemical class 0.000 claims abstract description 6
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 4
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 4
238000005119 centrifugation Methods 0.000 claims abstract description 3
238000001914 filtration Methods 0.000 claims abstract description 3
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
238000006243 chemical reaction Methods 0.000 claims description 10
238000004519 manufacturing process Methods 0.000 claims description 6
239000011575 calcium Substances 0.000 claims description 5
239000007787 solid Substances 0.000 claims description 4
239000000725 suspension Substances 0.000 claims description 4
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
229910052791 calcium Inorganic materials 0.000 claims description 3
VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 3
239000001639 calcium acetate Substances 0.000 claims description 3
229960005147 calcium acetate Drugs 0.000 claims description 3
235000011092 calcium acetate Nutrition 0.000 claims description 3
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
229910001622 calcium bromide Inorganic materials 0.000 claims description 2
239000001110 calcium chloride Substances 0.000 claims description 2
229910001628 calcium chloride Inorganic materials 0.000 claims description 2
WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 claims description 2
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims 1
VHUJINUACVEASK-UHFFFAOYSA-J aluminum;cesium;disulfate;dodecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[Cs+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O VHUJINUACVEASK-UHFFFAOYSA-J 0.000 claims 1
239000002244 precipitate Substances 0.000 abstract description 2
229910021502 aluminium hydroxide Inorganic materials 0.000 abstract 1
239000001175 calcium sulphate Substances 0.000 abstract 1
235000011132 calcium sulphate Nutrition 0.000 abstract 1
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
-1 cesium halide Chemical class 0.000 description 4
RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 3
229910001863 barium hydroxide Inorganic materials 0.000 description 3
238000009835 boiling Methods 0.000 description 3
ZOAIGCHJWKDIPJ-UHFFFAOYSA-M caesium acetate Chemical compound [Cs+].CC([O-])=O ZOAIGCHJWKDIPJ-UHFFFAOYSA-M 0.000 description 3
ATZQZZAXOPPAAQ-UHFFFAOYSA-M caesium formate Chemical compound [Cs+].[O-]C=O ATZQZZAXOPPAAQ-UHFFFAOYSA-M 0.000 description 3
239000001569 carbon dioxide Substances 0.000 description 3
229910002092 carbon dioxide Inorganic materials 0.000 description 3
159000000006 cesium salts Chemical class 0.000 description 3
MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 2
CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical class [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 description 2
HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 2
229940044172 calcium formate Drugs 0.000 description 2
239000004281 calcium formate Substances 0.000 description 2
235000019255 calcium formate Nutrition 0.000 description 2
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
239000000292 calcium oxide Substances 0.000 description 2
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
239000000706 filtrate Substances 0.000 description 2
238000006386 neutralization reaction Methods 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
239000012266 salt solution Substances 0.000 description 2
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
241000238631 Hexapoda Species 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
150000001553 barium compounds Chemical class 0.000 description 1
229940059251 calcium bromide Drugs 0.000 description 1
229960002713 calcium chloride Drugs 0.000 description 1
235000011148 calcium chloride Nutrition 0.000 description 1
FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical class [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
239000001354 calcium citrate Chemical class 0.000 description 1
229960004256 calcium citrate Drugs 0.000 description 1
229940043430 calcium compound Drugs 0.000 description 1
150000001674 calcium compounds Chemical class 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
KIZFHUJKFSNWKO-UHFFFAOYSA-M calcium monohydroxide Chemical compound [Ca]O KIZFHUJKFSNWKO-UHFFFAOYSA-M 0.000 description 1
229910052602 gypsum Inorganic materials 0.000 description 1
239000010440 gypsum Substances 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
235000013337 tricalcium citrate Nutrition 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D17/00—Rubidium, caesium or francium compounds

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
Processing Of Solid Wastes (AREA)
Inorganic Insulating Materials (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Catalysts (AREA)

SK1311-95A 1993-04-24 1994-04-19 Spôsob výroby solí cézia z kamenca hlinitocézneho SK280404B6 (sk)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE4313480A DE4313480C1 (de)	1993-04-24	1993-04-24	Verfahren zur Herstellung von Cäsiumsalzen aus Cäsium-Aluminium-Alaun
PCT/EP1994/001202 WO1994025422A1 (de)	1993-04-24	1994-04-19	Verfahren zur herstellung von cäsiumsalzen aus cäsium-aluminium-alaun

Publications (2)

Publication Number	Publication Date
SK131195A3 SK131195A3 (en)	1996-04-03
SK280404B6 true SK280404B6 (sk)	2000-01-18

Family

ID=6486296

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK1311-95A SK280404B6 (sk)	1993-04-24	1994-04-19	Spôsob výroby solí cézia z kamenca hlinitocézneho

Country Status (22)

Country	Link
US (1)	US5605669A (cs)
EP (1)	EP0695286B1 (cs)
JP (1)	JP4079991B2 (cs)
KR (1)	KR100303251B1 (cs)
CN (1)	CN1055677C (cs)
AT (1)	ATE161818T1 (cs)
AU (1)	AU679528B2 (cs)
BR (1)	BR9406214A (cs)
CA (1)	CA2161245C (cs)
CZ (1)	CZ287380B6 (cs)
DE (2)	DE4313480C1 (cs)
DK (1)	DK0695286T3 (cs)
FI (1)	FI112204B (cs)
HU (1)	HU214206B (cs)
LV (1)	LV11540B (cs)
NO (1)	NO303984B1 (cs)
PL (1)	PL177619B1 (cs)
RO (1)	RO113983B1 (cs)
SK (1)	SK280404B6 (cs)
WO (1)	WO1994025422A1 (cs)
ZA (1)	ZA942813B (cs)
ZW (1)	ZW4994A1 (cs)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
SK285016B6 (sk) *	1995-04-06	2006-04-06	Cabot Corporation	Spôsob výroby céznej soli
US6015535A (en) *	1995-04-06	2000-01-18	Cabot Corporation	Process for producing purified cesium compound from cesium alum
US6652820B2 (en)	2001-04-02	2003-11-25	Cabot Corporation	Methods of making cesium salts and other alkali metal salts
UA92905C2 (ru) *	2005-01-27	2010-12-27	Хеметалль Гмбх	Способ получения растворов гидроксида цезия
US7759273B2 (en) *	2005-04-20	2010-07-20	Cabot Corporation	Methods of forming an alkali metal salt
CN110256232B (zh) *	2019-06-28	2022-05-03	百杰瑞(荆门)新材料有限公司	一种甲酸铯生产方法
CN110172575B (zh) *	2019-07-05	2021-03-05	新疆有色金属研究所	一种铯矾原料的处理方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2481455A (en) *	1948-06-01	1949-09-06	Dow Chemical Co	Cesium bromide separation
GB949483A (en) *	1961-05-25	1964-02-12	Atomic Energy Authority Uk	Improvements in or relating to the recovery of caesium
US3207571A (en) *	1962-04-09	1965-09-21	San Antonio Chemicals Inc	Process for preparing cesium compounds from cesium alum
US3130010A (en) *	1962-12-04	1964-04-21	Dow Chemical Co	Process for production of high purity cesium metal and cesium compounds
DE1253252B (de) *	1963-03-01	1967-11-02	Atomic Energy Commission	Verfahren zum Abtrennen von radioaktivem Caesium aus waessrigen Loesungen
US3489509A (en) *	1967-05-18	1970-01-13	Kewanee Oil Co	Process for recovery of cesium compounds of high purity

1993
- 1993-04-24 DE DE4313480A patent/DE4313480C1/de not_active Expired - Lifetime
1994
- 1994-04-19 HU HU9503041A patent/HU214206B/hu not_active IP Right Cessation
- 1994-04-19 ZW ZW4994A patent/ZW4994A1/xx unknown
- 1994-04-19 US US08/537,927 patent/US5605669A/en not_active Expired - Lifetime
- 1994-04-19 BR BR9406214A patent/BR9406214A/pt not_active IP Right Cessation
- 1994-04-19 SK SK1311-95A patent/SK280404B6/sk unknown
- 1994-04-19 EP EP94914402A patent/EP0695286B1/de not_active Expired - Lifetime
- 1994-04-19 CA CA002161245A patent/CA2161245C/en not_active Expired - Lifetime
- 1994-04-19 CZ CZ19952737A patent/CZ287380B6/cs not_active IP Right Cessation
- 1994-04-19 AT AT94914402T patent/ATE161818T1/de not_active IP Right Cessation
- 1994-04-19 AU AU66792/94A patent/AU679528B2/en not_active Expired
- 1994-04-19 WO PCT/EP1994/001202 patent/WO1994025422A1/de not_active Ceased
- 1994-04-19 KR KR1019950704634A patent/KR100303251B1/ko not_active Expired - Lifetime
- 1994-04-19 DE DE59404963T patent/DE59404963D1/de not_active Expired - Lifetime
- 1994-04-19 RO RO95-01847A patent/RO113983B1/ro unknown
- 1994-04-19 PL PL94311231A patent/PL177619B1/pl unknown
- 1994-04-19 JP JP52382394A patent/JP4079991B2/ja not_active Expired - Lifetime
- 1994-04-19 DK DK94914402.6T patent/DK0695286T3/da active
- 1994-04-19 CN CN94191890A patent/CN1055677C/zh not_active Expired - Lifetime
- 1994-04-22 ZA ZA942813A patent/ZA942813B/xx unknown
1995
- 1995-10-17 NO NO954134A patent/NO303984B1/no not_active IP Right Cessation
- 1995-10-23 FI FI955049A patent/FI112204B/fi not_active IP Right Cessation
- 1995-10-24 LV LVP-95-321A patent/LV11540B/lv unknown

Also Published As

Publication number	Publication date
ATE161818T1 (de)	1998-01-15
AU6679294A (en)	1994-11-21
RO113983B1 (ro)	1998-12-30
CZ273795A3 (en)	1996-12-11
EP0695286B1 (de)	1998-01-07
SK131195A3 (en)	1996-04-03
CN1055677C (zh)	2000-08-23
FI955049L (fi)	1995-10-23
DE4313480C1 (de)	1994-04-14
DE59404963D1 (de)	1998-02-12
AU679528B2 (en)	1997-07-03
ZW4994A1 (en)	1994-11-23
FI112204B (fi)	2003-11-14
NO954134D0 (no)	1995-10-17
BR9406214A (pt)	1996-01-09
KR100303251B1 (ko)	2001-11-22
NO303984B1 (no)	1998-10-05
HUT72014A (en)	1996-03-28
PL311231A1 (en)	1996-02-05
NO954134L (no)	1995-10-17
JP4079991B2 (ja)	2008-04-23
FI955049A0 (fi)	1995-10-23
CZ287380B6 (en)	2000-11-15
HU9503041D0 (en)	1995-12-28
LV11540B (en)	1996-12-20
US5605669A (en)	1997-02-25
HU214206B (hu)	1998-01-28
LV11540A (lv)	1996-10-20
EP0695286A1 (de)	1996-02-07
WO1994025422A1 (de)	1994-11-10
PL177619B1 (pl)	1999-12-31
DK0695286T3 (da)	1998-02-09
CN1121705A (zh)	1996-05-01
JPH08509235A (ja)	1996-10-01
CA2161245C (en)	2001-04-10
ZA942813B (en)	1995-10-23
CA2161245A1 (en)	1994-11-10

Publication	Publication Date	Title
US3894144A (en)	1975-07-08	Process for making sulfate-containing basic aluminum chloride
US4120737A (en)	1978-10-17	Manufacture of calcium sulphate alpha hemihydrate
GB2128977A (en)	1984-05-10	Process for the manufacture of basic aluminium chlorosulphates
SK280404B6 (sk)	2000-01-18	Spôsob výroby solí cézia z kamenca hlinitocézneho
US5603912A (en)	1997-02-18	Basic aluminum hydroxychlorosulfate process and product therefrom
US4105579A (en)	1978-08-08	Process for producing pharmaceutical grade aluminum hydroxide gels
GB710015A (en)	1954-06-02	An improved process for the production of finely divided silica
US4401633A (en)	1983-08-30	Two step process for the preparation of zeolite A by hydrothermal treatment of heulandite
AU551374B2 (en)	1986-04-24	A method for recovering useful products from waste products obtained when manufacturing aluminium hydroxide
CA1160425A (en)	1984-01-17	Preparation of dihydroxyaluminium sodium carbonate
US4831171A (en)	1989-05-16	Process for synthesizing an ammonia complex of zinc bisdithiocarbamate
US5258168A (en)	1993-11-02	Production of alunites
US4612184A (en)	1986-09-16	High specific surface hydrargillite
US3846081A (en)	1974-11-05	Process for separating sodium sulfate from brines
JPH0812328A (ja)	1996-01-16	水酸化第二銅の製造法
JPS61286219A (ja)	1986-12-16	ポリ塩化アルミニウムの製造方法
US3875291A (en)	1975-04-01	Process for making cryolite
CA1106761A (en)	1981-08-11	Process for producing aluminum hydroxide gels and resulting product
RU2229443C2 (ru)	2004-05-27	Способ получения химически осажденного карбоната кальция
JPH0710536A (ja)	1995-01-13	酸性アルミニウム塩の製造方法
CS277373B6 (sk)	1993-01-13	Spósob přípravy tetrakyanonikelnatanov kovov alkalických zemin
JPH0517128A (ja)	1993-01-26	チオシアン酸金塩の製造方法
CS257576B1 (cs)	1988-05-16	Způsob přípravy hrubozmného hydratovaného oxidu hlinitého