IL100431A - Asymmetrical hydrogenation of (E)-2-methyl-3-phenyl-2-propen-1-ol using rhodium complex of atropisomeric phosphine as catalyst - Google Patents

Asymmetrical hydrogenation of (E)-2-methyl-3-phenyl-2-propen-1-ol using rhodium complex of atropisomeric phosphine as catalyst

Info

Publication number
IL100431A
IL100431A IL10043191A IL10043191A IL100431A IL 100431 A IL100431 A IL 100431A IL 10043191 A IL10043191 A IL 10043191A IL 10043191 A IL10043191 A IL 10043191A IL 100431 A IL100431 A IL 100431A
Authority
IL
Israel
Prior art keywords
formula
methyl
phenyl
lower alkyl
group
Prior art date
Application number
IL10043191A
Other languages
English (en)
Other versions
IL100431A0 (en
Original Assignee
Ciba Geigy Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag
Publication of IL100431A0 publication Critical patent/IL100431A0/xx
Publication of IL100431A publication Critical patent/IL100431A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C07C5/11—Partial hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/027—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements containing only one hetero ring
    • C07D295/03—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements containing only one hetero ring with the ring nitrogen atoms directly attached to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/18—Monohydroxylic alcohols containing only six-membered aromatic rings as cyclic part
    • C07C33/20—Monohydroxylic alcohols containing only six-membered aromatic rings as cyclic part monocyclic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Steroid Compounds (AREA)
  • Saccharide Compounds (AREA)
IL10043191A 1990-12-21 1991-12-19 Asymmetrical hydrogenation of (E)-2-methyl-3-phenyl-2-propen-1-ol using rhodium complex of atropisomeric phosphine as catalyst IL100431A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH410090 1990-12-21

Publications (2)

Publication Number Publication Date
IL100431A0 IL100431A0 (en) 1992-09-06
IL100431A true IL100431A (en) 1995-12-31

Family

ID=4269826

Family Applications (1)

Application Number Title Priority Date Filing Date
IL10043191A IL100431A (en) 1990-12-21 1991-12-19 Asymmetrical hydrogenation of (E)-2-methyl-3-phenyl-2-propen-1-ol using rhodium complex of atropisomeric phosphine as catalyst

Country Status (16)

Country Link
EP (1) EP0492401B1 (cs)
JP (1) JPH04295440A (cs)
KR (1) KR920011975A (cs)
AT (1) ATE133403T1 (cs)
CA (1) CA2058112A1 (cs)
CZ (1) CZ280199B6 (cs)
DE (1) DE59107308D1 (cs)
DK (1) DK0492401T3 (cs)
ES (1) ES2082104T3 (cs)
FI (1) FI915962L (cs)
GR (1) GR3018831T3 (cs)
HU (1) HU210521B (cs)
IE (1) IE71201B1 (cs)
IL (1) IL100431A (cs)
MX (1) MX9102682A (cs)
TW (1) TW200449B (cs)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5374727A (en) * 1992-06-19 1994-12-20 Hoffmann-La Roche Inc. Asymmetric hydrogenation of dihydro-pyrido [1,2-a]indoles
IT1276165B1 (it) 1995-11-24 1997-10-27 Caffaro Spa Ind Chim Procedimento per la sintesi enantioselettiva di derivati chirali di s-3-(4'-tert-butil)-fenil-2-metil propilammina, fungicidi sistemici
US6222039B1 (en) 1998-07-13 2001-04-24 Hoffman-La Roche Inc. Process for the preparation of chiral lactones
EP0974590A1 (en) * 1998-07-13 2000-01-26 F. Hoffmann-La Roche Ag Process for the preparation of chiral lactones by asymetrical hydrogenation
DE102004047836A1 (de) 2004-09-29 2006-03-30 Basf Ag Verfahren zur Herstellung von optisch aktiven 2-Methylalkanolen
US20080171892A1 (en) * 2005-03-17 2008-07-17 Basf Aktiengesellschaft Method for Producing Optically Active 3-Phenylpropionic Acid Derivatives and Follow-On Products of the Latter

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT354187B (de) * 1976-11-22 1979-12-27 Hoffmann La Roche Fungizides mittel
DE3001303A1 (de) * 1980-01-16 1981-07-23 Basf Ag, 6700 Ludwigshafen Optisch aktive phenylpropan-derivate, ihre herstellung und verwendung

Also Published As

Publication number Publication date
EP0492401B1 (de) 1996-01-24
FI915962A0 (fi) 1991-12-18
HU914088D0 (en) 1992-03-30
EP0492401A1 (de) 1992-07-01
DE59107308D1 (de) 1996-03-07
CS387591A3 (en) 1992-07-15
IL100431A0 (en) 1992-09-06
JPH04295440A (ja) 1992-10-20
ATE133403T1 (de) 1996-02-15
ES2082104T3 (es) 1996-03-16
CA2058112A1 (en) 1992-06-22
DK0492401T3 (da) 1996-03-04
IE71201B1 (en) 1997-02-12
CZ280199B6 (cs) 1995-11-15
TW200449B (cs) 1993-02-21
MX9102682A (es) 1992-06-01
HU210521B (en) 1995-04-28
KR920011975A (ko) 1992-07-25
IE914509A1 (en) 1992-07-01
GR3018831T3 (en) 1996-04-30
FI915962A7 (fi) 1992-06-22
HUT59650A (en) 1992-06-29
FI915962L (fi) 1992-06-22

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Legal Events

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