IL35356A - 0,0-dialkyl-thionophosphoric acid esters and their use as insecticides - Google Patents

0,0-dialkyl-thionophosphoric acid esters and their use as insecticides

Info

Publication number: IL35356A
Authority: IL; Israel
Prior art keywords: parts; insecticides; active ingredient; denotes; formula
Prior art date: 1969-10-01

Application number

IL35356A

Other languages

English (en)

Other versions

IL35356A0 (en

Original Assignee

Basf Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1969-10-01

Filing date

1970-09-28

Publication date

1974-11-29

1970-09-28 Application filed by Basf Ag filed Critical Basf Ag

1970-11-30 Publication of IL35356A0 publication Critical patent/IL35356A0/xx

1974-11-29 Publication of IL35356A publication Critical patent/IL35356A/en

Links

150000002148 esters Chemical class 0.000 title claims description 13
239000002917 insecticide Substances 0.000 title claims description 8
239000002253 acid Substances 0.000 title description 3
125000003118 aryl group Chemical group 0.000 claims description 5
238000000034 method Methods 0.000 claims description 5
125000000217 alkyl group Chemical group 0.000 claims description 4
241000238631 Hexapoda Species 0.000 claims description 3
239000007788 liquid Substances 0.000 claims description 3
239000007787 solid Substances 0.000 claims description 3
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 27
239000004480 active ingredient Substances 0.000 description 23
239000000243 solution Substances 0.000 description 13
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
239000003921 oil Substances 0.000 description 7
150000001875 compounds Chemical class 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
-1 alkyl radical Chemical class 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
238000003756 stirring Methods 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 4
230000000749 insecticidal effect Effects 0.000 description 4
159000000000 sodium salts Chemical class 0.000 description 4
239000002904 solvent Substances 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
239000000839 emulsion Substances 0.000 description 3
239000012948 isocyanate Substances 0.000 description 3
150000002513 isocyanates Chemical class 0.000 description 3
239000000203 mixture Substances 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
239000000725 suspension Substances 0.000 description 3
UDATXMIGEVPXTR-UHFFFAOYSA-N 1,2,4-triazolidine-3,5-dione Chemical class O=C1NNC(=O)N1 UDATXMIGEVPXTR-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
241000256113 Culicidae Species 0.000 description 2
241000257226 Muscidae Species 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
239000002585 base Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000012141 concentrate Substances 0.000 description 2
238000001816 cooling Methods 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
230000026731 phosphorylation Effects 0.000 description 2
238000006366 phosphorylation reaction Methods 0.000 description 2
238000010992 reflux Methods 0.000 description 2
229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
235000017557 sodium bicarbonate Nutrition 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
YJLUBHOZZTYQIP-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)NN=N2 YJLUBHOZZTYQIP-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
241000256118 Aedes aegypti Species 0.000 description 1
241001124076 Aphididae Species 0.000 description 1
241000238662 Blatta orientalis Species 0.000 description 1
241000238660 Blattidae Species 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
241000257159 Musca domestica Species 0.000 description 1
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical class [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
208000010513 Stupor Diseases 0.000 description 1
241000607479 Yersinia pestis Species 0.000 description 1
210000001015 abdomen Anatomy 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000003342 alkenyl group Chemical group 0.000 description 1
125000004183 alkoxy alkyl group Chemical group 0.000 description 1
125000006350 alkyl thio alkyl group Chemical group 0.000 description 1
HXBPYFMVGFDZFT-UHFFFAOYSA-N allyl isocyanate Chemical compound C=CCN=C=O HXBPYFMVGFDZFT-UHFFFAOYSA-N 0.000 description 1
239000013011 aqueous formulation Substances 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
210000004369 blood Anatomy 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000003518 caustics Substances 0.000 description 1
JWMMHPDEZMMJEB-UHFFFAOYSA-N chloro-diethyl-sulfanylidene-$l^{5}-phosphane Chemical compound CCP(Cl)(=S)CC JWMMHPDEZMMJEB-UHFFFAOYSA-N 0.000 description 1
UGOLAPHJCTVIEW-UHFFFAOYSA-N chloro-dimethyl-sulfanylidene-$l^{5}-phosphane Chemical compound CP(C)(Cl)=S UGOLAPHJCTVIEW-UHFFFAOYSA-N 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
238000007865 diluting Methods 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
125000004119 disulfanediyl group Chemical group *SS* 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
230000001804 emulsifying effect Effects 0.000 description 1
GFIGIXMFDHSXBF-UHFFFAOYSA-N ethyl n-amino-n-methylcarbamate Chemical compound CCOC(=O)N(C)N GFIGIXMFDHSXBF-UHFFFAOYSA-N 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000000227 grinding Methods 0.000 description 1
125000001188 haloalkyl group Chemical group 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000002429 hydrazines Chemical class 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
230000001418 larval effect Effects 0.000 description 1
231100000053 low toxicity Toxicity 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
238000002156 mixing Methods 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
150000007530 organic bases Chemical class 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000000575 pesticide Substances 0.000 description 1
FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000007363 ring formation reaction Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000000926 separation method Methods 0.000 description 1
235000011121 sodium hydroxide Nutrition 0.000 description 1
230000002269 spontaneous effect Effects 0.000 description 1
239000007921 spray Substances 0.000 description 1
CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
- C07D249/10—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D249/12—Oxygen or sulfur atoms
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having three nitrogen atoms as the only ring hetero atoms
- C07F9/6518—Five-membered rings

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
General Health & Medical Sciences (AREA)
Health & Medical Sciences (AREA)
Pest Control & Pesticides (AREA)
Molecular Biology (AREA)
Agronomy & Crop Science (AREA)
Biochemistry (AREA)
Plant Pathology (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

IL35356A 1969-10-01 1970-09-28 0,0-dialkyl-thionophosphoric acid esters and their use as insecticides IL35356A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE19691949490 DE1949490A1 (de)	1969-10-01	1969-10-01	Phosphorsaeureester Materialien

Publications (2)

Publication Number	Publication Date
IL35356A0 IL35356A0 (en)	1970-11-30
IL35356A true IL35356A (en)	1974-11-29

Family

ID=5747025

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL35356A IL35356A (en)	1969-10-01	1970-09-28	0,0-dialkyl-thionophosphoric acid esters and their use as insecticides

Country Status (9)

Country	Link
JP (1)	JPS4911071B1 (fr)
BE (1)	BE756952A (fr)
CH (1)	CH526263A (fr)
DE (1)	DE1949490A1 (fr)
FR (1)	FR2068216A5 (fr)
GB (1)	GB1315017A (fr)
IL (1)	IL35356A (fr)
NL (1)	NL7014464A (fr)
ZA (1)	ZA706675B (fr)

0
- BE BE756952D patent/BE756952A/fr unknown
1969
- 1969-10-01 DE DE19691949490 patent/DE1949490A1/de active Pending
1970
- 1970-09-25 FR FR7034864A patent/FR2068216A5/fr not_active Expired
- 1970-09-28 IL IL35356A patent/IL35356A/en unknown
- 1970-09-29 JP JP45084750A patent/JPS4911071B1/ja active Pending
- 1970-09-29 CH CH1441270A patent/CH526263A/de not_active IP Right Cessation
- 1970-09-30 ZA ZA706675*A patent/ZA706675B/xx unknown
- 1970-09-30 GB GB4641870A patent/GB1315017A/en not_active Expired
- 1970-10-01 NL NL7014464A patent/NL7014464A/xx unknown

Also Published As

Publication number	Publication date
CH526263A (de)	1972-08-15
ZA706675B (en)	1971-07-28
JPS4911071B1 (fr)	1974-03-14
BE756952A (fr)	1971-04-01
FR2068216A5 (fr)	1971-08-20
IL35356A0 (en)	1970-11-30
GB1315017A (en)	1973-04-26
DE1949490A1 (de)	1971-04-08
NL7014464A (fr)	1971-04-05

Publication	Publication Date	Title
SU733504A3 (ru)	1980-05-05	Инсектицидный состав
US2994638A (en)	1961-08-01	Agent for combating rodents
US3205231A (en)	1965-09-07	Phosphoric, phosphonic, thionophosphoric or thionophosphinic acid esters
SU589892A3 (ru)	1978-01-25	Инсектоакарицидное средство
US3232951A (en)	1966-02-01	Phosphoric, phosphonic and phosphinic acid esters of 3-hydroxybenzisazoles, and their thio analogues
SU469231A3 (ru)	1975-04-30	Инсектицид,акарицид и нематоцид
US4237168A (en)	1980-12-02	N-(4-Chloro-2-methylphenyl)-N-hydroxy methanimidamide and its pesticidal use
IL35356A (en)	1974-11-29	0,0-dialkyl-thionophosphoric acid esters and their use as insecticides
US4567170A (en)	1986-01-28	3-Chloro-3-phenylprop-2-enyl thiophosphates and their use for controlling pests
US3284455A (en)	1966-11-08	Phosphonic and thionophosphonic quinolyl esters
SU713527A3 (ru)	1980-01-30	Способ борьбы с насекомыми, клещами и нематодами
US3932631A (en)	1976-01-13	Certain organophosphorus compounds used to control insects
SU643068A3 (ru)	1979-01-15	Способ борьбы с насекомыми и клещами
DE1280256B (de)	1968-10-17	Neue O, O-Dialkylthionophosphorsaeureester und Verfahren zur Herstellung derselben
US4582825A (en)	1986-04-15	2-(substituted phenyl)-3-chloro-2-butene thio phosphates as insecticides
US3286000A (en)	1966-11-15	Phosphorus acid ester-containing isonitriles
US4612306A (en)	1986-09-16	Oximinophosphoric acid derivatives and their use for controlling pests
US4062951A (en)	1977-12-13	Organophosphorus compounds, compositions containing them and their method of use
DE2363208C3 (de)	1982-03-11	Thiolphosphorsäureester
SU615838A3 (ru)	1978-07-15	Инсектоакарицидонематоцидное средство
US3798230A (en)	1974-03-19	O,o-dialkyl-o-(1-oxa-2,4-diazolidinon-5-yl-3)-thionophosphates
US3718661A (en)	1973-02-27	Phosphoric esters
US3320261A (en)	1967-05-16	Pyridyl and quinolyl mercapto methyl phosphorus esters
US3284547A (en)	1966-11-08	Phosphoric esters
EP0224217B1 (fr)	1989-06-21	Dérivés d'acide phosphorique, procédé pour leur préparation et leur utilisation pour combattre les vermines