JP2731479B2 - ３−エチル−１−ヘキセンの重合体及びその製造法 - Google Patents

３−エチル−１−ヘキセンの重合体及びその製造法

Info

Publication number: JP2731479B2
Authority: JP; Japan
Prior art keywords: hexene; ethyl; methyl; pentene; dimethyl
Prior art date: 1991-01-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP4011299A

Other languages

English (en)

Japanese (ja)

Other versions

JPH04311707A (ja

Inventor

マービンストリックレンフィル

アルフレッドドレイクチャールズ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Phillips Petroleum Co

Original Assignee

Phillips Petroleum Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-01-25

Filing date

1992-01-24

Publication date

1998-03-25

1992-01-24 Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co

1992-11-04 Publication of JPH04311707A publication Critical patent/JPH04311707A/ja

1998-03-25 Application granted granted Critical

1998-03-25 Publication of JP2731479B2 publication Critical patent/JP2731479B2/ja

2013-03-25 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

229920000642 polymer Polymers 0.000 title claims abstract description 35
OLGHJTHQWQKJQQ-UHFFFAOYSA-N 3-ethylhex-1-ene Chemical compound CCCC(CC)C=C OLGHJTHQWQKJQQ-UHFFFAOYSA-N 0.000 title claims abstract description 27
238000000034 method Methods 0.000 title claims description 25
239000003054 catalyst Substances 0.000 claims abstract description 17
238000002844 melting Methods 0.000 claims abstract description 17
230000008018 melting Effects 0.000 claims abstract description 17
229920001577 copolymer Polymers 0.000 claims abstract description 9
-1 organometallic halide compound Chemical class 0.000 claims abstract description 9
229920001519 homopolymer Polymers 0.000 claims abstract description 8
239000000178 monomer Substances 0.000 claims description 21
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 9
238000004519 manufacturing process Methods 0.000 claims description 7
239000004711 α-olefin Substances 0.000 claims description 7
125000004432 carbon atom Chemical group C* 0.000 claims description 5
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims description 5
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 5
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 4
150000002430 hydrocarbons Chemical group 0.000 claims description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
239000005977 Ethylene Substances 0.000 claims description 3
RXYYKIMRVXDSFR-UHFFFAOYSA-N 3,3-dimethylhex-1-ene Chemical compound CCCC(C)(C)C=C RXYYKIMRVXDSFR-UHFFFAOYSA-N 0.000 claims description 2
TXBZITDWMURSEF-UHFFFAOYSA-N 3,3-dimethylpent-1-ene Chemical compound CCC(C)(C)C=C TXBZITDWMURSEF-UHFFFAOYSA-N 0.000 claims description 2
WFHXQNMTMDKVJG-UHFFFAOYSA-N 3,4-dimethylpent-1-ene Chemical compound CC(C)C(C)C=C WFHXQNMTMDKVJG-UHFFFAOYSA-N 0.000 claims description 2
FVGYFLMOMXMNKY-UHFFFAOYSA-N 3-ethyloct-1-ene Chemical compound CCCCCC(CC)C=C FVGYFLMOMXMNKY-UHFFFAOYSA-N 0.000 claims description 2
YPVPQMCSLFDIKA-UHFFFAOYSA-N 3-ethylpent-1-ene Chemical compound CCC(CC)C=C YPVPQMCSLFDIKA-UHFFFAOYSA-N 0.000 claims description 2
YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 claims description 2
RITONZMLZWYPHW-UHFFFAOYSA-N 3-methylhex-1-ene Chemical compound CCCC(C)C=C RITONZMLZWYPHW-UHFFFAOYSA-N 0.000 claims description 2
GLUPFQMLFXGTNL-UHFFFAOYSA-N 3-methyloct-1-ene Chemical compound CCCCCC(C)C=C GLUPFQMLFXGTNL-UHFFFAOYSA-N 0.000 claims description 2
LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 claims description 2
SUJVAMIXNUAJEY-UHFFFAOYSA-N 4,4-dimethylhex-1-ene Chemical compound CCC(C)(C)CC=C SUJVAMIXNUAJEY-UHFFFAOYSA-N 0.000 claims description 2
KLCNJIQZXOQYTE-UHFFFAOYSA-N 4,4-dimethylpent-1-ene Chemical compound CC(C)(C)CC=C KLCNJIQZXOQYTE-UHFFFAOYSA-N 0.000 claims description 2
AXKWWYRUXIIHCO-UHFFFAOYSA-N 4-ethyl-3-methylhex-1-ene Chemical compound CCC(CC)C(C)C=C AXKWWYRUXIIHCO-UHFFFAOYSA-N 0.000 claims description 2
SUWJESCICIOQHO-UHFFFAOYSA-N 4-methylhex-1-ene Chemical compound CCC(C)CC=C SUWJESCICIOQHO-UHFFFAOYSA-N 0.000 claims description 2
JIUFYGIESXPUPL-UHFFFAOYSA-N 5-methylhex-1-ene Chemical compound CC(C)CCC=C JIUFYGIESXPUPL-UHFFFAOYSA-N 0.000 claims description 2
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
229910052794 bromium Inorganic materials 0.000 claims description 2
239000000460 chlorine Chemical group 0.000 claims description 2
229910052801 chlorine Chemical group 0.000 claims description 2
229910052731 fluorine Inorganic materials 0.000 claims description 2
239000011737 fluorine Substances 0.000 claims description 2
WEPNJTDVIIKRIK-UHFFFAOYSA-N 2-methylhept-2-ene Chemical compound CCCCC=C(C)C WEPNJTDVIIKRIK-UHFFFAOYSA-N 0.000 claims 1
125000001153 fluoro group Chemical group F* 0.000 claims 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 1
239000000203 mixture Substances 0.000 abstract description 20
229910052723 transition metal Inorganic materials 0.000 abstract description 2
150000003624 transition metals Chemical class 0.000 abstract description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 25
238000006116 polymerization reaction Methods 0.000 description 15
238000006243 chemical reaction Methods 0.000 description 10
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
229920000098 polyolefin Polymers 0.000 description 6
239000002904 solvent Substances 0.000 description 6
150000001336 alkenes Chemical class 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 5
239000012071 phase Substances 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 4
239000003085 diluting agent Substances 0.000 description 4
239000007791 liquid phase Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
238000001035 drying Methods 0.000 description 3
239000007789 gas Substances 0.000 description 3
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
239000002002 slurry Substances 0.000 description 3
AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
YCTDZYMMFQCTEO-UHFFFAOYSA-N 3-octene Chemical compound CCCCC=CCC YCTDZYMMFQCTEO-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
229920006125 amorphous polymer Polymers 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000006471 dimerization reaction Methods 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
239000012535 impurity Substances 0.000 description 2
UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
239000002574 poison Substances 0.000 description 2
231100000614 poison Toxicity 0.000 description 2
239000007787 solid Substances 0.000 description 2
229910052717 sulfur Inorganic materials 0.000 description 2
239000011593 sulfur Substances 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical group CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
OWWRMMIWAOBBFK-UHFFFAOYSA-N 3,4-dimethylhex-1-ene Chemical compound CCC(C)C(C)C=C OWWRMMIWAOBBFK-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000005234 alkyl aluminium group Chemical group 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000001273 butane Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000006757 chemical reactions by type Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
230000002779 inactivation Effects 0.000 description 1
239000011630 iodine Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000007788 liquid Substances 0.000 description 1
GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
238000010926 purge Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
150000003623 transition metal compounds Chemical class 0.000 description 1
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/14—Monomers containing five or more carbon atoms

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

JP4011299A 1991-01-25 1992-01-24 ３−エチル−１−ヘキセンの重合体及びその製造法 Expired - Lifetime JP2731479B2 (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US64599291A	1991-01-25	1991-01-25
US645992		1991-01-25

Publications (2)

Publication Number	Publication Date
JPH04311707A JPH04311707A (ja)	1992-11-04
JP2731479B2 true JP2731479B2 (ja)	1998-03-25

Family

ID=24591298

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP4011299A Expired - Lifetime JP2731479B2 (ja)	1991-01-25	1992-01-24	３−エチル−１−ヘキセンの重合体及びその製造法

Country Status (12)

Country	Link
US (2)	US5475068A (2)
EP (1)	EP0498230B1 (2)
JP (1)	JP2731479B2 (2)
KR (1)	KR0168863B1 (2)
AT (1)	ATE155147T1 (2)
CA (1)	CA2055667C (2)
DE (1)	DE69220687T2 (2)
DK (1)	DK0498230T3 (2)
ES (1)	ES2103835T3 (2)
GR (1)	GR3024564T3 (2)
SG (1)	SG47512A1 (2)
TW (1)	TW218023B (2)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US12606652B2 (en) *	2020-03-31	2026-04-21	Dow Global Technologies Llc	Polymerization of C6—C14 a-olefin monomers and polymers thereof

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE548964A (2) *	1955-06-23	1900-01-01
US4342854A (en) *	1956-01-11	1982-08-03	Phillips Petroleum Company	Solid polymers of 4-methyl-1-pentene
US2933483A (en) *	1958-09-30	1960-04-19	Eastman Kodak Co	Olefin polymerization catalyst containing a metal halide and hexaphenylethane
NL249481A (2) *	1959-03-17
BE614201A (2) *	1961-02-23
US3264277A (en) *	1964-04-27	1966-08-02	Shell Oil Co	Olefin polymerization process in the presence of a ziegler-natta type catalyst modified with tributyl phosphite
US3562241A (en) *	1965-11-15	1971-02-09	Phillips Petroleum Co	Process for the production of 1-olefin polymers having increased melt index
GB1145886A (en) *	1966-11-29	1969-03-19	British Petroleum Co	Crystalline copolymers
US3718635A (en) *	1969-12-16	1973-02-27	Mitsul Petrochem Ind Ltd	Process for polymerization of olefins and catalyst composition therefor
US3686155A (en) *	1970-04-10	1972-08-22	Joseph Wagensommer	Novel process for copolymerization of alpha olefins and ethylene
FR2099150A5 (2) *	1970-06-18	1972-03-10	Mitsui Toatsu Chemicals
CA1274944A (en) *	1986-07-14	1990-10-02	Mitsui Chemicals, Inc.	Branched alpha-olefin polymer composition and process for its production
US4810688A (en) *	1987-10-23	1989-03-07	Phillips Petroleum Company	Catalyst support and catalyst for olefin dimerization
JPH0488003A (ja) *	1990-07-30	1992-03-19	Mitsui Petrochem Ind Ltd	分枝α‐オレフィンの重合方法

1991
- 1991-11-15 CA CA002055667A patent/CA2055667C/en not_active Expired - Fee Related
1992
- 1992-01-10 TW TW081100141A patent/TW218023B/zh active
- 1992-01-24 DE DE69220687T patent/DE69220687T2/de not_active Expired - Fee Related
- 1992-01-24 DK DK92101137.5T patent/DK0498230T3/da active
- 1992-01-24 EP EP92101137A patent/EP0498230B1/en not_active Expired - Lifetime
- 1992-01-24 ES ES92101137T patent/ES2103835T3/es not_active Expired - Lifetime
- 1992-01-24 AT AT92101137T patent/ATE155147T1/de not_active IP Right Cessation
- 1992-01-24 SG SG1996002579A patent/SG47512A1/en unknown
- 1992-01-24 JP JP4011299A patent/JP2731479B2/ja not_active Expired - Lifetime
- 1992-01-24 KR KR1019920001027A patent/KR0168863B1/ko not_active Expired - Fee Related
1995
- 1995-05-03 US US08/433,291 patent/US5475068A/en not_active Expired - Lifetime
- 1995-05-04 US US08/434,219 patent/US5536802A/en not_active Expired - Fee Related
1997
- 1997-08-28 GR GR970402203T patent/GR3024564T3/el unknown

Also Published As

Publication number	Publication date
ATE155147T1 (de)	1997-07-15
DE69220687T2 (de)	1997-11-06
DK0498230T3 (da)	1997-09-22
JPH04311707A (ja)	1992-11-04
TW218023B (2)	1993-12-21
KR0168863B1 (ko)	1999-03-20
EP0498230A3 (en)	1992-10-14
ES2103835T3 (es)	1997-10-01
GR3024564T3 (en)	1997-12-31
SG47512A1 (en)	1998-04-17
DE69220687D1 (de)	1997-08-14
CA2055667C (en)	1997-03-04
US5475068A (en)	1995-12-12
US5536802A (en)	1996-07-16
EP0498230B1 (en)	1997-07-09
KR920014833A (ko)	1992-08-25
EP0498230A2 (en)	1992-08-12

Legal Events

Date

Code

Title

Description

2004-04-28

A02

Decision of refusal

Effective date: 20040427

Free format text: JAPANESE INTERMEDIATE CODE: A02

Publication	Publication Date	Title
EP0628565B1 (en)	2000-04-26	Bis fluorenyl metallocenes and use thereof
US5130284A (en)	1992-07-14	Sold catalyst component for the polymerization of olefins and an olefin polymerization catalyst
US4724255A (en)	1988-02-09	Catalyst components, a catalyst and a process for the polymerization olefins
AU1904499A (en)	1999-07-12	Nickel diimine catalysts with methylalumoxane as cocatalyst, method of polymerization of olefins therewith and polymers produced
JPH06511502A (ja)	1994-12-22	二形態分子量分布を有するポリオレフィンの製造方法
JPS6333761B2 (2)	1988-07-06
JPH0699507B2 (ja)	1994-12-07	触媒成分及び重合用触媒系
NO173940B (no)	1993-11-15	Fremgangsmaate ved fremstilling av en prokatalysator for anvendelse sammen med en kokatalysator ved polymerisasjon av olefiner
US4199476A (en)	1980-04-22	Olefin polymerization catalyst
EP0938508B1 (en)	2003-09-24	Process for making propylene homo or copolymers
JPS633010A (ja)	1988-01-08	オレフイン類重合用触媒
JPH04234407A (ja)	1992-08-24	α−オレフィンの重合に使用できる助触媒組成物
US3933934A (en)	1976-01-20	Fabrication of atactic waxes of polyolefin
JP2731479B2 (ja)	1998-03-25	３−エチル−１−ヘキセンの重合体及びその製造法
NO157063B (no)	1987-10-05	Fremgangsmte for fremstilling av etylen-propylen-blokk-sampolymerer.
US3309346A (en)	1967-03-14	Polymerization process employing catalyst containing metal compounds
US4058653A (en)	1977-11-15	Process for the preparation of polymers of but-1-ene
JPH0118929B2 (2)	1989-04-07
US4211671A (en)	1980-07-08	Olefin polymerization catalyst
JPS5817522B2 (ja)	1983-04-07	α↓−オレフイン重合体を製造する方法
US6992033B2 (en)	2006-01-31	Process for preparation of catalyst composition for ethylene polymerization
JPS62177003A (ja)	1987-08-03	オレフィン類重合用触媒
JPS5812886B2 (ja)	1983-03-10	ポリオレフインノセイゾウホウホウ
JPS6034961B2 (ja)	1985-08-12	高密度エチレン重合体の製法
JPH05178930A (ja)	1993-07-20	α−オレフィン−フルオロビニルエーテル共重合体の製造方法